CN1226817A - 染发组合物及方法 - Google Patents
染发组合物及方法 Download PDFInfo
- Publication number
- CN1226817A CN1226817A CN98800624A CN98800624A CN1226817A CN 1226817 A CN1226817 A CN 1226817A CN 98800624 A CN98800624 A CN 98800624A CN 98800624 A CN98800624 A CN 98800624A CN 1226817 A CN1226817 A CN 1226817A
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- CN
- China
- Prior art keywords
- alkyl
- compositions
- halogen
- carbon atom
- hydrogen
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract description 119
- 239000000118 hair dye Substances 0.000 title claims abstract description 16
- 238000000034 method Methods 0.000 title claims abstract description 10
- -1 2-hydroxyphenyl benzotriazole compound Chemical class 0.000 claims abstract description 87
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 29
- 239000004094 surface-active agent Substances 0.000 claims abstract description 27
- 239000000975 dye Substances 0.000 claims abstract description 15
- 230000001590 oxidative effect Effects 0.000 claims abstract description 13
- 230000003647 oxidation Effects 0.000 claims abstract description 9
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 9
- 229910052799 carbon Inorganic materials 0.000 claims description 47
- 125000000217 alkyl group Chemical group 0.000 claims description 46
- 229910052739 hydrogen Inorganic materials 0.000 claims description 40
- 239000001257 hydrogen Substances 0.000 claims description 33
- 229910052736 halogen Inorganic materials 0.000 claims description 28
- 150000002367 halogens Chemical class 0.000 claims description 28
- 239000007822 coupling agent Substances 0.000 claims description 19
- YHCGGLXPGFJNCO-UHFFFAOYSA-N 2-(2H-benzotriazol-4-yl)phenol Chemical compound OC1=CC=CC=C1C1=CC=CC2=C1N=NN2 YHCGGLXPGFJNCO-UHFFFAOYSA-N 0.000 claims description 18
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 18
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 17
- 239000011734 sodium Substances 0.000 claims description 16
- 239000003945 anionic surfactant Substances 0.000 claims description 13
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 13
- 229920001577 copolymer Polymers 0.000 claims description 12
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 11
- 125000001931 aliphatic group Chemical group 0.000 claims description 11
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 11
- 125000002091 cationic group Chemical group 0.000 claims description 10
- 125000003342 alkenyl group Chemical group 0.000 claims description 9
- 229920006318 anionic polymer Polymers 0.000 claims description 8
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 8
- 239000003153 chemical reaction reagent Substances 0.000 claims description 8
- 239000000047 product Substances 0.000 claims description 8
- 229910052708 sodium Inorganic materials 0.000 claims description 8
- 239000002280 amphoteric surfactant Substances 0.000 claims description 7
- 125000006704 (C5-C6) cycloalkyl group Chemical group 0.000 claims description 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 6
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 5
- 241001597008 Nomeidae Species 0.000 claims description 5
- 150000001450 anions Chemical class 0.000 claims description 5
- 239000007859 condensation product Substances 0.000 claims description 5
- 239000010685 fatty oil Substances 0.000 claims description 5
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 4
- 241000144217 Limnanthes alba Species 0.000 claims description 4
- 229910019142 PO4 Inorganic materials 0.000 claims description 4
- 125000003545 alkoxy group Chemical group 0.000 claims description 4
- GQOKIYDTHHZSCJ-UHFFFAOYSA-M dimethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](C)(C)CC=C GQOKIYDTHHZSCJ-UHFFFAOYSA-M 0.000 claims description 4
- 125000004185 ester group Chemical group 0.000 claims description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 4
- PGFXOWRDDHCDTE-UHFFFAOYSA-N hexafluoropropylene oxide Chemical group FC(F)(F)C1(F)OC1(F)F PGFXOWRDDHCDTE-UHFFFAOYSA-N 0.000 claims description 4
- 229920001519 homopolymer Polymers 0.000 claims description 4
- 239000010452 phosphate Chemical group 0.000 claims description 4
