CN1422116A - 生产蜡预混合物的方法 - Google Patents
生产蜡预混合物的方法 Download PDFInfo
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- CN1422116A CN1422116A CN01807944A CN01807944A CN1422116A CN 1422116 A CN1422116 A CN 1422116A CN 01807944 A CN01807944 A CN 01807944A CN 01807944 A CN01807944 A CN 01807944A CN 1422116 A CN1422116 A CN 1422116A
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- 150000003457 sulfones Chemical class 0.000 description 1
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- INISTDXBRIBGOC-XMMISQBUSA-N tau-fluvalinate Chemical compound N([C@H](C(C)C)C(=O)OC(C#N)C=1C=C(OC=2C=CC=CC=2)C=CC=1)C1=CC=C(C(F)(F)F)C=C1Cl INISTDXBRIBGOC-XMMISQBUSA-N 0.000 description 1
- ZZYSLNWGKKDOML-UHFFFAOYSA-N tebufenpyrad Chemical compound CCC1=NN(C)C(C(=O)NCC=2C=CC(=CC=2)C(C)(C)C)=C1Cl ZZYSLNWGKKDOML-UHFFFAOYSA-N 0.000 description 1
- XQTLDIFVVHJORV-UHFFFAOYSA-N tecnazene Chemical compound [O-][N+](=O)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl XQTLDIFVVHJORV-UHFFFAOYSA-N 0.000 description 1
- CJDWRQLODFKPEL-UHFFFAOYSA-N teflubenzuron Chemical compound FC1=CC=CC(F)=C1C(=O)NC(=O)NC1=CC(Cl)=C(F)C(Cl)=C1F CJDWRQLODFKPEL-UHFFFAOYSA-N 0.000 description 1
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- QGHREAKMXXNCOA-UHFFFAOYSA-N thiophanate-methyl Chemical group COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC QGHREAKMXXNCOA-UHFFFAOYSA-N 0.000 description 1
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- HYVWIQDYBVKITD-UHFFFAOYSA-N tolylfluanid Chemical compound CN(C)S(=O)(=O)N(SC(F)(Cl)Cl)C1=CC=C(C)C=C1 HYVWIQDYBVKITD-UHFFFAOYSA-N 0.000 description 1
- BAZVSMNPJJMILC-UHFFFAOYSA-N triadimenol Chemical compound C1=NC=NN1C(C(O)C(C)(C)C)OC1=CC=C(Cl)C=C1 BAZVSMNPJJMILC-UHFFFAOYSA-N 0.000 description 1
- NKNFWVNSBIXGLL-UHFFFAOYSA-N triazamate Chemical compound CCOC(=O)CSC1=NC(C(C)(C)C)=NN1C(=O)N(C)C NKNFWVNSBIXGLL-UHFFFAOYSA-N 0.000 description 1
