CN1291068C - 从电解质中析出锌镍合金的方法 - Google Patents
从电解质中析出锌镍合金的方法 Download PDFInfo
- Publication number
- CN1291068C CN1291068C CNB021424853A CN02142485A CN1291068C CN 1291068 C CN1291068 C CN 1291068C CN B021424853 A CNB021424853 A CN B021424853A CN 02142485 A CN02142485 A CN 02142485A CN 1291068 C CN1291068 C CN 1291068C
- Authority
- CN
- China
- Prior art keywords
- ionogen
- salt
- derivative
- current density
- zinc
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims abstract description 30
- 229910045601 alloy Inorganic materials 0.000 title abstract description 9
- 239000000956 alloy Substances 0.000 title abstract description 9
- 239000003792 electrolyte Substances 0.000 title abstract description 7
- 229910007567 Zn-Ni Inorganic materials 0.000 title 1
- 229910007614 Zn—Ni Inorganic materials 0.000 title 1
- 150000003839 salts Chemical class 0.000 claims abstract description 54
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 30
- QELJHCBNGDEXLD-UHFFFAOYSA-N nickel zinc Chemical compound [Ni].[Zn] QELJHCBNGDEXLD-UHFFFAOYSA-N 0.000 claims abstract description 28
- 229910021529 ammonia Inorganic materials 0.000 claims abstract description 15
- PVNIIMVLHYAWGP-UHFFFAOYSA-N Niacin Chemical compound OC(=O)C1=CC=CN=C1 PVNIIMVLHYAWGP-UHFFFAOYSA-N 0.000 claims description 52
- 239000011664 nicotinic acid Substances 0.000 claims description 26
- 229960003512 nicotinic acid Drugs 0.000 claims description 26
- 235000001968 nicotinic acid Nutrition 0.000 claims description 26
- CUBCNYWQJHBXIY-UHFFFAOYSA-N benzoic acid;2-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=CC=C1.OC(=O)C1=CC=CC=C1O CUBCNYWQJHBXIY-UHFFFAOYSA-N 0.000 claims description 23
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 14
- 230000002378 acidificating effect Effects 0.000 claims description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 7
- 235000014655 lactic acid Nutrition 0.000 claims description 7
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 claims description 4
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 abstract description 17
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 abstract description 14
- 229910000990 Ni alloy Inorganic materials 0.000 abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 6
- 229910052751 metal Inorganic materials 0.000 abstract description 4
- 239000002184 metal Substances 0.000 abstract description 4
- 238000000151 deposition Methods 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 description 38
- 238000000576 coating method Methods 0.000 description 38
- 239000007788 liquid Substances 0.000 description 22
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 20
- 238000007747 plating Methods 0.000 description 20
- 230000000694 effects Effects 0.000 description 17
- 239000000463 material Substances 0.000 description 13
- 229910052759 nickel Inorganic materials 0.000 description 11
- 238000009713 electroplating Methods 0.000 description 10
- 239000000203 mixture Substances 0.000 description 10
- 238000012360 testing method Methods 0.000 description 10
- 239000002131 composite material Substances 0.000 description 7
- 150000001413 amino acids Chemical class 0.000 description 6
- 239000002351 wastewater Substances 0.000 description 6
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 6
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 5
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 5
- 229910052725 zinc Inorganic materials 0.000 description 5
- 239000011701 zinc Substances 0.000 description 5
- 208000037656 Respiratory Sounds Diseases 0.000 description 4
- 125000001931 aliphatic group Chemical group 0.000 description 4
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 4
- 239000004327 boric acid Substances 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 239000001211 (E)-4-phenylbut-3-en-2-one Substances 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 3
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000013543 active substance Substances 0.000 description 3
