CN1359110A - 一种复合导电材料的制备方法 - Google Patents
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- CN1359110A CN1359110A CN01135296A CN01135296A CN1359110A CN 1359110 A CN1359110 A CN 1359110A CN 01135296 A CN01135296 A CN 01135296A CN 01135296 A CN01135296 A CN 01135296A CN 1359110 A CN1359110 A CN 1359110A
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- 239000002131 composite material Substances 0.000 title claims abstract description 11
- 239000004020 conductor Substances 0.000 title claims abstract description 11
- 238000000034 method Methods 0.000 title abstract description 10
- 239000000835 fiber Substances 0.000 claims abstract description 26
- 239000000126 substance Substances 0.000 claims abstract description 26
- 238000007747 plating Methods 0.000 claims abstract description 21
- 238000004544 sputter deposition Methods 0.000 claims abstract description 11
- 238000002360 preparation method Methods 0.000 claims abstract description 10
- 238000005516 engineering process Methods 0.000 claims abstract description 8
- 239000004744 fabric Substances 0.000 claims abstract description 6
- 238000009713 electroplating Methods 0.000 claims abstract description 5
- 238000005406 washing Methods 0.000 claims abstract description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 24
- 239000011159 matrix material Substances 0.000 claims description 12
- 229910052759 nickel Inorganic materials 0.000 claims description 12
- 239000000463 material Substances 0.000 claims description 11
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 10
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 5
- 229910052802 copper Inorganic materials 0.000 claims description 5
- 239000010949 copper Substances 0.000 claims description 5
- 239000006260 foam Substances 0.000 claims description 5
- 229910052697 platinum Inorganic materials 0.000 claims description 5
- 229920000768 polyamine Polymers 0.000 claims description 5
- 239000004033 plastic Substances 0.000 claims description 4
- 239000004677 Nylon Substances 0.000 claims description 3
- 239000004743 Polypropylene Substances 0.000 claims description 3
- 229920004933 Terylene® Polymers 0.000 claims description 3
- 229910052786 argon Inorganic materials 0.000 claims description 3
- 239000004619 high density foam Substances 0.000 claims description 3
- 229920001778 nylon Polymers 0.000 claims description 3
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 3
- -1 polypropylene Polymers 0.000 claims description 3
- 229920001155 polypropylene Polymers 0.000 claims description 3
- 229920000728 polyester Polymers 0.000 claims description 2
- 210000003934 vacuole Anatomy 0.000 claims description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- 239000012300 argon atmosphere Substances 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- 239000011810 insulating material Substances 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 229920002635 polyurethane Polymers 0.000 abstract 1
- 239000004814 polyurethane Substances 0.000 abstract 1
- 238000005096 rolling process Methods 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 description 3
- 229910018095 Ni-MH Inorganic materials 0.000 description 1
- 229910018477 Ni—MH Inorganic materials 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/66—Selection of materials
- H01M4/661—Metal or alloys, e.g. alloy coatings
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/14—Metallic material, boron or silicon
- C23C14/20—Metallic material, boron or silicon on organic substrates
- C23C14/205—Metallic material, boron or silicon on organic substrates by cathodic sputtering