- FFSJPOPLSWBGQY-UHFFFAOYSA-N triazol-4-one Chemical compound O=C1C=NN=N1 FFSJPOPLSWBGQY-UHFFFAOYSA-N 0.000 description 1
- NFACJZMKEDPNKN-UHFFFAOYSA-N trichlorfon Chemical compound COP(=O)(OC)C(O)C(Cl)(Cl)Cl NFACJZMKEDPNKN-UHFFFAOYSA-N 0.000 description 1
- DQJCHOQLCLEDLL-UHFFFAOYSA-N tricyclazole Chemical compound CC1=CC=CC2=C1N1C=NN=C1S2 DQJCHOQLCLEDLL-UHFFFAOYSA-N 0.000 description 1
- RROQIUMZODEXOR-UHFFFAOYSA-N triforine Chemical compound O=CNC(C(Cl)(Cl)Cl)N1CCN(C(NC=O)C(Cl)(Cl)Cl)CC1 RROQIUMZODEXOR-UHFFFAOYSA-N 0.000 description 1
- AMHNZOICSMBGDH-UHFFFAOYSA-L zineb Chemical compound [Zn+2].[S-]C(=S)NCCNC([S-])=S AMHNZOICSMBGDH-UHFFFAOYSA-L 0.000 description 1
- DUBNHZYBDBBJHD-UHFFFAOYSA-L ziram Chemical compound [Zn+2].CN(C)C([S-])=S.CN(C)C([S-])=S DUBNHZYBDBBJHD-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/26—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests in coated particulate form
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/12—Powders or granules
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/36—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
Landscapes
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Abstract
本发明涉及一种生产包含农业化学活性物质的蜡预混合物的新方法，其中在具有边缘锋利的混合装置的混合器中，将至少一种固态的农业化学活性物质和至少一种植物或矿物油组成的细粉碎的混合物与细粉碎的蜡混合。在高混合速度下混合这些混合物，混合器中的温度低于所用蜡的熔融温度。任选向如此制备的产品中加入另一些添加剂。
Description
本申请涉及一种制备包含农业化学活性材料的蜡预混合物的方法。
在水上栽培中，例如在稻田中，在施加粒状的农业化学活性物质时，经常出现粒状的颗粒从水面下沉、活性物质溶解出来在该区域出现有害的高浓度的危险。为了避免这种过高的局部剂量，已经有人提出采用漂浮的颗粒，漂浮的颗粒在水面上释放在各种情况下所需浓度的活性物质(参见JP-A 88-35 504和JP-A 93-155 703)。例如，已经公开采用蜡熔融体处理农业化学活性物质，然后将其冷却，并将所得的固体产物粉碎，将粉碎的产物与惯用的添加剂混合，再将混合物施加到适宜的载体材料上以制备这种漂浮颗粒的方法。这种方法的缺点是，在熔融体冷却后获得的蜡预混合物粉碎困难，在磨碎过程之后，活性物质颗粒不能被蜡覆层完全包住。
现已发现，可以采用一种新的方法制备包含农业化学活性物质的蜡预混合物，即在一个具有锋利边缘的混合装置的混合器中，在高搅拌速度下，将细粉碎的蜡加入到下列物料组成的细粉碎的混合物中：——至少一种固态的农业化学活性物质，和——至少一种植物或动物油，混合器中的温度，低于所用蜡的熔点，如果需要，随后将另一些添加剂加到所制备的产品中。
十分意外地表明，实施根据本发明的方法，不产生所用成分的物理混合物，而是由封闭的蜡覆层包住活性物质的颗粒。非常使人意外的是，这种蜡预混合物只有在混合器的混合装置具有锋利的边缘时才能采用根据本发明的方法获得。
