CN1401427A - 一种用于费托合成的含钴废催化剂的回收方法 - Google Patents
一种用于费托合成的含钴废催化剂的回收方法 Download PDFInfo
- Publication number
- CN1401427A CN1401427A CN 02130057 CN02130057A CN1401427A CN 1401427 A CN1401427 A CN 1401427A CN 02130057 CN02130057 CN 02130057 CN 02130057 A CN02130057 A CN 02130057A CN 1401427 A CN1401427 A CN 1401427A
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- CN
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- Prior art keywords
- cobalt
- spent catalyst
- fischer
- nitric acid
- extracting
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000003054 catalyst Substances 0.000 title claims abstract description 33
- 238000000034 method Methods 0.000 title claims abstract description 19
- 238000011084 recovery Methods 0.000 title claims abstract description 19
- 230000015572 biosynthetic process Effects 0.000 title abstract description 3
- 238000003786 synthesis reaction Methods 0.000 title abstract description 3
- 239000002699 waste material Substances 0.000 title description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 24
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229910017604 nitric acid Inorganic materials 0.000 claims abstract description 18
- 229910021503 Cobalt(II) hydroxide Inorganic materials 0.000 claims abstract description 8
- ASKVAEGIVYSGNY-UHFFFAOYSA-L cobalt(ii) hydroxide Chemical compound [OH-].[OH-].[Co+2] ASKVAEGIVYSGNY-UHFFFAOYSA-L 0.000 claims abstract description 8
- 238000001704 evaporation Methods 0.000 claims abstract description 8
- 230000008020 evaporation Effects 0.000 claims abstract description 8
- 239000002244 precipitate Substances 0.000 claims abstract description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 42
- 229910017052 cobalt Inorganic materials 0.000 claims description 41
- 239000010941 cobalt Substances 0.000 claims description 41
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 14
- 239000004215 Carbon black (E152) Substances 0.000 claims description 8
- 239000000706 filtrate Substances 0.000 claims description 8
- 229930195733 hydrocarbon Natural products 0.000 claims description 8
- 150000002430 hydrocarbons Chemical class 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 238000001556 precipitation Methods 0.000 claims description 8
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 7
- 238000002425 crystallisation Methods 0.000 claims description 7
- 230000008025 crystallization Effects 0.000 claims description 7
- 238000004090 dissolution Methods 0.000 claims description 7
- 239000000047 product Substances 0.000 claims description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
- ZYHMJXZULPZUED-UHFFFAOYSA-N propargite Chemical compound C1=CC(C(C)(C)C)=CC=C1OC1C(OS(=O)OCC#C)CCCC1 ZYHMJXZULPZUED-UHFFFAOYSA-N 0.000 claims description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- 238000005406 washing Methods 0.000 claims description 2
- 238000001914 filtration Methods 0.000 abstract 2
- QGUAJWGNOXCYJF-UHFFFAOYSA-N cobalt dinitrate hexahydrate Chemical compound O.O.O.O.O.O.[Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O QGUAJWGNOXCYJF-UHFFFAOYSA-N 0.000 abstract 1
- 239000007789 gas Substances 0.000 description 8
- 238000003916 acid precipitation Methods 0.000 description 5
- 239000013078 crystal Substances 0.000 description 5
