CN1203213A - Compound fertilizer and producing method thereof - Google Patents
Compound fertilizer and producing method thereof Download PDFInfo
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- CN1203213A CN1203213A CN 97112328 CN97112328A CN1203213A CN 1203213 A CN1203213 A CN 1203213A CN 97112328 CN97112328 CN 97112328 CN 97112328 A CN97112328 A CN 97112328A CN 1203213 A CN1203213 A CN 1203213A
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G1/00—Mixtures of fertilisers belonging individually to different subclasses of C05
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Abstract
A compound fertilizer contains the water-soluble compounds of N, P, K, Ca, Mg, S, rare-earth elements, Si, B, Fe,Cu, Na, Zn, Mn, Al, Ge, Li, Cr, Se, Sr, Cl, Co, Mo and Ti, and features high yield increased by 5-30%, low loss of said active components, increasing the power of crops resisting against drought, cold, diseases and pests, improving soil and low cost.
Description
The present invention relates to fertilizer field, more particularly, relate to comprehensive compound fertilizer of a kind of nutritive ingredient and manufacture method thereof.
Existing fertilizer is divided into inorganic fertilizer (chemical fertilizer of nitrogenous, phosphorus, potassium etc., mineral manure etc.), fertilizer (comprising organic commercial fertilizer and farm manure etc.) and several big classes of bacterial manure substantially.Wherein, the advantage of bacterial manure is that consumption is few, instant effect, short long effective.But shortcoming is its production and the very strict technical qualification of service requirements, is difficult for grasping for vast farmers, and it preserves also relatively difficulty, and price is rather stiff, so the use of bacterial manure still fails to be in full swing in the vast rural area of China so far.Simultaneously, when using bacterial manure, the necessary nitrogen of plant-growth, phosphorus, potassium etc. also will lean on inorganic fertilizer or fertilizer to provide, and is therefore also cumbersome.The advantage of inorganic fertilizer is the content height of effective quick-acting compositions, farm crop are to the utilization ratio height of effective quick-acting compositions, but the kind of its effective quick-acting compositions less (common compound fertilizer also do not comprise can by the 6-8 kind effective constituent of crop absorption), therefore can not satisfy comprehensive needs of farm crop, when the life-time service inorganic fertilizer, can cause soil progressively barren, cause the farm crop anti-adversity poor, make the downgrade of agricultural-food.Particularly under the situation that multiple crop index increases year by year for many years, above-mentioned situation is even more serious.The advantage of fertilizer is that effective quick-acting composition is more comprehensive, can strengthen the anti-adversity of farm crop, improves the quality of agricultural-food, and can improve and protect soil, increases fertility of land.But its shortcoming is that the total content of effective quick-acting compositions is lower, and the absorption of farm crop is slower, and effect of increasing production is not remarkable.And the source of fertilizer is comparatively limited, can't satisfy the needs in vast rural area.
The objective of the invention is to provide a kind of compound complete smart fertilizer that can have the advantage of above-mentioned a few class fertilizer concurrently and can overcome its shortcoming.
The inventor finds after through long-term deep research, plant comprehensively in the necessary element of growth, and not only three kinds in nitrogen, phosphorus, potassium far away, for example, in major element, calcium, magnesium, sulphur are also very important to the growth of plant; And in trace element, rare earth element can also strengthen the anti-adversity ability of farm crop significantly except the growth that can promote farm crop.Other a lot of trace elements can both play good promoter action to the growth of plant.On the basis of this research, the inventor has found a kind ofly contains nitrogen, phosphorus, potassium, calcium, magnesium, sulphur, rare earth (mixing), silicon, boron, iron, copper, sodium, zinc, manganese, aluminium, germanium, lithium, chromium, selenium, strontium, chlorine, cobalt, molybdenum, the titanium compound fertilizer prescription of totally 24 kinds of compositions, and the preparation method of this compound fertilizer.Use compound fertilizer of the present invention, farm crop are increased production significantly, and can strengthen its anti-adversity ability significantly.And can improve and protect soil, increase fertility of land, thereby can guarantee the volume increase year after year of farm crop.Because this discovery, thereby finished the present invention.
