CN1297197C - N－（1－腈基－1，2－二甲基）－2－（2，4－二氯－3－甲基－苯氧基）丙酰胺杀菌、杀虫组合物1 - Google Patents
N－（1－腈基－1，2－二甲基）－2－（2，4－二氯－3－甲基－苯氧基）丙酰胺杀菌、杀虫组合物1 Download PDFInfo
- Publication number
- CN1297197C CN1297197C CNB2004100836452A CN200410083645A CN1297197C CN 1297197 C CN1297197 C CN 1297197C CN B2004100836452 A CNB2004100836452 A CN B2004100836452A CN 200410083645 A CN200410083645 A CN 200410083645A CN 1297197 C CN1297197 C CN 1297197C
- Authority
- CN
- China
- Prior art keywords
- methyl
- dimethyl
- rice
- propionamide
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- QLNJFJADRCOGBJ-UHFFFAOYSA-N propionamide Chemical compound CCC(N)=O QLNJFJADRCOGBJ-UHFFFAOYSA-N 0.000 title claims abstract description 28
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 11
- 239000003899 bactericide agent Substances 0.000 title claims abstract description 10
- 229940080818 propionamide Drugs 0.000 title claims description 27
- 239000000203 mixture Substances 0.000 title abstract description 42
- 230000002070 germicidal effect Effects 0.000 title 1
- 239000000575 pesticide Substances 0.000 title 1
- 239000002917 insecticide Substances 0.000 claims abstract description 24
- -1 chloro-3-methyl-phenoxy Chemical group 0.000 claims description 31
- 239000005660 Abamectin Substances 0.000 claims description 6
- RRZXIRBKKLTSOM-XPNPUAGNSA-N avermectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 RRZXIRBKKLTSOM-XPNPUAGNSA-N 0.000 claims description 4
- 241000209094 Oryza Species 0.000 description 30
- 235000007164 Oryza sativa Nutrition 0.000 description 30
- 235000009566 rice Nutrition 0.000 description 30
- 239000000375 suspending agent Substances 0.000 description 27
- 230000003449 preventive effect Effects 0.000 description 19
- 239000000843 powder Substances 0.000 description 17
- DSOOGBGKEWZRIH-UHFFFAOYSA-N nereistoxin Chemical compound CN(C)C1CSSC1 DSOOGBGKEWZRIH-UHFFFAOYSA-N 0.000 description 12
- 238000004659 sterilization and disinfection Methods 0.000 description 12
- 238000009736 wetting Methods 0.000 description 12
- 241000238631 Hexapoda Species 0.000 description 11
- 239000013543 active substance Substances 0.000 description 11
- 201000010099 disease Diseases 0.000 description 11
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 11
- 238000002360 preparation method Methods 0.000 description 11
- 230000001954 sterilising effect Effects 0.000 description 11
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 10
- 239000004202 carbamide Substances 0.000 description 10
- 239000003630 growth substance Substances 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- 239000002728 pyrethroid Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 241000426497 Chilo suppressalis Species 0.000 description 5
- 241001249129 Scirpophaga incertulas Species 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- 241001060517 Dicranolaius bellulus Species 0.000 description 4
- KYGZCKSPAKDVKC-UHFFFAOYSA-N Oxolinic acid Chemical compound C1=C2N(CC)C=C(C(O)=O)C(=O)C2=CC2=C1OCO2 KYGZCKSPAKDVKC-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 241000607479 Yersinia pestis Species 0.000 description 4
- 239000012752 auxiliary agent Substances 0.000 description 4
- 230000001580 bacterial effect Effects 0.000 description 4
- CWFOCCVIPCEQCK-UHFFFAOYSA-N chlorfenapyr Chemical compound BrC1=C(C(F)(F)F)N(COCC)C(C=2C=CC(Cl)=CC=2)=C1C#N CWFOCCVIPCEQCK-UHFFFAOYSA-N 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- 229940042795 hydrazides for tuberculosis treatment Drugs 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- XUNYDVLIZWUPAW-UHFFFAOYSA-N (4-chlorophenyl) n-(4-methylphenyl)sulfonylcarbamate Chemical compound C1=CC(C)=CC=C1S(=O)(=O)NC(=O)OC1=CC=C(Cl)C=C1 XUNYDVLIZWUPAW-UHFFFAOYSA-N 0.000 description 3
