CN1274219C - 甲胺基阿维菌素苯甲酸盐杀虫、杀螨组合物 - Google Patents
甲胺基阿维菌素苯甲酸盐杀虫、杀螨组合物 Download PDFInfo
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Abstract
一种杀虫组合物，其含有至少一种特异性昆虫生长调节剂、生物源、沙蚕毒素、有机磷、拟除虫菊酯和/或其他类杀虫剂和如下I结构的4″-甲基胺基-4″-去氧阿维菌素B1苯甲酸盐——甲胺基阿维菌素苯甲酸盐。
Description
本发明涉及甲胺基阿维菌素苯甲酸盐与特异性昆虫生长调节剂、生物源、沙蚕毒素、有机磷、拟除虫菊酯和/或其他类杀虫剂组成的杀虫、杀螨组合物。
甲胺基阿维菌素苯甲酸盐是从发酵产品阿维菌素B1开始的一种新型的半合成杀虫剂，它对鳞翅目昆虫的幼虫活性极高，主要是胃毒作用，兼有触杀作用。甲胺基阿维菌素苯甲酸盐可以渗透到目标作物的表皮，形成一个有效成分的储存层，因而可以有长期的残效。如果与特异性昆虫生长调节剂、生物源、沙蚕毒素、有机磷、拟除虫菊酯和/或其他类杀虫剂制成组合物，它们的杀虫效果可以有很大程度的增加，他们对环境的相容性更好，同时还可以减轻害虫的抗药性，减轻农民负担。
适用于本发明的组合物的特异性昆虫生长调节剂、生物源、沙蚕毒素、有机磷、拟除虫菊酯和/或其他类杀虫剂实例如下：
(A)特异性昆虫生长调节剂杀虫剂
1、灭幼脲(Chlorbenzuron)
2、杀虫隆(triflumuron)
3、伏虫隆(teflubenzuron)
4、氟铃脲(hexatlumuron)
5、除虫脲(diflubenzuron)
6、氟螨脲(flucycloxuron)
7、环虫酰肼(chromafenozide)
8、氟虫脲(flufenoxurom)
9、甲氧虫酰肼(methoxyfenozide)
10、虫酰肼(tebufenozide)
(B)生物源杀虫剂
1、苏云金杆菌(Bacullus thuringiensis)
2、阿维菌素(abamectin)
(C)沙蚕毒素杀虫剂
1、杀虫单
2、杀虫双(dimthypo)
(D)有机磷杀虫剂
1、三唑磷(Triazophos)
2、毒死蜱(chlorpyrifos)
(E)拟除虫菊酯杀虫剂
1、溴氰菊酯(deltamethrin)
2、氰戊菊酯(fenvalerate)
3、氟氯氰菊酯(cyfluthrin)
4、高效氯氟氰菊酯(lambdacyhalothrin)
5、氯氰菊酯(cypermethrin)
6、高效氯氰菊酯
(F)其他类杀虫剂
1、溴虫腈(chlorfenapyr)
2、吡虫啉(imidacloprid)
3、氟虫腈(fipronil)
在上面A、B、C、D、E和F组中给出的普通名称表示具有以下IUPAC名称的化合物：
(A)特异性昆虫生长调节剂
(1)1-邻氯苯甲酰基-3-(4-氯苯基)脲；
(2)1-2(2-氯苯甲酰基)-3-(4-三氟甲氧基苯基)脲；
(3)N-(3，5-二氯-2，4-二氟苯基)-N’-(2，6-二氟苯甲酰)脲；
(4)1-[3，5-二氯-4-(1，1，2，2-四氟乙氧基)苯基]-3-(2，6-二氟苯甲酰基)脲；
(5)1-(4-氯苯基)-3-(2，6-二氟苯甲酰基)脲；
(6)1-[α-(4-氯-α-环丙基亚苄基氨基一氧)对-甲苯基]-3-(2，6-二氟苯甲酰基)脲；
(7)2’-叔丁基-5-甲基-2’-(3，5-二甲基苯甲酰基)色满-6-甲酰肼；
(8)1-[4-(2-氯-α，α，α-三氟-对甲苯氧基)-2氟苯基]-3-(2，6-二氟苯甲酰)脲；
(9)N-叔丁基-N’-(3-甲基-2-甲苯甲酰基)-3，5-二甲基苯甲酰肼；
(10)1-(1，1-二甲基乙基)-1-(4-乙基苯甲酰基)-3，5，-二甲基苯甲酰肼。
(B)生物源杀虫剂
(1)苏云金杆菌；
(2)阿维菌素。
(C)沙蚕毒素类杀虫剂
(1)2-N，N-二甲胺基-1-硫代硫酸钠基-3-硫代硫酸基丙烷；
(2)2-N，N-二甲胺基-1、3-双(硫代磺酸钠基)丙烷。
(D)有机磷类杀虫剂
(1)O，O-二乙基-O-1-苯基-1，2，4-三唑-3-硫代磷酸酯；
(2)O，O-二乙基-O-(3，5，6-三氯-2-吡啶基)硫逐磷酸酯；
(E)拟除虫菊酯类杀虫剂
(1)右旋-顺式-2，2-二甲基-3-(2，2-二溴乙烯基)环丙烷羧酸 (S)-α氰基-3-苯氧基苄酯；
(2)α-氰基-3-苯氧苄基(R，S)-2-(4-氯苯基)-3-甲基丁酸酯；
(3)α-氰基-3-苯氧基-4-氟苄基(IR，3R)-3-(2，2-二氯乙烯基)-2，2-二甲基环丙烷羧酸酯；
(4)3-(2-氯-3，3，3-三氟丙烯基)-2，2-二甲基环丙烷羧酸-α-氰基-3-苯氧苄基酯；
(5)α-氰基-(3-苯氧苄基)(1RS)-1R，3R-3-(2，2-二氯乙烯基)-2，2-二甲基环丙烷羰酸酯；