That is to say, the invention provides a kind of compound fertilizer, it is characterized in that it contains following ingredients:
The composition weight part
Nitrogen 10-15
Phosphorus 4-6
Potassium 4-6
Calcium 4-5
Magnesium 4-5
Sulphur 2-3
Rare earth (mixing) 0.2-0.6
Silicon 0.7-1
Boron 0.3-0.5
Iron 0.2-0.5
Copper 0.2-0.5
Sodium 0.5-1
Zinc 0.3-0.7
Manganese 0.1-0.3
Aluminium 0.2-0.5
Germanium 0.01-0.03
Lithium 0.01-0.03
Chromium 0.02-0.05
Selenium 0.01-0.03
Strontium 0.01-0.03
Chlorine 0.02-0.05
Cobalt 0.01-0.03
Molybdenum 0.0005-0.0015
Titanium 0.0005-0.0015
More than each composition all exist with the state of water-soluble cpds.
At length explain the present invention below.Wherein said water-soluble cpds is generally vitriol or nitrate, also can be their negatively charged ion state.For example nitrogen can be the nitrogen in the ammonium sulfate, also can be the nitrogen in the nitrate radical; Silicon can be the silicon in the water glass; Chlorine can be the chlorine in the sodium-chlor etc.
When using compound fertilizer fertilising of the present invention, preferably first water uses its dilution back, and the ratio of dilution preferably makes the content of nitrogen in the fertilizer after dilution in the scope of 10-15 weight %, and all the other components in proportions are analogized by above-mentioned prescription.
More preferably the compound fertilizer above-mentioned composition combines with organic commercial fertilizer, and it in conjunction with ratio (weight ratio) preferably
Above-mentioned composition: organic commercial fertilizer=1: (1-10), in above-mentioned composition, the weight percent of nitrogen is 10-15 weight %, and all the other components in certain proportion are analogized, and the surplus of less than 100 weight % partly is a water;
Said organic commercial fertilizer is meant urea and/or the volatile salt of nitrogenous 46 weight %.
Especially preferably the compound fertilizer above-mentioned composition combines with bacterial manure, and it in conjunction with ratio (weight ratio) is:
Above-mentioned composition: bacterial manure=1: (0.01-0.03), in above-mentioned composition, the weight percent of nitrogen is 10-15 weight %, and all the other components in certain proportion are analogized, and the surplus of less than 100 weight % partly is a water;
Said bacterial manure is meant the azotogen that capital, Jiangxi biological chemical fertilizer company limited produces, and vinelandii concentration is 5 * 10
3-5 * 10
8Individual/ml.
Most preferably the compound fertilizer above-mentioned composition combines with organic commercial fertilizer and bacterial manure and constitutes, it in conjunction with ratio (weight ratio) is: above-mentioned composition: organic commercial fertilizer: bacterial manure=1: (1-10): (0.01-0.03), in above-mentioned composition, the weight percent of nitrogen is 10-15 weight %, all the other components in certain proportion are analogized, and the surplus of less than 100 weight % partly is a water; The definition of organic commercial fertilizer and bacterial manure is the same.
In addition, the present invention also provides a kind of manufacture method of compound fertilizer, it is characterized in that, it is levigate and meet following ratio (weight part) scope according to each component proportions in the final finished fertilizer and mix the formation composition mutually to contain the water-soluble cpds of following various compositions, and said composition and ratio thereof (weight part) are as follows:
The composition weight part
Nitrogen 10-15
Phosphorus 4-6
Potassium 4-6
Calcium 4-5
Magnesium 4-5
Sulphur 2-3
Rare earth (mixing) 0.2-0.6
Silicon 0.7-1
Boron 0.3-0.5
Iron 0.2-0.5
Copper 0.2-0.5
Sodium 0.5-1
Zinc 0.3-0.7
Manganese 0.1-0.3
Aluminium 0.2-0.5
Germanium 0.01-0.03
Lithium 0.01-0.03
Chromium 0.02-0.05
Selenium 0.01-0.03
Strontium 0.01-0.03
Chlorine 0.02-0.05
Cobalt 0.01-0.05
Molybdenum 0.0005-0.0015
Titanium 0.0005-0.0015
In addition, the inventor is also noted that, medical stone contains many above-mentioned necessary for plant growth elements that are, as long as it is medical stone is levigate, and use the dilute sulphuric acid acidifying, stack retting 3-7 days, just can make wherein useful element become soluble sulphate discharges, after its pH value being adjusted to the scope of 5-7 with alkali, analyze the wherein water-soluble salt content of contained above-mentioned essential element, supply aforementioned proportion for the nothing that does not reach aforementioned proportion is plain with its soluble salt then, can obtain compound fertilizer of the present invention, because China contains relatively large medical stone is arranged, and as long as wherein the total content of rare earth element is more than 3 weight %, usually all contain above-mentioned element, therefore, utilize medical stone can reduce production costs greatly for raw material.