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Metallurgy (AREA)
- Mechanical Engineering (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Chemically Coating (AREA)
- Electroplating Methods And Accessories (AREA)
- Laminated Bodies (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Physical Vapour Deposition (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
Abstract
一种复合导电材料的制备方法,本发明涉及一种对绝缘物体进行导电化处理制备复合导电材料的方法,属于电镀技术领域。包括:以聚胺酯高密度泡沫片、化纤丝编织网、化纤编织布或化纤毡为基体,在氩气保护下用真空离子溅射法镀镍、铜或铂,温度170±5℃,离子溅射浓度2～2.5克/平方米;再用现有电镀技术在上述材料上连续镀镍、铜或铂,最后水洗、烘干、打卷。本发明的方法复合导电材料导电性好,可连续机械化生产降低成本,产品成卷便于存储、运输。本发明的方法还克服了现有技术中化学镀的污染问题。
Description
(一)技术领域
本发明涉及一种对绝缘物体进行导电化处理制备复合导电材料的方法，属于电镀
技术领域。
(二)技术背景
随着泡沫镍在镍氢电池上使用的普及，制备泡沫镍所需的导电基体基本也出现了多元化发展。另外现有的屏蔽材料多是导电布，成本高、薄、塑胶结合较难。目前在非金属材料上制备导电基体广泛采用的化学镀、涂导电胶等工艺已明显不能满足环保及产品质量的要求。化学镀成本高，污染严重，导电胶工艺不能很好地解决质量问题。一般真空镀产品易氧化。而目前兴起的电磁屏蔽的需求对电阻值的要求非常低，在0.2～5Ω左右，传统工艺无法满足现代工业的要求。
(三)发明内容
本发明针对已有技术的不足，提供一种导电性好的复合导电材料的制备方法。
本发明的方法包括：
1.基体：聚胺脂高密度泡沫片、化纤丝编织网、化纤编织布或化纤毡。
所述化纤是涤纶、聚酯、丙纶或尼龙。
所述聚胺脂泡沫孔径300～500μ，厚1.5～3.0mm，化纤丝编织网网孔是六角形、方形或圆形，孔径0.5～2.0mm，六角孔、方孔以过孔中心对角连线的长为孔径，化纤丝径0.1～0.2mm。
2.将上述基体在氩气保护下用真空离子溅射法镀镍、铜或铂，温度170±5℃，真空度1～9×10-8KPa，基体移动速度1.5～2.5米/分钟，离子溅射浓度2～2.5克/平方米。
此时材料导电性为R＝5～35KΩ。
3.然后采用现有塑料电镀技术和深孔镀的工艺在上述材料上连续镀镍、铜或铂。
此时材料的导电性为R＝0.1～8Ω。
4.将上述材料水洗、烘干或凉干，打卷。
本发明与已有技术相比，具有以下优良效果，1.由此得到的复合导电材料导电性好，泡沫镍所需的导电基体，还可用作屏蔽材料，应用于计算机、家电或军事电子产品领域。2.连续机械化生产使得人为因素减少，产品质量得以保证，人员减少而生产效率可提高。3.本发明方法可生产长片产品，将其卷成卷儿，便于存储、运输，便于裁剪。4.本发明的方法克服了现有技术中化学镀的污染问题，降低了生产成本。
(四)具体实施方案
下面结合实施例对本发明在进一步说明。
实施例1.镀镍导电材料的制备，步骤如下：
1.基体：聚胺脂高密度泡沫片。
2.离子镀镍：将基体在氩气保护下用真空离子溅射法镀镍，温度170℃，真空度8×10-8KPa，基体移动速度2米/分钟，离子溅射浓度2克/平方米。
3.然后采用现有塑料电镀技术在上述材料上连续镀镍。
4.将上述材料水洗、烘干，打卷。
实施例2.化纤编织布上镀铜，步骤如实施例1，所不同的是：
基体为涤纶化纤编织布，离子溅射浓度2.2克/平方米。
实施例3.化纤丝编织网上镀铂，步骤如实施例1，所不同的是：
基体为尼龙化纤丝编织网，离子溅射浓度1.8克/平方米。化纤丝编织网网孔是六角形，孔径1.0mm，以过孔中心对角连线的长为孔径，化纤丝径0.2mm。
实施例4.化纤毡上镀镍，步骤如实施例2，所不同的是：
基体是丙纶化纤毡，离子溅射浓度2.4克/平方米。
Claims (3)
1.一种复合导电材料的制备方法，包括步骤如下：
(1)基体：聚胺脂高密度泡沫片、化纤丝编织网、化纤编织布或化纤毡；
(2)将上述基体在氩气保护下用真空离子溅射法镀镍、铜或铂，温度170±5℃，真空度1～9×10-8KPa，基体移动速度1.5～2.5米/分钟，离子溅射浓度2～2.5克/平方米；
(3)然后采用现有塑料电镀技术和深孔镀的工艺在上述材料上连续镀镍、铜或铂；
(4)将上述材料水洗、烘干或凉干，打卷。
2.如权利要求1所述的复合导电材料的制备方法，其特征在于，所述化纤是涤纶、聚酯、丙纶或尼龙。
3.如权利要求1所述的复合导电材料的制备方法，其特征在于，所述聚胺脂泡沫孔径300～500μ，厚1.5～3.0mm，化纤丝编织网网孔是六角形、方形或圆形，孔径0.5～2.0mm，六角孔、方孔以过孔中心对角连线的长为孔径，化纤丝径0.1～0.2mm。
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB011352965A CN1148465C (zh) | 2001-12-24 | 2001-12-24 | 一种复合导电材料的制备方法 |
| AU2002357554A AU2002357554A1 (en) | 2001-12-24 | 2002-12-24 | A method of producing a composite electroconductive material |
| PCT/CN2002/000908 WO2003056058A1 (en) | 2001-12-24 | 2002-12-24 | A method of producing a composite electroconductive material |
| JP2002372627A JP2003286588A (ja) | 2001-12-24 | 2002-12-24 | 複合伝導性材料の調製方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB011352965A CN1148465C (zh) | 2001-12-24 | 2001-12-24 | 一种复合导电材料的制备方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1359110A true CN1359110A (zh) | 2002-07-17 |
| CN1148465C CN1148465C (zh) | 2004-05-05 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB011352965A Expired - Lifetime CN1148465C (zh) | 2001-12-24 | 2001-12-24 | 一种复合导电材料的制备方法 |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JP2003286588A (zh) |
| CN (1) | CN1148465C (zh) |
| AU (1) | AU2002357554A1 (zh) |
| WO (1) | WO2003056058A1 (zh) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101928920A (zh) * | 2010-08-25 | 2010-12-29 | 北京航空航天大学 | 一种多层复合丝旋转制备装置及制备方法 |
| CN103434210A (zh) * | 2013-08-05 | 2013-12-11 | 盐城工学院 | 一种导电稳定的高分子材料-金属薄膜复合材料制备方法 |
| CN105350045A (zh) * | 2015-10-30 | 2016-02-24 | 浙江理工大学 | 一种电镀铜导电纤维的制备方法 |
