CN1298616C - 一种碘酸钾的制造方法 - Google Patents
一种碘酸钾的制造方法 Download PDFInfo
- Publication number
- CN1298616C CN1298616C CNB2004100478895A CN200410047889A CN1298616C CN 1298616 C CN1298616 C CN 1298616C CN B2004100478895 A CNB2004100478895 A CN B2004100478895A CN 200410047889 A CN200410047889 A CN 200410047889A CN 1298616 C CN1298616 C CN 1298616C
- Authority
- CN
- China
- Prior art keywords
- potassium
- reaction system
- potassium hydroxide
- aqueous solution
- iodate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- JLKDVMWYMMLWTI-UHFFFAOYSA-M potassium iodate Chemical compound [K+].[O-]I(=O)=O JLKDVMWYMMLWTI-UHFFFAOYSA-M 0.000 title claims abstract description 22
- 239000001230 potassium iodate Substances 0.000 title claims abstract description 22
- 235000006666 potassium iodate Nutrition 0.000 title claims abstract description 22
- 229940093930 potassium iodate Drugs 0.000 title claims abstract description 22
- 238000002360 preparation method Methods 0.000 title abstract 2
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 claims abstract description 48
- 238000006243 chemical reaction Methods 0.000 claims abstract description 30
- 238000000034 method Methods 0.000 claims abstract description 18
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 12
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000001103 potassium chloride Substances 0.000 claims abstract description 6
- 235000011164 potassium chloride Nutrition 0.000 claims abstract description 6
- 239000007787 solid Substances 0.000 claims abstract description 5
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 73
- 239000007864 aqueous solution Substances 0.000 claims description 24
- 229910052740 iodine Inorganic materials 0.000 claims description 19
- 239000011630 iodine Substances 0.000 claims description 19
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 17
- 238000001914 filtration Methods 0.000 claims description 10
- ACAYDTMSDROWHW-UHFFFAOYSA-M potassium;iodic acid;iodate Chemical compound [K+].OI(=O)=O.[O-]I(=O)=O ACAYDTMSDROWHW-UHFFFAOYSA-M 0.000 claims description 9
- 230000007935 neutral effect Effects 0.000 claims description 8
- 238000001035 drying Methods 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 7
- 238000005406 washing Methods 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 5
- 239000000243 solution Substances 0.000 claims description 5
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 4
- 239000000460 chlorine Substances 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 4
- 238000007323 disproportionation reaction Methods 0.000 claims description 4
- 239000012452 mother liquor Substances 0.000 claims description 4
- 229910052801 chlorine Inorganic materials 0.000 claims description 3
- -1 iodine ions Chemical class 0.000 claims description 2
- 239000011259 mixed solution Substances 0.000 claims description 2
- LUMVCLJFHCTMCV-UHFFFAOYSA-M potassium;hydroxide;hydrate Chemical compound O.[OH-].[K+] LUMVCLJFHCTMCV-UHFFFAOYSA-M 0.000 claims description 2
- 239000000047 product Substances 0.000 abstract description 18
- 230000003647 oxidation Effects 0.000 abstract description 8
- 238000007254 oxidation reaction Methods 0.000 abstract description 8
- 238000004519 manufacturing process Methods 0.000 abstract description 6
- 230000008901 benefit Effects 0.000 abstract description 4
- 239000006227 byproduct Substances 0.000 abstract description 3
- 239000002699 waste material Substances 0.000 abstract description 3
- 230000001590 oxidative effect Effects 0.000 abstract description 2
- 239000007788 liquid Substances 0.000 abstract 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 8
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 6
- 239000012153 distilled water Substances 0.000 description 4
- 230000001105 regulatory effect Effects 0.000 description 3
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 239000005457 ice water Substances 0.000 description 2
- XMBWDFGMSWQBCA-UHFFFAOYSA-M iodide Chemical compound [I-] XMBWDFGMSWQBCA-UHFFFAOYSA-M 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229910017604 nitric acid Inorganic materials 0.000 description 2