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 4
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 4
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 3
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 3
- 125000001118 alkylidene group Chemical group 0.000 claims description 3
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 3
- 238000011010 flushing procedure Methods 0.000 claims description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical group [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 3
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 2
- BMOKHTQIBPRXSL-UHFFFAOYSA-N 2h-benzotriazole;sodium Chemical compound [Na].C1=CC=CC2=NNN=C21 BMOKHTQIBPRXSL-UHFFFAOYSA-N 0.000 claims description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical group CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 2
- 229920001774 Perfluoroether Polymers 0.000 claims description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 2
- 150000008051 alkyl sulfates Chemical class 0.000 claims description 2
- 229920003086 cellulose ether Polymers 0.000 claims description 2
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 2
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 125000005010 perfluoroalkyl group Chemical group 0.000 claims description 2
- 125000003884 phenylalkyl group Chemical group 0.000 claims description 2
- 229910052700 potassium Inorganic materials 0.000 claims description 2
- 239000011591 potassium Substances 0.000 claims description 2
- 239000002888 zwitterionic surfactant Substances 0.000 claims description 2
- 150000001721 carbon Chemical group 0.000 claims 11
- 150000002431 hydrogen Chemical class 0.000 claims 7
- JZMJDSHXVKJFKW-UHFFFAOYSA-N methyl sulfate Chemical compound COS(O)(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-N 0.000 claims 1
- 125000000466 oxiranyl group Chemical group 0.000 claims 1
- 238000004043 dyeing Methods 0.000 abstract description 9
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 230000005855 radiation Effects 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 description 37
- 150000001875 compounds Chemical class 0.000 description 23
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 13
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 11
- 239000003921 oil Substances 0.000 description 10
- 235000019198 oils Nutrition 0.000 description 10
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 9
- 229960003237 betaine Drugs 0.000 description 9
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 9
- 150000003839 salts Chemical class 0.000 description 9
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 8
- 235000014113 dietary fatty acids Nutrition 0.000 description 8
- 239000000194 fatty acid Substances 0.000 description 8
- 229930195729 fatty acid Natural products 0.000 description 8
- 241001502050 Acis Species 0.000 description 7
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 7
- 239000007788 liquid Substances 0.000 description 7
- 229910052710 silicon Inorganic materials 0.000 description 7
- 239000010703 silicon Substances 0.000 description 7
- PLIKAWJENQZMHA-UHFFFAOYSA-N 4-aminophenol Chemical compound NC1=CC=C(O)C=C1 PLIKAWJENQZMHA-UHFFFAOYSA-N 0.000 description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 150000001412 amines Chemical class 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- 150000004665 fatty acids Chemical class 0.000 description 6
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 6
- 229920001296 polysiloxane Polymers 0.000 description 6
- CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical class NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 description 5
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 5
- 235000019993 champagne Nutrition 0.000 description 5
- 238000004040 coloring Methods 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 210000000582 semen Anatomy 0.000 description 5
- 229910052709 silver Inorganic materials 0.000 description 5
- 239000004332 silver Substances 0.000 description 5
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 239000000908 ammonium hydroxide Substances 0.000 description 4
