CN1268207C - 甲胺基阿维菌素苯甲酸盐杀虫、杀螨组合物 - Google Patents
甲胺基阿维菌素苯甲酸盐杀虫、杀螨组合物 Download PDFInfo
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- CN1268207C CN1268207C CNB2004100568425A CN200410056842A CN1268207C CN 1268207 C CN1268207 C CN 1268207C CN B2004100568425 A CNB2004100568425 A CN B2004100568425A CN 200410056842 A CN200410056842 A CN 200410056842A CN 1268207 C CN1268207 C CN 1268207C
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Classifications
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
一种杀虫组合物，其含有至少一种特异性昆虫生长调节剂、生物源、沙蚕毒素、有机磷、拟除虫菊酯和/或其他类杀虫剂和如下I结构的4″-甲基氨基-4″-去氧阿维菌素B1苯甲酸盐——甲胺基阿维菌素苯甲酸盐。
Description
本发明涉及甲胺基阿维菌素苯甲酸盐与特异性昆虫生长调节剂、生物源、沙蚕毒素、有机磷、拟除虫菊酯和/或其他类杀虫剂组成的杀虫、杀螨组合物。
甲胺基阿维菌素苯甲酸盐是从发酵产品阿维菌素B1开始的一种新型的半合成杀虫剂，它对鳞翅目昆虫的幼虫活性极高，主要是胃毒作用，兼有触杀作用。甲胺基阿维菌素苯甲酸盐可以渗透到目标作物的表皮，形成一个有效成分的储存层，因而可以有长期的残效。如果与特异性昆虫生长调节剂、生物源、沙蚕毒素、有机磷、拟除虫菊酯和/或其他类杀虫剂制成组合物，它们的杀虫效果可以有很大程度的增加，他们对环境的相容性更好，同时还可以减轻害虫的抗药性，减轻农民负担。
适用于本发明的组合物的特异性昆虫生长调节剂、生物源、沙蚕毒素、有机磷、拟除虫菊酯和/或其他类杀虫剂实例如下：
(A)特异性昆虫生长调节剂杀虫剂
1、灭幼脲(Chlorbenzuron)
2、杀虫隆(triflumuron)
3、伏虫隆(teflubenzuron)
4、氟铃脲(hexatlumuron)
5、除虫脲(diflubenzuron)
6、氟螨脲(flucycloxuron)
7、环虫酰肼(chromafenozide)
8、氟虫脲(flufenoxurom)
9、甲氧虫酰肼(methoxyfenozide)
10、虫酰肼(tebufenozide)
(B)生物源杀虫剂
1、苏云金杆菌(Bacullus thuringiensis)
2、阿维菌素(abamectin)
(C)沙蚕毒素杀虫剂
1、杀虫单
2、杀虫双(dimthypo)
(D)有机磷杀虫剂
1、三唑磷(Triazophos)
2、毒死蜱(chlorpyrifos)
(E)拟除虫菊酯杀虫剂
1、溴氰菊酯(deltamethrin)
2、氰戊菊酯(fenvalerate)
3、氟氯氰菊酯(cyfluthrin)
4、高效氯氟氰菊酯(lambdacyhalothrin)
5、氯氰菊酯(cypermethrin)
6、高效氯氰菊酯
(F)其他类杀虫剂
1、溴虫腈(chlorfenapyr)
2、吡虫啉(imidacloprid)
3、氟虫腈(fipronil)
在上面A、B、C、D、E和F组中给出的普通名称表示具有以下IUPAC名称的化合物：
(A)特异性昆虫生长调节剂
(1)1-邻氯苯甲酰基-3-(4-氯苯基)脲；
(2)1-2(2-氯苯甲酰基)-3-(4-三氟甲氧基苯基)脲；
(3)N-(3，5-二氯-2，4-二氟苯基)-N’-(2，6-二氟苯甲酰)脲；