- 239000005995 Aluminium silicate Substances 0.000 description 3
- 241001530056 Athelia rolfsii Species 0.000 description 3
- 239000005893 Diflubenzuron Substances 0.000 description 3
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 3
- 239000005786 Flutolanil Substances 0.000 description 3
- 239000005906 Imidacloprid Substances 0.000 description 3
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 3
- 241001161749 Stenchaetothrips biformis Species 0.000 description 3
- 239000005938 Teflubenzuron Substances 0.000 description 3
- 235000012211 aluminium silicate Nutrition 0.000 description 3
- 229940019503 diflubenzuron Drugs 0.000 description 3
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 3
- 229910052731 fluorine Inorganic materials 0.000 description 3
- 239000011737 fluorine Substances 0.000 description 3
- 229940056881 imidacloprid Drugs 0.000 description 3
- YWTYJOPNNQFBPC-UHFFFAOYSA-N imidacloprid Chemical compound [O-][N+](=O)\N=C1/NCCN1CC1=CC=C(Cl)N=C1 YWTYJOPNNQFBPC-UHFFFAOYSA-N 0.000 description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 3
- 230000000361 pesticidal effect Effects 0.000 description 3
- 210000004894 snout Anatomy 0.000 description 3
- CJDWRQLODFKPEL-UHFFFAOYSA-N teflubenzuron Chemical compound FC1=CC=CC(F)=C1C(=O)NC(=O)NC1=CC(Cl)=C(F)C(Cl)=C1F CJDWRQLODFKPEL-UHFFFAOYSA-N 0.000 description 3
- PCKNFPQPGUWFHO-SXBRIOAWSA-N (Z)-flucycloxuron Chemical compound FC1=CC=CC(F)=C1C(=O)NC(=O)NC(C=C1)=CC=C1CO\N=C(C=1C=CC(Cl)=CC=1)\C1CC1 PCKNFPQPGUWFHO-SXBRIOAWSA-N 0.000 description 2
- YRIZYWQGELRKNT-UHFFFAOYSA-N 1,3,5-trichloro-1,3,5-triazinane-2,4,6-trione Chemical compound ClN1C(=O)N(Cl)C(=O)N(Cl)C1=O YRIZYWQGELRKNT-UHFFFAOYSA-N 0.000 description 2
- IBSREHMXUMOFBB-JFUDTMANSA-N 5u8924t11h Chemical compound O1[C@@H](C)[C@H](O)[C@@H](OC)C[C@@H]1O[C@@H]1[C@@H](OC)C[C@H](O[C@@H]2C(=C/C[C@@H]3C[C@@H](C[C@@]4(O3)C=C[C@H](C)[C@@H](C(C)C)O4)OC(=O)[C@@H]3C=C(C)[C@@H](O)[C@H]4OC\C([C@@]34O)=C/C=C/[C@@H]2C)/C)O[C@H]1C.C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 IBSREHMXUMOFBB-JFUDTMANSA-N 0.000 description 2
- 241000193388 Bacillus thuringiensis Species 0.000 description 2
- 241001414720 Cicadellidae Species 0.000 description 2
- 241001498622 Cixius wagneri Species 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- 239000005800 Kresoxim-methyl Substances 0.000 description 2
- 239000005917 Methoxyfenozide Substances 0.000 description 2
- 244000061176 Nicotiana tabacum Species 0.000 description 2
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 2
- 239000005814 Pencycuron Substances 0.000 description 2
- 239000005820 Prochloraz Substances 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- 241000194622 Tagosodes orizicolus Species 0.000 description 2
- 239000005937 Tebufenozide Substances 0.000 description 2
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 2
- 235000009754 Vitis X bourquina Nutrition 0.000 description 2
- 235000012333 Vitis X labruscana Nutrition 0.000 description 2
- 240000006365 Vitis vinifera Species 0.000 description 2
- 235000014787 Vitis vinifera Nutrition 0.000 description 2
- 229950008167 abamectin Drugs 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- 229940097012 bacillus thuringiensis Drugs 0.000 description 2
