CN1236678C - 氰菌胺杀菌、杀虫组合物 - Google Patents
氰菌胺杀菌、杀虫组合物 Download PDFInfo
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- CN1236678C CN1236678C CN 01123749 CN01123749A CN1236678C CN 1236678 C CN1236678 C CN 1236678C CN 01123749 CN01123749 CN 01123749 CN 01123749 A CN01123749 A CN 01123749A CN 1236678 C CN1236678 C CN 1236678C
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- zarilamid
- rice
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- suspending agent
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Abstract
一种杀菌剂、杀虫剂组合物，其含有至少一种特异性昆虫生长调节剂、生物源、沙蚕毒素、有机磷、拟除虫菊酯和/或其他类杀虫剂和如下I结构的N-(1-腈基-1，2-二甲基)-2-(2，4-二氯苯氧基)丙酰胺——氰菌胺。
Description
本发明涉及氰菌胺与特异性昆虫生长调节剂、生物源、沙蚕毒素、有机磷、拟除虫菊酯和/或其他类杀虫剂组成的杀菌、杀虫组合物。
杀菌剂氰菌胺为黑色素生物合成抑制剂，具有良好的内吸和残留活性。本发明人通过研究，发现含氰菌胺杀菌剂与特异性昆虫生长调节剂、生物源、沙蚕毒素、有机磷、拟除虫菊酯和/或其他类杀虫剂组成的杀菌、杀虫组合物，对水稻病虫害具有很好的活性。对稻田比较难治的虫害如螟虫(二化螟、三化螟)、飞虱、叶蝉、稻蓟马、稻甲虫等有很好的防效。
将氰菌胺与特异性昆虫生长调节剂、生物源、沙蚕毒素、有机磷、拟除虫菊酯和/或其他类杀虫剂混在一起同时防治水稻稻瘟病、纹枯病等或水稻稻瘟病、纹枯病，水稻螟虫、飞虱、叶蝉、稻蓟马、稻甲虫等未见报道。
适用于本发明的组合物的特异性昆虫生长调节剂、生物源、沙蚕毒素、有机磷、拟除虫菊酯和/或其他类杀虫剂实例如下：
(A)特异性昆虫生长调节剂杀虫剂
1、灭幼脲(Chlorbenzuron)
2、杀虫隆(triflumuron)
3、伏虫隆(teflubenzuron)
4、氟铃脲(hexatlumuron)
5、除虫脲(diflubenzuron)
6、氟螨脲(flucycloxuron)
7、环虫酰肼(chromafenozide)
8、氟虫脲(flufenoxurom)
9、甲氧虫酰肼(methoxyfenozide)
10、虫酰肼(tebufenozide)
(B)生物源杀虫剂
1、苏云金杆菌(Bacullus thuringiensis)
2、阿维菌素(abamectin)
3、甲胺基阿维菌素苯甲酸盐(emamectin benzoate)
(C)沙蚕毒素杀虫剂
1、杀虫单
2、杀虫双(dimthypo)
(D)有机磷杀虫剂
1、三唑磷(Triazophos)
2、毒死蜱(chlorpyrifos)
(E)拟除虫菊酯杀虫剂
1、氟氯氰菊酯(cyfluthrin)
2、高效氯氟氰菊酯(lambdacyhalothrin)
3、高效氯氰菊酯
4、醚菊酯(etofenprox)
(F)其他类杀虫剂
1、溴虫腈(chlorfenapyr)
2、吡虫啉(imidacloprid)
