CN103204734A - Nanometer rare earth selenium silicon titanium macro-trace element composite nutrition fertilizer - Google Patents
Nanometer rare earth selenium silicon titanium macro-trace element composite nutrition fertilizer Download PDFInfo
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Abstract
The invention discloses nanometer rare earth selenium silicon titanium macro trace element composite nutrition fertilizer, which belongs to the technology field of composite nutrition fertilizer preparation production in agricultural production. Because of various pollutions, the heavy metal content of crops exceeds the standard, elements are not balanced, and thus various diseases are caused. According to the technical sheme of the invention, based on the relationship between soil crops and rare earth elements, selenium, silicon, titanium, macro trace elements needed by human body, as well as the fertilizer , inorganic elements are converted into organic compounds by plants, and nanometer technology is used to help people to obtain enough nutrients from crops grown in the soil so as to maintain human body element balance. Therefore, the purposes of element balance, disease prevention and human body health are reached by timely applying the element composite nutrition fertilizer to the soil and crops during growth.
Description
Technical field:
Nano rare earth selenium silicon titanium macro micro element compound nutritional fertilizer of the present invention is to belong to the agricultural crops family balcony gourd, fruit and vegetable fertile preparation of the comprehensive compound nutritional of the nuisanceless high-quality nutritive element of the safety non-pollution production technical field of growing.
Background technology:
21 century is " green " century, it is human industrial development, economic liftoff, human society, welfare, spirit, the epoch that material is increasing, also be that the modern humans lives and can't leave the highly developed science and technology society of high-tech, but while high-speed development of science and technology, going deep into of Industrial Revolution, caused global serious environmental water quality again, soil, the pollution of air, the sharp increase of developing country's population in addition, improving constantly of grain demand amount, excessive use chemical fertilizer, agricultural chemicals causes the soil salt accumulation, soil, water quality, air, food crop, trace element is in great shortage in the food such as gourd, fruit and vegetable, and harmful heavy metal and pesticide residue day by day increase the weight of.To how solving the contradiction that economic liftoff and shortage of resources, population growth, environmental pollution, food safety and human health lengthen one's life, it is the challenge that the 21 century mankind face jointly.21 century is the century of one " green ", face serious environmental pollution day by day, countries in the world have been paid attention on the basis of implementing Sustainable development, take the action of essence, caused the self-examination that people are extensive and deep to only paying close attention to the production of food in the past and the conventional food mode of production of economic benefit, must consider the mode of production and method, to resource, environment, the consumer group's long-range health affected, and the problems that lengthen one's life of people's in-vivo element balance, health.Elemental abundance in the tissue is similar substantially to the crustal elements abundance, and human body just can be healthy.We know that element mainly directly or indirectly enters human body by rock system, water system, soil and botanical system in the geologic media, and then influence HUMAN HEALTH.Usually matrix is the main system of biosphere trace element, has controlled the general trend of various trace elements in the coenocorrelation, and content of elements and proterties have just determined the basic configuration of trace element in the ecotope in the soil.It is no doubt important to use in the soil micronutrient levels, but but the size of the proterties of these elements, particle diameter in other words in the soil absorption rate of trace element, plant then even more important.The main source of nutrition that plant then grows and yields positive results with the trace element in the soil.Human because picked-up grain, gourd, fruit and vegetable, the water of edible natural, breathe the air of nature, because what be subjected to that element in the environment distributes is unbalanced, thereby it is unbalance to influence people's in-vivo element, cause developing of multiple disease, the research tectonic environment is understood by system thus, soil, water quality, air, plant is food crop especially, the rich scarce situation of trace element in the gourd, fruit and vegetable, use nano rare earth selenium silicon titanium macro micro element compound nutritional fertilizer targetedly, to increasing farm crop, micronutrient levels reaches people's in-vivo element balance in the gourd, fruit and vegetable food, and is most important to preventing and treating human multiple disease.
Summary of the invention
The object of the present invention is to provide a kind of nano rare earth selenium silicon titanium macro micro element compound nutritional fertilizer.
