CN1227229A - 热稳定性改进的α-取代的丙烯酸酯接枝共聚物 - Google Patents
热稳定性改进的α-取代的丙烯酸酯接枝共聚物 Download PDFInfo
- Publication number
- CN1227229A CN1227229A CN99102451A CN99102451A CN1227229A CN 1227229 A CN1227229 A CN 1227229A CN 99102451 A CN99102451 A CN 99102451A CN 99102451 A CN99102451 A CN 99102451A CN 1227229 A CN1227229 A CN 1227229A
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- CN
- China
- Prior art keywords
- olefin
- propylene
- alpha
- ethene
- carbon atom
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
- C08F265/06—Polymerisation of acrylate or methacrylate esters on to polymers thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
- C08F255/04—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms on to ethene-propene copolymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C08F255/08—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having four or more carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F263/00—Macromolecular compounds obtained by polymerising monomers on to polymers of esters of unsaturated alcohols with saturated acids as defined in group C08F18/00
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Graft Or Block Polymers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Polymerisation Methods In General (AREA)
- Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
Abstract
Description
聚合物组成(重量%) | 在下列温度(℃)下的重量损失 | |||||
1% | 2% | 3% | 4% | 5% | 10% | |
MMA(100%) | 228 | 289 | 305 | 315 | 322 | 346 |
MMA/MeAc(4.4%) | 264 | 296 | 309 | 321 | 333 | 360 |
MMA/MAA(1%) | 294 | 316 | 331 | 343 | 350 | 371 |
MMA/MAA(2%) | 302 | 329 | 342 | 351 | 357 | 375 |
MMA/MAA(3%) | 300 | 329 | 346 | 356 | 363 | 381 |
MMA/MAA(5%) | 320 | 345 | 356 | 363 | 368 | 383 |
MMA/MAA(10%) | 315 | 347 | 360 | 368 | 374 | NA |
MMA/MAA(20%) | 313 | 347 | 363 | 373 | 379 | NA |
试样 | 1 | 2 | 3 | 4 | 5 | 6 | 对照 |
MMA/MAA(1%)(重量%) | 38.6 | ||||||
MMA/MAA(2%)(重量%) | 38.6 | ||||||
MMA/MAA(3%)(重量%) | 38.6 | ||||||
MMA/MAA(5%)(重量%) | 38.6 | ||||||
MMA/MAA(10%)(重量%) | 38.6 | ||||||
MMA/MAA(20%)(重量%) | 38.6 | ||||||
MMA/MeAc(4.4%)(重量%) | 38.6 | ||||||
BMWD PP(重量%) | 42.9 | 42.9 | 42.9 | 42.9 | 42.9 | 42.9 | 42.9 |
Engage 8150(重量%) | 14.55 | 14.55 | 14.55 | 14.55 | 14.55 | 14.55 | 14.55 |
Pationic 1240(重量%) | 0.05 | 0.05 | 0.05 | 0.05 | 0.05 | 0.05 | 0.05 |
Irganox LC20 FF(重量%) | 0.20 | 0.20 | 0.20 | 0.20 | 0.20 | 0.20 | 0.20 |
Tinuvin 328(重量%) | 0.30 | 0.30 | 0.30 | 0.30 | 0.30 | 0.30 | 0.30 |
Tinuvin 770(重量%) | 0.24 | 0.24 | 0.24 | 0.24 | 0.24 | 0.24 | 0.24 |
Chimmasorb 119(重量%) | 0.24 | 0.24 | 0.24 | 0.24 | 0.24 | 0.24 | 0.24 |
黑色颜料(重量%) | 2.91 | 2.91 | 2.91 | 2.91 | 2.91 | 2.91 | 2.91 |
悬臂梁式冲击(ft.lb/in) | 13.8 | 13 | 12.7 | 13.7 | 13.4 | 8.7 | 13.2 |
拉伸强度(psi) | 4371 | 4427 | 4354 | 4435 | 4328 | 4320 | 4360 |
屈服伸长率(%) | 6.12 | 5.9 | 5.9 | 5.7 | 5.7 | 5.6 | 6.23 |
断裂伸长率w/伸长计(%) | 173 | 179 | 185 | 85 | 134 | 187 | 168 |
熔合线强度(psi) | 3456 | 3482 | 3369 | 3484 | 3417 | 3515 | 3310 |
在熔合线的断裂伸长率(%) | 5.5 | 5.5 | 5 | 5.4 | 5.5 | 6.1 | 4.9 |
保留的强度(%) | 79.1 | 78.7 | 77.4 | 78.6 | 79.0 | 81.4 | 75.9 |
在0.05”/分的挠曲模量(kpsi) | 213.8 | 217.2 | 214.6 | 222.6 | 217.2 | 213.9 | 214.7 |
在0.05”/分的弯曲强度(psi) | 6012 | 6117 | 6077 | 6345 | 6191 | 6108 | 6067 |
在66psi(1/8”)的H.D.T.(℃) | 97.6 | 98.2 | 98.2 | 99.4 | 102 | 102 | 92.1 |
