CN1377377A - 聚乙烯的制备 - Google Patents

聚乙烯的制备 Download PDF

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Publication number
CN1377377A
CN1377377A CN00813383A CN00813383A CN1377377A CN 1377377 A CN1377377 A CN 1377377A CN 00813383 A CN00813383 A CN 00813383A CN 00813383 A CN00813383 A CN 00813383A CN 1377377 A CN1377377 A CN 1377377A
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CN
China
Prior art keywords
groups
group
carbon group
polymerization catalyst
bonded
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Pending
Application number
CN00813383A
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English (en)
Chinese (zh)
Inventor
L·王
M·斯皮努
J·D·西特伦
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EIDP Inc
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EI Du Pont de Nemours and Co
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Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Publication of CN1377377A publication Critical patent/CN1377377A/zh
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/607—Catalysts containing a specific non-metal or metal-free compound
    • C08F4/609—Catalysts containing a specific non-metal or metal-free compound organic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61904—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with another component of C08F4/60
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
    • C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2314/00—Polymer mixtures characterised by way of preparation
    • C08L2314/06—Metallocene or single site catalysts

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
CN00813383A 1999-09-29 2000-09-28 聚乙烯的制备 Pending CN1377377A (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US15658899P 1999-09-29 1999-09-29
US60/156,588 1999-09-29

Related Child Applications (1)

Application Number Title Priority Date Filing Date
CN2006101423259A Division CN1939934B (zh) 1999-09-29 2000-09-28 聚乙烯的制备

Publications (1)

Publication Number Publication Date
CN1377377A true CN1377377A (zh) 2002-10-30

Family

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Family Applications (2)

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CN00813383A Pending CN1377377A (zh) 1999-09-29 2000-09-28 聚乙烯的制备
CN2006101423259A Expired - Lifetime CN1939934B (zh) 1999-09-29 2000-09-28 聚乙烯的制备

Family Applications After (1)

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Country Status (11)

Country Link
US (3) US6555631B1 (https=)
EP (1) EP1228110B1 (https=)
JP (1) JP2003510427A (https=)
KR (1) KR20020037364A (https=)
CN (2) CN1377377A (https=)
AT (1) ATE282645T1 (https=)
AU (1) AU7726800A (https=)
BR (2) BR0014639B1 (https=)
CA (1) CA2379607A1 (https=)
DE (1) DE60016014T2 (https=)
WO (1) WO2001023443A1 (https=)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101098899B (zh) * 2004-04-26 2011-04-13 巴塞尔聚烯烃股份有限公司 聚乙烯和用于它的制备的催化剂组合物
CN101970514B (zh) * 2008-03-13 2013-11-20 陶氏环球技术有限责任公司 乙烯与另一聚合物组合的长链支化(lcb)、嵌段或互联共聚物

