CN1325537C - 乳液聚合硅橡胶－基冲击改性剂、制备方法及其共混物 - Google Patents

乳液聚合硅橡胶－基冲击改性剂、制备方法及其共混物 Download PDF

Info

Publication number
CN1325537C
CN1325537C CNB998141739A CN99814173A CN1325537C CN 1325537 C CN1325537 C CN 1325537C CN B998141739 A CNB998141739 A CN B998141739A CN 99814173 A CN99814173 A CN 99814173A CN 1325537 C CN1325537 C CN 1325537C
Authority
CN
China
Prior art keywords
silicone rubber
thermoplastic
weight
styrene
acrylonitrile
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CNB998141739A
Other languages
English (en)
Chinese (zh)
Other versions
CN1329630A (zh
Inventor
D·H·克雷格
R·胡
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SABIC Global Technologies BV
Original Assignee
General Electric Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by General Electric Co filed Critical General Electric Co
Publication of CN1329630A publication Critical patent/CN1329630A/zh
Application granted granted Critical
Publication of CN1325537C publication Critical patent/CN1325537C/zh
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02—Homopolymers or copolymers of hydrocarbons
    • C08L25/04—Homopolymers or copolymers of styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/12—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/06—Preparatory processes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/22—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
    • C08G77/28—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen sulfur-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/42—Block-or graft-polymers containing polysiloxane sequences
    • C08G77/442—Block-or graft-polymers containing polysiloxane sequences containing vinyl polymer sequences
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/08—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds
    • C08L51/085—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds on to polysiloxanes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Graft Or Block Polymers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Silicon Polymers (AREA)
CNB998141739A 1998-12-07 1999-10-04 乳液聚合硅橡胶－基冲击改性剂、制备方法及其共混物 Expired - Fee Related CN1325537C (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US20707398A 1998-12-07 1998-12-07
US09/207,073 1998-12-07
US09/207073 1998-12-07

Publications (2)

Publication Number Publication Date
CN1329630A CN1329630A (zh) 2002-01-02
CN1325537C true CN1325537C (zh) 2007-07-11

Family

ID=22769103

Family Applications (1)

Application Number Title Priority Date Filing Date
CNB998141739A Expired - Fee Related CN1325537C (zh) 1998-12-07 1999-10-04 乳液聚合硅橡胶－基冲击改性剂、制备方法及其共混物

Country Status (7)

Country Link
US (2) US6433077B1 (enExample)
EP (1) EP1141093B1 (enExample)
JP (1) JP2002531654A (enExample)
CN (1) CN1325537C (enExample)
DE (1) DE69938462T2 (enExample)
ES (1) ES2304067T3 (enExample)
WO (1) WO2000034359A1 (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108641042A (zh) * 2013-08-13 2018-10-12 三菱化学株式会社 含聚有机硅氧烷的接枝共聚物、树脂组合物、成形体、滑动性改良剂和滑动部件

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6465568B1 (en) * 2000-09-11 2002-10-15 Dow Corning Corporation Anionic and cationic silicone emulsions
JP2003096141A (ja) * 2001-09-21 2003-04-03 Nippon A & L Kk 耐衝撃性改質剤の製造方法及び耐衝撃性樹脂の製造方法
JP4980526B2 (ja) * 2001-09-21 2012-07-18 日本エイアンドエル株式会社 グラフト重合体の製造方法及び耐衝撃性樹脂の製造方法
EP1634923A1 (en) * 2003-06-12 2006-03-15 Kaneka Corporation Rubber-modified styrene resin composition
DE102004023911A1 (de) 2004-05-13 2005-12-01 Wacker-Chemie Gmbh Verfahren zur diskontinuierlichen Herstellung von Silicon-Emulsionen
CN100381484C (zh) * 2005-03-04 2008-04-16 华东理工大学 核壳型聚硅氧烷复合粒子的制备方法
WO2006102518A1 (en) * 2005-03-24 2006-09-28 Bridgestone Corporation Compounding silica-reinforced rubber with low volatile organic compound (voc) emission
EP2139946A1 (en) 2007-04-18 2010-01-06 Dow Global Technologies Inc. Improved monovinylidene aromatic polymers comprising sulfanylsilane functionalized elastomeric polymers
US7911513B2 (en) * 2007-04-20 2011-03-22 General Instrument Corporation Simulating short depth of field to maximize privacy in videotelephony
US7915368B2 (en) 2007-05-23 2011-03-29 Bridgestone Corporation Method for making alkoxy-modified silsesquioxanes
US8501895B2 (en) * 2007-05-23 2013-08-06 Bridgestone Corporation Method for making alkoxy-modified silsesquioxanes and amino alkoxy-modified silsesquioxanes
US8962746B2 (en) 2007-12-27 2015-02-24 Bridgestone Corporation Methods of making blocked-mercapto alkoxy-modified silsesquioxane compounds
US8513371B2 (en) * 2007-12-31 2013-08-20 Bridgestone Corporation Amino alkoxy-modified silsesquioxanes and method of preparation
US8794282B2 (en) * 2007-12-31 2014-08-05 Bridgestone Corporation Amino alkoxy-modified silsesquioxane adhesives for improved metal adhesion and metal adhesion retention to cured rubber
KR101612980B1 (ko) 2008-08-29 2016-04-15 미쯔비시 레이온 가부시끼가이샤 실리콘계 중합체 함유 비닐 중합체의 분체 및 그의 제조 방법, 수지 조성물 및 성형체
US8642691B2 (en) 2009-12-28 2014-02-04 Bridgestone Corporation Amino alkoxy-modified silsesquioxane adhesives for improved metal adhesion and metal adhesion retention to cured rubber
CN114016318A (zh) 2014-12-31 2022-02-08 株式会社普利司通 用于将钢合金粘附到橡胶的氨基烷氧基改性倍半硅氧烷粘合剂
US10633539B2 (en) 2016-03-10 2020-04-28 Momentive Performance Materials Inc. Composition comprising organosiloxane nano latex and preparation of organosiloxane nano latex