- 244000052616 bacterial pathogen Species 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Substances ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 238000012136 culture method Methods 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000004495 emulsifiable concentrate Substances 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- RYLHNOVXKPXDIP-UHFFFAOYSA-N flufenoxuron Chemical compound C=1C=C(NC(=O)NC(=O)C=2C(=CC=CC=2F)F)C(F)=CC=1OC1=CC=C(C(F)(F)F)C=C1Cl RYLHNOVXKPXDIP-UHFFFAOYSA-N 0.000 description 2
- 125000006332 fluoro benzoyl group Chemical group 0.000 description 2
- PTCGDEVVHUXTMP-UHFFFAOYSA-N flutolanil Chemical compound CC(C)OC1=CC=CC(NC(=O)C=2C(=CC=CC=2)C(F)(F)F)=C1 PTCGDEVVHUXTMP-UHFFFAOYSA-N 0.000 description 2
- 238000011081 inoculation Methods 0.000 description 2
- 238000011835 investigation Methods 0.000 description 2
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 2
- QCAWEPFNJXQPAN-UHFFFAOYSA-N methoxyfenozide Chemical compound COC1=CC=CC(C(=O)NN(C(=O)C=2C=C(C)C=C(C)C=2)C(C)(C)C)=C1C QCAWEPFNJXQPAN-UHFFFAOYSA-N 0.000 description 2
- 150000002825 nitriles Chemical class 0.000 description 2
- 239000003986 organophosphate insecticide Substances 0.000 description 2
- WBTYBAGIHOISOQ-UHFFFAOYSA-N pent-4-en-1-yl 2-[(2-furylmethyl)(imidazol-1-ylcarbonyl)amino]butanoate Chemical compound C1=CN=CN1C(=O)N(C(CC)C(=O)OCCCC=C)CC1=CC=CO1 WBTYBAGIHOISOQ-UHFFFAOYSA-N 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- TVLSRXXIMLFWEO-UHFFFAOYSA-N prochloraz Chemical compound C1=CN=CN1C(=O)N(CCC)CCOC1=C(Cl)C=C(Cl)C=C1Cl TVLSRXXIMLFWEO-UHFFFAOYSA-N 0.000 description 2
- 239000001294 propane Substances 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 229950009390 symclosene Drugs 0.000 description 2
- QYPNKSZPJQQLRK-UHFFFAOYSA-N tebufenozide Chemical compound C1=CC(CC)=CC=C1C(=O)NN(C(C)(C)C)C(=O)C1=CC(C)=CC(C)=C1 QYPNKSZPJQQLRK-UHFFFAOYSA-N 0.000 description 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- QSOHVSNIQHGFJU-UHFFFAOYSA-L thiosultap disodium Chemical compound [Na+].[Na+].[O-]S(=O)(=O)SCC(N(C)C)CSS([O-])(=O)=O QSOHVSNIQHGFJU-UHFFFAOYSA-L 0.000 description 2
- KAATUXNTWXVJKI-NSHGMRRFSA-N (1R)-cis-(alphaS)-cypermethrin Chemical compound CC1(C)[C@@H](C=C(Cl)Cl)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-NSHGMRRFSA-N 0.000 description 1
- ZXQYGBMAQZUVMI-RDDWSQKMSA-N (1S)-cis-(alphaR)-cyhalothrin Chemical compound CC1(C)[C@H](\C=C(/Cl)C(F)(F)F)[C@@H]1C(=O)O[C@@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 ZXQYGBMAQZUVMI-RDDWSQKMSA-N 0.000 description 1
- WCXDHFDTOYPNIE-RIYZIHGNSA-N (E)-acetamiprid Chemical compound N#C/N=C(\C)N(C)CC1=CC=C(Cl)N=C1 WCXDHFDTOYPNIE-RIYZIHGNSA-N 0.000 description 1
- YPSCQJTUAKNUNF-UHFFFAOYSA-N 2-chloro-n-[(4-chlorophenyl)carbamoyl]benzamide Chemical compound C1=CC(Cl)=CC=C1NC(=O)NC(=O)C1=CC=CC=C1Cl YPSCQJTUAKNUNF-UHFFFAOYSA-N 0.000 description 1
- BPEXTIMJLDWDTL-UHFFFAOYSA-N 2`-Methylacetanilide Chemical compound CC(=O)NC1=CC=CC=C1C BPEXTIMJLDWDTL-UHFFFAOYSA-N 0.000 description 1
- NNPRCLUGHFXSOU-UHFFFAOYSA-N 4-chloro-n-[cyano(ethoxy)methyl]benzamide Chemical compound CCOC(C#N)NC(=O)C1=CC=C(Cl)C=C1 NNPRCLUGHFXSOU-UHFFFAOYSA-N 0.000 description 1
- ZOCSXAVNDGMNBV-UHFFFAOYSA-N 5-amino-1-[2,6-dichloro-4-(trifluoromethyl)phenyl]-4-[(trifluoromethyl)sulfinyl]-1H-pyrazole-3-carbonitrile Chemical compound NC1=C(S(=O)C(F)(F)F)C(C#N)=NN1C1=C(Cl)C=C(C(F)(F)F)C=C1Cl ZOCSXAVNDGMNBV-UHFFFAOYSA-N 0.000 description 1
- 239000005875 Acetamiprid Substances 0.000 description 1
- 241001425390 Aphis fabae Species 0.000 description 1