(6)2，2-二甲基-3-(2，2-二氯乙烯基)环丙烷羧酸-α-氰基-(3-苯氧基)-苄酯。
(F)其他类杀虫剂
(1)4-溴-2-(4-氯苯基)-1-乙氧基甲基-5-三氟甲基吡咯-3-腈；
(2)1-(6-氯-3-吡啶基甲基)-N-硝基亚咪唑烷-2-基胺；
(3)(±)-5-氨基-1-(2，6-二氯-α，α，α-三氟-对-甲苯基)-4-三氟甲基亚磺酰基吡唑-3-腈；
对于本发明的组合物来说，上文所列的特异性昆虫生长调节剂中较佳的为灭幼脲、伏虫隆、除虫脲、氟虫脲、虫酰肼。
本发明的组合物可以是二组合，也可以是三种以上前述化合物形成的组合物。
本发明的组合物的各种成份的作用机制不同，它们之间相互增效，害虫、害螨的抗药性降低，所以组合物的杀虫效果明显高于各个组分单用时的杀虫效果，且杀虫谱更广。
本发明的组合物可以用于多种作物防治多种害虫、害螨，对小麦、烟草、果树、葡萄、蔬菜、棉花及林业上的鳞翅目害虫有特效。如粘虫、烟草青虫、烟草夜蛾、粉纹夜蛾、马铃薯甲虫、棉叶螨、甜菜蚜、梨小食心虫、葡萄小卷蛾、甜菜夜蛾、小菜蛾、斜纹夜蛾、菜青虫、松毛虫、棉铃虫等。
本发明组合物中甲胺基阿维菌素苯甲酸盐与特异性昆虫生长调节剂、生物源、沙蚕毒素、有机磷、拟除虫菊酯和/或其他类杀虫剂的比例基于活性组份的重量份数为1∶160～80∶1，最佳为1∶40～40∶1。
本发明的组合物还可以包含乳化剂、溶剂、助剂或填料，其所占组合物的重量份数为0.5％～95％。
本发明的组合物可以配成溶液、乳液、粒剂、可湿性粉剂、水剂、悬浮剂、粉剂、粉尘剂、糊剂、可溶性粉剂、微乳剂、乳油、气雾剂、烟剂和缓释剂。
本发明的组合物还要加入乳化剂、分散剂、润湿剂等表面活性物质，以增加组合物的稳定性、润湿性、渗透性。
本发明描述的产物可以呈成品制剂形式，即产物中物质已经混合。然而组合物的成份也可以单独以制剂提供，在使用前在罐内直接混合。
本发明的组合物也可以含有其它活性组份，例如其它具有除草、杀虫或杀菌性能的化合物，也可以与杀线虫剂、防护剂、生长调节剂、植物营养素或土壤调节剂混合。
本发明的组合物可以按普通的方法使用，如浇注、喷射、喷雾、喷粉或放烟。
本发明组合物可以用以下实施例说明：
实施例1 10.2％悬浮剂配制
甲胺基阿维菌素苯甲酸盐 0.2％(重量)
灭幼脲 10％(重量)
助剂 11％(重量)
填料 36.8％(重量)
水 42％(重量)
将各种组份混合在一起，在砂磨机中研磨至有效成分粒径小于3μm。
实施例2 50.5％可溶性粉剂配制
甲胺基阿维菌素苯甲酸盐 0.5％(重量)
杀虫单 50％(重量)
助剂 4％(重量)
填料 45.5％(重量)
将各种物料依次加入混合釜中，在搅拌条件下，使其充分混合，经调制、喷雾而成。
实施例3 15.6％粒剂配制
甲胺基阿维菌素苯甲酸盐 0.6％(重量)
三唑磷 15％(重量)
膨润土 30％(重量)
滑石 52.4％(重量)
硫铵 2％(重量)
将各种物料依次加入混合釜中，在搅拌条件下，使其充分混合，经捏合、溶解、干燥、碎解、造粒成功。
实施例4 10.2％甲胺基阿维菌素苯甲酸盐·灭悬浮剂
对甜菜夜蛾的防治效果
地点：上海
| 处理 | 喷药后3天 | 喷药后7天 | 差异 | |||
| 减退率(％) | 防效(％) | 减退率(％) | 防效(％) | 0.05 | 0.01 | |
| 0.2％甲胺基阿维菌素苯甲酸盐+10％灭幼脲 | 96.93 | 96.88 | 99.05 | 99.03 | a | A |
| 1％甲胺基阿维菌素苯甲酸盐EC | 93.71 | 93.61 | 95.48 | 95.38 | b | B |
| 20％灭幼脲SC | 89.89 | 89.72 | 90.51 | 90.31 | c | C |
| CK | 1.63 | - | 2.07 | - | d | D |
实施例5 50.5％甲胺基阿维菌素苯甲酸盐·杀虫单可溶性粉剂
对棉铃虫的防治效果
地点：淄博
| 处理 | 喷药后3天 | 喷药后7天 | 差异 | |||
| 减退率(％) | 防效(％) | 减退率(％) | 防效(％) | 0.05 | 0.01 | |
| 0.5％甲胺基阿维菌素苯甲酸盐+50％杀虫单 | 92.20 | 92.07 | 94.22 | 94.07 | a | A |
| 1％甲胺基阿维菌素苯甲酸盐EC | 90.55 | 90.39 | 92.02 | 91.82 | b | B |
| 90％杀虫单可溶性粉剂 | 83.55 | 83.28 | 84.99 | 84.61 | c | C |
| CK | 1.63 | - | 2.45 | - | d | D |
实施例6 8.2％甲胺基阿维菌素苯甲酸盐·灭悬浮剂
对苹果卷叶蛾的防治效果
地点；烟台
| 处理 | 喷药后3天 | 喷药后7天 | 差异 | |||