根据本发明的方法，其特征在于具有一系列的优点。例如，所需的成分可大量的容易获得。而且，这种方法可以在不需大耗费的通常的设备中进行。此外，可以直接继续处理所制备的蜡预混合物；不需要磨碎过程。
在实施根据本发明的方法时，适宜的农业化学活性物质，是适合植物处理的所有活性物质，其熔点为约40℃以上。在本发明的情况下，应将农业化学活性物质理解为系指杀真菌剂、杀细菌剂、杀虫剂、杀螨剂、杀线虫剂、除草剂、和植物生长调节剂。
可以列举的杀真菌剂的实例是：
2-苯胺基-4-甲基-6-环丙基嘧啶；2′，6′-二溴-2-甲基-4′-三氟-甲氧基-4′-三氟甲基-1，3-噻唑-5-甲酰苯胺；2，6-二氯-N-(4-三氟甲基苄基)苯甲酰胺；(E)-2-甲氧基亚氨基-N-甲基-2-(苯氧苯基)-乙酰胺；aldimorph、敌菌灵、戊环唑、腈嘧菌酯、苯霜灵、苯菌灵、双苯三唑醇、灭瘟素、糠菌唑、磺酸丁嘧啶、多菌灵、萎锈灵、甲基克杀螨、百菌清、霜脲氰、环唑醇、氯环丙酰胺、防霉酚、苄氯三唑醇、抑菌灵、氯硝胺、乙霉威、恶醚唑、甲嘧醇、烯酰吗啉、烯唑醇、二唑农、十二烷胍、腙菌酮、氧唑菌、乙嘧啶、氯唑灵、双氯苯嘧啶、苯氰唑、fenhexamide、种衣酯、拌种咯、苯锈啶、丁苯吗啉、氟啶胺、氟噁菌、氟唑喹菌酮、氟哇唑、磺菌胺、氟酰胺、粉唑醇、乙磷铝、四氯苯酞、麦穗宁、呋霜灵、双胍辛、己唑醇、甲羟异恶唑、抑霉唑、酰胺唑、双胍辛醋酸盐、异稻瘟净、异菌脲、稻瘟灵、iprovalicarb、亚胺菌、嘧菌胺、灭锈胺、甲霜灵、环戊唑菌、磺菌威、担菌威、代森联、腈菌唑、氟苯嘧啶醇、甲呋酰胺、恶酰胺、氧化萎锈灵、戊菌唑、戊菌隆、烯丙异噻唑、咪鲜安、二甲菌核利、丙环唑、甲基代森锌、啶斑肟、二甲嘧菌胺、五氯硝基苯、喹氧灵、螺噁茂胺、戊唑醇、酞枯酸、四氯硝基苯、氟醚唑、噻菌灵、噻菌腈、甲基托布津、福美双、对甲抑菌灵、三唑酮、三唑醇、唑菌嗪、杨菌胺、三环唑、环吗啉、氟菌唑、嗪氨灵、戊叉唑菌、trifloxstrobin、有效霉素、烯菌酮、代森锌、福美锌、2-[2-(1-氯环丙基)-3-(2-氯苯基)-2-羟丙基]-2，4-二氢-[1，2，4]-三唑-3-硫酮、和1-(3，5-二甲基异恶唑-4-磺酰基)-2-氯-6，6-二氟-[1，3]-二氧-[4，5-f]-苯并咪唑。
可以列举的杀虫剂、杀螨剂、和杀线虫剂的实例是：
齐墩螨素、棉铃威、涕灭威、双甲脒、齐墩螨素、AZ 60541、三唑锡、4-溴-2-(4-氯苯基)-1-(乙氧基甲基)-5-(三氟甲基)-1H-吡咯-3-腈、苯恶威、丙硫克百威、杀虫螨、乙体氟氯氰菊酯、氟氯菊酯、丁苯威、溴醚菊酯、混戊威、噻嗪酮、丁酮威、丁基哒螨酮、西维因、克百威、定虫隆、N-[(6-氯-3-吡啶基)-甲基]-N′-氰基-N-甲基乙亚氨基酰胺、四螨嗪、灭蝇胺、杀螨隆、地亚农、氯线磷、乙硫磷、伏虫脲、乐果、二恶硫磷、乙拌磷、emamectin、高氰戊菊酯、除蚜威、乙硫磷、醚菊酯、克线磷、喹螨醚、螨完锡、杀螟硫磷、丁苯威、苯硫威、双氧威、甲氰菊酯、fenpyrad、唑螨酯、倍硫磷、氰戊菊酯、锐劲特、氟啶蜱脲、氟螨脲、氟虫脲、氟醚菊酯、氟胺氰菊酯、安果、噻唑硫磷、fubfenprox、呋线威、氟铃脲、噻螨酮、咪蚜胺、氯唑磷、异丙胺磷、异丙威、恶唑磷、伊维菌素、λ-三氟氯氰菊酯、氟丙氧脲、灭蚜硫磷、甲硫威、灭多威、速灭威、米尔倍菌素、moxidectin、二溴磷、NC 185、硝胺烯啶、氧乐果、草肟威、砜吸硫磷、氯菊酯、稻丰散、甲拌磷、伏杀硫磷、辛硫磷、抗蚜威、甲基嘧啶硫磷、嘧啶硫磷、甲丙威、残杀威、发果、拒嗪酮、苯哒嗪硫磷、除虫菊、哒螨酮、嘧胺苯醚、蚊蝇醚、喹硫磷、水杨硫磷、硫线磷、灭虫硅醚、治螟磷、甲丙硫磷、艾克敌105、双苯酰肼、吡螨胺、伏虫隆、thiacloprid、thiafenox、thiamethoxan、硫双灭多威、己酮肟威、甲基乙拌磷、喹线磷、triazuron、敌百虫、杀虫隆、混杀威、完灭硫磷、二甲威、二甲苯威。
可以列举的除草剂的实例是：
吡虫清
苯黄隆
环丙黄隆
氟咔唑
procarbazone sodium
吡氟草胺
二氯丙酰苯胺
氨基氯哒嗪酮
达草灭
异苯敌草
甜菜宁
草不绿
乙草胺
去草胺
吡草胺
metalochlor
氟锁草醚
治草醚
绿麦隆
敌草隆
异丙隆
利谷隆
敌草腈
碘苯腈
苯噻草胺
磺氨黄隆
氯嘧黄隆
绿黄隆
醚黄隆
甲基黄隆
烟嘧黄隆
氟嘧黄隆
吡嘧黄隆
硫黄隆
噻黄隆
苯黄隆
莠去津
草净津
西玛津
苯嗪草
赛克津
草铵膦和
镇草宁。
可以列举的植物生长调节剂的实例是矮壮素阳离子和乙烯利。
实施根据本发明的方法可以使用的油类，是制备农业化学试剂通常使用的所有植物和矿物油。适宜的油类优选菜子油、葵花子油、豆油、棉子油、橄榄油、蓖麻油、和轻油。
