CN1273498C - 制备高分子量异丁烯聚合物的方法 - Google Patents

制备高分子量异丁烯聚合物的方法 Download PDF

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Publication number
CN1273498C
CN1273498C CNB028039823A CN02803982A CN1273498C CN 1273498 C CN1273498 C CN 1273498C CN B028039823 A CNB028039823 A CN B028039823A CN 02803982 A CN02803982 A CN 02803982A CN 1273498 C CN1273498 C CN 1273498C
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China
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substituted
group
groups
hydrocarbyl
halocarbonyl
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Expired - Fee Related
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CNB028039823A
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English (en)
Chinese (zh)
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CN1487955A (zh
Inventor
M·C·拜尔德
M·J·德雷维特
K·R·库马
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Bayer AG
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/08—Butenes
    • C08F10/10—Isobutene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/08—Isoprene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/08—Butenes
    • C08F110/10—Isobutene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/08—Butenes
    • C08F210/10—Isobutene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
CNB028039823A 2001-01-24 2002-01-24 制备高分子量异丁烯聚合物的方法 Expired - Fee Related CN1273498C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CA2,332,203 2001-01-24
CA002332203A CA2332203A1 (en) 2001-01-24 2001-01-24 Process for making high molecular weight isobutylene polymers

Publications (2)

Publication Number Publication Date
CN1487955A CN1487955A (zh) 2004-04-07
CN1273498C true CN1273498C (zh) 2006-09-06

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CNB028039823A Expired - Fee Related CN1273498C (zh) 2001-01-24 2002-01-24 制备高分子量异丁烯聚合物的方法

Country Status (8)

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US (2) US20040063879A1 (enExample)
EP (1) EP1355953B1 (enExample)
JP (1) JP2004520467A (enExample)
CN (1) CN1273498C (enExample)
CA (1) CA2332203A1 (enExample)
DE (1) DE60238816D1 (enExample)
RU (1) RU2298015C2 (enExample)
WO (1) WO2002059161A1 (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103588918A (zh) * 2013-11-07 2014-02-19 济南开发区星火科学技术研究院 一种丁基橡胶的制备方法

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006009942A1 (en) 2004-06-21 2006-01-26 Exxonmobil Chemical Patents Inc. Polymerization process
US7858736B2 (en) 2004-06-21 2010-12-28 Exxonmobil Chemical Patents Inc. Polymer recovery method
US7981984B2 (en) 2004-06-21 2011-07-19 Exxonmobil Chemical Patents Inc. Polymerization process
WO2006009945A1 (en) 2004-06-21 2006-01-26 Exxonmobil Chemical Patents Inc. Impact copolymers
US7799882B2 (en) 2005-06-20 2010-09-21 Exxonmobil Chemical Patents Inc. Polymerization process
KR20120024705A (ko) * 2009-05-29 2012-03-14 제이엑스 닛코닛세키에너지주식회사 이소부티렌계 중합체 및 이의 제조 방법
CN102597014B (zh) * 2009-09-25 2015-05-13 中国石油化工股份有限公司 阳离子聚合引发体系及聚合方法
US10174138B1 (en) * 2018-01-25 2019-01-08 University Of Massachusetts Method for forming highly reactive olefin functional polymers

Family Cites Families (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4910321A (en) * 1985-06-20 1990-03-20 University Of Akron Living catalysts, complexes and polymers therefrom
US4929683A (en) * 1986-08-25 1990-05-29 University Of Akron Living polymerization of olefin to end-functionalized polymers
US5384299A (en) * 1987-01-30 1995-01-24 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US5241025A (en) * 1987-01-30 1993-08-31 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US5621126A (en) * 1987-01-30 1997-04-15 Exxon Chemical Patents Inc. Monocyclopentadienyl metal compounds for ethylene-α-olefin-copolymer production catalysts
US5408017A (en) * 1987-01-30 1995-04-18 Exxon Chemical Patents Inc. High temperature polymerization process using ionic catalysts to produce polyolefins
PL276385A1 (en) * 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
US5153157A (en) * 1987-01-30 1992-10-06 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
USRE37788E1 (en) * 1987-01-30 2002-07-09 Exxon Chemical Patents, Inc. Monocyclopentadienyl metal compounds for ethylene-α-olefin-copolymer production catalysts
US5198401A (en) * 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US5391629A (en) * 1987-01-30 1995-02-21 Exxon Chemical Patents Inc. Block copolymers from ionic catalysts
US5763549A (en) * 1989-10-10 1998-06-09 Fina Technology, Inc. Cationic metallocene catalysts based on organoaluminum anions
US5387568A (en) * 1989-10-30 1995-02-07 Fina Technology, Inc. Preparation of metallocene catalysts for polymerization of olefins
US6294625B1 (en) * 1990-03-20 2001-09-25 Exxonmobil Chemical Patents Inc. Catalyst system of enhanced productivity and its use in polymerization process
US5801113A (en) * 1990-06-22 1998-09-01 Exxon Chemical Patents, Inc. Polymerization catalyst systems, their production and use
US5279119A (en) * 1991-02-25 1994-01-18 Wickes Manufacturing Company Hydraulic lock and bypass for vehicle hydraulic system
US5296433A (en) * 1992-04-14 1994-03-22 Minnesota Mining And Manufacturing Company Tris(pentafluorophenyl)borane complexes and catalysts derived therefrom
US6008307A (en) * 1994-04-28 1999-12-28 Exxon Chemical Patents Inc Process for producing olefin polymers using cationic catalysts
US6291389B1 (en) * 1994-04-28 2001-09-18 Exxonmobil Chemical Patents Inc. Cationic polymerization catalysts
US5439996A (en) * 1994-06-01 1995-08-08 Queen's University At Kingston Synthesis of polymers of vinyl ethers, 1,5-hexadiene and N-vinylcarbazole
US5448001A (en) * 1994-10-07 1995-09-05 Queen's University At Kingston Polymerization of iso-butylene
JPH11501342A (ja) * 1995-03-01 1999-02-02 ミネソタ マイニング アンド マニュファクチャリング カンパニー トリス（ペンタフルオロフェニル）ボレート錯体およびそれらから誘導された触媒
US5677405A (en) * 1995-05-24 1997-10-14 The B.F. Goodrich Company Homopolymers and copolymers of cationically polymerizable monomers and method of their preparation
WO2000004061A1 (en) * 1998-07-17 2000-01-27 Bayer Inc. Process for polymerizing cationically polymerizable olefin
US6506206B1 (en) * 1998-12-31 2003-01-14 Depuy Orthopaedics, Inc. Gel tourniquet cuff

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103588918A (zh) * 2013-11-07 2014-02-19 济南开发区星火科学技术研究院 一种丁基橡胶的制备方法
CN103588918B (zh) * 2013-11-07 2016-03-30 济南开发区星火科学技术研究院 一种丁基橡胶的制备方法

Also Published As

Publication number Publication date
US20080275201A1 (en) 2008-11-06
JP2004520467A (ja) 2004-07-08
WO2002059161A1 (en) 2002-08-01
US20040063879A1 (en) 2004-04-01
CA2332203A1 (en) 2002-07-24
CN1487955A (zh) 2004-04-07
RU2298015C2 (ru) 2007-04-27
EP1355953B1 (en) 2011-01-05
HK1063640A1 (en) 2005-01-07
EP1355953A1 (en) 2003-10-29
DE60238816D1 (de) 2011-02-17
RU2003125873A (ru) 2005-02-20

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