(4)1-[3，5-二氯-4-(1，1，2，2-四氟乙氧基)苯基]-3-(2，6-二氟苯甲酰基)脲；
(5)1-(4-氯苯基)-3-(2，6-二氟苯甲酰基)脲；
(6)1-[α-(4-氯-α-环丙基亚苄基氨基一氧)对-甲苯基]-3-(2，6-二氟苯甲酰基)脲；
(7)2’-叔丁基-5-甲基-2’-(3，5-二甲基苯甲酰基)色满-6-甲酰肼；
(8)1-[4-(2-氯-α，α，α-三氟-对甲苯氧基)-2氟苯基]-3-(2，6-二氟苯甲酰)脲；
(9)N-叔丁基-N’-(3-甲基-2-甲苯甲酰基)-3，5-二甲基苯甲酰肼；
(10)1-(1，1-二甲基乙基)-1-(4-乙基苯甲酰基)-3，5，-二甲基苯甲酰肼。
(B)生物源杀虫剂
(1)苏云金杆菌；
(2)阿维菌素。
(C)沙蚕毒素类杀虫剂
(1)2-N，N-二甲胺基-1-硫代硫酸钠基-3-硫代硫酸基丙烷；
(2)2-N，N-二甲胺基-1、3-双(硫代磺酸钠基)丙烷。
(D)有机磷类杀虫剂
(1)O，O-二乙基-O-1-苯基-1，2，4-三唑-3-硫代磷酸酯；
(2)O，O-二乙基-O-(3，5，6-三氯-2-吡啶基)硫逐磷酸酯；
(E)拟除虫菊酯类杀虫剂
(1)右旋-顺式-2，2-二甲基-3-(2，2-二溴乙烯基)环丙烷羧酸(S)-α-氰基-3-苯氧基苄酯；
(2)α-氰基-3-苯氧苄基(R，S)-2-(4-氯苯基)-3-甲基丁酸酯；
(3)α-氰基-3-苯氧基-4-氟苄基(IR，3R)-3-(2，2-二氯乙烯基)-2，2-二甲基环丙烷羧酸酯；
(4)3-(2-氯-3，3，3-三氟丙烯基)-2，2-二甲基环丙烷羧酸-α-氰基-3-苯氧苄基酯；
(5)α-氰基-(3-苯氧苄基)(1RS)-1R，3R-3-(2，2-二氯乙烯基)-2，2-二甲基环丙烷羰酸酯；
(6)2，2-二甲基-3-(2，2-二氯乙烯基)环丙烷羧酸-α-氰基-(3-苯氧基)-苄酯。
(F)其他类杀虫剂
(1)4-溴-2-(4-氯苯基)-1-乙氧基甲基-5-三氟甲基吡咯-3-腈；
(2)1-(6-氯-3-吡啶基甲基)-N-硝基亚咪唑烷-2-基胺；
(3)(±)-5-氨基-1-(2，6-二氯-α，α，α-三氟-对-甲苯基)-4-三氟甲基亚磺酰基吡唑-3-腈；
对于本发明的组合物来说，上文所列的特异性昆虫生长调节剂中较佳的为灭幼脲、定虫隆、伏虫隆、除虫脲、氟虫脲、虫酰肼。
本发明的组合物可以是二组合，也可以是三种以上前述化合物形成的组合物。
本发明的组合物的各种成份的作用机制不同，它们之间相互增效，害虫、害螨的抗药性降低，所以组合物的杀虫效果明显高于各个组分单用时的杀虫效果，且杀虫谱更广。
本发明的组合物可以用于多种作物防治多种害虫、害螨，对小麦、烟草、果树、葡萄、蔬菜、棉花及林业上的鳞翅目害虫有特效。如粘虫、烟草青虫、烟草夜蛾、粉纹夜蛾、马铃薯甲虫、棉叶螨、甜菜蚜、梨小食心虫、葡萄小卷蛾、甜菜夜蛾、小菜蛾、斜纹夜蛾、菜青虫、松毛虫、棉铃虫等。
本发明组合物中甲胺基阿维菌素苯甲酸盐与特异性昆虫生长调节剂、生物源、沙蚕毒素、有机磷、拟除虫菊酯和/或其他类杀虫剂的比例基于活性组份的重量份数为1∶160～80∶1，最佳为1∶40～40∶1。
本发明的组合物还可以包含乳化剂、溶剂、助剂或填料，其所占组合物的重量份数为0.5％～95％。
本发明的组合物可以配成溶液、乳液、粒剂、可湿性粉剂、水剂、悬浮剂、粉剂、粉尘剂、糊剂、可溶性粉剂、微乳剂、乳油、气雾剂、烟剂和缓释剂。
本发明的组合物还要加入乳化剂、分散剂、润湿剂等表面活性物质，以增加组合物的稳定性、润湿性、渗透性。
本发明描述的产物可以呈成品制剂形式，即产物中物质已经混合。然而组合物的成份也可以单独以制剂提供，在使用前在罐内直接混合。
本发明的组合物也可以含有其它活性组份，例如其它具有除草、杀虫或杀菌性能的化合物，也可以与杀线虫剂、防护剂、生长调节剂、植物营养素或土壤调节剂混合。
本发明的组合物可以按普通的方法使用，如浇注、喷射、喷雾、喷粉或放烟。
本发明组合物可以用以下实施例说明：
实施例1 10.2％悬浮剂配制
甲胺基阿维菌素苯甲酸盐 0.2％(重量)