Thereby, the present invention also provides a kind of manufacture method of compound fertilizer, it is characterized in that, the medical stone of a kind of rare earth element total content more than 3 weight % is levigate, then with dilute sulphuric acid with the medical stone acidifying, keep the pH value under the acidic conditions below 2 with maifanite powder stack retting 3-7, with alkali its pH value is adjusted to the scope of 5-7 then, analyze the water-soluble salt content of wherein contained above-mentioned essential element, supply aforementioned proportion for the element of deficiency qualification ratio with its soluble salt then.
In above-mentioned method, wherein saidly be used to supply the used soluble salt of qualification ratio and be preferably conventional commodity chemical fertilizer.
Compare with the various fertilizer of prior art, the advantage of compound fertilizer of the present invention is: obvious effect of increasing production, increase production 5-30% than equivalent urea more.Therefore the few volatilization loss of effective constituent keep the time of fertilizer efficiency long.Can improve the drought resisting of farm crop, the ability of cold-resistant, disease and insect resistance significantly; can improve agricultural product quality; and can improve and protect soil; and production cost is lower, the required investment of factory of estimate building production compound fertilizer of the present invention (Quan Jingfei) only be equivalent to approximately etc. the scale urea plant investment 10%.
Enumerate embodiment and application examples below and further explain the present invention.Embodiment 1
The medical stone that a kind of mishmetal content is 3.5 weight % is levigate to 125 μ m (120 order), then with thinning ratio be the dilute sulphuric acid of 1: 1 (volume) with medical stone: the ratio of dilute sulphuric acid=1: 2 is carried out acidifying, keeping the pH value to be lower than under 1.5 the condition stack retting 5 days, with ammoniacal liquor the pH value of this slaking thing is adjusted to 6-7 then, at this moment the product that obtains has caking phenomenon, and obtaining product is crushed to 841 μ m (20 order).The soluble salt content of the wherein contained above-mentioned essential element of sampling analysis then.Wherein: calcium, magnesium, sulphur, rare earth, silicon, iron, copper, zinc, manganese, aluminium, germanium have met or exceeded aforementioned proportion all.In the element of not enough aforementioned proportion, except nitrogen, phosphorus, potassium were supplied by commercially available chemical fertilizer, other corresponding water-soluble salts with commercially available industrial chemicals added, and make various components in proportions meet the weight part ratio of above-mentioned qualification.
In following application examples, for the purpose of more convenient and clearer, compound fertilizer of the present invention is called complete smart fertile.
Application examples 1
Complete smart fertilizer of the present invention is done the contrast of equivalent fertilizer efficiency with urea, be used for the Ipomoea batatas crop, test site is a Shanghai Suburb.Test area respectively is 85 mu, and output is got every mu mean value.
The result: every mu of Ipomoea batatas output of executing 18kg urea is 1352kg/ mu, and every mu of Ipomoea batatas output of using the complete smart fertile 18kg of the present invention is 1855kg/ mu.As seen, the complete smart fertile units increased in production of the present invention is than many 503kg/ of equivalent urea mu, and promptly stimulation ratio is 503/1352=37.2%.
Application examples 2
The test area is Yantai, Shandong, and subjects is apple (all being the Fuji apple), and with urea and complete smart fertile contrast the of the present invention, each tests 100 strains, presses the single plant yield average computation.
The result: the apple production average out to 190kg/ strain of 2.5kg urea is used in every strain, and the complete smart fertile apple production average out to 240kg/ strain of 2.5kg the present invention is used in every strain.As seen, the complete smart fertile units increased in production individual plant apple of the present invention is than many 50kg/ of equivalent urea strain, and promptly stimulation ratio is 50/190=26.3%.
Application examples 3
The test area is a suburb of Shanghai, and subjects is a peanut, and with urea and complete smart fertile contrast the of the present invention, each tests 45 mu, by every per mu yield average computation.