适合实施根据本发明方法的蜡是适合制备农业化学试剂、熔点为80-120℃、具有蜡稠度的所有材料。优选采用分子量为约10000的褐煤蜡，例如石蜡、聚乙烯蜡，改性的聚乙烯蜡，例如磺酰基化的蜡等，此外还可是褐煤蜡酸的酯类，也可以是部分皂化的褐煤蜡酸的酯类。
适合实施根据本发明方法的添加剂是制备农业化学试剂过程中通常用作添加剂的所有物质。适合采用的载体，例如优选磨碎的天然矿物，例如高岭土、粘土、滑石、白垩、石英、硅镁土、蒙脱石、或硅藻土等，还有磨碎的合成岩石，例如高度分散的二氧化硅、氧化铝、和硅酸盐。
实施根据本发明的方法可以使用的混合器是适合制备蜡预混合物的所有惯用的混合器。然而，前提是混合器可以被加热，并具有边缘锋利的搅拌装置。在这种情况下优选具有如剑类的磨光的或单侧削平的搅拌装置的混合器。
在实施根据本发明的方法时，必须保持搅拌速度高。这种方法优选在搅拌装置外端的速度至少18m/s，优选18-40m/s下进行。
在实施根据本发明的方法时，温度可以在一定范围内变化。该方法一般在温度10-80℃，优选在20-50℃下进行。
根据本发明的方法一般在大气压下进行。然而，该方法也可以在升高或降低的压力下进行。
在实施根据本发明的方法时，农业化学活性物质颗粒的尺寸和蜡颗粒的尺寸可以在一定范围内变化。优选采用直径20-180μ的活性物质颗粒和直径4-150μ的蜡颗粒。
在实施根据本发明的方法时，所采用的各个成分的比例也可以在一定范围内变化。一般按下列方法进行，其中每1重量份农业化学活性物质加入：
——1.5-4.0重量份，优选1.9-3.0重量份的蜡，
——0.1-10重量份，优选0.5-3重量份的油，和
——0-70重量份，优选0-30重量份的添加剂。
具体而言，在实施根据本发明的方法时如此进行，在混合器中将一种或多种细粉碎形式的固态农业化学活性物质与至少一种植物或矿物油混合，然后加入细粉碎形式的蜡，在高速搅拌下，将混合物搅拌均匀，如果需要加入添加剂，再在高速搅拌下搅拌均匀。优选蜡和农业化学活性物质，如果需要还有添加剂以足够细的形式存在，都以粉碎的形式加入。如果在农业化学活性物质颗粒用蜡包覆之后再加入添加剂，则可将混合物与这些添加剂(如果一种以上)同时加入或逐次加入。优选在每次加入另一种成分之后都进行均匀化步骤。
采用根据本发明的方法可制备的蜡预混合物是细粉碎的能自由流动的产品，其中的农业化学活性物质颗粒完全由封闭的蜡覆层包封。
可以采用惯用的方法，将按照本发明制备的蜡预混合物转化，制成随后可以作为农业化学试剂使用的制剂。于是，例如将按照本发明制备的蜡预混合物如果需要可在加入另一些添加剂，例如粘着剂和/或表面活性剂之后施加到密度低的载体上，就可以制备漂浮在水上的颗粒。然而，也可以直接采用按照本发明制备的产品处理植物。
按照本发明制备的蜡预混合物和采用它们生产的农业化学试剂的特征在于，当采用预混合物/农业化学试剂处理植物时，它们包含的活性物质能在长期内均匀地释放。
现在采用下面的实施例来说明本发明。制备实施例 实施例1
在室温下，在具有剑式搅拌装置的混合器中，将15重量份平均直径20μ的粒状环丙黄隆，和2重量份的菜子油混合5分钟。
在室温下，向该混合物中加入30重量份平均直径5μ的粒状蜡(Cerridust5551，Clariant)，在室温下采用高速搅拌(搅拌器外端速度至少18m/s)混合所有的物料，直至形成均匀的产品为止。然后加入43重量份高度分散的二氧化硅，在室温下继续混合15分钟。然后加入10重量份的滑石，混合物在室温下再搅拌15分钟。于是获得由平均直径70μ的离散颗粒组成的、能自由流动的蜡预混合物。每一个活性物质颗粒都被封闭的蜡覆层包住。实施例2
在室温下，在具有剑式搅拌装置的混合器中，将15重量份平均直径20μ的粒状环丙黄隆，和2重量份的菜子油混合5分钟。
在室温下，向该混合物中加入30重量份平均直径5μ的粒状蜡(Sanwax171 P，Sankyo化学工业公司)，在室温下采用高速搅拌(搅拌器外端速度至少18m/s)混合所有的物料，直至形成均匀的产品为止。然后加入43重量份高度分散的二氧化硅，在室温下继续混合15分钟。然后加入10重量份的滑石，混合物在室温下再搅拌15分钟。于是获得由平均直径60μ的离散颗粒组成的、能自由流动的蜡预混合物。每一个活性材料颗粒都被封闭的蜡覆层包住。实施例3
在室温下，在具有剑式搅拌装置的混合器中，将15重量份平均直径20μ的粒状环丙黄隆，和2重量份的轻油混合5分钟。