- 150000001768 cations Chemical class 0.000 description 4
- 238000005660 chlorination reaction Methods 0.000 description 4
- 239000004205 dimethyl polysiloxane Substances 0.000 description 4
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 4
- 238000005562 fading Methods 0.000 description 4
- 239000000796 flavoring agent Substances 0.000 description 4
- 235000013355 food flavoring agent Nutrition 0.000 description 4
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 description 4
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 4
- 159000000000 sodium salts Chemical class 0.000 description 4
- AIDLAEPHWROGFI-UHFFFAOYSA-N 2-methylbenzene-1,3-dicarboxylic acid Chemical compound CC1=C(C(O)=O)C=CC=C1C(O)=O AIDLAEPHWROGFI-UHFFFAOYSA-N 0.000 description 3
- DHHFDKNIEVKVKS-MVUYWVKGSA-N Betanin Natural products O=C(O)[C@@H]1NC(C(=O)O)=C/C(=C\C=[N+]/2\[C@@H](C(=O)[O-])Cc3c\2cc(O)c(O[C@H]2[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O2)c3)/C1 DHHFDKNIEVKVKS-MVUYWVKGSA-N 0.000 description 3
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 3
- 229910004298 SiO 2 Inorganic materials 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229930006000 Sucrose Natural products 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 150000001340 alkali metals Chemical class 0.000 description 3
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 3
- 150000001342 alkaline earth metals Chemical class 0.000 description 3
- 150000001336 alkenes Chemical class 0.000 description 3
- 125000005466 alkylenyl group Chemical group 0.000 description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 3
- 235000001014 amino acid Nutrition 0.000 description 3
- 150000001413 amino acids Chemical class 0.000 description 3
- 125000004103 aminoalkyl group Chemical group 0.000 description 3
- 125000000129 anionic group Chemical group 0.000 description 3
- 230000002421 anti-septic effect Effects 0.000 description 3
- 239000001654 beetroot red Substances 0.000 description 3
- 235000012677 beetroot red Nutrition 0.000 description 3
- 235000002185 betanin Nutrition 0.000 description 3
- 229920006317 cationic polymer Polymers 0.000 description 3
- 229940096386 coconut alcohol Drugs 0.000 description 3
- 229940008099 dimethicone Drugs 0.000 description 3
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 239000003995 emulsifying agent Substances 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 239000008103 glucose Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 229920001282 polysaccharide Polymers 0.000 description 3
- 239000005017 polysaccharide Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000000344 soap Substances 0.000 description 3
- 239000005720 sucrose Substances 0.000 description 3
- 125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 description 3
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
- JECYNCQXXKQDJN-UHFFFAOYSA-N 2-(2-methylhexan-2-yloxymethyl)oxirane Chemical compound CCCCC(C)(C)OCC1CO1 JECYNCQXXKQDJN-UHFFFAOYSA-N 0.000 description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
- ATVJXMYDOSMEPO-UHFFFAOYSA-N 3-prop-2-enoxyprop-1-ene Chemical compound C=CCOCC=C ATVJXMYDOSMEPO-UHFFFAOYSA-N 0.000 description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 2
- DHHFDKNIEVKVKS-FMOSSLLZSA-N Betanin Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1OC(C(=C1)O)=CC(C[C@H]2C([O-])=O)=C1[N+]2=C\C=C\1C=C(C(O)=O)N[C@H](C(O)=O)C/1 DHHFDKNIEVKVKS-FMOSSLLZSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-DUZGATOHSA-N D-isoascorbic acid Chemical compound OC[C@@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-DUZGATOHSA-N 0.000 description 2
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 description 2
- 239000005642 Oleic acid Substances 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical group OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 229920000289 Polyquaternium Polymers 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- LUSZGTFNYDARNI-UHFFFAOYSA-N Sesamol Chemical compound OC1=CC=C2OCOC2=C1 LUSZGTFNYDARNI-UHFFFAOYSA-N 0.000 description 2