Technical solution of the present invention is:
A kind of nano rare earth selenium silicon titanium macro micro element compound nutritional fertilizer is characterized in that:
1, universal nano rare earth selenium silicon titanium macro micro element compound nutritional fertilizer is formed % by following proportion by weight
(1) organoselenium or nanometer selenium 0.6; (11) phosphoric acid 8;
(2) organic germanium Ge-132 0.4; (12) potassium silicate 6;
(3) the medical stone nano powder 6; (13) lime acetate 8;
(4) the tourmalinite nano powder 4; (14) magnesium chloride 6;
(5) the rare earth nano powder 2; (15) ferric sulfate 0.2;
(6) calcium nitrate tetrahydrate 18; (16) zinc sulfate 0.4;
(7) silicon-dioxide SiO
210; (17) copper sulfate 0.2;
(8) potassium primary phosphate 3.8; (18) boric acid 2;
(9) bitter salt 12; (19) manganous sulfate 4;
(10) titanium dioxide TiO
28; (20) ammonium molybdate 0.4;
Above component sum is 100%;
2, a kind of nano rare earth selenium silicon titanium macro micro element compound nutritional fertilizer is characterized in that: be applicable to the grand micro-compound nutritional fertilizer of gourd, fruit and vegetable nano rare earth selenium silicon titanium, form % by following proportion by weight
(1) Se-rich lucid ganoderma mycelium nano powder 6; (11) manganous sulfate 4;
(2) Ganoderma rich in germanium mycelium nano powder 4; (12) boric acid 6;
(3) the medical stone nano powder 8; (13) Sodium orthomolybdate 2;
(4) the tourmalinite nano powder 6; (14) chelated iron 6;
(5) the rare earth nano powder 4; (15) titanium dioxide TiO
24;
(6) nitrocalcite 10; (16) silicon oxide sio
25;
(7) saltpetre 15; (17) copper sulfate 2;
(8) potassium primary phosphate 1; (18) urea 8;
(9) sal epsom 5; (19) phosphoric acid 2;
(10) zinc sulfate 1; (20) sodium metavanadate 1;
Above component sum is 100%;
3, a kind of nano rare earth selenium silicon titanium macro micro element compound nutritional fertilizer is characterized in that: be applicable to flowers and trees bonsai nano rare earth selenium silicon titanium macro micro element compound nutritional fertilizer, form % by following mass parts composition proportion
(1) biological red selenium 5; (11) manganous sulfate 0.4;
(2) Ganoderma rich in germanium mycelium nano powder 4; (12) zinc sulfate 0.6;
(3) the medical stone nano powder 6; (13) copper sulfate 0.2;
(4) very ice stone nano powder 5; (14) ammonium molybdate 0.2;
(5) the rare earth nano powder 3; (15) boric acid 0.8;
(6) nitrocalcite 15; (16) titanium oxide TiO2 2;
(7) ammonium nitrate 7; (17) potassium primary phosphate 3;
(8) saltpetre 4; (18) silicon-dioxide SiO2 0.6;
(9) sal epsom 5; (19) water adds to 100%;
(10) ferric sulfate 5;
World's all things on earth all is made up of atoms of elements, and the people can not make an exception certainly.Various organs such as people's skin, muscle, bone, the heart, liver, spleen, lung, kidney, stomach, body fluid, blood, though all formed by cell or gene molecule, but all organs, body fluid, blood, cell or gene molecule all are made up of various atoms of elements, various atoms of elements are to form the most basic unit of temporal, also are ingredient, cell, body fluid, blood, organ and the most basic unit of whole human body.All be to live at the earth's surface over millions of year from the human evolution, by breathing, drinking water and take food, make the exchange of substance of human body and earth surface and energy exchange reach running balance, the temperature of human body keeps about 37 ℃, be that energy exchange reaches running balance, this is well-known sign.The average content of tens kinds of elements of average content and the earth's crust of tens kinds of elements is consistent in the normal human, the average content of tens kinds of elements also is consistent in the average content of tens kinds of elements in normal human's blood and the seawater, but because earth's crust surface, in order to improve the unit surface crop yield to satisfy population growth food crop requirement, excessively in the farmland, use chemical fertilizer, agricultural chemicals to cause the accumulation of soil salt, Industrial Revolution, industrial expansion have caused the global environment severe contamination again; The development of communications and transportation has caused atmospheric pollution again, accelerates soil pollution like this.The residual quantity of harmful heavy metal lead, mercury, arsenic, cadmium and pesticide residue day by day increases the weight of to cause trace element day by day to lack of proper care in the food such as food crop that grown out by soil.Be mainly derived from soil as human body necessary 16 kinds of trace element zincs, iron, manganese, copper, cobalt, chromium, molybdenum, vanadium, tin, strontium, nickel, iodine, fluorine, selenium, germanium, silicon: the essential trace element relevant with plant-growth of generally acknowledging has boron, manganese, molybdenum, zinc, copper, iron, chlorine etc. at present, and what easily absorb for animals and plants is micro-organic in the soil, comprise in water-soluble attitude, exchange state and the part organic trace element that can be utilized by plant absorbing, be referred to as the validity trace element.Certainly it also will depend on potential of hydrogen, redox potential, soil matter degree, the permeability of soil, activity, organic content and the soil absorptive character etc. of microorganism.Usually slant acidity soil available