在室温下，向该混合物中加入45重量份平均直径5μ的粒状蜡(Cerridust5551，Clariant)，在室温下采用高速搅拌(搅拌器外端速度至少18m/s)混合所有的物料，直至形成均匀的产品为止。然后加入28重量份高度分散的二氧化硅，在室温下继续混合15分钟。然后加入10重量份的滑石，混合物在室温下再搅拌15分钟。于是获得由平均直径60μ的离散颗粒组成的、能自由流动的蜡预混合物。每一个活性材料颗粒都被封闭的蜡覆层包住。对比例 对比例A
按实施例1的方法，所不同的是，采用没有锋利边缘的搅拌装置。
在室温下，在具有倒圆的搅拌装置的混合器中，将15重量份平均直径20μ的粒状环丙黄隆，和2重量份的菜子油混合5分钟。
在室温下，向该混合物中加入30重量份平均直径5μ的粒状蜡(Cerridust5551，Clariant)，在室温下采用高速搅拌(搅拌器外端速度至少18m/s)混合所有的物料，直至形成均匀的产品为止。然后加入43重量份高度分散的二氧化硅，在室温下继续混合15分钟。然后加入10重量份的滑石，混合物在室温下再搅拌15分钟。于是获得由团粒组成的蜡预混合物。对比例B
按实施例1的方法，但不使用任何油。
在室温下，在具有剑式搅拌装置的混合器中，将15重量份平均直径20μ的粒状环丙黄隆，与30重量份平均直径5μ的粒状蜡(Cerridust5551，Clariant)混合，在室温下采用高速搅拌(搅拌器外端速度至少18m/s)混合该混合物，直至形成均匀的产品为止。然后加入43重量份高度分散的二氧化硅，在室温下继续混合15分钟。然后加入10重量份的滑石，混合物在室温下再搅拌15分钟。于是获得由部分以蜡包覆的活性材料颗粒和单独的蜡颗粒组成的预混合物。对比例C
采用熔融方法制备蜡预混合物。
在混合器中，将32重量份的片状褐煤蜡加热到110℃，生成熔融体。在110℃，在搅拌下，向该熔融体中加入15重量份平均直径5μ的粒状环丙黄隆。在110℃下将所得的悬浮体高速搅拌10min，然后混合器在全速下继续搅拌，与此同时，分批加入26.5重量份高度分散的二氧化硅。在搅拌下加入26.5重量份的滑石，同时将所得的能流动的粉末冷却到室温。于是获得由团粒组成的蜡预混合物。其中约10重量％的环丙黄隆被分解。
Claims (6)
1.一种制备包含农业化学活性物质的蜡预混合物的方法，其特征在于，在具有锋利边缘的混合装置的混合器中，在高搅拌速度下，将细粉碎的蜡加到下列物料组成的细粉碎的混合物中：——至少一种固态的农业化学活性物质，和——至少一种植物或矿物油，混合器中的温度，低于所用蜡的熔点，如果需要，随后向所制备的产品中加入另一些添加剂。
2.权利要求1的方法，其特征在于，所采用的农业化学活性物质，是杀真菌剂、杀细菌剂、杀虫剂、杀螨剂、杀线虫剂、除草剂、或植物生长调节剂。
3.权利要求1的方法，其特征在于，采用菜子油、葵花子油、豆油、棉子油、橄榄油、蓖麻油、或轻油作为植物油或矿物油。
4.权利要求1的方法，其特征在于，采用褐煤蜡、石蜡、聚乙烯蜡、或改性的聚乙烯蜡作为蜡成分。
5.权利要求1的方法，其特征在于，采用磨碎的天然或合成岩石作为添加剂。
6.权利要求1的方法，其特征在于，采用10-80℃的温度。
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| Application Number | Priority Date | Filing Date | Title |
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| DE10018396A DE10018396A1 (de) | 2000-04-13 | 2000-04-13 | Verfahren zur Herstellung von Wachs-Vormischungen |
| DE10018396.4 | 2000-04-13 |
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| CN1422116A true CN1422116A (zh) | 2003-06-04 |
| CN1217575C CN1217575C (zh) | 2005-09-07 |
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| EP (1) | EP1276373A2 (zh) |
| JP (1) | JP2003530407A (zh) |
| KR (1) | KR20020087462A (zh) |