- 241000243812 Arenicola marina Species 0.000 description 1
- 239000005887 Chromafenozide Substances 0.000 description 1
- 241001364569 Cofana spectra Species 0.000 description 1
- 241000012249 Dendrolimus spectabilis Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 239000005899 Fipronil Substances 0.000 description 1
- 239000005903 Gamma-cyhalothrin Substances 0.000 description 1
- 241000219146 Gossypium Species 0.000 description 1
- 241001441330 Grapholita molesta Species 0.000 description 1
- 241000255967 Helicoverpa zea Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 241001177117 Lasioderma serricorne Species 0.000 description 1
- 241000258916 Leptinotarsa decemlineata Species 0.000 description 1
- 241000409991 Mythimna separata Species 0.000 description 1
- DZZOJKGQQSORQI-UHFFFAOYSA-N N1C(=O)NC(=O)NC1=O.ClBr Chemical compound N1C(=O)NC(=O)NC1=O.ClBr DZZOJKGQQSORQI-UHFFFAOYSA-N 0.000 description 1
- 241000255969 Pieris brassicae Species 0.000 description 1
- 241000500437 Plutella xylostella Species 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- 241000256247 Spodoptera exigua Species 0.000 description 1
- 241000985245 Spodoptera litura Species 0.000 description 1
- 241001480238 Steinernema Species 0.000 description 1
- 241001454295 Tetranychidae Species 0.000 description 1
- 208000002474 Tinea Diseases 0.000 description 1
- 241000893966 Trichophyton verrucosum Species 0.000 description 1
- 241000255993 Trichoplusia ni Species 0.000 description 1
- 239000005942 Triflumuron Substances 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 244000098338 Triticum aestivum Species 0.000 description 1
- 240000006677 Vicia faba Species 0.000 description 1
- 241001272684 Xanthomonas campestris pv. oryzae Species 0.000 description 1
- ZXQYGBMAQZUVMI-UHFFFAOYSA-N [cyano-(3-phenoxyphenyl)methyl] 3-(2-chloro-3,3,3-trifluoroprop-1-enyl)-2,2-dimethylcyclopropane-1-carboxylate Chemical compound CC1(C)C(C=C(Cl)C(F)(F)F)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 ZXQYGBMAQZUVMI-UHFFFAOYSA-N 0.000 description 1
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- YLFIGGHWWPSIEG-UHFFFAOYSA-N aminoxyl Chemical compound [O]N YLFIGGHWWPSIEG-UHFFFAOYSA-N 0.000 description 1
- HIVLDXAAFGCOFU-UHFFFAOYSA-N ammonium hydrosulfide Chemical compound [NH4+].[SH-] HIVLDXAAFGCOFU-UHFFFAOYSA-N 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 229940073608 benzyl chloride Drugs 0.000 description 1
- 230000000035 biogenic effect Effects 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- MVPPADPHJFYWMZ-IDEBNGHGSA-N chlorobenzene Chemical group Cl[13C]1=[13CH][13CH]=[13CH][13CH]=[13CH]1 MVPPADPHJFYWMZ-IDEBNGHGSA-N 0.000 description 1
- HPNSNYBUADCFDR-UHFFFAOYSA-N chromafenozide Chemical compound CC1=CC(C)=CC(C(=O)N(NC(=O)C=2C(=C3CCCOC3=CC=2)C)C(C)(C)C)=C1 HPNSNYBUADCFDR-UHFFFAOYSA-N 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- YMGUBTXCNDTFJI-UHFFFAOYSA-N cyclopropanecarboxylic acid Chemical compound OC(=O)C1CC1 YMGUBTXCNDTFJI-UHFFFAOYSA-N 0.000 description 1
- QQODLKZGRKWIFG-QSFXBCCZSA-N cyfluthrin Chemical compound CC1(C)[C@@H](C=C(Cl)Cl)[C@H]1C(=O)O[C@@H](C#N)C1=CC=C(F)C(OC=2C=CC=CC=2)=C1 QQODLKZGRKWIFG-QSFXBCCZSA-N 0.000 description 1
- 229960001591 cyfluthrin Drugs 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- GCKZANITAMOIAR-XWVCPFKXSA-N dsstox_cid_14566 Chemical compound [O-]C(=O)C1=CC=CC=C1.C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H]([NH2+]C)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 GCKZANITAMOIAR-XWVCPFKXSA-N 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- GOWLARCWZRESHU-AQTBWJFISA-N ferimzone Chemical compound C=1C=CC=C(C)C=1C(/C)=N\NC1=NC(C)=CC(C)=N1 GOWLARCWZRESHU-AQTBWJFISA-N 0.000 description 1