content is higher, and this not only is conducive to crop yield, also can optimize crop quality, increases the content of the element zinc that is conducive to HUMAN HEALTH in the crop, iron, manganese.Use molydbenum fertilizer as soybean and can improve protein and fatty content in the seed, zinc fertilizer can improve protein in the rice grain, starch, sugar and potassium, magnesium, copper equal size, can also improve the corn total amino acid content.Winter wheat is used the content that zinc, manganese fertilizer can increase aleuronat and pure gluten in the seed, and manganese and copper fertilizer can improve the content of mucedin in the winter rye seed.The tea tree application of zinc fertilizer can improve the formation condition of plant young shoot, promotes the accumulation of catechol in the tealeaves, and boron fertilizer can improve aminoacids content in the tealeaves, and manganese fertilizer can improve ascorbic content in the tealeaves.The application of selenium fertilizer on agricultural in recent years, more and more be subjected to domestic and international pollution-free food production, the attention of processing, rationally use selenium fertilizer and zinc fertilizer, can not only improve output, optimize crop quality, can also utilize selenium and zinc to the antagonistic action of some harmful element, reduce in the green food plumbous, the content of cadmium, confirm by experiment: selenium, zinc can make vegetables to plumbous in the soil, the absorption of cadmium reduces 30-50%, pea seedlings with the composite nutritive solution seed soaking cultivation that contains selenium, not only make in the bean seedlings and plumbously to reduce nearly 1 times, and selenium is enriched to more than 10 times, output improves 17-40%, height of seedling increases 18-47%, and the brown mould variable area is reduced to 0 from 90%, and this is to selenium, zinc is rational Application on agricultural crops, can solve heavy metal in soil effectively pollutes, be that the new measure that utilizes the exploitation that promotes green food is arranged, be conducive to promote the human elementary picked-up, health lengthens one's life.Its implementation method has＜1〉Plant Transformation method, mainly is that selenium fertilizer is executed in utilization or root is annotated, the method for foliar spray selenium aerosol, makes plants such as food crop, vegetables, tealeaves, fruit increase selenium content.＜2〉animal conversion method, be in animal-feed, to add selenium, make organic selenium content increase in the animal product, thereby obtain Se-enriched egg, Se-enriched honey, but preferably add organoselenium in the animal-feed, if adding inorganic selenium will play for safety, because inorganic selenium has toxicity, if improper use can cause poisoning, inorganic selenium is difficult for by gastrointestinal absorption simultaneously, unabsorbed selenium is discharged by ight soil, pollutes the environment.Japan bans use of inorganic selenium in the regulation animal-feed.Develop rich selenium animal food for this reason and preferably select organoselenium for use, as yeast rich in selenium, rich selenium cereal forage feed animal, to ensure the security of selenium-enriched food.The method that external great majority are mended selenium is to adopt Na
2SeO
3Its method is: with Na
2SeO
3Be made into different concns or seed soaking or spray, make selenium by crop absorption, produce the agricultural-food of certain selenium content, its crop species, comprise crop products such as paddy rice, corn, soybean, tealeaves, tobacco leaf, gourd, fruit and vegetable, in many cases, the selenium in the rich selenium livestock product is that the approach by soil → plant → animal enters product, also is no lack of the example of directly admixing feed applications with selenium source certainly.Studies have shown that, appropriate supplement selenium, make that various nutritive ingredients tend to balance in the soil, naturally improve crop to the absorption rate of other fertilizer nutritive element, promote growth and the volume increase of crop, add and can change elementary composition in the plant materials behind the selenium, the amino acid in the agricultural-food and VITAMIN also increase than the content of the common agricultural-food that do not add selenium.Length is executed selenium-enriched fertilizer, can alleviate the chemical residue in the soil, improves and activating soil, and reduces the use of farm crop nitrate effectively.＜3〉microbial enrichment method, be exactly a kind of bacterium selenium that is named as biological selenium that occurs recently, its selenium content is more high, be 15000mg/L, be rich selenium product, be a kind ofly to produce via microbial fermentation, during the fermentation, fermented liquid is from the original light yellow redness that becomes, at microscopically, the motion of the ZM bacterium of red color visible, each thalline be as a sack of containing selenium, in filled red biological selenium, through international online retrieval, this red biological selenium is that the highest biological selenium that leads the world technology level of China's independent development selenium content is as China's agricultural crops especially selenium-rich rice, wheat, soya bean, peanut, garlic, the artificial ganoderma, the Application and Development of genseng provides valuable first chance, human-body biological is mended selenium solved big problem.