在264psi(1/8”)的H.D.T.(℃) | 59 | 59.4 | 59.9 | 60.3 | 59.9 | 59.6 | 59.2 |
熔体流动速率(3.8kg,230℃) | 6.4 | 6.4 | 6.2 | 5 | 5.2 | 5.8 | 10.2 |
MMA/MAA中的MAA(重量%) | 总pph | Mw(103) | Mn(103) | XSRT(重量%) | 接枝效率(%) |
0 | 41.8 | 264 | 113 | 22.9 | 22.3 |
1 | 46.1 | 239 | 104 | 24.0 | 24.5 |
2 | 45.6 | 239 | 103 | 21.7 | 30.7 |
3 | 45.0 | 227 | 107 | 21.0 | 32.3 |
5 | 42.4 | 225 | 80 | 22.5 | 24.4 |
MMA/MeAc(4.4%) | 50.1 | 124 | 48 | 28.5 | 14.5 |
Claims (13)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/032,479 | 1998-02-27 | ||
US09/032,479 US6046273A (en) | 1998-02-27 | 1998-02-27 | Thermal stability of alpha-substituted acrylate graft copolymers |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1227229A true CN1227229A (zh) | 1999-09-01 |
CN1187384C CN1187384C (zh) | 2005-02-02 |
Family
ID=21865149
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB991024516A Expired - Fee Related CN1187384C (zh) | 1998-02-27 | 1999-02-26 | 热稳定性改进的α-取代的丙烯酸酯接枝共聚物 |
Country Status (12)
Country | Link |
---|---|
US (1) | US6046273A (zh) |
EP (1) | EP0939089B1 (zh) |
JP (1) | JPH11292939A (zh) |
KR (1) | KR19990072977A (zh) |
CN (1) | CN1187384C (zh) |
AT (1) | ATE276290T1 (zh) |
AU (1) | AU751574B2 (zh) |
BR (1) | BR9900840A (zh) |
CA (1) | CA2262471C (zh) |
DE (1) | DE69920077T2 (zh) |
TW (1) | TW552273B (zh) |
ZA (1) | ZA991541B (zh) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE1012637A3 (fr) | 1999-04-29 | 2001-01-09 | Solvay | Polyolefines et procede pour leur fabrication. |
US6806319B2 (en) * | 2001-08-08 | 2004-10-19 | Basell Polioelfine Italia S.P.A. | Retarding the thermal degradation of polymers using unsaturated aliphatic compounds |
US6777484B2 (en) | 2001-08-08 | 2004-08-17 | Basell Poliolefine Italia S.P.A. | Polypropylene graft copolymer/fluorinated polyolefin blends |
WO2004046214A2 (en) | 2002-10-15 | 2004-06-03 | Exxonmobil Chemical Patents Inc. | Multiple catalyst system for olefin polymerization and polymers produced therefrom |
US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5229456A (en) * | 1988-03-29 | 1993-07-20 | Rohm And Haas Company | Graft copolymers and blends thereof with polyolefins |
IT1230133B (it) * | 1989-04-28 | 1991-10-14 | Himont Inc | Composizioni polipropileniche plasto-elastiche |
CA2025393A1 (en) * | 1989-09-27 | 1991-03-28 | Newman Bortnick | Graft copolymer impact modifier |
CA2031406C (en) * | 1989-12-21 | 2002-05-28 | Paolo Galli | Graft copolymers of polyolefins and a method of producing same |
US5140074A (en) * | 1990-01-26 | 1992-08-18 | Himont Incorporated | Method of producing olefin polymer graft copolymers |
US5212246A (en) * | 1990-09-28 | 1993-05-18 | Himont Incorporated | Olefin polymer films |
IL99498A0 (en) * | 1990-10-05 | 1992-08-18 | Himont Inc | Blends of graft copolymers of propylene polymer material and of olefinic rubber material |
EP0560496A1 (en) * | 1992-02-24 | 1993-09-15 | Rohm And Haas Company | Processing of polar polymers and mixtures obtained thereby |
US5310794A (en) * | 1992-03-31 | 1994-05-10 | Himont Incorporated | Theromoplastic blends containing graft copolymers of polyacrylates as impact modifiers |
JP3279714B2 (ja) * | 1993-04-09 | 2002-04-30 | 鐘淵化学工業株式会社 | ポリオレフィン系樹脂組成物およびその製造法、ならびにそれからなる成形体 |