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- PLZVEHJLHYMBBY-UHFFFAOYSA-N Tetradecylamine Chemical compound CCCCCCCCCCCCCCN PLZVEHJLHYMBBY-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 150000003863 ammonium salts Chemical group 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 125000002511 behenyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 2
- 239000012964 benzotriazole Substances 0.000 description 2
- 238000004061 bleaching Methods 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- IJOOHPMOJXWVHK-UHFFFAOYSA-N chlorotrimethylsilane Chemical compound C[Si](C)(C)Cl IJOOHPMOJXWVHK-UHFFFAOYSA-N 0.000 description 2
- 230000003750 conditioning effect Effects 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 2
- 229910000397 disodium phosphate Inorganic materials 0.000 description 2
- 235000019800 disodium phosphate Nutrition 0.000 description 2
- JMGZBMRVDHKMKB-UHFFFAOYSA-L disodium;2-sulfobutanedioate Chemical compound [Na+].[Na+].OS(=O)(=O)C(C([O-])=O)CC([O-])=O JMGZBMRVDHKMKB-UHFFFAOYSA-L 0.000 description 2
- QIVLQXGSQSFTIF-UHFFFAOYSA-M docosyl(trimethyl)azanium;methyl sulfate Chemical compound COS([O-])(=O)=O.CCCCCCCCCCCCCCCCCCCCCC[N+](C)(C)C QIVLQXGSQSFTIF-UHFFFAOYSA-M 0.000 description 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 230000037308 hair color Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 239000002563 ionic surfactant Substances 0.000 description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
- 235000010446 mineral oil Nutrition 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
- 125000002811 oleoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 229940055577 oleyl alcohol Drugs 0.000 description 2
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 2
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Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/55—Phosphorus compounds
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/494—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom
- A61K8/496—Triazoles or their condensed derivatives, e.g. benzotriazoles
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
Abstract
本发明涉及一种用于氧化性染发的组合物,按照组合物总重算,该组合物含有:0.0001—20%至少一种主要中间体和至少一种偶合剂用于形成氧化染料,0.01—10%的吸收波长范围为200至400nm的紫外射线的2-羟基苯基苯并三唑化合物,0.5—20%表面活性剂,和10—65%水;一种两组分套装产品,其中装有染发组合物和显色剂;还涉及使用该套装产品进行氧化性染发的方法。
Description
技术领域
本发明属于染发的方法及组合物领域。
背景技术
氧化性染料系统用于头发的永久染色。但是,用氧化性染料染色的头发暴露在阳光下容易褪色,且红色调特别易受影响,。因此,需要在暴露于紫外光时显示出改良的抵抗褪色的染发系统。
本发明的目的就是提供一种染发系统,它对紫外线引起的褪色具有改良的抵抗力。
发明概述
本发明涉及氧化性染发组合物,按照组合物总重算,其中包括:
约0.0001-20%(结合重量)至少一种主要中间体和至少一种偶合剂用于形成氧化染料,
约0.01-10%的吸收波长范围为200至400nm的紫外射线的2-羟基苯基苯并三唑化合物,
约0.5-20%表面活性剂,和
约10-65%水。
本发明还涉及用于氧化性染发的两组分套装产品,其中包括:
装有组合物的第一个容器,按照组合物总重算,其中含有:
约0.0001-20%(结合重量)至少一种主要中间体和至少一种偶合剂用于形成氧化染料,
约0.01-10%的吸收波长范围为200至400nm的紫外射线的2-羟基苯基苯并三唑化合物,
约0.5-20%表面活性剂,和
约10-65%水;和
装有显色剂组合物的第二个容器,按照组合物总重算,其中含有:
约0.5-45%的过氧化氢,
约0.1-10%的硅氧烷(silicone)调理剂,
约0.01-5%阴离子聚合物,和
约1-99%水。
本发明还涉及氧化性染发的方法,包括下列步骤:
a)将组合物A和组合物B混合得到的组合物施用于头发,其中组合物A按照组合物总重算含有:
约0.0001-20%(结合重量)至少一种主要中间体和至少一种偶合剂用于形成氧化染料,
约0.01-10%的吸收波长范围为200至400nm的紫外射线的2-羟基苯基苯并三唑化合物,
约0.5-20%表面活性剂,和
约10-65%水;且
组合物B含有,按照组合物总重算:
约0.5-45%的过氧化氢,
约0.1-10%的硅氧烷(silicone)调理剂,
约0.01-5%阴离子聚合物,和
约1-99%水,
b)使所述组合物在头发上保留2至60分钟,
c)用水冲洗头发。
发明详述
除非特别指明,所有提到的百分数均为重量百分数。本发明组合物的pH在7至11范围内,且组合物A优选含有65%或更少的水。主要中间体和偶合剂
本发明组合物含有0.0001-20%,优选0.001-15%,更优选0.01-10%(结合重量)的至少一种主要中间体和至少一种偶合剂。最好是,主要中间体的含量为约0.0001-5%重量且偶合剂的含量为约0.0001-5%重量。主要中间体和偶合剂是众所周知的头发染色组分,包括邻位或对位取代的氨基苯酚类或亚苯基二胺类,例如下列通式的对-亚苯基二胺:其中R1和R2各自独立地是氢,C1-6烷基,或被一个或多个羟基、甲氧基、甲基磺酰氨基、氨基羰基、糠基、未取代的苯基、或氨基取代的苯基取代的C1-C6烷基;R3和R6各自独立地为氢,C1-6烷基,C1-6烷氧基,卤素,或被一个或多个羟基取代的C1-6烷基;且R4和R5各自独立地是氢,C1-6低级烷氧基,C1-6低级烷基,或卤素。合适的主要中间体的例子有对-氨基苯酚,对-联苯酚,邻-氨基苯酚,邻-亚苯基二胺,邻-二酚,和杂环化合物。合适的主要中间体的例子包括对-亚苯基二胺,2-甲基-1,4-二氨基苯,2,6-二甲基-1,4-二氨基苯,2,5-二甲基-1,4-二氨基苯,2,3-二甲基-1,4-二氨基苯,2-氯-1,4-二氨基苯,2-甲氧基-1,4-二氨基苯,1-苯基氨基-4-氨基苯,1-二甲基氨基-4-氨基苯,1-二乙基氨基-4-氨基苯,1-双(β-羟乙基)氨基-4-氨基苯,1-甲氧乙基氨基-4-氨基苯,2-羟甲基-1,4-二氨基苯,2-羟乙基-1,4-二氨基苯,2-异丙基-1,4-二氨基苯,1-羟丙基-4-氨基苯,2,6-二甲基-3-甲氧基-1,4-二氨基苯,1-氨基-4-羟基苯,及它们的衍生物。
优选的主要中间体有对-亚苯基二胺,对-氨基苯酚,邻-氨基苯酚,N,N-双(2-羟乙基)-对-亚苯基二胺,2,5-二氨基甲苯,及其盐和它们的混合物。