Make the main source that transforms into the biogenic organoselenium of inorganic selenium by culturing micro-organisms, many microorganisms such as yeast rich in selenium, the Se-rich lucid ganoderma bacterium, their fast growth, it is convenient to cultivate, various culture condition are easy to control and grasp, harvest cycle is short, for example yeast is the excellent carrier of gathering trace element, it contains rich nutrient substances such as protein accounts for 40-50%, abundant indispensable amino acid is wherein arranged, vitamin B group, the proteolytic enzyme of needed by human, amylase and the numerous nucleic acid of number class, polysaccharose substance, pass through culturing micro-organisms, make inorganic selenium change into organoselenium, mainly be with yeast rich in selenium and rich selenium fungi, by the barms of selecting to be fit to, under specific culture environment, adding essential an amount of trace element makes and is rich in our needed trace element in the yeast cell of acquisition and refers to the selenium element here, this bio-transformation beneficiation technologies, be to realize by the suitable instruction cultivation of the biology dosage that goes down to posterity progressively, Ganoderma fungi and for example, be that selenium rich ability is the strongest, the selenium of its enrichment mainly contains albumen selenium, organic selenium such as polysaccharide selenium and nucleic acid selenium exist, use fermentation engineering, the technology of more organoselenium is obtained in the microbial transformation of cultivating the selenium resource by the rich selenium of edible mushrooms, namely adds Na at substratum
2SeO
3Concentration can make the interior selenium content of Ganoderma mycelium replenish biological red selenium up to 5000-8000mg/kg with 50mg/kg; Also having Ganoderma mycelium enriched germanium (Ge) also is the organic germanium that the microbial transformation of using fermentation engineering to cultivate the germanium resource is obtained, and shows that by dialysis and detection germanium reaches 497-3300mg/g, illustrates that inorganic Ge changes into organic germanium in the Ganoderma mycelium by cultivation.GeO in the nutrient solution
2Under solutions of weak acidity, with GeO
4+Form exists, and organic carboxyl acid wherein becomes organic chromic salts with the germanium chelating, or is called the Ganoderma rich in germanium mycelium.
Germanium has the effect that promotes plant-growth, can guarantee that also rice seedling grows vigorously in cold ice environment, experimental results show that germanium can promote the growth of genseng and improve its quality, strengthen with the disease-resistant cold tolerance of the genseng of organic germanium cultivation, find that in recent years wild Ganoderma, wild mountain ginseng are germanic respectively up to 2000 * 10
-6With 4000 * 10
-6No wonder the mankind are described as elixir, celestial grass, help medicine, miraculous cure to glossy ganoderma, genseng since ancient times, it can promote HUMAN HEALTH, regulates physiological function, anti-inflammatory, antibiotic, anticancer, anti-aging.Selenium germanium is united utilization, can effectively remove human free radical, the organic germanium pharmacological action mainly shows the key that three band oxygen are arranged in its unique molecular structure that has, oral absorption can provide a large amount of oxygen to systemic cell, improve metabolism, strengthen cellular activity, promote tissue regeneration, the ability of strengthening immunity and resist the disease, anti-cancer, anticancer, anticancer formation, blood viscosity lowering, blood flow increasing improves blood circulation and organ dysfunction, increases blood vessel elasticity, bring high blood pressure down, prevent that cardiovascular and cerebrovascular diseases and cerebral thrombosis, cerebral apoplexy from forming.Germanium distributes very extensive in living organism, many enzymes in the organism, in the cortex and grey matter of human brain, cell walls, plastosome, karyomit(e), all contain element Ge in the subcellular components such as lysosome, because the special medical health-care effect that the biological activity of germanium and it are risen in human body, caused chemist in the world, pharmacologist and nutritionist be interest and concern greatly, be called as " jinx of human diseases ", " the help germanium of 21st century ", " 21st century lifespring ", " nova in the vibrations world ", good names such as " bodyguards of HUMAN HEALTH ", because germanium also is the conditioning agent of plant-growth, can promote cereal, vegetables, the growth of fruit etc. and improvement quality, be added on nano rare earth selenium silicon titanium macro micro element compound nutritional fertilizer and be applied in the soil of crop growth, soil is the natural treasure-house of the needed trace element of plant-growth.Plant absorbs these and contains the essential nutritive ingredient of the numerous elements of selenium germanium from soil and compound nutritional fertilizer, keep its life movement process of growing, and the numerous elemental compositions of these selenium germanium are stored in rhizome, leaf, the fruit, this kind of plant rhizome, leaf, fruit are as the food of animal, these are rich in the numerous trace element of selenium germanium then transfers in the humans and animals body from plant, thereby makes element in the humans and animals body effectively be regulated, replenish and antagonism lengthens one's life people's in-vivo element balance, health.
Find according to the scientific research in millions of years of human evolution: the balance of keeping tens kinds of elements in the human body is the factor of the long-lived most critical of human health, that is to say that the content of certain element in human body not only should not be too much but also unsuitable very few, it is just the most healthy just in time to meet the Human Physiology requirement.The 2nd, between tens kinds of elements a suitable ratio ability co-ordination to be arranged in the human body, just be of value to healthy, human body only meets these two equilibrium conditionss and could live 150 years old natural span of life.Yet element is to synthesize necessary picked-up through food chain in human body automatically, next is the nasal respiration of water and air per os, gastrointestinal absorption enters human body, and human body is to the height of various element absorption rates and restricted by multiple factor, organic compound with a kind of element is all higher than specific absorption and the bioavailability of mineral compound, the mineral compound salt particle diameter of solubility is little, the trace element salt can pass through cell coat, enter in the cell so the absorption rate height through Microvillares plasma membrane then, and insoluble trace compound, because of particle grain size big, can be by the effective filtering of cell coat of constantly outwards moving, so holes that comes off through the old chrotoplast in fine hair top on a small quantity and to enter in the intestinal villus absorption rate little only, in order to address the above problem, inorganic states of the present invention becomes the organic compound through Plant Transformation, and with its grain size nanometer.Human only managing replenished poor day by day micronutrient element in soil, just can keep this balance of human elementary, to guarantee that soil can be that the growth of crop normal growth provides enough trace elements, so, in time an amount of uses elements compounding nutrition fertilizer in soil and plant growing process, become to keep important channel and the means of this balance.