The result: every mu of peanut yield of using 17.5kg urea is a 292kg/ mu, and every mu of peanut yield of using the complete smart fertilizer of 17.5kg the present invention is a 394kg/ mu.As seen, the complete smart fertile units increased in production of the present invention is than many 102kg/ of equivalent urea mu, and promptly stimulation ratio is 102/292=34.9%.
Application examples 4
The test area is Rizhao City suburb, Shandong, and subjects is a paddy rice, and with urea and complete smart fertile contrast the of the present invention, each tests 60 mu, by every per mu yield average computation.
The result: every mu of paddy rice single cropping output of using 17.5kg urea is 321.8kg/ mu, and every mu to use the complete smart rich water rice single cropping output of 17.5kg the present invention be 381kg/ mu.As seen, the complete smart fertile units increased in production of the present invention is than many 59.2kg/ of equivalent urea mu, and promptly stimulation ratio is 59.2/321.8=18.4%.
Claims (6)
1, a kind of compound fertilizer is characterized in that, it is the composition that contains following ingredients:
The composition weight part
Nitrogen 10-15
Phosphorus 4-6
Potassium 4-6
Calcium 4-5
Magnesium 4-5
Sulphur 2-3
Rare earth (mixing) 0.2-0.6
Silicon 0.7-1
Boron 0.3-0.5
Iron 0.2-0.5
Copper 0.2-0.5
Sodium 0.5-1
Zinc 0.3-0.7
Manganese 0.1-0.3
Aluminium 0.2-0.5
Germanium 0.01-0.03
Lithium 0.01-0.03
Chromium 0.02-0.05
Selenium 0.01-0.03
Strontium 0.01-0.03
Chlorine 0.02-0.05
Cobalt 0.01-0.03
Molybdenum 0.0005-0.0015
Titanium 0.0005-0.0015
More than each composition all exist with the state of water-soluble cpds.
2, compound fertilizer as claimed in claim 1 is characterized in that, it is combined with organic commercial fertilizer by above-mentioned composition and constitutes, and it in conjunction with ratio (weight ratio) is:
Above-mentioned composition: organic commercial fertilizer=1: (1-10), in above-mentioned composition, the weight percent of nitrogen is 10-15 weight %, and all the other components in certain proportion are analogized, and the surplus of less than 100 weight % partly is a water;
Said organic commercial fertilizer is meant urea and/or the volatile salt of nitrogenous 46 weight %.
3, compound fertilizer as claimed in claim 1 is characterized in that, it is combined with bacterial manure by above-mentioned composition and constitutes, and it in conjunction with ratio (weight ratio) is:
Above-mentioned composition: bacterial manure=1: (0.01-0.03), in above-mentioned composition, the weight percent of nitrogen is 10-15 weight %, and all the other components in certain proportion are analogized, and the surplus of less than 100 weight % partly is a water;
Said bacterial manure is meant the azotogen that capital, Jiangxi biological chemical fertilizer company limited produces, and vinelandii concentration is 5 * 10
3-5 * 10
8Individual/ml.
4, compound fertilizer as claimed in claim 1 is characterized in that, it is combined with organic commercial fertilizer and bacterial manure by above-mentioned composition and constitutes, and it in conjunction with ratio (weight ratio) is:
Above-mentioned composition: organic commercial fertilizer: bacterial manure=1: (1-10): (0.01-0.03), in above-mentioned composition, the weight percent of nitrogen is 10-15 weight %, and all the other components in certain proportion are analogized, and the surplus of less than 100 weight % partly is a water;
Said organic commercial fertilizer is meant urea and/or the volatile salt of nitrogenous 46 weight %;
Said bacterial manure is meant the azotogen that capital, Jiangxi biological chemical fertilizer company limited produces, and vinelandii concentration is 5 * 10
3-5 * 10
8Individual/ml.