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4690986A (en) * 1984-05-30 1987-09-01 Mitsubishi Rayon Co., Ltd. Impact-resistant thermoplastic polyorganosiloxane-based graft copolymer and process for producing same
US5726270A (en) * 1996-12-26 1998-03-10 General Electric Company Process for the synthesis of mono-modal aqueous dispersions of polysiloxanes
EP0850978A2 (en) * 1996-12-30 1998-07-01 General Electric Company Process for the synthesis of multimodal aqueous dispersions of polysiloxanes

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH106968D (enExample) * 1965-01-21 1900-01-01
US3898300A (en) * 1974-01-31 1975-08-05 Dow Corning Emulsion polymerization method to produce a polymeric styrene-acrylonitrile-polyorganosiloxane composition and product
CA1328139C (en) * 1985-12-12 1994-03-29 Daniel Graiver Methods for making polydiorganosiloxane microemulsions
US4935464A (en) * 1987-04-30 1990-06-19 Toray Silicone Company Limited Organopolysiloxane microemulsion, process for its production and application thereof
DE3717073A1 (de) * 1987-05-21 1988-12-08 Wacker Chemie Gmbh Siliconharzpulver und verfahren zu deren herstellung
US5106908A (en) * 1988-11-14 1992-04-21 General Electric Company Polyorganosiloxane/polyvinyl-based graft (meth)acrylate polymers
DE3913114A1 (de) * 1989-04-21 1990-10-25 Bayer Ag Waermeformbestaendige polycarbonat-formmassen
US5543460A (en) * 1992-02-06 1996-08-06 Mitsubishi Rayon Co., Ltd. Graft copolymer particles their production and compositions comprising them
CA2089284A1 (en) * 1992-02-18 1993-08-19 Kenneth G. Himelrick Process for producing polydiorganosiloxane based graft copolymers
JPH07286129A (ja) * 1994-04-18 1995-10-31 Japan Synthetic Rubber Co Ltd コーティング用水系分散体
WO1997010283A1 (en) * 1995-09-12 1997-03-20 Kaneka Corporation Particulate silicone-modified acrylic rubber, particulate graft copolymer based on silicone-modified acrylic rubber, and thermoplastic resin composition
JPH0995534A (ja) * 1995-09-28 1997-04-08 Toshiba Silicone Co Ltd ポリオルガノシロキサン粒子の連続製造方法
JP3689984B2 (ja) * 1996-06-11 2005-08-31 Ｊｓｒ株式会社 熱可塑性樹脂組成物
JPH10176017A (ja) * 1996-12-17 1998-06-30 Techno Polymer Kk 塩化ビニル系樹脂用改質剤およびそれを用いた塩化ビニル系樹脂組成物
US5900460A (en) * 1997-01-03 1999-05-04 General Electric Company Process for the synthesis of structured aqueous dispersions of polysiloxanes
DE19739963A1 (de) * 1997-09-11 1999-03-18 Wacker Chemie Gmbh Fluoreszierende Gruppen aufweisende Organosiliciumverbindungen, deren Herstellung und Verwendung
US6169149B1 (en) * 1998-12-04 2001-01-02 General Electric Company Emulsion polymerized silicone-acrylate rubber impact modifiers thermoplastic blends, and methods for making
US6214927B1 (en) * 1999-11-02 2001-04-10 General Electric Company Method for making aqueous emulsions of functionalized organopolysiloxanes