3、氟虫腈(fipronil)
4、噻嗪酮(buprofezin)
5、啶虫咪(acetamiprid)
6、烯啶虫胺(nitenpyram)
7、呋虫胺(dinotefuran)
8、噻虫嗪(thiamethoxam)
9、噻虫啉(thiacloprid)
10、噻虫胺(clothianidin)
在上面A、B、C、D、E和F组中给出的普通名称表示具有以下IUPAC名称的化合物：
(A)特异性昆虫生长调节剂
(1)1-邻氯苯甲酰基-3-(4-氯苯基)脲；
(2)1-2(2-氯苯甲酰基)-3-(4-三氟甲氧基苯基)脲；
(3)N-(3，5-二氯-2，4-二氟苯基)-N’-(2，6-二氟苯甲酰)脲；
(4)1-[3，5-二氯-4-(1，1，2，2-四氟乙氧基)苯基]-3-(2，6-二氟苯甲酰基)脲；
(5)1-(4-氯苯基)-3-(2，6-二氟苯甲酰基)脲；
(6)1-[α-(4-氯-α-环丙基亚苄基氨基一氧)对-甲苯基]-3-(2，6-二氟苯甲酰基)脲；
(7)2’-叔丁基-5-甲基-2’-(3，5-二甲基苯甲酰基)色满-6-甲酰肼；
(8)1-[4-(2-氯-α，α，α-三氟-对甲苯氧基)-2氟苯基]-3-(2，6-二氟苯甲酰)脲；
(9)N-叔丁基-N’-(3-甲基-2-甲苯甲酰基)-3，5-二甲基苯甲酰肼；
(10)N-叔丁基-N’-(4-乙基苯甲酰基)-3，5-二甲基苯甲酰肼。
(B)生物源杀虫剂
(1)苏云金杆菌；
(2)阿维菌素；
(3)4″-甲基氨基-4″-去氧阿维菌素B1苯甲酸盐。
(C)沙蚕毒素类杀虫剂
(1)2-N，N-二甲胺基-1-硫代硫酸钠基-3-硫代硫酸基丙烷；
(2)2-N，N-二甲胺基-1、3-双(硫代磺酸钠基)丙烷。
(D)有机磷类杀虫剂
(1)O，O-二乙基-O-1-苯基-1，2，4-三唑-3-硫代磷酸酯；
(2)O，O-二乙基-O-(3，5，6-三氯-2-吡啶基)硫逐磷酸酯；
(E)拟除虫菊酯类杀虫剂
(1)α-氰基-3-苯氧基-4-氟苄基(IR，3R)-3-(2，2-二氯乙烯基)-2，2-二甲基环丙烷羧酸酯；
(2)3-(2-氯-3，3，3-三氟丙烯基)-2，2-二甲基环丙烷羧酸-α-氰基-3-苯氧苄基酯；
(3)2，2-二甲基-3-(2，2-二氯乙烯基)环丙烷羧酸-α-氰基-(3-苯氧基)-苄酯；
(4)2-(4-乙氧基苯基)-2-甲基丙基-3-苯氧基苄基醚。
(F)其他类杀虫剂
(1)4-溴-2-(4-氯苯基)-1-乙氧基甲基-5-三氟甲基吡咯-3-腈；
(2)1-(6-氯-3-吡啶基甲基)-N-硝基亚咪唑烷-2-基胺；
(3)(±)-5-氨基-1-(2，6-二氯-α，α，α-三氟-对-甲苯基)-4-三氟甲基亚磺酰基吡唑-3-腈；
(4)2-特-丁基亚氨基-3-异丙基-5-苯基-1，3，5-噻二嗪-4-酮；
(5)(E)-N1-[(6-氯-3-吡啶)甲基]-N2-氰基-N1-甲基乙咪；
(6)(E)-N-(6-氯-3-吡啶甲基)-N-乙基-N’-甲基-2-硝基亚乙烯基二胺；
(7)(RS)-1-甲基-2-硝基-3-[(3-四氢呋哺)甲基]胍；
(8)3-(2-氯-1，3-噻唑-5-基甲基)-5-甲基-1，3，5-恶二嗪-4-基叉(硝基)胺；
(9)3-(6-氯-3-吡啶甲基)-1，3-噻唑啉-2-基叉氰胺；
(10)(E)-1-[(2-氯-1，3-噻唑-5-基)甲基]-3-甲基-2-硝基胍。
对于本发明的组合物来说，上文所列的特异性昆虫生长调节剂中较佳的为灭幼脲、伏虫隆、除虫脲、氟虫脲、虫酰肼。
对于本发明的组合物来说，上文所列的其他类杀虫剂中较佳的为溴虫腈、吡虫啉、氟虫腈、噻嗪酮、啶虫咪、烯啶虫胺、呋虫胺、噻虫嗪、噻虫啉、噻虫胺。