| WO2016074360A1 (zh) * | 2014-11-12 | 2016-05-19 | 惠州建邦精密塑胶有限公司 | 一种塑胶表面形成的金属层结构及其表面处理工艺 |
| CN108103506A (zh) * | 2017-12-18 | 2018-06-01 | 常德力元新材料有限责任公司 | 一种泡沫金属屏蔽材料的制备方法 |
| CN108707935A (zh) * | 2018-05-30 | 2018-10-26 | 信利光电股份有限公司 | 一种在绝缘材料上制备铜膜的方法 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03100197A (ja) * | 1989-09-12 | 1991-04-25 | Nippon G Ii Plast Kk | ポリマーブレンド成形品へのメッキ処理方法 |
| EP0423947B1 (en) * | 1989-09-22 | 1994-09-07 | Minnesota Mining And Manufacturing Company | Process for electroplating electroactive polymers and articles derived therefrom |
| JPH03274261A (ja) * | 1990-03-26 | 1991-12-05 | Hitachi Chem Co Ltd | 高分子フイルムに金属層を形成させる方法 |
| JPH05222578A (ja) * | 1992-02-14 | 1993-08-31 | Electroplating Eng Of Japan Co | 貴金属めっき製品の製造方法 |
| CN1040237C (zh) * | 1995-03-11 | 1998-10-14 | 吉林大学 | 一种海绵状泡沫镍的制备方法 |
-
2001
- 2001-12-24 CN CNB011352965A patent/CN1148465C/zh not_active Expired - Lifetime
-
2002
- 2002-12-24 AU AU2002357554A patent/AU2002357554A1/en not_active Abandoned
- 2002-12-24 WO PCT/CN2002/000908 patent/WO2003056058A1/zh not_active Application Discontinuation
- 2002-12-24 JP JP2002372627A patent/JP2003286588A/ja active Pending
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101928920A (zh) * | 2010-08-25 | 2010-12-29 | 北京航空航天大学 | 一种多层复合丝旋转制备装置及制备方法 |
| CN101928920B (zh) * | 2010-08-25 | 2012-01-11 | 北京航空航天大学 | 一种多层复合丝旋转制备装置及制备方法 |
| CN103434210A (zh) * | 2013-08-05 | 2013-12-11 | 盐城工学院 | 一种导电稳定的高分子材料-金属薄膜复合材料制备方法 |
| WO2016074360A1 (zh) * | 2014-11-12 | 2016-05-19 | 惠州建邦精密塑胶有限公司 | 一种塑胶表面形成的金属层结构及其表面处理工艺 |
| CN105350045A (zh) * | 2015-10-30 | 2016-02-24 | 浙江理工大学 | 一种电镀铜导电纤维的制备方法 |
| CN108103506A (zh) * | 2017-12-18 | 2018-06-01 | 常德力元新材料有限责任公司 | 一种泡沫金属屏蔽材料的制备方法 |
| CN108707935A (zh) * | 2018-05-30 | 2018-10-26 | 信利光电股份有限公司 | 一种在绝缘材料上制备铜膜的方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| AU2002357554A1 (en) | 2003-07-15 |
| CN1148465C (zh) | 2004-05-05 |
| WO2003056058A1 (en) | 2003-07-10 |
| JP2003286588A (ja) | 2003-10-10 |
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Effective date of registration: 20040514 Address after: High tech Zone Xinyu South Road Ji'nan city Shandong province 250101 first Qilu Software building room 212 Patentee after: Shandong Tiannuo Photovoltaic Material Co., Ltd. Address before: 274700 No. 407, Wang Xiang Road, Yucai Road, Yuncheng County, Shandong Province, Shahe Patentee before: Xia Dengfeng |
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| C57 | Notification of unclear or unknown address | ||
| DD01 | Delivery of document by public notice |
Addressee: Bao Guangming Document name: Notice of conformity |
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| DD01 | Delivery of document by public notice |
Addressee: Limited by Share Ltd responsible for collecting Tiannuo photoelectric material Document name: Notification that Application Deemed not to be Proposed |
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| C56 | Change in the name or address of the patentee | ||
| CP03 | Change of name, title or address |
Address after: Yuxing Road Flyover District of Ji'nan city in Shandong province 250119 New Material Industrial Park No. 517 Patentee after: Tiannuo Photoelectric Material Co., Ltd. Address before: High tech Zone Xinyu South Road Ji'nan city Shandong province 250101 first Qilu Software building room 212 Patentee before: Shandong Tiannuo Photovoltaic Material Co., Ltd. |
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| CX01 | Expiry of patent term | ||
| CX01 | Expiry of patent term |
Granted publication date: 20040505 |