The medical stone dissolving out capability is good, being soaked in water can stripping calcium Ca, magnesium Mg, more than 40 kind of element such as potassium K, sodium Na, strontium Sr, selenium Se, zinc Zn, iodine I, metasilicic acid and mineral substance, the ability that superpower absorption is arranged and purify water is to be main component with the silicic acid aluminum oxide, silicon-dioxide SiO
2Account for 59.60%, aluminium sesquioxide Al
2O
3Account for 16.50%, silicon is the element that content is only second to oxygen in the earth's crust, also be the mineral matrix of most plant-growths on the earth, silicon is the essential nutritive element of paddy growth, and the silicon element can improve plant type of rice, promote photosynthesis, improve resistant to lodgingly, diseases and insect pests resistance improves rice yield, paddy rice is a representative happiness silicon plant, and it can absorb a large amount of silicon.Silicon is 5-20% at the paddy rice in-vivo content, uses siliceous fertilizer and can improve Soil Nitrogen Supplying, increases paddy rice to the absorption of silicon, nitrogen, phosphorus, regulates paddy rice in the demand of different steps to nitrogen, phosphorus, potassium element.Adopt silicon, nitrogen, the phosphorus compound uses, can improve nitrogen, the utilization ratio of phosphate fertilizer, and can adjust silicon nitrogen ratio and silicon phosphorus ratio more coordinates nutrition, strengthen the ability of the anti-high nitrogen of paddy rice, alleviate because nitrogen fertilizer application is caused remaining green when it is due to become yellow and ripe partially, excessive growth, unfavorable phenomenons such as lodging, raising absorbs other nutritive element, increase nitrogen and potassium content in output and the paddy rice seed, improve the paddy rice salt tolerance, make the sodium generation chemical reaction in Calucium Silicate powder and the saltings, reduce the harm of sodium ion, it is reported that rice application siliceous fertilizer and calcium phosphorus fertiliser containing magnesium are very remarkable to the effect that suppresses Rice Absorbed Cadmium, can suppress simultaneously the strontium in arsenic and the radioactive ash, caesium, the absorption of cadmium, prevent hydrogen sulfide, methane etc. namely prevent the phenomenon of the mashed root of paddy rice to the influence of rice root.Siliceous fertilizer can promote the decomposition of fertilizer, the effect of inhibition soil germ.Under the condition of waterflooding, use the oxidation capacity that siliceous fertilizer can promote root system, suppress the excessive absorption of ferrimanganic, poison thereby alleviate ferrimanganic, in a word, execute siliceous fertilizer and not only improve rice aroma, significantly improve the polished rice rate.Now a large amount of research is verified, silicon is not only bone, cartilaginous tissue and reticular tissue normal growth trace elements necessary, find after deliberation, silicon can make that collagen content obviously increases in bone and the cartilage matrix, the content of oxyproline total protein and noncollagen protein also significantly increases simultaneously, prolyl hydroxylase is key enzyme in the collagen building-up process, and its active reaction collagen biosynthetic process is rapid.Add silicon and can make that the activity of prolyl hydroxylase increases in the osseous tissue in vitro culture chicken embryo frontal bone nutrient solution, illustrating in the collagen biosynthesizing needs element silicon.The X ray trace element analysis shows that in the scleroblast in young osteogenesis district, silicon is one of important element.Its content and calcium, magnesium, phosphorus approach, it mainly accumulates in the osteoblastic plastosome, further specifying silicon is performance important physical effect during bone and cartilage matrix form, silicon can also promote phoirocyte to form extracellular matrix, make polysaccharide content increase rising in collagen content, the matrix, element silicon is mainly concentrated among bone, lung, lymphoglandula, pancreas, suprarenal gland, nail and the hair, content is the highest in reticular tissue such as aorta, tracheae, tendon, bone and skin, and arteriole, cornea, sclera also have quite high content.Silicon can enter in the fetus body by placenta, is the main component of the amorphous link material in collagen spandex and extracellular, and silicon also is present in the various enzymes, keeps the normal development of body and the formation of bone.It is to constitute one of osteoblastic main component, and it participates in the calcification process of bone.Content for silicon in the patient tissues such as osteoporosis, nail fragility, pulmonary disorder, poor growth is lower than 50% than the normal people, and silicon can strengthen blood vessel, particularly the spandex intensity of tunica intima elastic layer, antiatherogenic effect.Silicon can effectively prevent and treat osteoporosis.While silicon-dioxide SiO
2Also be oxide compound titanium dioxide TiO in medical stone commonly used in the common far-infrared radiation material
2Account for 0.78%, it be the far-infrared radiation material be again the representative of photochemical catalysis formula sterilant, it has the effect of degradable organic pollutant, so paid close attention to its catalytic activity height at home and abroad widely, chemical property is stablized non-secondary pollution, nontoxic to human body, cost is low, so be widely used in waste water control and purify air, this material antibacterial ability is strong, has a broad antifungal spectrum, has and namely imitates antibacterial effect.TiO