- 238000000921 elemental analysis Methods 0.000 description 5
- 229910052739 hydrogen Inorganic materials 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 3
- 229910052726 zirconium Inorganic materials 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000003729 cation exchange resin Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- MZZUATUOLXMCEY-UHFFFAOYSA-N cobalt manganese Chemical compound [Mn].[Co] MZZUATUOLXMCEY-UHFFFAOYSA-N 0.000 description 1
- WHDPTDWLEKQKKX-UHFFFAOYSA-N cobalt molybdenum Chemical compound [Co].[Co].[Mo] WHDPTDWLEKQKKX-UHFFFAOYSA-N 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Abstract
Description
Claims (3)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB021300577A CN1190266C (zh) | 2002-08-19 | 2002-08-19 | 一种用于费托合成的含钴废催化剂的回收方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB021300577A CN1190266C (zh) | 2002-08-19 | 2002-08-19 | 一种用于费托合成的含钴废催化剂的回收方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1401427A true CN1401427A (zh) | 2003-03-12 |
CN1190266C CN1190266C (zh) | 2005-02-23 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CNB021300577A Expired - Fee Related CN1190266C (zh) | 2002-08-19 | 2002-08-19 | 一种用于费托合成的含钴废催化剂的回收方法 |
Country Status (1)
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CN (1) | CN1190266C (zh) |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2005002701A2 (en) * | 2003-07-02 | 2005-01-13 | Chevron U.S.A. Inc. | Catalytic filtering of a fischer-tropsch derived hydrocarbon stream |
CN101395288B (zh) * | 2006-03-03 | 2011-04-13 | 约翰森·马瑟公开有限公司 | 催化剂再处理 |
CN101700913B (zh) * | 2009-11-17 | 2011-05-18 | 中南民族大学 | 利用费托合成用氧化铝负载钴基废催化剂制备高纯硝酸钴 |
CN102311146A (zh) * | 2010-07-06 | 2012-01-11 | 重庆紫光化工股份有限公司 | 一种钴盐的回收方法 |
CN102311341A (zh) * | 2010-07-06 | 2012-01-11 | 重庆紫光化工股份有限公司 | 丙二酸酯的羰化合成方法 |
US8282705B2 (en) | 2007-06-18 | 2012-10-09 | Crisolteq Oy | Method for recovering metals from a spent catalyst composition |
CN103074494A (zh) * | 2011-10-25 | 2013-05-01 | 荆门市格林美新材料有限公司 | 废旧钴钼系催化剂回收钼钴的方法 |
EP2824075A4 (en) * | 2012-03-05 | 2015-11-18 | Wuhan Kaidi Eng Tech Res Inst | PROCESS FOR THE PREPARATION OF HIGH-PURITY COBALT NITRATE CRYSTALS FROM CO / SIO2 WAS CATALYSTS |
CN105543496A (zh) * | 2015-12-29 | 2016-05-04 | 武汉凯迪工程技术研究总院有限公司 | 费托合成废催化剂Co-Rh/Al2O3中金属钴、铑和铝的回收方法 |
CN111282574A (zh) * | 2020-02-03 | 2020-06-16 | 中国矿业大学(北京) | 一种费托合成铁系催化剂的回收方法 |
-
2002
- 2002-08-19 CN CNB021300577A patent/CN1190266C/zh not_active Expired - Fee Related
Cited By (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2005002701A2 (en) * | 2003-07-02 | 2005-01-13 | Chevron U.S.A. Inc. | Catalytic filtering of a fischer-tropsch derived hydrocarbon stream |
WO2005002701A3 (en) * | 2003-07-02 | 2005-06-30 | Chevron Usa Inc | Catalytic filtering of a fischer-tropsch derived hydrocarbon stream |
GB2420789A (en) * | 2003-07-02 | 2006-06-07 | Chevron Usa Inc | Catalytic filtering of a fischer-tropsch derived hydrocarbon stream |
US7150823B2 (en) * | 2003-07-02 | 2006-12-19 | Chevron U.S.A. Inc. | Catalytic filtering of a Fischer-Tropsch derived hydrocarbon stream |
GB2420789B (en) * | 2003-07-02 | 2008-08-13 | Chevron Usa Inc | Catalytic filtering of a fischer-tropsch derived hydrocarbon stream |
CN101395288B (zh) * | 2006-03-03 | 2011-04-13 | 约翰森·马瑟公开有限公司 | 催化剂再处理 |