本发明的组合物可以是二组合，也可以是三种以上前述化合物形成的组合物。
本发明的组合物可以用于多种作物防治多种病害、虫害，对水稻、小麦、烟草、果树、葡萄、蔬菜、棉花及林业上的病害、虫害有特效。如水稻稻瘟病、水稻纹枯病、稻曲病、恶苗病、白叶枯病、细菌性条斑病、水稻螟虫、水稻飞虱、水稻叶蝉、水稻二化螟、水稻三化螟、稻蓟马、稻甲虫、粘虫、烟草青虫、烟草夜蛾、粉纹夜蛾、马铃薯甲虫、棉叶螨、甜菜蚜、梨小食心虫、葡萄小卷蛾、甜菜夜蛾、小菜蛾、斜纹夜蛾、菜青虫、松毛虫、棉铃虫等。
本发明组合物中氰菌胺与特异性昆虫生长调节剂、生物源、沙蚕毒素、有机磷、拟除虫菊酯和/或其他类杀虫剂的比例基于活性组份的重量份数为1∶160～80∶1，最佳为1∶40～40∶1。
本发明的组合物还可以包含乳化剂、溶剂、助剂或填料，其所占组合物的重量份数为0.5％～95％。
本发明的组合物可以配成溶液、乳液、粒剂、可湿性粉剂、水剂、悬浮剂、粉剂、粉尘剂、糊剂、可溶性粉剂、可溶性粒剂、微乳剂、乳油、气雾剂、烟剂和缓释剂。
本发明的组合物还要加入乳化剂、分散剂、润湿剂等表面活性物质，以增加组合物的稳定性、润湿性、渗透性。
本发明描述的产物可以呈成品制剂形式，即产物中物质已经混合。然而组合物的成份也可以单独以制剂提供，在使用前在罐内直接混合。
本发明的组合物也可以含有其它活性组份，例如其它具有除草、杀虫或杀菌性能的化合物，也可以与杀线虫剂、防护剂、生长调节剂、植物营养素或土壤调节剂混合。
本发明的组合物可以按普通的方法使用，如浇注、喷射、喷雾、喷粉或放烟。
本发明组合物可以用以下实施例说明：
实施例1 30％悬浮剂配制
氰菌胺1 5％(重量)
虫酰肼1 5％(重量)
助剂1 2％(重量)
填料2 6％(重量)
水 32％(重量)
将各种组份混合在一起，在砂磨机中研磨至有效成分粒径小于3μm。
实施例2 17％可湿性粉剂配制
氰菌胺 7％(重量)
三唑磷 10％(重量)
助剂 12％(重量)
填料 71％(重量)
将各种物料依次加入混合釜中，在搅拌条件下，使其充分混合，粉碎到粒径小于44μm。
实施例3 50％可溶性粉剂配制
氰菌胺 10％(重量)
杀虫单 40％(重量)
助剂 5％(重量)
填料 45％(重量)
将各种物料依次加入混合釜中，在搅拌条件下，使其充分混合，经调制、喷雾而成。
实施例4 10.5％粒剂配制
氰菌胺 10％(重量)
甲胺基阿维菌素苯甲酸盐 0.5％(重量)
膨润土 30％(重量)
滑石 57.5％(重量)
硫铵 2％(重量)
将各种物料依次加入混合釜中，在搅拌条件下，使其充分混合，经捏合、溶解、干燥、碎解、造粒成功。
实施例5 18％悬浮剂配制
氰菌胺 12％(重量)
溴虫腈 6％(重量)
助剂 12％(重量)
填料 26％(重量)
水 44％(重量)
将各种组份混合在一起，在砂磨机中研磨至有效成分粒径小于5μm。
实施例6 50％氰菌胺·杀虫单可溶性粉剂
防治对象：水稻稻瘟病、水稻二化螟、三化螟 地点：滨州
| 活性物质 | 剂量 | 杀虫防效％ | 杀菌防效％ |
| 50％氰菌胺·杀虫单可溶性粉剂 | 1000倍 | 95％ | 88％ |
| 80％杀虫单可溶性粉剂 | 1500倍 | 90％ | / |
| 20％氰菌胺悬浮剂 | 1000倍 | / | 85％ |
实施例7 16％氰菌胺·杀虫双悬浮剂
防治对象：水稻纹枯病、水稻飞虱 地点：滨州
| 活性物质 | 剂量 | 杀虫防效％ | 杀菌防效％ |
| 16％氰菌胺·杀虫双悬浮剂 | 800倍 | 91％ | 80％ |
| 18％杀虫双水剂 | 500倍 | 90％ | / |
| 20％氰菌胺悬浮剂 | 1000倍 | / | 82％ |