- -1 aromatic carboxylic acids Chemical class 0.000 description 3
- 229930008407 benzylideneacetone Natural products 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000008151 electrolyte solution Substances 0.000 description 3
- 230000003628 erosive effect Effects 0.000 description 3
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 description 3
- 239000001632 sodium acetate Substances 0.000 description 3
- 235000017281 sodium acetate Nutrition 0.000 description 3
- BWHOZHOGCMHOBV-BQYQJAHWSA-N trans-benzylideneacetone Chemical compound CC(=O)\C=C\C1=CC=CC=C1 BWHOZHOGCMHOBV-BQYQJAHWSA-N 0.000 description 3
- 235000005074 zinc chloride Nutrition 0.000 description 3
- 239000011592 zinc chloride Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- BSYNRYMUTXBXSQ-UHFFFAOYSA-N Aspirin Chemical compound CC(=O)OC1=CC=CC=C1C(O)=O BSYNRYMUTXBXSQ-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 229960001138 acetylsalicylic acid Drugs 0.000 description 2
- 238000005275 alloying Methods 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- NAOLWIGVYRIGTP-UHFFFAOYSA-N 1,3,5-trihydroxyanthracene-9,10-dione Chemical compound C1=CC(O)=C2C(=O)C3=CC(O)=CC(O)=C3C(=O)C2=C1 NAOLWIGVYRIGTP-UHFFFAOYSA-N 0.000 description 1
- 229910001208 Crucible steel Inorganic materials 0.000 description 1
- 229910000760 Hardened steel Inorganic materials 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical group [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000013016 damping Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- ILHIHKRJJMKBEE-UHFFFAOYSA-N hydroperoxyethane Chemical compound CCOO ILHIHKRJJMKBEE-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical class OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 235000012976 tarts Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/56—Electroplating: Baths therefor from solutions of alloys
- C25D3/565—Electroplating: Baths therefor from solutions of alloys containing more than 50% by weight of zinc
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/02—Anodisation
- C25D11/04—Anodisation of aluminium or alloys based thereon
- C25D11/06—Anodisation of aluminium or alloys based thereon characterised by the electrolytes used
- C25D11/10—Anodisation of aluminium or alloys based thereon characterised by the electrolytes used containing organic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electroplating And Plating Baths Therefor (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10146559A DE10146559A1 (de) | 2001-09-21 | 2001-09-21 | Verfahren zur Abscheidung einer Zink-Nickel-Legierung aus einem Elektrolyten |
| DE10146559.9 | 2001-09-21 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1410602A CN1410602A (zh) | 2003-04-16 |
| CN1291068C true CN1291068C (zh) | 2006-12-20 |
Family
ID=7699793
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB021424853A Expired - Lifetime CN1291068C (zh) | 2001-09-21 | 2002-09-20 | 从电解质中析出锌镍合金的方法 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US20030085130A1 (enrdf_load_stackoverflow) |
| EP (1) | EP1295967A3 (enrdf_load_stackoverflow) |
| JP (1) | JP4307810B2 (enrdf_load_stackoverflow) |
| KR (1) | KR100556604B1 (enrdf_load_stackoverflow) |
| CN (1) | CN1291068C (enrdf_load_stackoverflow) |
| DE (1) | DE10146559A1 (enrdf_load_stackoverflow) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006128154A1 (en) * | 2005-05-26 | 2006-11-30 | Pavco, Inc. | Trivalent chromium conversion coating and method of application thereof |
| CN101273157A (zh) * | 2005-06-20 | 2008-09-24 | 百富可公司 | 锌镍合金电镀系统 |
| ES2553730T3 (es) * | 2006-07-13 | 2015-12-11 | Enthone, Incorporated | Composición de electrolito y procedimiento para la deposición de una capa de aleación de zinc-níquel sobre un sustrato de hierro fundido o de acero fundido |
| DE102006035233A1 (de) * | 2006-07-26 | 2008-01-31 | Mahle International Gmbh | Galvanische Oberflächenbeschichtung eines Bauteils |