- VKJKEPKFPUWCAS-UHFFFAOYSA-M potassium chlorate Chemical compound [K+].[O-]Cl(=O)=O VKJKEPKFPUWCAS-UHFFFAOYSA-M 0.000 description 2
- MLIWQXBKMZNZNF-KUHOPJCQSA-N (2e)-2,6-bis[(4-azidophenyl)methylidene]-4-methylcyclohexan-1-one Chemical compound O=C1\C(=C\C=2C=CC(=CC=2)N=[N+]=[N-])CC(C)CC1=CC1=CC=C(N=[N+]=[N-])C=C1 MLIWQXBKMZNZNF-KUHOPJCQSA-N 0.000 description 1
- MGWGWNFMUOTEHG-UHFFFAOYSA-N 4-(3,5-dimethylphenyl)-1,3-thiazol-2-amine Chemical compound CC1=CC(C)=CC(C=2N=C(N)SC=2)=C1 MGWGWNFMUOTEHG-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- OSVXSBDYLRYLIG-UHFFFAOYSA-N chlorine dioxide Inorganic materials O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- CMMUKUYEPRGBFB-UHFFFAOYSA-L dichromic acid Chemical compound O[Cr](=O)(=O)O[Cr](O)(=O)=O CMMUKUYEPRGBFB-UHFFFAOYSA-L 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 1
- FJWLWIRHZOHPIY-UHFFFAOYSA-N potassium;hydroiodide Chemical compound [K].I FJWLWIRHZOHPIY-UHFFFAOYSA-N 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Description
Claims (6)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB2004100478895A CN1298616C (zh) | 2004-06-21 | 2004-06-21 | 一种碘酸钾的制造方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB2004100478895A CN1298616C (zh) | 2004-06-21 | 2004-06-21 | 一种碘酸钾的制造方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1712347A CN1712347A (zh) | 2005-12-28 |
CN1298616C true CN1298616C (zh) | 2007-02-07 |
Family
ID=35718169
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB2004100478895A Expired - Lifetime CN1298616C (zh) | 2004-06-21 | 2004-06-21 | 一种碘酸钾的制造方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN1298616C (zh) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102583252B (zh) * | 2012-04-10 | 2013-06-26 | 自贡市金典化工有限公司 | 一种高碘酸钠的生产方法 |
CN108083232A (zh) * | 2016-11-21 | 2018-05-29 | 国药集团化学试剂有限公司 | 一种碘酸钾的制备方法 |
CN107934917A (zh) * | 2017-12-13 | 2018-04-20 | 西陇科学股份有限公司 | 一种高产率碘酸钾的生产方法 |
CN108593838A (zh) * | 2018-03-26 | 2018-09-28 | 河北省农林科学院农业资源环境研究所 | 一种能够滴定吸收在硼酸溶液中的铵盐的基准物质 |
CN108996475B (zh) * | 2018-09-07 | 2020-05-12 | 山东博苑医药化学有限公司 | 一种制备高纯碘酸钾的方法 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1117943A (zh) * | 1994-09-03 | 1996-03-06 | 连云港市化工研究所 | 一种制备纯碘酸溶液及其盐类的工业方法 |
-
2004
- 2004-06-21 CN CNB2004100478895A patent/CN1298616C/zh not_active Expired - Lifetime
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1117943A (zh) * | 1994-09-03 | 1996-03-06 | 连云港市化工研究所 | 一种制备纯碘酸溶液及其盐类的工业方法 |
Also Published As
Publication number | Publication date |
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CN1712347A (zh) | 2005-12-28 |
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SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
C56 | Change in the name or address of the patentee |
Owner name: GUANGDONG XILONG CHEMICAL CO., LTD. Free format text: FORMER NAME: SHANTOU XILONG CHEMICAL INDUSTRY CO., LTD. |
|
CP03 | Change of name, title or address |
Address after: Guangdong city of Shantou province Chaoshan Road West Long Street No. 1-3 zip code: 515064 Patentee after: Guangdong Xilong chemical Limited by Share Ltd. Address before: Guangdong city of Shantou province Chaoshan Road West Long Street 2 ZIP Code: 515064 Patentee before: Guangdong Xilong Chemical Co.,Ltd. Address after: Guangdong city of Shantou province Chaoshan Road West Long Street 2 ZIP Code: 515064 Patentee after: Guangdong Xilong Chemical Co.,Ltd. Address before: Guangdong city of Shantou province Chaoshan Road West Long Street 2 ZIP Code: 515064 Patentee before: XILONG CHEMICAL INDUSTRY Co.,Ltd. SHANTOU |
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C56 | Change in the name or address of the patentee | ||
CP01 | Change in the name or title of a patent holder |
Address after: 515064 Guangdong city of Shantou province Chaoshan Road West Long Street No. 1-3 Patentee after: XILONG SCIENTIFIC Co.,Ltd. Address before: 515064 Guangdong city of Shantou province Chaoshan Road West Long Street No. 1-3 Patentee before: XILONG CHEMICAL Co.,Ltd. |
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CX01 | Expiry of patent term | ||
CX01 | Expiry of patent term |
Granted publication date: 20070207 |