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4690986A (en) * 1984-05-30 1987-09-01 Mitsubishi Rayon Co., Ltd. Impact-resistant thermoplastic polyorganosiloxane-based graft copolymer and process for producing same
US5726270A (en) * 1996-12-26 1998-03-10 General Electric Company Process for the synthesis of mono-modal aqueous dispersions of polysiloxanes
EP0850978A2 (en) * 1996-12-30 1998-07-01 General Electric Company Process for the synthesis of multimodal aqueous dispersions of polysiloxanes

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108641042A (zh) * 2013-08-13 2018-10-12 三菱化学株式会社 含聚有机硅氧烷的接枝共聚物、树脂组合物、成形体、滑动性改良剂和滑动部件
CN108641042B (zh) * 2013-08-13 2020-09-11 三菱化学株式会社 含聚有机硅氧烷的接枝共聚物、树脂组合物、成形体、滑动性改良剂和滑动部件

Also Published As

Publication number Publication date
DE69938462D1 (de) 2008-05-15
EP1141093B1 (en) 2008-04-02
US20020188063A1 (en) 2002-12-12
JP2002531654A (ja) 2002-09-24
WO2000034359A1 (en) 2000-06-15
US6433077B1 (en) 2002-08-13
DE69938462T2 (de) 2009-01-15
WO2000034359A9 (en) 2001-04-12
EP1141093A1 (en) 2001-10-10
ES2304067T3 (es) 2008-09-01
CN1329630A (zh) 2002-01-02

Similar Documents

Publication Publication Date Title
CN1325537C (zh) 乳液聚合硅橡胶－基冲击改性剂、制备方法及其共混物
RU2289595C2 (ru) Акрил-силиконовые гибридные модификаторы ударной вязкости, способ их получения и содержащие их композиции на основе винилхлоридной смолы
JP2614707B2 (ja) 中空構造を持つ乳化重合体の製造方法
EP0433727B1 (en) Silica-core silicone-shell particles, emulsion containing the same dispersed therein, and process for producing the emulsion
JP2693391B2 (ja) 架橋された、ラジカル生成基を有するオルガノポリシロキサン、その製法及びグラフトコポリマーの製法
JP4520641B2 (ja) 乳化重合シリコーン−アクリレートゴム耐衝撃性改良剤、熱可塑性ブレンド及び製造方法
JP2002138210A (ja) マルチプルポリマー添加剤系
CN114262485A (zh) 一种改性高分子材料及其制备方法和应用
US5543460A (en) Graft copolymer particles their production and compositions comprising them
US5804655A (en) Silicone-modified acrylic rubber particles, graft copolymer particles of silicone-modified acrylic rubber and thermoplastic resin composition
JP2002138211A (ja) ポリマー添加剤系
US4865917A (en) Thermoplastic silicone rubber graft polymers (I)
JPH0730140B2 (ja) ゲル化重合体微粒子の分散液の製造方法
JPH0791385B2 (ja) オルガノポリシロキサン／有機ポリマー組成物の製造方法
US20020147271A1 (en) Emulsion polymerized silicone rubber-based impact modifiers, method for making, and blends thereof
EP0584363B1 (en) Graft copolymer particle, production thereof, and composition thereof
JP3736711B2 (ja) ブロック共重合体及びその製造方法
JPH05262893A (ja) ポリフェニレンエーテルとシリコーン／有機重合体耐衝撃性向上剤との配合物から得られる成形品の鏡面光沢を調節する方法
US4985492A (en) Polyphenylene ether molding compositions
RU2278872C1 (ru) Способ получения катионного латекса с полыми полимерными частицами
WO2001060510A1 (en) Process for making cationic hollow particle latex and a composition obtainable therefrom useful for coating and/or impregnating
EP0534476A1 (en) Polyorganosiloxane compositions
CN120118447A (zh) 含硅丙烯酸酯-苯乙烯-丙烯腈核壳接枝共聚物、其胶乳及制备方法
JPH03231925A (ja) シリカコア‐シリコーンシェル体、これを分散含有するエマルジョンおよびエマルジョンの製造方法
JP2023143674A (ja) 樹脂組成物及び成形体

Legal Events

Date Code Title Description
C06 Publication
C10 Entry into substantive examination
PB01 Publication
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
ASS Succession or assignment of patent right

Owner name: SAUDI ARABIA BASE CREATION PLASTICS IP PRIVATE CO

Free format text: FORMER OWNER: GENERAL ELECTRIC CO.

Effective date: 20080822

C41 Transfer of patent application or patent right or utility model
TR01 Transfer of patent right

Effective date of registration: 20080822

Address after: Holland city Aupu zoom Bergen

Patentee after: SABIC INNOVATIVE PLASTICS IP B.V.

Address before: American New York

Patentee before: General Electric Co.

C17 Cessation of patent right
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20070711

Termination date: 20091104