实施例8 12.5％氰菌胺·氟虫腈悬浮剂
防治对象：水稻稻曲病、稻甲虫 地点：滨州
| 活性物质 | 剂量 | 杀虫防效％ | 杀菌防效％ |
| 12.5％氰菌胺·氟虫腈悬浮剂 | 1000倍 | 91％ | 81％ |
| 5％氟虫腈悬浮剂 | 2000倍 | 90％ | / |
| 20％氰菌胺悬浮剂 | 1000倍 | / | 82％ |
实施例918％氰菌胺·溴虫腈悬浮剂
防治对象：水稻白叶枯病、稻叶蝉 地点：滨州
| 活性物质 | 剂量 | 杀虫防效％ | 杀菌防效％ |
| 18％氰菌胺·溴虫腈悬浮剂 | 800倍 | 94％ | 86％ |
| 10％溴虫腈悬浮剂 | 2000倍 | 95％ | / |
| 20％氰菌胺悬浮剂 | 1000倍 | / | 87％ |
实施例10 30％氰菌胺·虫酰肼悬浮剂
防治对象：水稻稻曲病、水稻二化螟、三化螟 地点：滨州
| 活性物质 | 剂量 | 杀虫防效％ | 杀菌防效％ |
| 30％氰菌胺·虫酰肼悬浮剂 | 1000倍 | 99％ | 92％ |
| 20％虫酰肼悬浮剂 | 1000倍 | 98％ | / |
| 20％氰菌胺悬浮剂 | 1000倍 | / | 90％ |
实施例11 10.5％氰菌胺·阿维菌素WP
防治对象：水稻纹枯病、水稻二化螟、三化螟 地点：滨州
| 活性物质 | 剂量 | 杀虫防效％ | 杀菌防效％ |
| 10.5％氰菌胺·阿维菌素可湿性粉剂 | 1000倍 | 97％ | 89％ |
| 0.5％阿维菌素乳油 | 2000倍 | 96％ | / |
| 20％氰菌胺悬浮剂 | 1000倍 | / | 90％ |
实施例1216％氰菌胺·吡虫啉WP
防治对象：水稻稻瘟病、水稻飞虱 地点：滨州
| 活性物质 | 剂量 | 杀虫防效％ | 杀菌防效％ |
| 16％氰菌胺·吡虫啉可湿性粉剂 | 800倍 | 90％ | 91％ |
| 10％吡虫啉可湿性粉剂 | 1500倍 | 92％ | / |
| 20％氰菌胺悬浮剂 | 1000倍 | / | 90％ |
实施例13 20％氰菌胺·高效氯氰菊酯悬浮剂
防治对象：水稻稻瘟病、水稻飞虱 地点：滨州
| 活性物质 | 剂量 | 杀虫防效％ | 杀菌防效％ |
| 20％氰菌胺·高效氯氰菊酯悬浮剂 | 1000倍 | 91％ | 87％ |
| 5％高效氯氰菊酯乳油 | 1500倍 | 90％ | / |
| 20％氰菌胺悬浮剂 | 1000倍 | / | 86％ |
实施例14 30％氰菌胺·辛硫磷悬浮剂
防治对象：水稻恶苗病、水稻叶蝉 地点：滨州
| 活性物质 | 剂量 | 杀虫防效％ | 杀菌防效％ |
| 30％氰菌胺·辛硫磷悬浮剂 | 1000倍 | 94％ | 85％ |
| 20％辛硫磷乳油 | 1000倍 | 93％ | / |
| 20％氰菌胺悬浮剂 | 1000倍 | / | 85％ |
Claims (1)
1.一种杀菌剂、杀虫剂组合物，其含有N-叔丁基-N’-(4-乙基苯甲酰基)-3，5-二甲基苯甲酰肼和如下I结构的N-(1-腈基-1，2-二甲基)-2-(2，4-二氯苯氧基)丙酰胺——氰菌胺；其中结构式I与N-叔丁基-N’-(4-乙基苯甲酰基)-3，5-二甲基苯甲酰肼的比例基于活性组分的重量份数为1∶160至80∶1。
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| CN1399877A (zh) | 2003-03-05 |
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