灭幼脲 10％(重量)
助剂 11％(重量)
填料 36.8％(重量)
水 42％(重量)
将各种组份混合在一起，在砂磨机中研磨至有效成分粒径小于3μm。
实施例2 3.5％可湿性粉剂配制
甲胺基阿维菌素苯甲酸盐 0.5％(重量)
定虫隆 3％(重量)
助剂 10％(重量)
填料 86.5％(重量)
将各种物料依次加入混合釜中，在搅拌条件下，使其充分混合，粉碎到粒径小于44μm。
实施例3 50.5％可溶性粉剂配制
甲胺基阿维菌素苯甲酸盐 0.5％(重量)
杀虫单 50％(重量)
助剂 4％(重量)
填料 45.5％(重量)
将各种物料依次加入混合釜中，在搅拌条件下，使其充分混合，经调制、喷雾而成。
实施例4 15.6％粒剂配制
甲胺基阿维菌素苯甲酸盐 0.6％(重量)
三唑磷 15％(重量)
膨润土 30％(重量)
滑石 52.4％(重量)
硫铵 2％(重量)
将各种物料依次加入混合釜中，在搅拌条件下，使其充分混合，经捏合、溶解、干燥、碎解、造粒成功。
实施例5 10.2％甲胺基阿维菌素苯甲酸盐·灭悬浮剂对甜菜夜蛾的防治效果
地点：上海
| 处理 | 喷药后3天 | 喷药后7天 | 差异 | |||
| 减退率(％) | 防效(％) | 减退率(％) | 防效(％) | 0.05 | 0.01 | |
| 0.2％甲胺基阿维菌素苯甲酸盐+10％灭幼脲 | 96.93 | 96.88 | 99.05 | 99.03 | a | A |
| 1％甲胺基阿维菌素苯甲酸盐EC | 93.71 | 93.61 | 95.48 | 95.38 | b | B |
| 20％灭幼脲SC | 89.89 | 89.72 | 90.51 | 90.31 | c | C |
| CK | 1.63 | - | 2.07 | - | d | D |
实施例6 50.5％甲胺基阿维菌素苯甲酸盐·杀虫单可溶性粉剂对棉铃虫的防治效果
地点：淄博
| 处理 | 喷药后3天 | 喷药后7天 | 差异 | |||
| 减退率(％) | 防效(％) | 减退率(％) | 防效(％) | 0.05 | 0.01 | |
| 0.5％甲胺基阿维菌素苯甲酸盐+50％杀虫单 | 92.20 | 92.07 | 94.22 | 94.07 | a | A |
| 1％甲胺基阿维菌素苯甲酸盐EC | 90.55 | 90.39 | 92.02 | 91.82 | b | B |
| 90％杀虫单可溶性粉剂 | 83.55 | 83.28 | 84.99 | 84.61 | c | C |
| CK | 1.63 | - | 2.45 | - | d | D |
实施例7 8.2％甲胺基阿维菌素苯甲酸盐·灭悬浮剂对苹果卷叶蛾的防治效果
地点；烟台
| 处理 | 喷药后3天 | 喷药后7天 | 差异 | |||
| 减退率(％) | 防效(％) | 减退率(％) | 防效(％) | 0.05 | 0.01 | |
| 0.2％甲胺基阿维菌素苯甲酸盐+8％灭幼脲 | 92.04 | 91.89 | 96.45 | 96.37 | a | A |
| 1％甲胺基阿维菌素苯甲酸盐EC | 89.51 | 89.32 | 91.90 | 91.71 | b | B |
| 20％灭幼脲SC | 86.57 | 86.32 | 87.30 | 87.00 | c | C |
| CK | 1.80 | - | 2.30 | - | d | D |
实施例8 3.5％甲胺基阿维菌素苯甲酸盐·定虫可湿性粉剂对烟青虫的防治效果
地点：青州
| 处理 | 喷药后3天 | 喷药后7天 | 差异 | |||
| 减退率(％) | 防效(％) | 减退率(％) | 防效(％) | 0.05 | 0.01 | |
| 0.5％甲胺基阿维菌素苯甲酸盐+3％定虫隆 | 95.43 | 95.32 | 99.03 | 99.00 | a | A |
| 1％甲胺基阿维菌素苯甲酸盐EC | 90.49 | 90.27 | 93.42 | 93.21 | b | B |