合适的偶合剂包括,例如,下列通式的化合物:其中R1是未取代的的羟基或氨基,或被一个或多个C1-6羟基烷基取代的羟基或氨基,R3和R5各自独立地是氢、羟基、氨基,或被C1-6烷基、C1-6烷氧基、或C1-6羟烷基取代的氨基;且R2,R4,和R6各自独立地是氢,C1-6烷氧基,C1-6烷氧基、C1-6羟烷基,或C1-6烷基,或R3和R4一起形成亚甲二氧基基团。这类化合物的例子包括如苯酚的间衍生物,例如间-二酚类,间-氨基苯酚类,间-亚苯基二胺类等,它们可以是未取代的,或在氨基或苯环上被烷基,羟烷基,烷基氨基等取代。合适的偶合剂包括3,4-亚甲二氧基苯酚,3,4-亚甲二氧基-1-[(β-羟乙基)氨基]苯,1-甲氧基-2-氨基-4-[(β-羟乙基)氨基]苯,1-羟基-3-(二甲基氨基)苯,6-甲基-1-羟基-3-[(β-羟乙基)氨基]苯,2,4-二氯-1-羟基-3-氨基苯,1-羟基-3-(二乙基氨基)苯,1-羟基-2-甲基-3-氨基苯,2-氯-6-甲基-1-羟基-3-氨基苯,1,3-二氨基苯,6-甲氧基-1,3-二氨基苯,6-羟基乙氧基-1,3-二氨基苯,6-甲氧基-5-乙基-1,3-二氨基苯,6-乙氧基-1,3-二氨基苯,1-双(β-羟乙基)氨基-3-氨基苯,2-甲基-1,3-二氨基苯,6-甲氧基-1-氨基-[(β-羟乙基)氨基]苯,6-(β-氨基乙氧基)-1,3-二氨基苯,6-(β-羟基乙氧基)-1-氨基-3-(甲基氨基)苯,6-羧甲基氧基-1,3-二氨基苯,6-乙氧基-1-双(β-羟基乙基)氨基-3-氨基苯,6-羟乙基-1,3-二氨基苯,1-羟基-2-异丙基-5-甲基苯,1,3-二羟基苯,2-氯-1,3-二羟基苯,2-甲基-1,3-二羟基苯,4-氯-1,3-二羟基苯,5,6-二氯-2-甲基-1,3-二羟基苯,1-羟基-3-氨基-苯,1-羟基-3-(氨基甲酰基甲基氨基)苯,6-羟基苯并吗啉,4-甲基-6-二羟基吡啶,2,6-二羟基吡啶,2,6-二氨基吡啶,6-氨基苯并吗啉,1-苯基-3-甲基-5-吡唑酮,1-羟基萘,1,7-二羟基萘,1,5-二羟基萘,和它们的混合物。
优选的偶合剂包括间苯二酚,1-萘酚,5-氨基-邻-甲酚,2-甲基间苯二酚,间-氨基苯酚,间-亚苯基二胺,1-苯基-3-甲基-吡唑-5-酮,它们的盐或它们的混合物。2-羟基苯基苯并三唑化合物
本发明的组合物含有0.01-10%,优选0.01-8%,更优选0.01-5%的2-羟基苯基苯并三唑化合物,它可以吸收波长范围在200至400nm,优选250至390nm的紫外射线。应指出的是在染发剂中的许多主要中间体和偶合剂也能够吸收此波长范围内的紫外(UV)射线,据信这是当暴露于紫外光时头发颜色易褪色的一个原因。不受此解释的限制,据信用于本发明组合物的苯并三唑化合物除了与头发纤维的外表面复合外,还至少部分地渗入发干。可认为它们能作为UV射线的主要吸收剂起作用,因此可防止,或至少减少,染发剂分子本身吸收UV射线并因此降解的趋势。
合适的用于本发明组合物的2-羟基苯基苯并三唑化合物与染发剂分子不同,因为,它们优选地不合氨基取代基。适用于本发明组合物的2-羟基苯基苯并三唑化合物对应于下列通式(a),(b)和(c)中的一种:
通式(a)具有如下结构:其中R1,R2,R3,R4,和R5各自独立地是H,羟基,羧基,卤素,或C1 -40直链或支链烷基,C1-40直链或支链烷氧基,C2-20烷氧羰基,C1-40烷基取代的苯基,C5-6环烷基,SO3H,SO3Na,或其中E1和E2分别是H或C1-4烷基,且E3是H,卤素,或C1-4烷基;R3是H,卤素,OH,C1-40直链或支链烷基,SO3Na,C5-6环烷基,苯基,C1-10烷基取代的苯基,或其中E1和E2分别是H,或C1-4烷基,且E3是H,卤素,或C1-4直链或支链烷基。
这类化合物的例子公开于美国专利5,240,975;4,904,712;4,921,966;5,097,041;5,095,062;4,973,701;4,587,346;和4,675,352。
通式(b)化合物具有如下通式:其中T1是氢,卤素,C1-4烷基,SO3H,或SO3Na,T2是C1-12烷基,SO3H或SO3NaE1是氢,卤素,或---OE2E2是氢,或C1-18烷基,E3是氢,C1-4烷基,卤素,SO3H或SO3Na,E4是氢,卤素,或OE5E5是氢或C1-18烷基,且E6是氢,羟基,或羧基。
这些化合物的例子公开于美国专利No.5,387,691,该文献这里引作参考。
合适的还有以下通式(c)的2-羟基苯基苯并三唑酯:其中R1,R2,和R3各自独立地是H,卤素,或含酯基团,条件是有至少一个含酯基。这些2-羟基苯基苯并三唑酯的例子公开于美国专利4,996,326,该文献这里引作参考。
R1是氢,卤素,C1-4烷基,或C1-4烷氧基,
R2是C1-18烷基,5-12个碳原子的环烷基,或7-15个碳原子的苯基烷基,E是1-10个碳原子的支链或直链亚烷基或所述亚烷基中插入1-3个选自-O-,-S-,-SO2-,-COO-,-OOC-的基团,Rf是1-12个碳原子的全氟代直链或支链烷基,被一个或多个2-6个碳原子的全氟代烷氧基取代的2-6个碳原子的全氟代烷基,或低聚的(六氟丙烯氧化物)端基(oligo(hexafluoropropene oxide)terminalgroup)。这些化合物的例子在美国专利No.5,312,852中有描述,该文献这里引作参考。
优选的是通式(a)中R1和R2都是氢的化合物。更优选的是那些R1和R2都是氢,且R3是SO3Na或SO3H的化合物。后一组中所述的优选的化合物是其中R1,R2和R4是H,R3是SO3Na或SO3H,且R5是C1-10直链或支链烷基的化合物。最优选的化合物是其中R1,R2和R4是H,R3是SO3Na,且R5是C1-10支链烷基的化合物。一个实例是CTFA(化妆品、盥洗用品和香料协会)名称为异丁基苯并三唑磺酸钠的化合物。此物质可由Ciba-Geigy买到,商品名称为Cibafast W Liquid,它是一种阴离子型物质。表面活性剂
本发明组合物含有0.5-20%,优选0.5-15%,更优选0.5-10%的表面活性剂。合适的表面活性剂可以是阴离子型,非离子型,两性型,或两性离子型。阴离子表面活性剂
阴离子表面活性剂包括具有通式ROSO3M和RO(C2H4O)xSO3M的烷基硫酸盐和烷基醚硫酸盐,其中R是具有约10-20个碳原子的烷基或链烯基,x为1至约10,且M是水溶性阳离子如铵,钠,钾,或三乙醇胺阳离子。
另一类可用于本发明组合物的阴离子表面活性剂是有机物与硫酸反应产物的水溶性盐,其具有通式:
R1--SO3--M其中R1选自具有约8-约24个碳原子,优选12-约18个碳原子的直链或支链的饱和的脂肪烃基,M是阳离子。这些阴离子表面活性剂的例子是烃如具有8-24个碳原子的正链烷烃,和磺化剂如三氧化硫的有机硫酸反应产物的盐。
也适合于作为阴离子表面活性剂的是脂肪酸用羟乙基磺酸酯化并用氢氧化钠中和的反应产物。脂肪酸可以是例如椰子油的衍生物。
另外,琥珀酸盐和琥珀酰亚胺酸盐也是合适的阴离子表面活性剂。这类化合物包括例如N-十八烷基磺基琥珀酸钠;N-(1,2-二羧乙基)-N-十八烷基磺基琥珀酸四钠盐;和磺基琥珀酸钠的酯,例如,磺基琥珀酸钠的二己基酯,磺基琥珀酸钠的二辛基酯等。
其它合适的阴离子表面活性剂包括12至24个碳原子的烯烃磺酸盐。术语“烯烃磺酸盐”是指用未络合的三氧化硫磺化α烯烃,然后中和酸性反应混合物,使得在反应中形成的任何磺内酯都水解成相应的羟基链烷烃磺酸盐。制备烯烃磺酸盐的α烯烃是具有约12-24个碳原子的,优选约14-16个碳原子的单烯烃。
其它类的合适的阴离子表面活性剂有β-烷氧基烷烃磺酸盐或它们的水溶性皂如C10-20脂肪酸的盐,例如椰子和牛脂基皂。优选的盐为铵盐,钾盐,和钠盐。
另一类阴离子表面活性剂包括N-酰基氨基酸表面活性剂及其盐(碱金属,碱土金属,和铵盐),它们具有下列通式:其中R1是C8-24烷基或链烯基,优选C10-18;R2是H,C1-4烷基,苯基,或-CH2COOM;R3是CX2-或C1-2烷氧基,其中每个X分别是H或C1-6烷基或烷基酯,n是1-4,且M是H或如上所述的成盐阳离子。这类表面活性剂的例子有N-酰基肌氨酸盐,包括月桂酰肌氨酸盐,肉豆蔻酰肌氨酸盐,椰子酰肌氨酸盐,和油酰肌氨酸盐,优选是钠或钾盐形式。非离子表面活性剂
组合物中可含有一种或多种非离子表面活性剂,以代替或补充阴离子表面活性剂。非离子表面活性剂一般是烯化氧基团和疏水性化合物的缩合产物。非离子表面活性剂的种类有:
(a)长链二烷基亚砜,含有一个约1-3个碳原子的短链烷基或羟基烷基和一个长疏水链,它可以是含有8-20个碳原子的烷基,链烯基,羟烷基,或酮烷基,0-10个环氧乙烷单元,和0或1个甘油基部分。
(b)聚山梨酸酯,如脂肪酸的蔗糖酯。这类材料的例子包括蔗糖椰子酸盐,蔗糖山嵛酸酯等。
(c)烷基苯酚的聚氧化乙烯缩合物,例如烷基部分具有6-20个碳原子的烷基苯酚与环氧乙烷的缩合产物,每摩尔烷基苯酚存在约10-60摩尔环氧乙烷。
(d)环氧丙烷与乙二胺的反应产物与环氧乙烷的缩合产物。
(e)具有8-18个碳原子的脂肪醇与环氧乙烷的缩合产物,例如椰子醇/环氧乙烷的缩合物,每摩尔椰子醇具有10-30摩尔环氧乙烷,椰子醇部分具有10-14个碳原子。
(f)长链叔胺氧化物如相应于以下通式的化合物:
R1R2R3NO其中R1包括具有约8-18个碳原子的烷基,链烯基或单羟基烷基,0-约10个环氧乙烷部分,和0-约1个甘油基部分,且R2和R3分别是含有约1-约3个碳原子的烷基或单羟基烷基。
(g)长链叔膦氧化物如相应于以下通式的化合物:
RR1R2PO其中R包括具有8-18个碳原子的烷基,链烯基或单羟基烷基,0-10个环氧乙烷部分,和约0或1个甘油基部分,且R2和R3分别是含有约1-3个碳原子的烷基或单羟基烷基。
(h)烷基多糖,具有6-30个,优选10个碳原子的疏水基团和多糖基如葡萄糖,半乳糖等。合适的烷基多糖是辛基,壬基,癸基,十一烷基,十二烷基,十三烷基,十四烷基,十五烷基,十六烷基,十七烷基,和十八烷基的二-,三-,四-,五-和六葡糖苷,半乳糖苷,乳糖苷,葡萄糖,果糖苷,果糖等。
(ⅰ)聚乙二醇(PEG)甘油基脂肪酸酯,具有结构式
RC(O)OCH2CH(OH)CH2(OCH2CH2)nOH其中n是5-200且RC(O)-是烃基羰基其中R优选为具有7-19个碳原子的脂族基团。