| 减退率(％) | 防效(％) | 减退率(％) | 防效(％) | 0.05 | 0.01 | |
| 0.2％甲胺基阿维菌素苯甲酸盐+8％灭幼脲 | 92.04 | 91.89 | 96.45 | 96.37 | a | A |
| 1％甲胺基阿维菌素苯甲酸盐EC | 89.51 | 89.32 | 91.90 | 91.71 | b | B |
| 20％灭幼脲SC | 86.57 | 86.32 | 87.30 | 87.00 | c | C |
| CK | 1.80 | - | 2.30 | - | d | D |
实施例7 15.6％甲胺基阿维菌素苯甲酸盐·三唑磷粒剂
对菜青虫的防治效果
试验地点：滨州
| 处理 | 喷药后3天 | 喷药后7天 | 差异 | |||
| 减退率(％) | 防效(％) | 减退率(％) | 防效(％) | 0.05 | 0.01 | |
| 0.6％甲胺基阿维菌素苯甲酸盐+15％三唑磷 | 87.76 | 87.62 | 93.24 | 93.08 | a | A |
| 1％甲胺基阿维菌素苯甲酸盐EC | 83.40 | 83.21 | 91.82 | 91.62 | b | B |
| 40％三唑磷EC | 72.64 | 72.32 | 77.07 | 76.52 | c | C |
| CK | 1.15 | - | 2.35 | - | d | D |
实施例8 4.5％甲胺基阿维菌素苯甲酸盐·氯氰乳油
对小菜蛾的防治效果
试验地点：青州
| 处理 | 喷药后3天 | 喷药后7天 | 差异 | |||
| 减退率(％) | 防效(％) | 减退率(％) | 防效(％) | 0.05 | 0.01 | |
| 0.5％甲胺基阿维菌素苯甲酸盐+4％氯氰菊酯 | 92.19 | 92.06 | 97.06 | 97.03 | a | A |
| 1％甲胺基阿维菌素苯甲酸盐EC | 86.93 | 86.71 | 94.31 | 94.25 | b | B |
| 20％氯氰菊酯EC | 68.83 | 68.32 | 71.63 | 71.32 | c | C |
| CK | 1.62 | - | 1.07 | - | d | D |
实施例9 10.5％甲胺基阿维菌素苯甲酸盐·虫酰肼悬浮剂
对甜菜夜蛾的防治效果
试验地点：上海
| 处理 | 喷药后3天 | 喷药后7天 | 差异 | |||
| 减退率(％) | 防效(％) | 减退率(％) | 防效(％) | 0.05 | 0.01 | |
| 0.5％甲胺基阿维菌素苯甲酸盐+10％虫酰肼 | 93.63 | 93.50 | 97.06 | 97.03 | a | A |
| 1％甲胺基阿维菌素苯甲酸盐EC | 89.34 | 89.12 | 94.21 | 94.15 | b | B |
| 20％虫酰肼SC | 87.29 | 87.02 | 93.67 | 93.60 | b | B |
| CK | 2.05 | - | 1.05 | - | c | C |
实施例10 5.5％甲胺基阿维菌素苯甲酸盐·溴虫腈悬浮剂
对菜青虫的防治效果
试验地点：淄博
| 处理 | 喷药后3天 | 喷药后7天 | 差异 | |||
| 减退率(％) | 防效(％) | 减退率(％) | 防效(％) | 0.05 | 0.01 | |
| 0.5％甲胺基阿维菌素苯甲酸盐+5％溴虫腈 | 89.61 | 89.51 | 93.62 | 93.49 | a | A |
| 1％甲胺基阿维菌素苯甲酸盐EC | 85.34 | 85.19 | 84.74 | 84.73 | b | B |
| 10％溴虫腈SC | 83.00 | 82.83 | 83.94 | 83.62 | b | B |
| CK | 0.98 | - | 1.96 | - | c | C |
Claims (1)
1.一种杀虫组合物，其含有一种特异性昆虫生长调节剂和如下I结构的4″-甲基胺基-4″-去氧阿维菌素B1苯甲酸盐——甲胺基阿维菌素苯甲酸盐；其中特异性昆虫生长调节剂是1-邻氯苯甲酰基-3-(4-氯苯基)脲；其中结构式I与特异性昆虫生长调节剂的比例基于活性组分的重量份数为1∶160至80∶1；除活性组份外还含有乳化剂、溶剂、助剂和填料。
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| CN107079921A (zh) | 2008-12-31 | 2017-08-22 | 安道麦马克西姆有限公司 | 用于控制植物中的昆虫的方法 |
| CN102037994A (zh) * | 2010-12-30 | 2011-05-04 | 江苏腾龙生物药业有限公司 | 一种含有甲氨基阿维菌素苯甲酸盐和稻丰散农药组合物 |
| CN103027056A (zh) * | 2011-09-30 | 2013-04-10 | 张长平 | 一种复合杀虫药物组合物、应用和其制剂 |