2The performance of anti-microbial effect is undertaken by katalysis, nano-TiO
2The hole and the electronics that produced by rayed are with the H that is adsorbed in the surface
2O and O
2Form active very strong free radical OH and superoxide ion O
2 -Isoreactivity oxygen.Because the free radical that generates has very strong oxidative decomposition capacity, and extremely strong chemically reactive is arranged, can react with the organism of the toxin that comprises bacterium and secretion thereof on the one hand, thereby with killing bacteria, and bacterium remains and toxin are decomposed into CO
2And H
2O, thereby TiO
2It is the most efficient a kind of antiseptic-germicide of clean environmental protection.Solving atmospheric pollution at present mainly is physisorphtion, and as active carbon adsorption, ozone purification method, Cottrell process, anion fine-purification method etc., but these methods self have the disadvantage that is difficult to overcome, and utilize photocatalytic nanometer TiO
2Purify air the final product CO of energy degradation of organic substances
2And H
2O does not have it to change the appearance of toxic byproduct, can not cause secondary pollution.The water treatment method efficient traditional with water treatment is low, cost is high, has secondary pollution problems, studies show that the farmland that big area is polluted by water, and uses nano-TiO
2Can handle multiple toxic compounds, can be with the hydro carbons in the water, halohydrocarbon, acid surfaces promoting agent dyestuff, itrogenous organic substance, organic phosphorous insecticide, wood preservative and fuel wet goods complete oxidation soon are CO
2, H
2Innoxious substances such as O.Nano-TiO in addition
2At aspects such as degraded wool spinning waste water from dyestuff, organic bromine or phosphorus pesticides certain effect is arranged also, inorganics is at TiO
2The surface also has photochemical activity, for example the chromium Cr in the waste water
6+Have stronger carcinogenesis, under acidic conditions, TiO
2To Cr
6+Have tangible photo catalytic reduction effect, in pH value is 2.5 system, behind the rayed 1h, Cr
6+Be reduced to Cr
3+Reduction effect reaches 85%.The organic compound that has been found that more than 3000 kind of difficult degradation up to now can pass through nano-TiO under ultraviolet irradiation
2Or ZnO and fast degraded, particularly organic contamination substrate concentration height in water, pollution in wide area field farm crop are difficult to degraded again with its change method, use and are rich in TiO
2Nanometer microelement nutrition fertilizer the harm problem that Organic pollutants concentration is high in the obvious degradation water is arranged, this just effectively solves the big area floods and causes the pollution problem in farmland.Titanium dioxide three aluminium Al in the major ingredient of medical stone
2O
3Be the representative of far-infrared radiation formula sterilization, account for 16.5% in the medical stone ingredient, iron protoxide accounts for 1.29%, and ferric oxide FeO accounts for 1.4%, and ferric oxide accounts for 2.58%, is the material that effectively absorption or shielding electromagnetic wave are polluted.Natural anion generator, applied research is maximum is tourmalinite, very ice stone, is to be the ring texture silicate material of feature with the boracic.The key character of this material is under certain condition, can produce thermoelectric effect and piezoelectric effect, namely be under the situation of temperature and pressure, even small variation, also can cause the potential difference between the tourmalinite crystal, be voltage, this static voltage is very high, and strengthen along with the nanoparticle refinement after the tourmalinite pulverizing, its ability is enough to make airborne molecule generation ionization, therefore after in micro-element nutrition fertilizer, adding the tourmalinite nano-powder, under certain external energy fluctuation, as temperature, sunlight, pressure, under the effect of wind-force etc., by tourmalinite nanocrystalline powders two ends have forever just, negative polarity and common water, airborne water molecules or plant, the water molecules contact of soil surface just can produce the ionisation effect that sparks, and is H with water molecules ionization
+And OH
-H
+Be combined with the electronics that tourmalinite discharges and be neutralized into the H atom, and OH
-With other water molecules, can generate hydroxyl negative ion (H continuously
3O
2)
-Through the water of this process, no matter be sour water or alkaline water, all can have the alkalescent water that benefits human body, its main component and medical stone roughly the same also contain Al
2O
3, TiO
2, Fe
2O
3, SiO
2Deng.
Zinc is the essential trace element of rice growth, is composition and the activator of making the object endoenzyme, application of zinc fertilizer ZnSO
47H
2O can strengthen enzymic activity in the paddy rice body, thereby strengthen the root system vigor, hundred increase the 5-10 bar, strengthen tillering ability, advance process of growth, generally tillered in 1-3 days ahead of time, promote the field tiller number, all many 0.24-1.6 of the root and stem of certain plants, improve and divide the root and stem of certain plants percentage of earbearing tiller, the many 0.6-1.5 of every root and stem of certain plants Cheng Sui, several of grains heavily increase the real grain of fringe and increase the 6.4%-10.6% grain, and thousand seed weight increases the average volume increase about 12.5% of 0.24-0.57 gram.