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US6458979B1 (en) * 1999-04-29 2002-10-01 E. I. Du Pont De Nemours And Company Polymerization of ethylene
CN100528356C (zh) * 2002-01-09 2009-08-19 纳幕尔杜邦公司 烯烃聚合催化剂
US7081506B2 (en) * 2003-10-23 2006-07-25 Fina Technology, Inc. Ethylene polymerization employing bis-imino pyridinyl transition metal catalyst components
US7410926B2 (en) * 2003-12-30 2008-08-12 Univation Technologies, Llc Polymerization process using a supported, treated catalyst system
DE102004020525A1 (de) * 2004-04-26 2005-11-10 Basell Polyolefine Gmbh Katalysatorsystem zur Olefinpolymerisation, dessen Herstellung und Verwendung
US7442819B2 (en) * 2004-07-09 2008-10-28 E. I. Du Pont De Nemours And Company Catalysts for olefin polymerization or oligomerization
EP1650231A1 (en) * 2004-10-21 2006-04-26 Total Petrochemicals Research Feluy Polyolefins prepared from a metallocene and a new single site catalyst components in a single reactor
US20070010626A1 (en) * 2005-07-11 2007-01-11 Shankernarayanan Manivakkam J Polyethylene compositions
US7268096B2 (en) 2005-07-21 2007-09-11 Chevron Phillips Chemical Company Lp Diimine metal complexes, methods of synthesis, and methods of using in oligomerization and polymerization
US7727926B2 (en) 2005-07-21 2010-06-01 Chevron Phillips Chemical Company Lp Diimine metal complexes, methods of synthesis, and method of using in oligomerization and polymerization
US7271121B2 (en) 2005-07-21 2007-09-18 Chevron Phillips Chemical Company Lp Diimine metal complexes, methods of synthesis, and methods of using in oligomerization and polymerization
US20070255026A1 (en) * 2006-04-28 2007-11-01 Fina Technology, Inc. Process for polyolefin production using fluorinated transition metal catalysts having a low pH
CN102574944B (zh) * 2009-08-17 2014-10-29 纳幕尔杜邦公司 改善的烯烃聚合方法
CN102712715B (zh) * 2010-01-21 2014-10-29 巴塞尔聚烯烃股份有限公司 在低聚催化剂存在下制备乙烯共聚物组合物的方法
US20130012659A1 (en) * 2010-03-29 2013-01-10 E I Dupont De Nemours And Company Lubricant component
JP2012224842A (ja) * 2011-03-30 2012-11-15 Sumitomo Chemical Co Ltd エチレン系重合体製造用触媒およびエチレン系重合体の製造方法
US9586872B2 (en) 2011-12-30 2017-03-07 Chevron Phillips Chemical Company Lp Olefin oligomerization methods
SG11201407130XA (en) 2012-05-09 2014-11-27 Sasol Tech Pty Ltd Tetramerisation of ethylene
EP3209722B1 (en) 2014-10-21 2025-07-16 Nova Chemicals (International) S.A. Ethylene interpolymer product with dilution index
CA2868640C (en) 2014-10-21 2021-10-26 Nova Chemicals Corporation Solution polymerization process
US9944661B2 (en) 2016-08-09 2018-04-17 Chevron Phillips Chemical Company Lp Olefin hydroboration
US10329412B2 (en) 2017-02-16 2019-06-25 Nova Chemicals (International) S.A. Caps and closures
US10442920B2 (en) 2017-04-19 2019-10-15 Nova Chemicals (International) S.A. Means for increasing the molecular weight and decreasing the density of ethylene interpolymers employing homogeneous and heterogeneous catalyst formulations
US10442921B2 (en) 2017-04-19 2019-10-15 Nova Chemicals (International) S.A. Means for increasing the molecular weight and decreasing the density employing mixed homogeneous catalyst formulations
US10995166B2 (en) 2017-11-07 2021-05-04 Nova Chemicals (International) S.A. Ethylene interpolymer products and films
US10683376B2 (en) 2017-11-07 2020-06-16 Nova Chemicals (International) S.A. Manufacturing ethylene interpolymer products at higher production rate
JP7050544B2 (ja) * 2018-03-27 2022-04-08 Ｅｎｅｏｓ株式会社 ワックス異性化油の製造方法
US10882987B2 (en) 2019-01-09 2021-01-05 Nova Chemicals (International) S.A. Ethylene interpolymer products having intermediate branching
US11046843B2 (en) 2019-07-29 2021-06-29 Nova Chemicals (International) S.A. Ethylene copolymers and films with excellent sealing properties

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101098899B (zh) * 2004-04-26 2011-04-13 巴塞尔聚烯烃股份有限公司 聚乙烯和用于它的制备的催化剂组合物
CN101970514B (zh) * 2008-03-13 2013-11-20 陶氏环球技术有限责任公司 乙烯与另一聚合物组合的长链支化(lcb)、嵌段或互联共聚物

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EP1228110A1 (en) 2002-08-07
US20040048989A1 (en) 2004-03-11
US6555631B1 (en) 2003-04-29
BR0017587B1 (pt) 2013-07-16
ATE282645T1 (de) 2004-12-15
CN1939934B (zh) 2010-09-01
WO2001023443A1 (en) 2001-04-05
AU7726800A (en) 2001-04-30
JP2003510427A (ja) 2003-03-18
US6921795B2 (en) 2005-07-26
DE60016014D1 (de) 2004-12-23
DE60016014T2 (de) 2005-11-24
CA2379607A1 (en) 2001-04-05
CN1939934A (zh) 2007-04-04
BR0014639A (pt) 2002-06-11
KR20020037364A (ko) 2002-05-18
EP1228110B1 (en) 2004-11-17
BR0014639B1 (pt) 2011-02-22
US20030149182A1 (en) 2003-08-07

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