| CN103300021B (zh) * | 2012-03-14 | 2016-08-17 | 陕西韦尔奇作物保护有限公司 | 一种环虫酰肼与生物源类的农药组合物 |
| CN106508926A (zh) * | 2016-12-12 | 2017-03-22 | 山东润博生物科技有限公司 | 一种甲氨基阿维菌素苯甲酸盐和溴虫腈的水悬浮剂及其制备方法和应用 |
| CN108041064A (zh) * | 2018-01-26 | 2018-05-18 | 山东汤普乐作物科学有限公司 | 一种含双三氟虫脲的杀虫微囊悬浮-悬浮剂及其制备方法 |
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Effective date of registration: 20110622 Address after: 256500 Shandong city of Binzhou province Hu Zhen Boxing County Chen Jingbo Industrial Park Patentee after: Shandong Chambroad Holding Co., Ltd. Address before: 256505 Boxing County, Shandong province Beijing Bo group Co-patentee before: Shi Qingling Patentee before: Ma Yunsheng Co-patentee before: Wang Zhaodong Co-patentee before: Wen Peihong Co-patentee before: Xu Boyong Co-patentee before: Cao Tongbo |
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Owner name: CHAMBROAD AGROCHEMICAL TECHNOLOGY CO., LTD. Free format text: FORMER OWNER: SHANDONG CHAMBROAD HOLDING CO., LTD. Effective date: 20141210 |
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Effective date of registration: 20141210 Address after: 256500 Shandong city of Binzhou province Hu Zhen Boxing County Chen Jingbo Industrial Park Beijing Bo agricultural Polytron Technologies Inc Patentee after: Jingbo Agrochemicals Technology Co., Ltd. Address before: 256500 Shandong city of Binzhou province Hu Zhen Boxing County Chen Jingbo Industrial Park Patentee before: Shandong Chambroad Holding Co., Ltd. |
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Address after: 256500 Boxing County Economic Development Zone, Binzhou, Shandong Patentee after: Beijing Agricultural Chemical Technology Co., Ltd. Address before: 256500 Jingbo Agrochemical Technology Co., Ltd. of Jingbo Industrial Park, Chenhu Town, Boxing County, Binzhou City, Shandong Province Patentee before: Jingbo Agrochemicals Technology Co., Ltd. |
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Granted publication date: 20060913 Termination date: 20200731 |
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