- 229940013764 fipronil Drugs 0.000 description 1
- ZHNUHDYFZUAESO-UHFFFAOYSA-N formamide Substances NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 description 1
- ZXQYGBMAQZUVMI-GCMPRSNUSA-N gamma-cyhalothrin Chemical compound CC1(C)[C@@H](\C=C(/Cl)C(F)(F)F)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 ZXQYGBMAQZUVMI-GCMPRSNUSA-N 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 150000007857 hydrazones Chemical class 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- ZOTBXTZVPHCKPN-HTXNQAPBSA-N kresoxim-methyl Chemical compound CO\N=C(\C(=O)OC)C1=CC=CC=C1COC1=CC=CC=C1C ZOTBXTZVPHCKPN-HTXNQAPBSA-N 0.000 description 1
- 239000005910 lambda-Cyhalothrin Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000004530 micro-emulsion Substances 0.000 description 1
- 230000001069 nematicidal effect Effects 0.000 description 1
- 239000005645 nematicide Substances 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 229960000321 oxolinic acid Drugs 0.000 description 1
- OGYFATSSENRIKG-UHFFFAOYSA-N pencycuron Chemical compound C1=CC(Cl)=CC=C1CN(C(=O)NC=1C=CC=CC=1)C1CCCC1 OGYFATSSENRIKG-UHFFFAOYSA-N 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- ATROHALUCMTWTB-OWBHPGMISA-N phoxim Chemical compound CCOP(=S)(OCC)O\N=C(\C#N)C1=CC=CC=C1 ATROHALUCMTWTB-OWBHPGMISA-N 0.000 description 1
- 229950001664 phoxim Drugs 0.000 description 1
- 239000003223 protective agent Substances 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000003516 soil conditioner Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- DHCDFWKWKRSZHF-UHFFFAOYSA-N sulfurothioic S-acid Chemical compound OS(O)(=O)=S DHCDFWKWKRSZHF-UHFFFAOYSA-N 0.000 description 1
- 238000013268 sustained release Methods 0.000 description 1
- 239000012730 sustained-release form Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 229930192474 thiophene Natural products 0.000 description 1
- 239000003053 toxin Substances 0.000 description 1
- 231100000765 toxin Toxicity 0.000 description 1
- XAIPTRIXGHTTNT-UHFFFAOYSA-N triflumuron Chemical compound C1=CC(OC(F)(F)F)=CC=C1NC(=O)NC(=O)C1=CC=CC=C1Cl XAIPTRIXGHTTNT-UHFFFAOYSA-N 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 238000009333 weeding Methods 0.000 description 1
- 239000004563 wettable powder Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
一种杀菌剂、杀虫剂组合物，其含有至少一种杀菌剂和/或杀虫剂和如下I结构的N-(1-腈基-1，2-二甲基)-2-(2，4-二氯-3-甲基-苯氧基)丙酰胺。
Description
本发明涉及N-(1-腈基-1，2-二甲基)-2-(2，4-二氯-3-甲基-苯氧基)丙酰胺与杀菌剂、特异性昆虫生长调节剂、生物源杀虫剂、沙蚕毒素杀虫剂、有机磷杀虫剂、拟除虫菊酯杀虫剂和/或其他类杀虫剂组成的杀菌、杀虫组合物。
杀菌剂N-(1-腈基-1，2-二甲基)-2-(2，4-二氯-3-甲基-苯氧基)丙酰胺，具有良好的内吸和残留活性。日本专利公开(特开平5-9165)报道该化合物活性优于氰菌胺。本发明人通过研究，发现含N-(1-腈基-1，2-二甲基)-2-(2，4-二氯-3-甲基-苯氧基)丙酰胺的化合物与杀菌剂、特异性昆虫生长调节剂、生物源杀虫剂、沙蚕毒素杀虫剂、有机磷杀虫剂、拟除虫菊酯杀虫剂和/或其他类杀虫剂组成的杀菌、杀虫组合物，对水稻病虫害具有很好的活性。对稻田比较难治的虫害如螟虫(二化螟、三化螟)、飞虱、叶蝉、稻蓟马、稻甲虫等有很好的防效，同时可有效防治水稻病害如稻瘟病、稻曲病、纹枯病、恶苗病、白叶枯病、细菌性条斑病。
将N-(1-腈基-1，2-二甲基)-2-(2，4-二氯-3-甲基-苯氧基)丙酰胺与杀菌剂、特异性昆虫生长调节剂、生物源杀虫剂、沙蚕毒素杀虫剂、拟除虫菊酯杀虫剂和/或其他类杀虫剂混在一起同时防治水稻稻瘟病、纹枯病等或水稻稻瘟病、纹枯病，水稻螟虫、飞虱、叶蝉、稻蓟马、稻甲虫等未见报道。
适用于本发明组合物的杀菌剂实例如下：
环丙酰胺(carpropamid)-2，2-二氯-N-[1-(4-氯苯基)乙基]-1-乙基-3-甲基环丙羧酰胺、井岗霉素-N-[(1S)-(1，4，6/5)-3-羰甲基-4，5，6-三羰基-2-环己烯基][O-β-D-吡喃葡萄糖基-(1-3)]-1S-(1，2，4/3，5)-2，3，4-三羰基-5-羰甲基环己基胺、噻枯唑-N，N-甲撑-双(2-氨基-5-巯基-1，3，4-噻二唑、异氰尿酸(三氯异氰尿酸、二氯异氰尿酸、氯溴异氰尿酸及其盐)、喹菌酮(oxolinic acid)、苯氧菌酯(kresoxim-methyl)-(E)-2-甲氧亚氨基-[2-(邻甲基苯氧基甲基)苯基]乙酸甲酯、戊菌隆(pencycuron)-1-(4-氯苄基)-1-环五烷基-3-苯基脲、氟酰胺(flutOlanil)--3′-异丙氧基-2-(三氟甲基)苯甲酰苯胺、噻氟酰胺(trifluzamide)-2’，6’-二溴-2-甲基-4’-三氟甲氧基-4-三氟甲基-1，3-噻二唑-5-羧酰苯胺、咪鲜胺(prochloraz)-N-丙基-N-[2-(2，4，6-三氯苯氧基)乙基]咪唑-1-甲酰胺、稻瘟酯(pefurazoate)-戊4-烯基-N-糠基-N-咪唑-1-基羰基-DL-高丙氨酸酯、嘧菌腙(ferimzone)-(Z)2’-甲基乙酰苯4，6-二甲基嘧啶-2-基腙。