5, a kind of manufacture method of compound fertilizer, it is characterized in that, it is levigate and meet following ratio (weight part) scope according to each component proportions in the final finished fertilizer and mix the formation composition mutually to contain the water-soluble cpds of following various compositions, and said composition and ratio thereof (weight part) are as follows:
The composition weight part
Nitrogen 10-15
Phosphorus 4-6
Potassium 4-6
Calcium 4-5
Magnesium 4-5
Sulphur 2-3
Rare earth (mixing) 0.2-0.6
Silicon 0.7-1
Boron 0.3-0.5
Iron 0.2-0.5
Copper 0.2-0.5
Sodium 0.5-1
Zinc 0.3-0.7
Manganese 0.1-0.3
Aluminium 0.2-0.5
Germanium 0.01-0.03
Lithium 0.01-0.03
Chromium 0.02-0.05
Selenium 0.01-0.03
Strontium 0.01-0.03
Chlorine 0.02-0.05
Cobalt 0.01-0.05
Molybdenum 0.0005-0.0015
Titanium 0.0005-0.0015
6, a kind of manufacture method of compound fertilizer, it is characterized in that, the medical stone of a kind of rare earth element total content more than 3 weight % is levigate, then with dilute sulphuric acid with the medical stone acidifying, keep the pH value under the acidic conditions below 2 with maifanite powder stack retting 3-7 days, with alkali its pH value is adjusted to the scope of 5-7 then, analyze the water-soluble salt content of wherein contained following essential element, supply the proportional range of following qualification composition for the element that does not reach following ratio (weight part) scope with its soluble salt then, the proportional range of said composition is:
The composition weight part
Nitrogen 10-15
Phosphorus 4-6
Potassium 4-6
Calcium 4-5
Magnesium 4-5
Sulphur 2-3
Rare earth (mixing) 0.2-0.6
Silicon 0.7-1
Boron 0.3-0.5
Iron 0.2-0.5
Copper 0.2-0.5
Sodium 0.5-1
Zinc 0.3-0.7
Manganese 0.1-0.3
Aluminium 0.2-0.5
Germanium 0.01-0.03
Lithium 0.01-0.03
Chromium 0.02-0.05
Selenium 0.01-0.03
Strontium 0.01-0.03
Chlorine 0.02-0.03 cobalt 0.01-0.05 molybdenum 0.0005-0.0015 titanium 0.0005-0.0015
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 97112328 CN1062255C (en) | 1997-06-19 | 1997-06-19 | Compound fertilizer and producing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 97112328 CN1062255C (en) | 1997-06-19 | 1997-06-19 | Compound fertilizer and producing method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1203213A true CN1203213A (en) | 1998-12-30 |
| CN1062255C CN1062255C (en) | 2001-02-21 |
Family
ID=5172213
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 97112328 Expired - Fee Related CN1062255C (en) | 1997-06-19 | 1997-06-19 | Compound fertilizer and producing method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1062255C (en) |
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100999416A (en) * | 2006-01-10 | 2007-07-18 | 吕周锋 | Fertilizer for preventing and treating gumming disease of fruit tree |
| CN100408523C (en) * | 2005-09-29 | 2008-08-06 | 吕周锋 | Fertilizer against plant root rot |
| CN100418931C (en) * | 2006-11-02 | 2008-09-17 | 西北农林科技大学 | Chromium-rich liquid and its use in production of chromium (Cr) -rich liquid3+) Application of pumpkin |
| CN101844947A (en) * | 2010-04-13 | 2010-09-29 | 龙宗友 | Trace element water-soluble fertilizer and preparation method thereof |
| CN102633578A (en) * | 2012-05-15 | 2012-08-15 | 贵州科农生态环保科技有限责任公司 | Karst shrub revetment vegetation selenium-enriched trace fertilizer and preparation method thereof |
| CN102795909A (en) * | 2012-09-08 | 2012-11-28 | 陈海滨 | Multi-microelement compound fertilizer, rice planted by using same and method for producing rice |
| CN103204734A (en) * | 2013-03-15 | 2013-07-17 | 成钢 | Nanometer rare earth selenium silicon titanium macro-trace element composite nutrition fertilizer |
| CN103755498A (en) * | 2014-01-23 | 2014-04-30 | 成都新柯力化工科技有限公司 | Water-soluble mineral fertilizer and preparation method thereof |