| US20100096274A1 (en) * | 2008-10-17 | 2010-04-22 | Rowan Anthony J | Zinc alloy electroplating baths and processes |
| DE202008014947U1 (de) | 2008-11-11 | 2009-03-12 | Enthone Inc., West Haven | Galvanisches Bad zur Abscheidung von zinkhaltigen Schichten |
| DE102008056776A1 (de) | 2008-11-11 | 2010-05-12 | Enthone Inc., West Haven | Galvanisches Bad und Verfahren zur Abscheidung von zinkhaltigen Schichten |
| DE102008058086B4 (de) * | 2008-11-18 | 2013-05-23 | Atotech Deutschland Gmbh | Verfahren und Vorrichtung zur Reinigung von galvanischen Bädern zur Abscheidung von Metallen |
| KR101183255B1 (ko) | 2012-04-13 | 2012-09-14 | 서영호 | 주석-아연 합금 도금액 |
| JP5740616B1 (ja) | 2014-09-25 | 2015-06-24 | ユケン工業株式会社 | 酸性亜鉛合金めっき浴用添加剤、酸性亜鉛合金めっき浴および亜鉛合金めっき部材の製造方法 |
| PL3015571T3 (pl) | 2014-10-27 | 2018-10-31 | Atotech Deutschland Gmbh | Kwasowa kompozycja kąpieli galwanicznej do powlekania cynkiem i stopem cynkowo- niklowym oraz sposób powlekania galwanicznego |
| PL3461933T3 (pl) | 2017-09-28 | 2020-03-31 | Atotech Deutschland Gmbh | Sposób elektrolitycznego osadzania warstwy stopu cynkowo-niklowego co najmniej na podłożu przeznaczonym do obróbki |
| EP3666929A1 (de) * | 2018-12-12 | 2020-06-17 | Dr.Ing. Max Schlötter GmbH & Co. KG | Borsäure- und ammoniumfreier zink-elektrolyt zur galvanischen abscheidung von zink-überzügen |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4388160A (en) * | 1980-02-20 | 1983-06-14 | Rynne George B | Zinc-nickel alloy electroplating process |
| US4515663A (en) * | 1984-01-09 | 1985-05-07 | Omi International Corporation | Acid zinc and zinc alloy electroplating solution and process |
| US4543166A (en) * | 1984-10-01 | 1985-09-24 | Omi International Corporation | Zinc-alloy electrolyte and process |
| DE3534147A1 (de) * | 1985-09-25 | 1987-04-02 | Elektro Brite Gmbh | Chloridhaltiges bad zur galvanischen abscheidung einer zink-nickel-legierung auf eisen |
| US4889602B1 (en) * | 1986-04-14 | 1995-11-14 | Dipsol Chem | Electroplating bath and method for forming zinc-nickel alloy coating |
| JPH01219188A (ja) * | 1988-02-26 | 1989-09-01 | Okuno Seiyaku Kogyo Kk | 亜鉛−ニッケル合金めっき浴 |
| US4832802A (en) * | 1988-06-10 | 1989-05-23 | Mcgean-Rohco, Inc. | Acid zinc-nickel plating baths and methods for electrodepositing bright and ductile zinc-nickel alloys and additive composition therefor |
| JP3329572B2 (ja) * | 1994-04-15 | 2002-09-30 | 福田金属箔粉工業株式会社 | 印刷回路用銅箔およびその表面処理方法 |
| KR100276701B1 (ko) * | 1994-08-31 | 2001-01-15 | 에모토 간지 | 전기아연-니켈 합금 도금액 및 그 합금 도금액을 이용한 강판의 제조방법 |
| JP2761470B2 (ja) * | 1994-08-31 | 1998-06-04 | 川崎製鉄株式会社 | 電気亜鉛−ニッケル合金めっき液およびめっき鋼板の製造方法 |
| US6238542B1 (en) * | 1998-09-15 | 2001-05-29 | Thomas Helden | Water soluble brighteners for zinc and zinc alloy electrolytes |
| ES2237003T3 (es) * | 1998-09-15 | 2005-07-16 | Lpw-Chemie Gmbh | Procedimiento para la deposicion galvanica de precipitados de cinc y/o de precipitados de aleaciones de cinc. |
-
2001
- 2001-09-21 DE DE10146559A patent/DE10146559A1/de not_active Withdrawn
-
2002
- 2002-09-19 EP EP02020926A patent/EP1295967A3/de not_active Withdrawn
- 2002-09-19 KR KR1020020057221A patent/KR100556604B1/ko not_active Expired - Lifetime
- 2002-09-20 CN CNB021424853A patent/CN1291068C/zh not_active Expired - Lifetime
- 2002-09-20 JP JP2002274993A patent/JP4307810B2/ja not_active Expired - Lifetime
- 2002-09-23 US US10/252,495 patent/US20030085130A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| EP1295967A3 (de) | 2005-05-11 |
| JP2003105585A (ja) | 2003-04-09 |
| DE10146559A1 (de) | 2003-04-10 |
| JP4307810B2 (ja) | 2009-08-05 |
| CN1410602A (zh) | 2003-04-16 |
| EP1295967A2 (de) | 2003-03-26 |
| US20030085130A1 (en) | 2003-05-08 |
| KR20030025876A (ko) | 2003-03-29 |
| KR100556604B1 (ko) | 2006-03-06 |
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|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CX01 | Expiry of patent term |
Granted publication date: 20061220 |
|
| CX01 | Expiry of patent term |