适用于本发明的组合物的特异性昆虫生长调节剂、生物源、沙蚕毒素、拟除虫菊酯和/或其他类杀虫剂实例如下：
(A)特异性昆虫生长调节剂杀虫剂
1、灭幼脲(Chlorbenzuron)
2、杀虫隆(triflumuron)
3、伏虫隆(teflubenzuron)
4、氟铃脲(hexatlumuron)
5、除虫脲(diflubenzuron)
6、氟螨脲(flucycloxuron)
7、环虫酰肼(chromafenozide)
8、氟虫脲(flufenoxurom)
9、甲氧虫酰肼(methoxyfenozide)
10、虫酰肼(tebufenozide)
(B)生物源杀虫剂
1、苏云金杆菌(Bacullus thuringiensis)
2、阿维菌素(abamectin)
3、甲胺基阿维菌素苯甲酸盐(emamectin benzoate)
(C)沙蚕毒素杀虫剂
1、杀虫单
2、杀虫双(dimthypo)
(D)拟除虫菊酯杀虫剂
1、氟氯氰菊酯(cyfluthrin)
2、高效氯氟氰菊酯(lambdacyhalothrin)
3、高效氯氰菊酯
(E)其他类杀虫剂
1、溴虫腈(chlorfenapyr)
2、吡虫啉(imidacloprid)
3、氟虫腈(fipronil)
4、啶虫咪(acetamiprid)
在上面A、B、C、D、E和F组中给出的普通名称表示具有以下IUPAC名称的化合物：
(A)特异性昆虫生长调节剂
(1)1-邻氯苯甲酰基-3-(4-氯苯基)脲；
(2)1-2(2-氯苯甲酰基)-3-(4-三氟甲氧基苯基)脲；
(3)N-(3，5-二氯-2，4-二氟苯基)-N’-(2，6-二氟苯甲酰)脲；
(4)1-[3，5-二氯-4-(1，1，2，2-四氟乙氧基)苯基]-3-(2，6-二氟苯甲酰基)脲；
(5)1-(4-氯苯基)-3-(2，6-二氟苯甲酰基)脲；
(6)1-[α-(4-氯-α-环丙基亚苄基氨基一氧)对-甲苯基]-3-(2，6-二氟苯甲酰基)脲；
(7)2’-叔丁基-5-甲基-2’-(3，5-二甲基苯甲酰基)色满-6-甲酰肼；
(8)1-[4-(2-氯-α，α，α-三氟-对甲苯氧基)-2氟苯基]-3-(2，6-二氟苯甲酰)脲；
(9)N-叔丁基-N’-(3-甲基-2-甲苯甲酰基)-3，5-二甲基苯甲酰肼；
(10)1-(1，1-二甲基乙基)-1-(4-乙基苯甲酰基)-3，5，-二甲基苯甲酰肼。
(B)生物源杀虫剂
(1)苏云金杆菌；
(2)阿维菌素；
(3)4″-甲基氨基-4″-去氧阿维菌素B1苯甲酸盐。
(C)沙蚕毒素类杀虫剂
(1)2-N，N-二甲胺基-1-硫代硫酸钠基-3-硫代硫酸基丙烷；
(2)2-N，N-二甲胺基-1、3-双(硫代磺酸钠基)丙烷。
(D)拟除虫菊酯类杀虫剂
(1)α-氰基-3-苯氧基-4-氟苄基(IR，3R)-3-(2，2-二氯乙烯基)-2，2-二甲基环丙烷羧酸酯；
(2)3-(2-氯-3，3，3-三氟丙烯基)-2，2-二甲基环丙烷羧酸-α-氰基-3-苯氧苄基酯；
(3)2，2-二甲基-3-(2，2-二氯乙烯基)环丙烷羧酸-α-氰基-(3-苯氧基)-苄酯；
(E)其他类杀虫剂
(1)4-溴-2-(4-氯苯基)-1-乙氧基甲基-5-三氟甲基吡咯-3-腈；
(2)1-(6-氯-3-吡啶基甲基)-N-硝基亚咪唑烷-2-基胺；
(3)(±)-5-氨基-1-(2，6-二氯-α，α，α-三氟-对-甲苯基)-4-三氟甲基亚磺酰基吡唑-3-腈；
(4)(E)-N1-[(6-氯-3-吡啶)甲基]-N2-氰基-N1-甲基乙咪；
对于本发明的组合物来说，上文所列的特异性昆虫生长调节剂中较佳的为灭幼脲、伏虫隆、除虫脲、氟虫脲、虫酰肼。
本发明的组合物可以是二组合，也可以是三种以上前述化合物形成的组合物。
本发明的组合物可以用于多种作物防治多种病害、虫害，对水稻、小麦、烟草、果树、葡萄、蔬菜、棉花及林业上的病害、虫害有特效。如水稻稻瘟病、水稻纹枯病、稻曲病、恶苗病、白叶枯病、细菌性条斑病、水稻螟虫、水稻飞虱、水稻叶蝉、水稻二化螟、水稻三化螟、稻蓟马、稻甲虫、粘虫、烟草青虫、烟草夜蛾、粉纹夜蛾、马铃薯甲虫、棉叶螨、甜菜蚜、梨小食心虫、葡萄小卷蛾、甜菜夜蛾、小菜蛾、斜纹夜蛾、菜青虫、松毛虫、棉铃虫等。
本发明组合物中N-(1-腈基-1，2-二甲基)-2-(2，4-二氯-3-甲基-苯氧基)丙酰胺与杀菌剂、特异性昆虫生长调节剂、生物源杀虫剂、沙蚕毒素杀虫剂、拟除虫菊酯杀虫剂和/或其他类杀虫剂的比例基于活性组份的重量份数为1∶160～80∶1，最佳为1∶40～40∶1。
本发明的组合物还可以包含乳化剂、溶剂、助剂或填料，其所占组合物的重量份数为0.5％～95％。
本发明的组合物可以配成溶液、乳液、粒剂、可湿性粉剂、水剂、悬浮剂、粉剂、粉尘剂、糊剂、可溶性粉剂、可溶性粒剂、微乳剂、乳油、气雾剂、烟剂和缓释剂。
本发明的组合物还要加入乳化剂、分散剂、润湿剂等表面活性物质，以增加组合物的稳定性、润湿性、渗透性。
本发明描述的产物可以呈成品制剂形式，即产物中物质已经混合。然而组合物的成份也可以单独以制剂提供，在使用前在罐内直接混合。
本发明的组合物也可以含有其它活性组份，例如其它具有除草、杀虫或杀菌性能的化合物，也可以与杀线虫剂、防护剂、生长调节剂、植物营养素或土壤调节剂混合。
本发明的组合物可以按普通的方法使用，如浇注、喷射、喷雾、喷粉或放烟。
本发明组合物可以用以下实施例说明：
实施例1 50％可湿性粉剂配制
N-(1-腈基-1，2-二甲基)-2-(2，4-二氯-3-甲基-苯氧基)丙酰胺 10％(重量)
三氯异氰尿酸 40％(重量)
十二烷基硫酸钠 2％(重量)
木质素磺酸钠 12％(重量)
高岭土 36％(重量)
将各种物料依次加入混合釜中，在搅拌条件下，使其充分混合，粉碎到粒径小于44μm。
实施例2 60％可湿性粉剂配制
N-(1-腈基-1，2-二甲基)-2-(2，4-二氯-3-甲基-苯氧基)丙酰胺 10％(重量)
喹菌酮 50％(重量)
十二烷基硫酸钠 2％(重量)
硅藻土 18％(重量)
木质素磺酸钠 4％(重量)
高岭土 16％(重量)
将各种物料依次加入混合釜中，在搅拌条件下，使其充分混合，粉碎到粒径小于44μm。
实施例3 50％可湿性粉剂配制
N-(1-腈基-1，2-二甲基)-2-(2，4-二氯-3-甲基-苯氧基)丙酰胺 20％(重量)
井岗霉素 30％(重量)
十二烷基硫酸钠 2％(重量)
硅藻土 20％(重量)
木质素磺酸钠 4％(重量)
高岭土 24％(重量)
将各种物料依次加入混合釜中，在搅拌条件下，使其充分混合，粉碎到粒径小于44μm。
实施例4 30％悬浮剂配制
N-(1-腈基-1，2-二甲基)-2-(2，4-二氯-3-甲基-苯氧基)丙酰胺 15％(重量)
虫酰肼 15％(重量)
助剂 12％(重量)
填料 26％(重量)
水 32％(重量)
将各种组份混合在一起，在砂磨机中研磨至有效成分粒径小于5μm。
实施例5 50％可溶性粉剂配制
N-(1-腈基-1，2-二甲基)-2-(2，4-二氯-3-甲基-苯氧基)丙酰胺 10％(重量)
杀虫单 40％(重量)
助剂 5％(重量)
填料 45％(重量)
将各种物料依次加入混合釜中，在搅拌条件下，使其充分混合，经调制、喷雾而成。
实施例6 10.5％粒剂配制
N-(1-腈基-1，2-二甲基)-2-(2，4-二氯-3-甲基-苯氧基)丙酰胺 10％(重量)
甲胺基阿维菌素苯甲酸盐 0.5％(重量)
膨润土 30％(重量)
滑石 57.5％(重量)
硫铵 2％(重量)
将各种物料依次加入混合釜中，在搅拌条件下，使其充分混合，经捏合、溶解、干燥、碎解、造粒成功。
实施例7 18％悬浮剂配制