| CN106146169A (en) * | 2016-08-08 | 2016-11-23 | 河南省农业科学院园艺研究所 | A kind of full dietary vegetable special-purpose irrigation fertilizer and preparation method thereof |
| WO2016193923A1 (en) * | 2015-06-04 | 2016-12-08 | I. D. Tech S.R.L. | Lithium and selenium containing composition for treating vegetables |
| CN106416689A (en) * | 2016-09-19 | 2017-02-22 | 任彦永 | Planting method for chromium-rich corn |
| CN106431662A (en) * | 2016-09-29 | 2017-02-22 | 印天寿 | Rice leaf fertilizer rich in trace elements of boron, molybdenum, selenium, chromium and cobalt and application thereof |
| CN106748291A (en) * | 2017-02-09 | 2017-05-31 | 赵瑜 | It is a kind of to contain 14 kinds of composite fluid Water soluble fertilizers of element and preparation method thereof |
| CN108358732A (en) * | 2018-05-28 | 2018-08-03 | 张森森 | A kind of richness germanium selenium-enriched health care organic fertilizer |
| CN111088051A (en) * | 2018-10-23 | 2020-05-01 | 南京化学工业园环保产业协同创新有限公司 | Environment-friendly soil spraying agent and preparation method thereof |
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1997
- 1997-06-19 CN CN 97112328 patent/CN1062255C/en not_active Expired - Fee Related
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100408523C (en) * | 2005-09-29 | 2008-08-06 | 吕周锋 | Fertilizer against plant root rot |
| CN100999416B (en) * | 2006-01-10 | 2010-11-17 | 吕周锋 | Fertilizer for preventing and treating gumming disease of fruit tree |
| CN100999416A (en) * | 2006-01-10 | 2007-07-18 | 吕周锋 | Fertilizer for preventing and treating gumming disease of fruit tree |
| CN100418931C (en) * | 2006-11-02 | 2008-09-17 | 西北农林科技大学 | Chromium-rich liquid and its use in production of chromium (Cr) -rich liquid3+) Application of pumpkin |
| CN101844947A (en) * | 2010-04-13 | 2010-09-29 | 龙宗友 | Trace element water-soluble fertilizer and preparation method thereof |
| CN101844947B (en) * | 2010-04-13 | 2012-11-07 | 龙宗友 | Trace element water-soluble fertilizer and preparation method thereof |
| CN102633578B (en) * | 2012-05-15 | 2013-12-18 | 贵州科农生态环保科技有限责任公司 | Karst shrub revetment vegetation selenium-enriched trace fertilizer and preparation method thereof |
| CN102633578A (en) * | 2012-05-15 | 2012-08-15 | 贵州科农生态环保科技有限责任公司 | Karst shrub revetment vegetation selenium-enriched trace fertilizer and preparation method thereof |
| CN102795909A (en) * | 2012-09-08 | 2012-11-28 | 陈海滨 | Multi-microelement compound fertilizer, rice planted by using same and method for producing rice |
| CN103204734A (en) * | 2013-03-15 | 2013-07-17 | 成钢 | Nanometer rare earth selenium silicon titanium macro-trace element composite nutrition fertilizer |
| CN103755498A (en) * | 2014-01-23 | 2014-04-30 | 成都新柯力化工科技有限公司 | Water-soluble mineral fertilizer and preparation method thereof |
| WO2016193923A1 (en) * | 2015-06-04 | 2016-12-08 | I. D. Tech S.R.L. | Lithium and selenium containing composition for treating vegetables |
| CN106146169A (en) * | 2016-08-08 | 2016-11-23 | 河南省农业科学院园艺研究所 | A kind of full dietary vegetable special-purpose irrigation fertilizer and preparation method thereof |
| CN106416689A (en) * | 2016-09-19 | 2017-02-22 | 任彦永 | Planting method for chromium-rich corn |
| CN106431662A (en) * | 2016-09-29 | 2017-02-22 | 印天寿 | Rice leaf fertilizer rich in trace elements of boron, molybdenum, selenium, chromium and cobalt and application thereof |
| CN106748291A (en) * | 2017-02-09 | 2017-05-31 | 赵瑜 | It is a kind of to contain 14 kinds of composite fluid Water soluble fertilizers of element and preparation method thereof |
| CN108358732A (en) * | 2018-05-28 | 2018-08-03 | 张森森 | A kind of richness germanium selenium-enriched health care organic fertilizer |
| CN111088051A (en) * | 2018-10-23 | 2020-05-01 | 南京化学工业园环保产业协同创新有限公司 | Environment-friendly soil spraying agent and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1062255C (en) | 2001-02-21 |
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