The trace element titanium is titanium dioxide TiO for example
2Also being the composition that medical stone contains, is the representative of photochemical catalysis formula sterilization, and antibacterial ability is strong, and has a broad antifungal spectrum has and namely imitates antibacterial effect.Titanium has the effect of powerful activating enzyme activity in the metabolism of plant-growth, can improve crop to nutrient absorbing, the ability of running and the disease-resistant worm of drought resisting, and can promote the synthetic of photosynthesis of plants and carbohydrate, thereby improve the yield and quality of crop, and harmless to the person poultry safety, do not pollute the environment again, be used for the effect that paddy rice, wheat, barley, corn, gourd, fruit and vegetable etc. all can obtain significant increasing both production and income.
Trace element generally has certain content in soil, but that its validity is influenced by soil is very big, in different soil and the different required trace elements of farm crop rich lack also different, generally scarce what what is mended.The present invention absorbs existing with water-soluble attitude nanoparticle state absorption in the mutual relationship of the little fertilizer of attention and soil and plant growth and the nutritive ingredient that absorbs in the past with water-soluble attitude ionic condition, because its big specific surface area of nanometer microelement, increased the surface-area that is exposed in the medium, promoted the dissolving of element to absorb, because the element particle diameter reduces, increased the distribution of element in plant materials, improved the bioavailability of trace element in plant materials greatly, increased the absorption of farm crop fruit micronutrient levels increase human elementary, thereby promoted the human elementary balance, but because the difference of pH value in the soil, required trace element also is not quite similar in the plant, they with electric charge and valence mumber difference, attracting each other can appear in interionic, antagonism mutually, suppress mutually, phenomenons such as antagonism influence crop and absorb.The present invention understands fully between little fertilizer, soil, the crop in conjunction with forefathers' experience accumulation and to concern looking through a great amount of information, say that generally molydbenum fertilizer and nitrogen, phosphorus, potash fertilizer mixing application effect are good, zinc fertilizer can mix with ammonium sulfate, ammonium chloride to be used, can not mix with urea, bicarbonate of ammonia, ammoniacal liquor use, boron fertilizer can mix use with nitrogen, phosphate fertilizer, copper fertilizer, manganese fertilizer, boron fertilizer can be mixed in proportion composite use under certain condition.The present invention namely makes element of volume according to the human body macroelement or makes major element refer to that namely common content is macroelement greater than everyone daily requirement amount of element of body weight 0.01% what the element more than the 100mg accounted for human body weight more than 99.95%, comprise 12 kinds of elements such as nitrogen, phosphorus, potassium, sodium, calcium, magnesium, chlorine, silicon.Trace element typically refers to content less than body weight 0.01%, the element of everyone every month requirement below 100mg, comprise that other the various elements beyond the major element only account for 0.05% of human body total amount, comprise that 14 kinds of elements such as the necessary iron of human body, copper, zinc, manganese, molybdenum, chromium, selenium, nickel, iodine, cobalt, vanadium, phosphorus, chlorine are trace element.
The present invention is according to grand, the micronutrient levels proportioning that contains in the human body of growing up and that required macro micro element and human body absorb in amount of element and the growing process day by day for each person every day is grand, trace element is through the composite existing nano rare earth selenium silicon titanium macro micro element compound nutritional fertilizer of forming % by the embodiment proportion by weight of scientific experiment, their compositions are by single element fertilizer preferred composite composition, and its single element fertilizer is selected from the following single element fertilizer of tradition.