N-(1-腈基-1，2-二甲基)-2-(2，4-二氯-3-甲基-苯氧基)丙酰胺 12％(重量)
溴虫腈 6％(重量)
助剂 12％(重量)
填料 26％(重量)
水 44％(重量)
将各种组份混合在一起，在砂磨机中研磨至有效成分粒径小于5μm。
实例8 50％可湿性粉剂试验
在温室中用实例3的制剂进行水稻稻瘟病防效试验。
试材：四叶期盆栽水稻苗 感染：水稻稻瘟病
试验方法：试验采用盆栽法，当水稻长至4叶期时，叶面喷雾处理，处理后24小时接种病菌。接种后10天进行结果调查。
| 活性物质 | 200ppm | 100ppm | 50ppm |
| N-(1-腈基-1，2-二甲基)-2-(2，4-二氯-3-甲基-苯氧基)丙酰胺 | 100.0％ | 93.7％ | 68.2％ |
| 井岗霉素 | 11.2％ | 0％ | 0％ |
| 50％混剂可湿性粉剂 | 97.3％ | 83.4％ | 57.3％ |
实例9 60％可湿性粉剂试验
在温室中用实例2的制剂进行水稻纹枯病防效试验。
试材：盆栽蚕豆叶 感染：水稻纹枯病
试验方法：试验采用盆栽法，叶面喷雾处理，处理后24小时接种病菌。接种后2天调查结果。
| 活性物质 | 200ppm | 100ppm | 50ppm |
| N-(1-腈基-1，2-二甲基)-2-(2，4-二氯-3-甲基-苯氧基)丙酰胺 | 99.0％ | 90.8％ | 67.5％ |
| 喹菌酮 | 75.0％ | 62.4％ | 30.6％ |
| 60％混剂可湿性粉剂 | 98.4％ | 90.0％ | 68.3％ |
实施例10 50％混剂可溶性粉剂
防治对象：水稻稻瘟病、水稻二化螟、三化螟 地点：滨州
| 活性物质 | 剂量 | 杀虫防效％ | 杀菌防效％ |
| 50％混剂可溶性粉剂 | 1000倍 | 96％ | 87％ |
| 80％杀虫单可溶性粉剂 | 1500倍 | 91％ | —— |
| 20％N-(1-腈基-1，2-二甲基)-2-(2，4-二氯-3-甲基-苯氧基)丙酰胺悬浮剂 | 1000倍 | —— | 85％ |
实施例11 16％混剂悬浮剂
防治对象：水稻纹枯病、水稻飞虱 地点：滨州
| 活性物质 | 剂量 | 杀虫防效％ | 杀菌防效％ |
| 16％混剂悬浮剂 | 800倍 | 90％ | 81％ |
| 18％杀虫双水剂 | 500倍 | 91％ | —— |
| 20％N-(1-腈基-1，2-二甲基)-2-(2，4-二氯-3-甲基-苯氧基)丙酰胺悬浮剂 | 1000倍 | —— | 83％ |
实施例12 12.5％混剂悬浮剂
防治对象：水稻稻曲病、稻甲虫 地点：滨州
| 活性物质 | 剂量 | 杀虫防效％ | 杀菌防效％ |
| 12.5％混剂悬浮剂 | 1000倍 | 92％ | 83％ |
| 5％氟虫腈悬浮剂 | 2000倍 | 91％ | —— |
| 20％N-(1-腈基-1，2-二甲基)-2-(2，4-二氯-3-甲基-苯氧基)丙酰胺悬浮剂 | 1000倍 | —— | 81％ |
实施例13 18％混剂悬浮剂
防治对象：水稻白叶枯病、稻叶蝉 地点：滨州
| 活性物质 | 剂量 | 杀虫防效％ | 杀菌防效％ |
| 18％混剂悬浮剂 | 800倍 | 93％ | 87％ |
| 10％溴虫腈悬浮剂 | 2000倍 | 96％ | —— |
| 20％N-(1-腈基-1，2-二甲基)-2-(2，4-二氯-3-甲基-苯氧基)丙酰胺悬浮剂 | 1000倍 | —— | 88％ |
实施例14 30％混剂悬浮剂
防治对象：水稻稻曲病、水稻二化螟、三化螟 地点：滨州
| 活性物质 | 剂量 | 杀虫防效％ | 杀菌防效％ |
| 30％混剂悬浮剂 | 1000倍 | 98％ | 93％ |
| 20％虫酰肼悬浮剂 | 1000倍 | 99％ | —— |
| 20％N-(1-腈基-1，2-二甲基)-2-(2，4-二氯-3-甲基-苯氧基)丙酰胺悬浮剂 | 1000倍 | —— | 90％ |
实施例15 10.5％混剂可湿性粉剂
防治对象：水稻纹枯病、水稻二化螟、三化螟 地点：滨州
| 活性物质 | 剂量 | 杀虫防效％ | 杀菌防效％ |
| 10.5％混剂可湿性粉剂 | 1000倍 | 97％ | 88％ |
| 0.5％阿维菌素乳油 | 2000倍 | 98％ | —— |
| 20％N-(1-腈基-1，2-二甲基)-2-(2，4-二氯-3-甲基-苯氧基)丙酰胺悬浮剂 | 1000倍 | —— | 87％ |
实施例16 16％混剂可湿性粉剂
防治对象：水稻稻瘟病、水稻飞虱 地点：滨州
| 活性物质 | 剂量 | 杀虫防效％ | 杀菌防效％ |
| 16％混剂可湿性粉剂 | 800倍 | 92％ | 90％ |
| 10％吡虫啉可湿性粉剂 | 1500倍 | 93％ | —— |
| 20％N-(1-腈基-1，2-二甲基)-2-(2，4-二氯-3-甲基-苯氧基)丙酰胺悬浮剂 | 1000倍 | —— | 88％ |
实施例17 20％混剂悬浮剂
防治对象：水稻稻瘟病、水稻飞虱 地点：滨州
| 活性物质 | 剂量 | 杀虫防效％ | 杀菌防效％ |
| 20％混剂悬浮剂 | 1000倍 | 92％ | 89％ |
| 5％高效氯氰菊酯乳油 | 1500倍 | 90％ | —— |
| 20％N-(1-腈基-1，2-二甲基)-2-(2，4-二氯-3-甲基-苯氧基)丙酰胺悬浮剂 | 1000倍 | —— | 88％ |
实施例18 30％混剂悬浮剂
防治对象：水稻恶苗病、水稻叶蝉 地点：滨州
| 活性物质 | 剂量 | 杀虫防效％ | 杀菌防效％ |
| 30％混剂悬浮剂 | 1000倍 | 93％ | 84％ |
| 20％辛硫磷乳油 | 1000倍 | 92％ | —— |
| 20％N-(1-腈基-1，2-二甲基)-2-(2，4-二氯-3-甲基-苯氧基)丙酰胺悬浮剂 | 1000倍 | —— | 86％ |
Claims (1)
1.一种杀菌剂、杀虫剂组合物，其含有阿维菌素和如下I结构的N-(1-腈基-1，2-二甲基)-2-(2，4-二氯-3-甲基-苯氧基)丙酰胺，其中结构式I与阿维菌素的比例基于活性组分的重量份数为1∶160至80∶1。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2004100836452A CN1297197C (zh) | 2001-07-31 | 2001-07-31 | N－（1－腈基－1，2－二甲基）－2－（2，4－二氯－3－甲基－苯氧基）丙酰胺杀菌、杀虫组合物1 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2004100836452A CN1297197C (zh) | 2001-07-31 | 2001-07-31 | N－（1－腈基－1，2－二甲基）－2－（2，4－二氯－3－甲基－苯氧基）丙酰胺杀菌、杀虫组合物1 |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 01123752 Division CN1399885A (zh) | 2001-07-31 | 2001-07-31 | N－(1－腈基－1,2－二甲基)－2－(2,4－二氯－3－甲基－苯氧基)丙酰胺杀菌、杀虫组合物 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1618287A CN1618287A (zh) | 2005-05-25 |
| CN1297197C true CN1297197C (zh) | 2007-01-31 |
Family
ID=34765806
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2004100836452A Expired - Fee Related CN1297197C (zh) | 2001-07-31 | 2001-07-31 | N－（1－腈基－1，2－二甲基）－2－（2，4－二氯－3－甲基－苯氧基）丙酰胺杀菌、杀虫组合物1 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1297197C (zh) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH059165A (ja) * | 1991-02-18 | 1993-01-19 | Mitsubishi Petrochem Co Ltd | 置換フエノキシカルボン酸アミド誘導体 |