US8282705B2 (en) | 2007-06-18 | 2012-10-09 | Crisolteq Oy | Method for recovering metals from a spent catalyst composition |
CN101700913B (zh) * | 2009-11-17 | 2011-05-18 | 中南民族大学 | 利用费托合成用氧化铝负载钴基废催化剂制备高纯硝酸钴 |
CN102311341A (zh) * | 2010-07-06 | 2012-01-11 | 重庆紫光化工股份有限公司 | 丙二酸酯的羰化合成方法 |
CN102311146A (zh) * | 2010-07-06 | 2012-01-11 | 重庆紫光化工股份有限公司 | 一种钴盐的回收方法 |
CN102311146B (zh) * | 2010-07-06 | 2013-11-13 | 重庆紫光化工股份有限公司 | 一种钴盐的回收方法 |
CN103074494A (zh) * | 2011-10-25 | 2013-05-01 | 荆门市格林美新材料有限公司 | 废旧钴钼系催化剂回收钼钴的方法 |
CN103074494B (zh) * | 2011-10-25 | 2014-12-31 | 荆门市格林美新材料有限公司 | 废旧钴钼系催化剂回收钼钴的方法 |
EP2824075A4 (en) * | 2012-03-05 | 2015-11-18 | Wuhan Kaidi Eng Tech Res Inst | PROCESS FOR THE PREPARATION OF HIGH-PURITY COBALT NITRATE CRYSTALS FROM CO / SIO2 WAS CATALYSTS |
RU2580744C1 (ru) * | 2012-03-05 | 2016-04-10 | Ухань Кайди Инджиниринг Текнолоджи Рисерч Инститьют Ко., Лтд. | СПОСОБ ПОЛУЧЕНИЯ КРИСТАЛЛОВ НИТРАТА КОБАЛЬТА ВЫСОКОЙ ЧИСТОТЫ ИЗ ОТРАБОТАННЫХ КАТАЛИЗАТОРОВ Сo/SiO2 |
CN105543496A (zh) * | 2015-12-29 | 2016-05-04 | 武汉凯迪工程技术研究总院有限公司 | 费托合成废催化剂Co-Rh/Al2O3中金属钴、铑和铝的回收方法 |
CN105543496B (zh) * | 2015-12-29 | 2017-10-20 | 武汉凯迪工程技术研究总院有限公司 | 费托合成废催化剂Co‑Rh/Al2O3中金属钴、铑和铝的回收方法 |
CN111282574A (zh) * | 2020-02-03 | 2020-06-16 | 中国矿业大学(北京) | 一种费托合成铁系催化剂的回收方法 |
CN111282574B (zh) * | 2020-02-03 | 2020-12-15 | 中国矿业大学(北京) | 一种费托合成铁系催化剂的回收方法 |
Also Published As
Publication number | Publication date |
---|---|
CN1190266C (zh) | 2005-02-23 |
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Owner name: ZHONGKE SYNTHETIC OIL TECHNOLOGY CO., LTD., DISTR Free format text: FORMER OWNER: SHANXI INST. OF COAL CHEMISTRY, CHINESE ACADEMY OF SCIENCES Effective date: 20070119 |
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Effective date of registration: 20070119 Address after: 030006, Shanxi Taiyuan hi tech Zone, South Central Cyberport, port 4, 2 floor, A and B Patentee after: SYNFUELS CHINA TECHNOLOGY Co.,Ltd. Address before: 165 mailbox 030001, Shanxi City, Taiyuan Province Patentee before: INSTITUTE OF COAL CHEMISTRY, CHINESE ACADEMY OF SCIENCES |
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C56 | Change in the name or address of the patentee | ||
CP02 | Change in the address of a patent holder |
Address after: 101407 Beijing city Huairou District Yanqi Economic Development Zone C District No. 1 south two Street Park Patentee after: SYNFUELS CHINA TECHNOLOGY Co.,Ltd. Address before: 030006, Shanxi Taiyuan hi tech Zone, South Central Cyberport, port 4, 2 floor, A and B Patentee before: SYNFUELS CHINA TECHNOLOGY Co.,Ltd. |
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CP01 | Change in the name or title of a patent holder |
Address after: 101407 No.1, south 2nd Yueyuan street, C District, Yanqi Economic Development Zone, Huairou District, Beijing Patentee after: Zhongke synthetic oil Technology Co.,Ltd. Address before: 101407 No.1, south 2nd Yueyuan street, C District, Yanqi Economic Development Zone, Huairou District, Beijing Patentee before: SYNFUELS CHINA TECHNOLOGY Co.,Ltd. |
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CP01 | Change in the name or title of a patent holder | ||
CF01 | Termination of patent right due to non-payment of annual fee | ||
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Granted publication date: 20050223 Termination date: 20210819 |