| CN (1) | CN1217575C (zh) |
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| CN103635084A (zh) * | 2011-04-20 | 2014-03-12 | 埃克索塞克特有限公司 | 用于蔬菜中的病原体控制的包衣组合物 |
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| JP5176221B2 (ja) * | 2004-11-04 | 2013-04-03 | 丸和バイオケミカル株式会社 | アセトラクテート合成阻害剤を含有する微粒剤。 |
| US20070071786A1 (en) * | 2005-09-27 | 2007-03-29 | Suterra Llc | Wax emulsion compositions for attracting insects and methods of using the same |
| EP2046123B1 (en) * | 2006-07-24 | 2014-09-24 | Syngenta Participations AG | Controlled release granules |
| GB0623398D0 (en) * | 2006-11-23 | 2007-01-03 | Exosect Ltd | Arthropod control |
| GB201106741D0 (en) | 2011-04-20 | 2011-06-01 | Exosect Ltd | Coating compositions for pathogen control in monocotyledonous plants |
| GB201106763D0 (en) * | 2011-04-20 | 2011-06-01 | Exosect Ltd | Compositions for growth and vigour in cotton |
| GB201106746D0 (en) * | 2011-04-20 | 2011-06-01 | Exosect Ltd | Coating compositions for pathogen control in oilseeds |
| WO2012143680A2 (en) * | 2011-04-20 | 2012-10-26 | Exosect Limited | Coating composition for plant structures |
| GB201106745D0 (en) * | 2011-04-20 | 2011-06-01 | Exosect Ltd | Coating compositons for pathogen control in ornamentals |
| GB201106758D0 (en) * | 2011-04-20 | 2011-06-01 | Exosect Ltd | Compositions for growth and vigour in vegetables |
| GB201106748D0 (en) * | 2011-04-20 | 2011-06-01 | Exosect Ltd | Coating compositions for pathogen control in cotton |
| GB201106761D0 (en) * | 2011-04-20 | 2011-06-01 | Exosect Ltd | Compositions for growth and vigour in ornamentals |
| GB201106744D0 (en) * | 2011-04-20 | 2011-06-01 | Exosect Ltd | Coating compositions for pathogen control in soybean |
| GB201106762D0 (en) * | 2011-04-20 | 2011-06-01 | Exosect Ltd | Compositions for growth and vigour from oilseeds |
| GB201106759D0 (en) * | 2011-04-20 | 2011-06-01 | Exosect Ltd | Compositions for growth and vigour in soybean |