-
2001
- 2001-07-31 CN CNB2004100836452A patent/CN1297197C/zh not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH059165A (ja) * | 1991-02-18 | 1993-01-19 | Mitsubishi Petrochem Co Ltd | 置換フエノキシカルボン酸アミド誘導体 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1618287A (zh) | 2005-05-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1130122C (zh) | 除草混合物 | |
| CN1111477A (zh) | 铵盐增效组合物 | |
| CN101080172A (zh) | 除草组合物 | |
| CN1242674C (zh) | 虫酰肼杀虫组合物 | |
| CN1364413A (zh) | 具有杀虫杀螨活性的组合物 | |
| CN1471822A (zh) | 具有杀虫活性的组合物 | |
| CN1436044A (zh) | 杀菌剂活性化合物组合物 | |
| CN1663373A (zh) | 昆虫生长调节组合物 | |
| CN1048851C (zh) | 杀虫和杀螨组合物 | |
| CN1252692A (zh) | 杀菌活性化合物的组合物 | |
| CN86102102A (zh) | 新型苯甲酰胺的制备工艺及其用途 | |
| CN1274219C (zh) | 甲胺基阿维菌素苯甲酸盐杀虫、杀螨组合物 | |
| CN1293806C (zh) | 杀虫·杀螨剂组合物 | |
| CN1107290A (zh) | 草坪杀虫剂 | |
| CN1297197C (zh) | N－（1－腈基－1，2－二甲基）－2－（2，4－二氯－3－甲基－苯氧基）丙酰胺杀菌、杀虫组合物1 | |
| CN1146320C (zh) | 用取代的苯甲酰脲增加大豆类种子产量的方法 | |
| CN1373636A (zh) | 防治稻类及其他农作物虫害的组合物和方法 | |
| CN1225168C (zh) | 用于对动物生活环境进行抗寄生虫处理的方法 | |
| CN1236678C (zh) | 氰菌胺杀菌、杀虫组合物 | |
| CN1399885A (zh) | N－(1－腈基－1,2－二甲基)－2－(2,4－二氯－3－甲基－苯氧基)丙酰胺杀菌、杀虫组合物 | |
| CN1163143C (zh) | 杀真菌混合物 | |
| CN1268207C (zh) | 甲胺基阿维菌素苯甲酸盐杀虫、杀螨组合物 | |
| CN1593143A (zh) | 含氰菌胺杀菌剂、杀虫剂组合物 | |
| CN87103191A (zh) | 杀真菌的吡啶基环丙烷甲酰胺类化合物 | |
| CN1659964A (zh) | 甲胺基阿维菌素苯甲酸盐杀虫、杀螨组合物1 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Free format text: FORMER OWNER: HU NAIDONG SHI QINGLING XU BOYONG MEN ZHEN Owner name: SHANDONG JINGBO AGROCHEMICALS LTD. Free format text: FORMER OWNER: MA YUNSHENG Effective date: 20110622 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: 256505 CHAMBROAD GROUP, BOXING COUNTY, SHANDONG PROVINCE TO: 256500 CHAMBROAD INDUSTRIAL PARK, CHENHU TOWN, BOXING COUNTY, BINZHOU CITY, SHANDONG PROVINCE |
|
| TR01 | Transfer of patent right |
Effective date of registration: 20110622 Address after: 256500 Shandong city of Binzhou province Hu Zhen Boxing County Chen Jingbo Industrial Park Patentee after: Shandong Jingbo Agrochemicals Ltd. Address before: 256505 Boxing County, Shandong province Beijing Bo group Co-patentee before: Hu Naidong Patentee before: Ma Yunsheng Co-patentee before: Shi Qingling Co-patentee before: Xu Boyong Co-patentee before: Men Zhen |
|
| ASS | Succession or assignment of patent right |
Owner name: JINGBO AGROCHEMICALS TECHNOLOGY CO., LTD. Free format text: FORMER OWNER: SHANDONG JINGBO AGROCHEMICALS, LTD. Effective date: 20111125 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20111125 Address after: 256500 Shandong city of Binzhou province Hu Zhen Boxing County Chen Jingbo Industrial Park Patentee after: Jingbo Agrochemicals Technology Co., Ltd. Address before: 256500 Shandong city of Binzhou province Hu Zhen Boxing County Chen Jingbo Industrial Park Patentee before: Shandong Jingbo Agrochemicals Ltd. |
|
| CP03 | Change of name, title or address |
Address after: 256500 Boxing County Economic Development Zone, Binzhou, Shandong Patentee after: Beijing Agricultural Chemical Technology Co., Ltd. Address before: 256500 Jingbo Industrial Park, Chenhu Town, Boxing County, Binzhou City, Shandong Province Patentee before: Jingbo Agrochemicals Technology Co., Ltd. |
|
| CP03 | Change of name, title or address | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20070131 Termination date: 20200731 |