CN1210105C - 载体金属催化剂、其制备方法和其在直接制备过氧化氢中的用途 - Google Patents

载体金属催化剂、其制备方法和其在直接制备过氧化氢中的用途 Download PDF

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Publication number
CN1210105C
CN1210105C CNB008138842A CN00813884A CN1210105C CN 1210105 C CN1210105 C CN 1210105C CN B008138842 A CNB008138842 A CN B008138842A CN 00813884 A CN00813884 A CN 00813884A CN 1210105 C CN1210105 C CN 1210105C
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catalyst
platinum
dried
metal
support
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Chinese (zh)
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CN1378484A (zh
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米歇尔·德维克
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Arkema France SA
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Atofina SA
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06Halogens; Compounds thereof
    • B01J27/128Halogens; Compounds thereof with iron group metals or platinum group metals
    • B01J27/13Platinum group metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18Stationary reactors having moving elements inside
    • B01J19/1868Stationary reactors having moving elements inside resulting in a loop-type movement
    • B01J19/1881Stationary reactors having moving elements inside resulting in a loop-type movement externally, i.e. the mixture leaving the vessel and subsequently re-entering it
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61Surface area
    • B01J35/615100-500 m2/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63Pore volume
    • B01J35/6350.5-1.0 ml/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/22Halogenating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/005Separating solid material from the gas/liquid stream
    • B01J8/006Separating solid material from the gas/liquid stream by filtration
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/20Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
    • B01J8/22Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid
    • B01J8/222Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid in the presence of a rotating device only
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/20Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
    • B01J8/22Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid
    • B01J8/224Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid the particles being subject to a circulatory movement
    • B01J8/228Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid the particles being subject to a circulatory movement externally, i.e. the particles leaving the vessel and subsequently re-entering it
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B15/00Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
    • C01B15/01Hydrogen peroxide
    • C01B15/029Preparation from hydrogen and oxygen
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00017Controlling the temperature
    • B01J2208/00106Controlling the temperature by indirect heat exchange
    • B01J2208/00168Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
    • B01J2208/00176Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles outside the reactor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00017Controlling the temperature
    • B01J2208/00106Controlling the temperature by indirect heat exchange
    • B01J2208/00168Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
    • B01J2208/00212Plates; Jackets; Cylinders
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/18Details relating to the spatial orientation of the reactor
    • B01J2219/185Details relating to the spatial orientation of the reactor vertical

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CNB008138842A 1999-07-16 2000-06-07 载体金属催化剂、其制备方法和其在直接制备过氧化氢中的用途 Expired - Fee Related CN1210105C (zh)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
FR99/09260 1999-07-16
FR9909260A FR2796311B1 (fr) 1999-07-16 1999-07-16 Reacteur multietage, ses applications et procede de fabrication du peroxyde d'hydrogene
FR99/10310 1999-08-09
FR9910310A FR2796312B1 (fr) 1999-07-16 1999-08-09 Catalyseur metallique supporte, sa preparation et ses applications dans la fabrication directe du peroxyde d'hydrogene

Related Child Applications (1)

Application Number Title Priority Date Filing Date
CNB2005100739688A Division CN100490969C (zh) 1999-07-16 2000-06-07 载体金属催化剂、其制备方法和其在直接制备过氧化氢中的用途

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Publication Number Publication Date
CN1378484A CN1378484A (zh) 2002-11-06
CN1210105C true CN1210105C (zh) 2005-07-13

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US (1) US6958138B1 (enExample)
EP (1) EP1204477B1 (enExample)
JP (1) JP4251809B2 (enExample)
KR (1) KR100554927B1 (enExample)
CN (1) CN1210105C (enExample)
AT (1) ATE454215T1 (enExample)
AU (1) AU764178B2 (enExample)
BR (1) BR0012222B1 (enExample)
CA (1) CA2378919C (enExample)
DE (1) DE60043657D1 (enExample)
EA (1) EA004475B1 (enExample)
FR (1) FR2796312B1 (enExample)
NO (1) NO323596B1 (enExample)
NZ (1) NZ516005A (enExample)
PL (1) PL353747A1 (enExample)
TR (1) TR200200073T2 (enExample)
WO (1) WO2001005501A1 (enExample)