(j)其它可使用的非离子表面活性剂包括C10-18烷基(C1-6)多羟基脂肪酸酰胺如C12-18甲基葡糖酰胺,N-烷氧基多羟基脂肪酸酰胺,N-丙基至N-己基C12-18葡糖酰胺等。两性表面活性剂
可用于本发明组合物的两性表面活性剂一般为脂肪族仲或叔胺衍生物,其中一个脂族基为8-18个碳原子的直链或支链烷基,且另一个脂族基含有阴离子基团,如羧基,磺酸基,硫酸基,磷酸基,或膦酸基。
合适的两性表面活性剂可以是具有下列通式的咪唑啉鎓化合物:其中R1是C8-22烷基或链烯基,优选C12-16;R2是氢或CH2CO2M,R3是CH2CH2OH或CH2CH2OCH2CH2COOM;R4是氢,CH2CH2OH,或CH2CH2OCH2CH2COOM,Z是CO2M或CH2CO2M,n是2或3,优选2,M是氢或一个阳离子如碱金属,碱土金属,铵,或链烷醇铵阳离子。这些材料的例子由Miranol,Inc.以MIRANOL的商品名称销售。
合适的两性表面活性剂还有单羧酸酯或二羧酸酯如椰子基两性型羧基丙酸,cocamphocarboxypropionate,cocoamphocarboxypropionicacid,cocamphocarboxyglycinate,和cocoamphoacetate。
其它类型的两性表面活性剂包括下式的氨基烷酸盐
R-NH(CH2)nCOOM
或亚氨基二烷酸盐:
R-N[(CH2)mCOOM]2及其混合物;其中n和m是1-4,R是C8-22烷基或链烯基,且M是氢,碱金属,碱土金属,铵或烷醇铵。这类两性表面活性剂的例子包括烷基氨基丙酸盐和烷基亚氨基二丙酸盐,它们是Miranol,Inc.以商品名称MIRATAINE或Henkel以商品名称DERIPHAT出售的产品,例如,N-月桂基-β-氨基丙酸,N-月桂基-β-亚氨基二丙酸,或它们的混合物。
两性离子表面活性剂也适用于本发明组合物。这类表面活性剂具有下列通式:其中R2包括具有约8-约18个碳原子的烷基,链烯基或羟基烷基,0-约10个环氧乙烷部分,和0或1个甘油基部分;Y选自氮,磷,和硫原子;R3是含有约1-3个碳原子的烷基或单羟基烷基;当Y是硫原子时X是1,当Y是氮或磷原子时,X是2;R4是含有约1-约4个碳原子的亚烷基或单羟基亚烷基;Z是选自羧酸基,磺酸基,膦酸基,和磷酸基的基团。
两性离子型表面活性剂包括甜菜碱,例如高级烷基甜菜碱如椰子基二甲基羧甲基甜菜碱,月桂基二甲基羧甲基甜菜碱,月桂基二甲基α羧甲基甜菜碱,鲸蜡基二甲基羧甲基甜菜碱,月桂基双-(2-羟乙基)羧甲基甜菜碱,硬脂基双-(2-羟丙基)羧甲基甜菜碱,油基二甲基γ-羧乙基甜菜碱及它们的混合物。合适的还有磺基和氨基甜菜碱如椰子基二甲基磺基丙基甜菜碱,硬脂基二甲基磺基丙基甜菜碱等。
另外,本发明组合物还可含有许多其它组分。优选本发明组合物含有0.01-15%,优选0.05-10%,更优选0.10-8%的阳离子型调理剂,它们是阳离子聚合物,季铵盐或脂肪胺的盐。季铵盐具有下列通式:其中R1是氢,1-22个碳原子的脂族基团,或芳族芳香基,或具有12-22个碳原子的烷芳基;R2是具有1-22个碳原子的脂族基团;R3和R4均是具有1-3个碳原子的烷基,且X是选自卤素,乙酸根,磷酸根,硝酸根和甲基硫酸根的阴离子,脂族基团除了碳原子和氢原子外还可含有醚键及酰氨基。
合适的季铵化合物可以是单长链烷基,二长链烷基,三长链烷基等。这类季铵盐的例子包括氯化烷基二甲基二十二烷基铵(behenalkonium chloride),氯化二十二烷基三甲基铵(behentrimonium chloride),甲基硫酸化二十二烷基三甲基铵(behentrimonium methosulfate),氯化烷基二甲基苄基铵,氯化异辛基苯二乙二醇醚二甲基苄基铵,苄基三乙基氯化铵,氯化烷基二甲基十六烷基铵,氯化十六烷基三甲基铵,溴化十六烷基三甲基铵,甲基硫酸化十六烷基三甲铵,甲苯磺酸化十六烷基三甲基铵,氯化十六烷基吡啶鎓,二(二十二烷基)/二(二十烷基)二甲基氯化铵,二(二十二烷基)二甲基氯化铵,甲基硫酸化二(二十二烷基)二甲基铵,二(辛基)/二(辛酰)二甲基氯化铵,二(十六烷基)二甲基氯化铵,和它们的混合物。
另外,具有下列通式的咪唑啉鎓盐也是合适的:其中R5是氢或C1-4烷基;R6是C1-4烷基;R7是C8-22烷基;R8是氢,或C1-22烷基;且X是定义如上的阴离子。
还适合作为阳离子头发调理剂的是脂族伯,仲,或叔胺盐,其中取代基具有12-22个碳原子。这类胺的例子包括二甲基十八胺,二甲基大豆胺,硬脂基胺,肉豆蔻基胺,十四烷基胺,乙基十八基胺等。
其它合适作为阳离子型调理剂的是阳离子聚合物如:
(a)纤维素醚的季化衍生物,如以商品名称JR-125,JR-400,JR-30M出售的聚合物。优选的是Polyquaternium10,它是羟乙基纤维素与三甲基铵取代的环氧化物反应得到的聚合的季铵盐。
(b)具有下式单体单元的乙烯基吡咯烷酮的共聚物:
其中R1是氢或甲基,优选甲基;
y是0或1,优选1;
R2是O或NH,优选NH;
R3是CxH2x其中x是2-18,或-CH2-CHOH-CH2-,优选CxH2x其中x是2;
R4是甲基,乙基,苯基,或C1-4取代的苯基,优选甲基;且
R5是甲基或乙基,优选甲基。
上式中优选的化合物是其中y是1,R2是NH,R3是CH2CH2,R4是甲基,且R5是甲基的化合物。这些化合物是已知的,CTFA名称为Polyquaternium28。
(c)二甲基二烯丙基氯化铵均聚物,或二甲基二烯丙基氯化铵和丙烯酰胺的共聚物。这类化合物由Merck以MERQUATTM的商品名称出售。
(d)衍生自丙烯酸或甲基丙烯酸的均聚物或共聚物,其中单体单元选自丙烯酰胺,甲基丙烯酰胺,双丙酮-丙烯酰胺,氮原子上被低级烷基取代的丙烯酰胺或甲基丙烯酰胺,丙烯酸或甲基丙烯酸的烷基酯,乙烯基吡咯烷酮,和乙烯基酯。
可用于本发明组合物中的阳离子聚合物的例子在美国专利Nos.5,240,450和5,573,709中有描述,这两篇文献在此引作参考。
本发明优选的组合物含有0.01-10%,优选0.05-5%,更优选0.1-3%的脂肪油。术语“脂肪油”是指在室温为液体或半固体的油,且一般含有至少一种脂肪化合物衍生自具有6-25个碳原子的直链或支链,饱和或不饱和烷基的脂肪酸。优选脂肪酸甘油酯。这类油的例子包括道氏池花籽油,杏仁油,鳄梨油,巴巴苏油,琉璃苣籽油,蓖麻油,椰子油,玉米油,榛子油,橄榄油,棕榈油,亚麻子油,以及所有在CTFA化妆品组分手册,第二版,1992,P507-508中公开的脂肪油,此文献在此引作参考。优选道氏池花籽油。
也可以包括0.001-5%,优选0.005-4%,更优选0.005-5%重量的一种或几种防腐剂。组合物中还可含有相同百分含量的乳化剂和湿润剂。
一般地,本发明的染料组合物为乳膏形式,即它显示出光滑的乳膏状纹理,在施用于头发上时不会流淌。
本发明还涉及一种两组分的用于氧化性染发的套装产品,其中包括:
装有一种组合物的第一个容器,按照组合物总重算,其中含有:
0.0001-20%的至少一种主要中间体和至少一种偶合剂用于形成氧化染料,
0.01-10%的吸收波长范围为200至400nm的紫外射线的2-羟基苯基苯并三唑化合物,
0.5-20%表面活性剂,和
10-65%水;且
装有显色组合物的第二个容器,按该组合物总重算,其中含有:
0.5-45%的过氧化氢,
0.1-10%的硅氧烷(silicone)头发调理剂,
0.01-5%阴离子聚合物,和
1-99%水。
硅氧烷头发调理剂在显色剂组合物中的存在量为总显色剂组合物重量的0.1-10%,优选0.5-8%,更优选0.5-5%。合适的硅氧烷头发调理剂包括挥发性或非挥发性硅氧烷液体,硅氧烷树脂,和硅氧烷半固体或固体。
挥发性硅氧烷是直链或环状硅氧烷,具有可测量的蒸汽压,规定其20℃的蒸汽压至少为2mm汞柱。挥发性硅氧烷的例子有具有下列通式的环状硅氧烷:其中n=3-7。
另外,也可用于本发明组合物的直链的挥发性硅氧烷具有如下通式:
(CH3)3Si-O-[Si(CH3)2-O]n-Si(CH3)3其中n=0-7,优选0-5。
硅氧烷头发调理剂可含有水不溶性非挥发性硅氧烷液体,包括聚烷基硅氧烷,聚芳基硅氧烷,聚烷基芳基硅氧烷,聚醚硅氧烷共聚物,含胺官能基硅氧烷,和它们的混合物。这类硅氧烷具有如下通式:其中R和R’分别是烷基,芳基或被一个或多个氨基取代的烷基,且x和y分别是0-100,000,条件是x+y至少等于1且A是甲硅烷氧基封端单元。优选其中A是甲基,R是甲基,且R’是至少被两个氨基取代的烷基,最优选是具有如下通式的胺功能基硅氧烷:其CTFA名称为三甲基甲硅烷基(氨乙基)氨丙基羟基二甲聚硅氧烷。
硅氧烷头发调理剂也可以是具有下列通式的硅氧烷聚合物:
[(RR’R”)3SiO1/2]x[SiO2]y其中R,R’和R”分别是C1-10直链或支链烷基或苯基,且x和y的值使(RR’R”)3SiO1/2单元与SiO2单元的比例为0.5∶1至1.5∶1。
优选R,R’和R”是C1-6烷基,更优选是甲基,且x和y的值使(CH3)3SiO1/2单元与SiO2单元的比例为0.75∶1。最优选的是这种三甲基甲硅烷氧基硅酸酯含有2.4-2.9重量百分比的羟基,它是硅酸的钠盐、氯代三甲基硅烷和异丙醇的反应产物。三甲基甲硅烷氧基硅酸酯的制备在美国专利Nos.2,676,182;3,541,205;和3,836,437中有描述,这些文献均在此引作参考。上述三甲基硅氧基硅酸酯也可从DowCorning公司以商品名称2-0749和2-0747购得,每种产品都是约40-60%挥发性硅氧烷和40-60%三甲基硅氧基硅酸酯的混合物。特别是Dow Corning 2-0749,它是一种含约50%三甲基硅氧基硅酸酯和约50%环二甲基硅氧烷的液体。此液体在25℃的粘度为200-700厘泊,在25℃时比重为1.00-1.10,且折光率为1.40-1.41。