| 5％定虫隆(抑太保)EC | 87.90 | 87.62 | 91.82 | 91.55 | b | B |
| CK | 2.30 | - | 3.14 | - | c | C |
实施例9 15.6％甲胺基阿维菌素苯甲酸盐·三唑磷粒剂对菜青虫的防治效果
试验地点：滨州
| 处理 | 喷药后3天 | 喷药后7天 | 差异 | |||
| 减退率(％) | 防效(％) | 减退率(％) | 防效(％) | 0.05 | 0.01 | |
| 0.6％甲胺基阿维菌素苯甲酸盐+15％三唑磷 | 87.76 | 87.62 | 93.24 | 93.08 | a | A |
| 1％甲胺基阿维菌素苯甲酸盐EC | 83.40 | 83.21 | 91.82 | 91.62 | b | B |
| 40％三唑磷EC | 72.64 | 72.32 | 77.07 | 76.52 | c | C |
| CK | 1.15 | - | 2.35 | - | d | D |
实施例10 4.5％甲胺基阿维菌素苯甲酸盐·氯氰乳油对小菜蛾的防治效果
试验地点：青州
| 处理 | 喷药后3天 | 喷药后7天 | 差异 | |||
| 减退率(％) | 防效(％) | 减退率(％) | 防效(％) | 0.05 | 0.01 | |
| 0.5％甲胺基阿维菌素苯甲酸盐+4％氯氰菊酯 | 92.19 | 92.06 | 97.06 | 97.03 | a | A |
| 1％甲胺基阿维菌素苯甲酸盐EC | 86.93 | 86.71 | 94.31 | 94.25 | b | B |
| 20％氯氰菊酯EC | 68.83 | 68.32 | 71.63 | 71.32 | c | C |
| CK | 1.62 | - | 1.07 | - | d | D |
实施例11 10.5％甲胺基阿维菌素苯甲酸盐·虫酰肼悬浮剂对甜菜夜蛾的防治效果
试验地点：上海
| 处理 | 喷药后3天 | 喷药后7天 | 差异 | |||
| 减退率(％) | 防效(％) | 减退率(％) | 防效(％) | 0.05 | 0.01 | |
| 0.5％甲胺基阿维菌素苯甲酸盐+10％虫酰肼 | 93.63 | 93.50 | 97.06 | 97.03 | a | A |
| 1％甲胺基阿维菌素苯甲酸盐EC | 89.34 | 89.12 | 94.21 | 94.15 | b | B |
| 20％虫酰肼SC | 87.29 | 87.02 | 93.67 | 93.60 | b | B |
| CK | 2.05 | - | 1.05 | - | c | C |
实施例12 5.5％甲胺基阿维菌素苯甲酸盐·溴虫腈悬浮剂对菜青虫的防治效果
试验地点：淄博
| 处理 | 喷药后3天 | 喷药后7天 | 差异 | |||
| 减退率(％) | 防效(％) | 减退率(％) | 防效(％) | 0.05 | 0.01 | |
| 0.5％甲胺基阿维菌素苯甲酸盐+5％溴虫腈 | 89.61 | 89.51 | 93.62 | 93.49 | a | A |
| 1％甲胺基阿维菌素苯甲酸盐EC | 85.34 | 85.19 | 84.74 | 84.73 | b | B |
| 10％溴虫腈SC | 83.00 | 82.83 | 83.94 | 83.62 | b | B |
| CK | 0.98 | - | 1.96 | - | c | C |
Claims (1)
1.一种杀虫组合物，其含有2-N，N-二甲胺基-1-硫代硫酸钠基-3-硫代硫酸基丙烷和如下I结构的4″-甲基氨基-4″-去氧阿维菌素B1苯甲酸盐——甲胺基阿维菌素苯甲酸盐；其中结构式I与2-N，N-二甲胺基-1-硫代硫酸钠基-3-硫代硫酸基丙烷的比例基于活性组分的重量份数为1∶100。
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