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EP1346767A1 (en) * 2002-03-15 2003-09-24 Council of Scientific and Industrial Research Multifunctional catalyst useful in the synthesis of chiral vicinal diols and process for the preparation thereof
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US7011807B2 (en) 2003-07-14 2006-03-14 Headwaters Nanokinetix, Inc. Supported catalysts having a controlled coordination structure and methods for preparing such catalysts
US7045479B2 (en) 2003-07-14 2006-05-16 Headwaters Nanokinetix, Inc. Intermediate precursor compositions used to make supported catalysts having a controlled coordination structure and methods for preparing such compositions
US7569508B2 (en) 2004-11-17 2009-08-04 Headwaters Technology Innovation, Llc Reforming nanocatalysts and method of making and using such catalysts
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US7563742B2 (en) 2006-09-22 2009-07-21 Headwaters Technology Innovation, Llc Supported nickel catalysts having high nickel loading and high metal dispersion and methods of making same
WO2009027439A2 (en) * 2007-08-30 2009-03-05 Solvay (Société Anonyme) Catalyst support and process for the preparation thereof
CN101402039B (zh) * 2008-11-13 2010-12-08 北京化工大学 一种负载型金属钯催化剂的制备方法
KR101474571B1 (ko) * 2009-05-13 2014-12-19 에스케이이노베이션 주식회사 고분자 전해질 다층박막 촉매 및 그 제조 방법
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CN103717304A (zh) * 2011-07-15 2014-04-09 索尔维公司 获得过氧化氢的方法和用于该方法的催化剂载体
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KR102055389B1 (ko) 2013-11-26 2019-12-12 에스케이이노베이션 주식회사 황산 처리된 Pt-Pd 담지 고분자 전해질 다층박막 촉매의 제조방법
CN109310998A (zh) * 2016-07-19 2019-02-05 三菱瓦斯化学株式会社 过氧化氢制造用贵金属催化剂和过氧化氢的制造方法
KR102002482B1 (ko) * 2017-10-12 2019-07-23 한국과학기술연구원 과산화수소 합성용 Immiscible 복합체 촉매 및 이를 이용한 과산화수소 합성 방법
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US11192091B2 (en) * 2019-03-22 2021-12-07 The Hong Kong University Of Science And Technology Palladium-ruthenium alloys for electrolyzers
CN110395696A (zh) * 2019-07-26 2019-11-01 四川轻化工大学 一种基于钯基双金属催化甲酸合成双氧水的方法

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Publication number Publication date
ATE454215T1 (de) 2010-01-15
BR0012222B1 (pt) 2011-03-22
PL353747A1 (en) 2003-12-01
CN1378484A (zh) 2002-11-06
WO2001005501A1 (fr) 2001-01-25
CA2378919C (fr) 2007-10-02
AU764178B2 (en) 2003-08-14
EP1204477A1 (fr) 2002-05-15
EP1204477B1 (fr) 2010-01-06
FR2796312B1 (fr) 2001-09-07
NO20016240D0 (no) 2001-12-19
NO323596B1 (no) 2007-06-11
JP2003520662A (ja) 2003-07-08
EA004475B1 (ru) 2004-04-29
CA2378919A1 (fr) 2001-01-25
KR20020040740A (ko) 2002-05-30
KR100554927B1 (ko) 2006-03-03
BR0012222A (pt) 2002-03-26
NO20016240L (no) 2001-12-19
NZ516005A (en) 2004-06-25
AU5538500A (en) 2001-02-05
US6958138B1 (en) 2005-10-25
DE60043657D1 (de) 2010-02-25
EA200200172A1 (ru) 2002-08-29
TR200200073T2 (tr) 2003-03-21
JP4251809B2 (ja) 2009-04-08
FR2796312A1 (fr) 2001-01-19

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