最好是显色剂组合物含有各为0.001-10%,优选0.005-5%,更优选0.01-4%的环二甲基硅氧烷,三甲基甲硅烷氧基硅酸酯,和水不溶性非挥发性硅氧烷,特别是三甲基甲硅烷基(氨乙基)氨丙基羟基二甲聚硅氧烷的混合物。
显色剂组合物还可含有0.001-5%,优选0.05-4%,更优选0.05-3%的一种或多种如在美国专利No.4,240,450中公开的阴离子聚合物,此文献在此引作参考。这类阴离子聚合物的例子有乙酸乙烯基酯和巴豆酸的共聚物,乙烯基酯或丙烯酸或甲基丙烯酸酯的接枝共聚物,从至少一种离子型单体,至少一种非离子型单体,聚乙二醇,和一种交联剂等聚合得到的交联的接枝共聚物等。优选丙烯酸酯型共聚物如steareth-10烯丙基醚丙烯酸酯共聚物。
显色剂组合物含有1-99%,优选10-99%,更优选60-97%的水。
两个容器是成套一起卖给顾客的。在染发之前,消费者将容器内的物质混合在一起,然后将混合物施用于头发。
最后,本发明涉及氧化性染发的方法,包括下列步骤:
a)对头发施用由组合物A和组合物B混合得到的组合物,其中组合物A含有,按照组合物总重算:
0.0001-20%至少一种主要中间体和至少一种偶合剂用于形成氧化染料,
0.01-10%的吸收波长范围为200至400nm的紫外射线的2-羟基苯基苯并三唑化合物,
0.5-20%表面活性剂,和
10-65%水;
组合物B含有,按照组合物总重算:
0.5-45%的过氧化氢,
0.1-10%的硅氧烷(silicone)头发调理剂,
0.01-5%阴离子聚合物,和
1-99%水,
b)使所述组合物在头发上保留2-60分钟,
c)用水冲洗头发。
组合物A和组合物B混合施用于头发上的时间根据所需染色效果而决定,一般为2-60,优选5-45,更优选10-35分钟。要达到最佳染色效果,优选的组合物A和组合物B的比例为0.5-1.5∶1.0-2.0,优选分别为1-1.5。经过一定的时间,用清水冲掉染色混合物,将头发弄干。
下面将用实施例进一步描述本发明,实施例只是用于举例说明本发明。实施例1
一种氧化性染发组合物制备如下:
w/w%
月桂基硫酸铵(阴离子表面活性剂) 2.00
丙二醇(湿润剂) 4.00
乙氧基二甘醇(溶剂) 2.00
单乙醇胺(pH调节剂) 5.00
海藻提取物(调理剂) 0.80
EDTA(络合剂) 0.80
异抗坏血酸(抗氧化剂) 0.20
亚硫酸钠(还原剂) 0.50
主要中间体和偶合剂(染料) 5.00
油酸(皂) 12.5
C16-C18醇(遮光剂) 4.00
乳化蜡(乳化剂) 2.00
Oleth-20(非离子表面活性剂) 1.00
Steareth-21(非离子表面活性剂) 0.70
道氏池花籽油(油) 0.75
油醇(油) 0.40
Polyquaternium 10(阳离子型调理剂) 0.20
Polyquaternium 28(阳离子型调理剂) 0.50
云母/二氧化钛(着色剂) 0.30
水解的小麦蛋白(调理剂) 1.00
Cibafast W液体*(紫外吸收剂) 1.00
香味剂 0.75
氢氧化铵(pH调节剂) 5.00
小麦氨基酸(调理剂) 1.00
水 适量
*异丁基苯并三唑磺酸钠,Ciba Geigy
组合物的制备方法是:先将前八种组分溶于水。然后加入主要中间体和偶合剂并加热溶解。剩余组分,除了氢氧化铵、小麦氨基酸、和香味剂以外,分别在主要中间体和偶合剂加入后混合加入。最后将剩余的水,氢氧化铵,小麦氨基酸,和香味剂加入组合物。实施例2
一种以过氧化氢为基础的与权利要求1所述的染发组合物一起使用的显色剂组合物制备如下:
w/w%对羟基苯甲酸甲酯(防腐剂) 0.05EDTA(络合剂) 0.02矿物油(油) 0.60C16-C18醇/ceteareth-20(80∶20)(乳化剂) 3.75环二甲基聚硅氧烷/三甲基甲硅烷氧基硅酸酯(50∶50) 0.01(硅氧烷调理剂)C16-C18醇(遮光剂) 0.40三甲基甲硅烷基(氨乙基)氨丙基羟基二甲聚硅氧烷 2.00(硅氧烷调理剂)磷酸氢二钠(pH调节剂) 0.03磷酸(pH调节剂) 0.03过氧化氢(35%的水溶液) 25.70Steareth-10烯丙基醚/丙烯酸酯共聚物 0.35(阴离子聚合物)水 适量
先将防腐剂溶于约一半水中。将溶液加热,并在搅拌下加入矿物油,C16-C18醇/ceteareth和C16-C18醇。将混合物冷却并加入硅氧烷。将磷酸氢二钠和磷酸溶于水并在加入硅氧烷之后与其余组分一起加入混合物中。实施例3
九十名女性志愿者参加了一个八周的双盲试验(double blindstudy),用于比较使用实施例1和2的组合物与使用L’Oréal优选染发剂的染发效果。L’Oréal优选染发剂含有下列组分,按照其包装上所列组分重新制备:染发剂:
水,椰油酰胺DEA,丁氧基乙醇,PEG-2牛脂胺,SD醇40,聚甘油基-4油醚,油醇,氢氧化铵,聚甘油基-2油醚,丙二醇,油酸,二乙基氨基丙基椰子基天冬酰胺钠,二亚乙基三胺五乙酸五钠盐,乙酸铵,染料中间体,偏亚硫酸钠,赤藻糖酸,香味剂。显色剂:
水,过氧化氢,C16-C18醇,油酰胺DEA,ceteareth-30,甘油,磷酸,二亚乙基三胺五乙酸五钠盐,锡酸钠,焦磷酸四钠盐。
每个参加者进行两个四周周期的试验。在第一个周期中,参加者的头发用第一种染发系统染色。在四周时间内,参加者被要求回答各种关于颜色的问题。然后,同一参加者使用第二种染发系统染色。在四周时间内,参加者被要求回答各种关于颜色的问题。所得试验结果如下:
1、与你染发第一天相比,你的头发褪色了吗?
本发明
肯定百分比颜色 周1 周2 周3 周4香槟金色 42 68 90 100特浅银灰色 45 64 73 73浅灰棕色 45 66 83 92浅棕色 83 66 75 66中棕色 58 83 92 92深棕色 17 25 50 66浅赤褐色 58 66 83 83平均 49 63 79 83
L’Oréal优选染发剂
肯定百分比
颜色 周1 周2 周3 周4香槟金色 56 78 83 83特浅银灰色 20 40 80 80浅灰棕色 66 83 83 83浅棕色 50 66 66 75中棕色 58 75 92 100深棕色 42 58 75 67浅赤褐色 58 66 92 92平均 50 68 82 83
2、与你染发第一天相比,你头发的颜色是否保持原有颜色?
本发明
肯定百分比
颜色 周1 周2 周3 周4香槟金色 74 63 53 42特浅银灰色 82 64 45 45浅灰棕色 83 58 50 42浅棕色 75 50 66 50中棕色 83 83 42 50深棕色 100 92 75 75浅赤褐色 75 50 42 42平均 81 66 53 49
L’Oréal优选染发剂
肯定百分比
颜色 周1 周2 周3 周4香槟金色 66 50 47 33特浅银灰色 90 80 66 60浅灰棕色 58 50 42 33浅棕色 83 66 83 50中棕色 66 58 42 42深棕色 92 92 67 67浅赤褐色 92 66 16 8平均 66 65 50 41
3、你是否认为留在你头发上的颜色的量是可接受的?
4周后的肯定百分比
本发明 L’Oréal优选染发剂
香槟金色 95 83
特浅银灰色 73 80
浅灰棕色 92 67
浅棕色 83 83
中棕色 83 83
深棕色 100 92
浅赤褐色 75 58
平均 87 78
4、如果你的头发褪色了,这变化(包括各种色调的变化):
1周几乎注意不到% 明显的% 特别明显的%
INV PREF INV PREF INV PREF
63 64 33 34 5 2
2周几乎注意不到% 明显的% 特别明显的%
INV PREF INV PREF INV PREF
49 52 47 43 4 5
3周几乎注意不到% 明显的% 特别明显的%
INV PREF INV PREF INV PREF
47 47 50 40 3 18
4周几乎注意不到% 明显的% 特别明显的%
INV PREF INV PREF INV PREF
39 38 55 33 5 29
INV=本发明
PREF=L’Oréal优选染发剂5、平均褪色:
平均褪色是计算那些参加者在一、二、三、和四周报告的褪色,汇总了七种色调的结果。参加者在一、二、三、和四周后报告的褪色按程度分为1-3级,1是最好,3是最差。所得数值结果平均得到平均值。头发颜色 平均值 标准误差本发明(n=74) 1.66A 0.07L’Oréal Preference(n=72) 1.92 0.10
上述结果证明本发明的染色组合物与L’Oréal优选染发剂相比在三周后显示出改进的染色牢度。
尽管本发明用优选的方案进行了描述,但并非把本发明的范围限制成上述的特定形式,相反地,在所附权利要求中规定的本发明的精神与范围之内的变动、修改和等同替换均将包括在内。
Claims (21)
1、一种氧化性染发组合物,按照组合物总重算,其中含有:
0.0001-20%至少一种主要中间体和至少一种偶合剂用于形成氧化染料,
0.01-10%的吸收波长范围为200至400nm的紫外射线的2-羟基苯基苯并三唑化合物,
0.5-20%表面活性剂,和
10-65%水。
2、权利要求1的组合物,其中2-羟基苯基苯并三唑化合物具有下列通式:
(a)其中R1,R2,R3,R4,和R5各自独立地是H,羟基,羧基,卤素,或C1 -40直链或支链烷基,C1-40直链或支链烷氧基,C2-20烷氧羰基,羧基,C1-40烷基取代的苯基,C5-6环烷基,SO3H,SO3Na,或其中E1和E2各自独立地是H或C1-4烷基,且E3是H,卤素,或C1-4烷基;R3是H,卤素,OH,C1-40直链或支链烷基,SO3Na,C5-6环烷基,苯基,C1-10烷基取代的苯基,或其中E1和E2分别是H,或C1-4烷基,且E3是H,卤素,或C1-4;