| GB201106764D0 (en) | 2011-04-20 | 2011-06-01 | Exosect Ltd | Composition for seed growth and vigour in monocots |
| RU2646090C1 (ru) * | 2016-12-27 | 2018-03-01 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Кубанский государственный аграрный университет имени И.Т. Трубилина" | Влагозащитное парафиновое покрытие плодовых прививок и черенков яблони |
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| US4206197A (en) * | 1975-11-26 | 1980-06-03 | The United States Of America As Represented By The Secretary Of The Navy | Chemical encapsulation and distribution |
| JPS6335504A (ja) * | 1986-07-31 | 1988-02-16 | Nissan Chem Ind Ltd | 放出制御させた除草用粒剤 |
| US5229356A (en) * | 1991-08-23 | 1993-07-20 | E. I. Du Pont De Nemours And Company | Slow release compositions comprising heterocyclic sulfonylurea herbicides, paraffin wax, hydrocarbon polymers, and particulate fillers |
| JPH05305226A (ja) * | 1992-04-28 | 1993-11-19 | Takeda Chem Ind Ltd | 粒子及びその製造法 |
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- 2001-04-05 KR KR1020027013169A patent/KR20020087462A/ko not_active Application Discontinuation
- 2001-04-05 CN CN01807944XA patent/CN1217575C/zh not_active Expired - Fee Related
- 2001-04-05 US US10/257,182 patent/US20030108584A1/en not_active Abandoned
- 2001-04-05 WO PCT/EP2001/003866 patent/WO2001078509A2/de not_active Application Discontinuation
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103635084A (zh) * | 2011-04-20 | 2014-03-12 | 埃克索塞克特有限公司 | 用于蔬菜中的病原体控制的包衣组合物 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1217575C (zh) | 2005-09-07 |
| WO2001078509A2 (de) | 2001-10-25 |
| KR20020087462A (ko) | 2002-11-22 |
| WO2001078509A3 (de) | 2002-04-04 |
| AU2001262171A1 (en) | 2001-10-30 |
| US20030108584A1 (en) | 2003-06-12 |
| DE10018396A1 (de) | 2001-10-18 |
| JP2003530407A (ja) | 2003-10-14 |
| EP1276373A2 (de) | 2003-01-22 |
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