US5409992A (en) * | 1994-02-28 | 1995-04-25 | Himont Incorporated | Calenderable blends containing broad molecular weight distribution propylene polymer material |
US6252005B1 (en) * | 1998-08-07 | 2001-06-26 | Montell Technology Company Bv | Thermal oxidative stability of acrylic polymers |
-
1998
- 1998-02-27 US US09/032,479 patent/US6046273A/en not_active Expired - Fee Related
-
1999
- 1999-02-19 EP EP99103297A patent/EP0939089B1/en not_active Expired - Lifetime
- 1999-02-19 AT AT99103297T patent/ATE276290T1/de not_active IP Right Cessation
- 1999-02-19 DE DE69920077T patent/DE69920077T2/de not_active Expired - Fee Related
- 1999-02-22 CA CA002262471A patent/CA2262471C/en not_active Expired - Fee Related
- 1999-02-25 JP JP11048360A patent/JPH11292939A/ja active Pending
- 1999-02-25 ZA ZA9901541A patent/ZA991541B/xx unknown
- 1999-02-26 KR KR1019990006478A patent/KR19990072977A/ko active IP Right Grant
- 1999-02-26 CN CNB991024516A patent/CN1187384C/zh not_active Expired - Fee Related
- 1999-02-26 BR BR9900840-8A patent/BR9900840A/pt active Search and Examination
- 1999-02-26 TW TW088102901A patent/TW552273B/zh active
- 1999-02-26 AU AU18454/99A patent/AU751574B2/en not_active Ceased
Also Published As
Publication number | Publication date |
---|---|
AU1845499A (en) | 1999-09-09 |
TW552273B (en) | 2003-09-11 |
US6046273A (en) | 2000-04-04 |
CA2262471C (en) | 2004-06-01 |
EP0939089B1 (en) | 2004-09-15 |
CN1187384C (zh) | 2005-02-02 |
DE69920077D1 (de) | 2004-10-21 |
DE69920077T2 (de) | 2005-09-08 |
CA2262471A1 (en) | 1999-08-27 |
KR19990072977A (ko) | 1999-09-27 |
ATE276290T1 (de) | 2004-10-15 |
EP0939089A1 (en) | 1999-09-01 |
AU751574B2 (en) | 2002-08-22 |
ZA991541B (en) | 1999-08-25 |
JPH11292939A (ja) | 1999-10-26 |
BR9900840A (pt) | 1999-12-21 |
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Legal Events
Date | Code | Title | Description |
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C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
ASS | Succession or assignment of patent right |
Owner name: CROMPTON CORP. Free format text: FORMER OWNER: BASELL POLIOLEFINE ITALIA SP Effective date: 20050812 Owner name: BASELL POLIOLEFINE ITALIA SP Free format text: FORMER OWNER: BASELL TECHNOLOGY CO., LTD. Effective date: 20050812 Owner name: BASELL TECHNOLOGY CO., LTD. Free format text: FORMER OWNER: MONTELL NORTH AMERICA INC. Effective date: 20050812 |
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C41 | Transfer of patent application or patent right or utility model | ||
TR01 | Transfer of patent right |
Effective date of registration: 20050812 Address after: American Connecticut Patentee after: CROMPTON Corp. Address before: Milan Italy Patentee before: BASELL POLIOLEFINE ITALIA S.P.A. Effective date of registration: 20050812 Address after: Milan Italy Patentee after: BASELL POLIOLEFINE ITALIA S.P.A. Address before: Holland Hoofddorp Patentee before: BASELL TECHNOLOGY Co.,B.V. Effective date of registration: 20050812 Address after: Holland Hoofddorp Patentee after: BASELL TECHNOLOGY Co.,B.V. Address before: Delaware Patentee before: Montell North America Inc. |
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C19 | Lapse of patent right due to non-payment of the annual fee | ||
CF01 | Termination of patent right due to non-payment of annual fee |