T1是氢,卤素,C1-4烷基,SO3H,或SO3Na,
T2是C1-12烷基,SO3H或SO3Na
E1是氢,卤素,或---OE2
E2是氢,或C1-18烷基,
E3是氢,C1-4烷基,卤素,SO3H或SO3Na,
E4是氢,卤素,或OE5
E5是氢或C1-18烷基,且
E6是氢,羟基,或羧基;
(d)其中
R1是氢,卤素,C1-4烷基,或C1-4烷氧基,
R2是C1-18烷基,5-12个碳原子的环烷基,或7-15个碳原子的苯基烷基,E是1-10个碳原子的支链或直链亚烷基或所述亚烷基中插入1-3个选自-O-,-S-,-SO2-,-COO-,-OOC-的基团,且Rf是1-12个碳原子的全氟代直链或支链烷基,被2-6个碳原子的全氟代烷氧基取代的2-6个碳原子的全氟代烷基,或低聚的(六氟丙烯氧化物)端基(oligo(hexafluoropropene oxide)terminal group);
(e)它们的混合物。
4、权利要求3的组合物,其中R1和R2是H。
5、权利要求5的组合物,其中R3是SO3Na或SO3H。
6、权利要求5的组合物,其中R5是C1-10直链或支链烷基。
7、权利要求5的组合物,其中R1,R2,和R3是H,R4是SO3Na,且R5是C1-10支链烷基。
8、权利要求1的组合物,其中2-羟基苯基苯并三唑化合物是异丁基苯并三唑磺酸钠。
10、权利要求9的组合物,其中阳离子头发调理剂是具有下列通式单体单元的乙烯基吡咯烷酮的共聚物:其中R1是氢或甲基,y是0或1,R2是O或NH,R3是CxH2x其中x是2-18,或-CH2-CHOH-CH2-,R4是甲基,乙基,苯基,或C1-4取代的苯基,且R5是甲基或乙基。
11、权利要求10的组合物,其中R1是甲基。
12、权利要求11的组合物,其中R2是NH。
13、权利要求12的组合物,其中R3是CH2CH2,R4是甲基,且R5是甲基。
14、权利要求1的组合物,其中表面活性剂选自阴离子表面活性剂,非离子表面活性剂,两性表面活性剂,两性离子表面活性剂,和它们的混合物。
15、权利要求14的组合物,其中表面活性剂选自阴离子表面活性剂,非离子表面活性剂,和它们的混合物。
16、权利要求15的组合物,其中阴离子表面活性剂是具有通式ROSO3M的烷基硫酸盐,具有通式RO(C2H4O)xSO3M的烷基醚硫酸盐,其中R是约10-20个碳原子烷基或链烯基,x是1-10且M是水溶性阳离子如铵,钠,钾或三乙醇胺阳离子。
17、权利要求15的组合物,其中非离子表面活性剂是环氧乙烷和具有8-18个碳原子的脂肪醇的缩合产物。
18、权利要求1的组合物,其中还含有0.01-10%的脂肪油。
19、权利要求18的组合物,其中脂肪油是道氏池花籽油。
20、一种用于氧化性染发的两组分套装产品,其中包括:
装有一种组合物的第一个容器,按照组合物总重算,其中含有:
0.0001-20%至少一种主要中间体和至少一种偶合剂用于形成氧化染料,
0.01-10%的吸收波长范围为200至400nm的紫外射线的2-羟基苯基苯并三唑化合物,
0.5-20%表面活性剂,和
10-65%水;和
含有显色剂组合物的第二容器,按照组合物总重算,该组合物中含有:
0.5-45%的过氧化氢,
0.1-10%的水不溶性的不挥发性硅氧烷,
0.01-5%阴离子聚合物,和
约1-99%水。
21、一种氧化性染发的方法,包括下列步骤:
a)将组合物A和组合物B混合得到的组合物施用于头发,其中组合物A含有,按照组合物总重算:
0.0001-20%至少一种主要中间体和至少一种偶合剂用于形成氧化染料,
0.01-10%的吸收波长范围为200至400nm的紫外射线的2-羟基苯基苯并三唑化合物,
0.5-20%表面活性剂,和
10-65%水;且
组合物B含有,按照组合物总重算:
5-45%的过氧化氢,
0.1-10%的水不溶性的不挥发性硅氧烷,
0.01-5%阴离子聚合物,和
1-99%的水;
b)所述组合物在头发上保留2-60分钟,
c)用水冲洗头发。
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-
1997
- 1997-03-18 US US08/819,809 patent/US5843193A/en not_active Expired - Lifetime
-
1998
- 1998-03-17 ES ES98911725T patent/ES2206904T3/es not_active Expired - Lifetime
- 1998-03-17 IL IL12706198A patent/IL127061A0/xx unknown
- 1998-03-17 WO PCT/US1998/005207 patent/WO1998041186A1/en not_active Application Discontinuation
- 1998-03-17 EP EP98911725A patent/EP0910330B1/en not_active Expired - Lifetime
- 1998-03-17 KR KR1019980709301A patent/KR20000011141A/ko not_active Application Discontinuation
- 1998-03-17 AU AU65613/98A patent/AU725070B2/en not_active Ceased
- 1998-03-17 BR BR9804784A patent/BR9804784A/pt not_active Application Discontinuation
- 1998-03-17 DE DE69819106T patent/DE69819106T2/de not_active Expired - Fee Related
- 1998-03-17 NZ NZ332989A patent/NZ332989A/xx unknown
- 1998-03-17 CA CA002255715A patent/CA2255715A1/en not_active Abandoned
- 1998-03-17 ID IDW980116A patent/ID21935A/id unknown
- 1998-03-17 JP JP54071798A patent/JP2001505923A/ja active Pending
- 1998-03-17 AT AT98911725T patent/ATE252361T1/de not_active IP Right Cessation
- 1998-03-17 CN CN98800624A patent/CN1226817A/zh active Pending
- 1998-03-18 PE PE1998000197A patent/PE71399A1/es not_active Application Discontinuation
- 1998-03-18 TW TW087104020A patent/TW513313B/zh not_active IP Right Cessation
- 1998-03-18 AR ARP980101223A patent/AR012104A1/es not_active Application Discontinuation
- 1998-03-18 ZA ZA982287A patent/ZA982287B/xx unknown
- 1998-11-17 NO NO985354A patent/NO985354L/no unknown
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NO985354L (no) | 1999-01-18 |
NZ332989A (en) | 2000-03-27 |
AU725070B2 (en) | 2000-10-05 |
KR20000011141A (ko) | 2000-02-25 |
ES2206904T3 (es) | 2004-05-16 |
PE71399A1 (es) | 1999-07-22 |
US5843193A (en) | 1998-12-01 |
IL127061A0 (en) | 1999-09-22 |
DE69819106D1 (de) | 2003-11-27 |
ATE252361T1 (de) | 2003-11-15 |
EP0910330B1 (en) | 2003-10-22 |
JP2001505923A (ja) | 2001-05-08 |
ZA982287B (en) | 1998-09-23 |
AU6561398A (en) | 1998-10-12 |
WO1998041186A1 (en) | 1998-09-24 |
ID21935A (id) | 1999-08-12 |
EP0910330A1 (en) | 1999-04-28 |
TW513313B (en) | 2002-12-11 |
DE69819106T2 (de) | 2004-07-22 |
BR9804784A (pt) | 1999-08-17 |
AR012104A1 (es) | 2000-09-27 |
CA2255715A1 (en) | 1998-09-24 |
EP0910330A4 (en) | 2001-03-21 |
NO985354D0 (no) | 1998-11-17 |
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