Single element fertilizer
(1) zinc fertilizer is selected Zinc vitriol, zinc chloride, zinc sulfate for use
(2) boron fertilizer is selected sodium borate decahydrate, borax, boric acid for use
(3) manganese fertilizer is selected Manganous sulfate monohydrate, manganous nitrate, manganous sulfate, Manganous chloride tetrahydrate for use
(4) copper fertilizer is selected Salzburg vitriol, Copper dichloride dihydrate, cupric nitrate, cupric chloride for use
(5) iron fertilizer is selected ferrous sulfate, iron trichloride, ferric sulfate for use
(6) molydbenum fertilizer is selected Sodium orthomolybdate, ammonium molybdate for use
(7) nitrogenous fertilizer is selected urea, ammonium sulfate, ammonium nitrate, bicarbonate of ammonia, ammonium chloride, ammonium phosphate for use
(8) phosphate fertilizer is selected ammonium phosphate, ammonium metaphosphate, calcium superphosphate, potassium primary phosphate for use
(9) potash fertilizer is selected vitriolate of tartar, saltpetre, potassium primary phosphate, potassium silicate, Repone K for use
(10) selenium fertilizer is selected five hydration Sodium Selenites, selenium Wei Er, organoselenium, nanometer selenium, selenium yeast sheet, Se-rich lucid ganoderma mycelium for use
(11) germanium fertilizer is selected organic germanium Ge-132, Ganoderma rich in germanium mycelium for use
(12) fertiliser containing magnesium is selected ammonium magnesium phosphate six hydrate, sal epsom, magnesium nitrate, magnesium chloride for use
(13) calcareous fertilisers are selected lime acetate, calcium sulphate dihydrate, calcium sulfate, nitrocalcite, calcium chloride for use
(14) sodium fertilizer is selected sodium bicarbonate, sodium pyrosulfate for use
(15) vanadium fertilizer is selected sodium metavanadate, ammonium meta-vanadate for use
(16) siliceous fertilizer is selected silicon-dioxide SiO for use
2, be the main component of medical stone
(17) rare-earth fertilizer, rare earth element comprises scandium Sc, yttrium Y, the lanthanum La of IIIB family in the periodic table of elements and the lanthanon that atom is treated number 57-71, totally 17 elements, and usually rare earth element being divided into the cerium group is light rare earths, contain scandium and lanthanum, Shi Zhi Eu and yttrium group are that heavy rare earths, yttrium and gadolinium are to lutetium
(18) rare earth, trace element compound fertilizer
(19) one in natural phant growth hormone, xanthohumic acid kind and grand, that trace element is formed composite fertilizer's rare earth element significantly effect be the diagnosis of hypoglycemic, anticoagulant, anti-inflammatory, antibiotic and sterilizing, anticancer and tumour, participate in immunologic process, prevent and delay multiple effect such as Atherosclerosis.
Plant middle-weight rare earths average content is 0.002-0.057 μ g/g, soil total content 0.01-0.02%.China is large agricultural country, and the rare earth deposit enriches, is widely used in agriculture growth regulator and fertilizer additive, is used for the effect of plant husbandry rare earth element aspect medicines and health protection anticoagulation is arranged, controls burn, anti-inflammatory sterilization, antitumor, arteriosclerosis, hypoglycemic, participation immunity etc.
The present invention is further described below in conjunction with examples of implementation:
Embodiment:
Embodiment 1: a kind of nano rare earth selenium silicon titanium macro micro element compound nutritional fertilizer is characterized in that: universal nano rare earth selenium silicon titanium macro micro element compound nutritional fertilizer, form % by following proportion by weight
(1) organoselenium or nanometer selenium 0.6; (11) phosphoric acid 8;
(2) organic germanium Ge-132 0.4; (12) potassium silicate 6;
(3) the medical stone nano powder 6; (13) lime acetate 8;
(4) the tourmalinite nano powder 4; (14) magnesium chloride 6;
(5) the rare earth nano powder 2; (15) ferric sulfate 0.2;
(6) calcium nitrate tetrahydrate 18; (16) zinc sulfate 0.4;
(7) silicon-dioxide SiO
210; (17) copper sulfate 0.2;
(8) potassium primary phosphate 3.8; (18) boric acid 2;
(10) bitter salt 12; (19) manganous sulfate 4;
(11) titanium dioxide TiO
28; (20) ammonium molybdate 0.4;
Above component sum is 100%;
Embodiment 2: a kind of nano rare earth selenium silicon titanium macro micro element compound nutritional fertilizer is characterized in that: be applicable to the grand micro-compound nutritional fertilizer of gourd, fruit and vegetable nano rare earth selenium silicon titanium, form % by following proportion by weight
(1) Se-rich lucid ganoderma mycelium nano powder 6; (11) manganous sulfate 4;
(2) Ganoderma rich in germanium mycelium nano powder 4; (12) boric acid 6;
(3) the medical stone nano powder 8; (13) Sodium orthomolybdate 2;
(4) the tourmalinite nano powder 6; (14) chelated iron 6;
(5) the rare earth nano powder 4; (15) titanium dioxide TiO
24;
(6) nitrocalcite 10; (16) silicon oxide sio
25;
(7) saltpetre 15; (17) copper sulfate 2;
(8) potassium primary phosphate 1; (18) urea 8;
(9) sal epsom 5; (19) phosphoric acid 2;
(10) zinc sulfate 1; (20) sodium metavanadate 1;
Above component sum is 100%;
Embodiment 3: a kind of nano rare earth selenium silicon titanium macro micro element compound nutritional fertilizer is characterized in that: be applicable to flowers and trees bonsai nano rare earth selenium silicon titanium macro micro element compound nutritional fertilizer, form % by following mass parts composition proportion
(1) biological red selenium 5; (11) manganous sulfate 0.4;
(2) Ganoderma rich in germanium mycelium nano powder 4; (12) zinc sulfate 0.6;
(3) the medical stone nano powder 6; (13) copper sulfate 0.2;
(4) very ice stone nano powder 5; (14) ammonium molybdate 0.2;
(5) the rare earth nano powder 3; (15) boric acid 0.8;
(6) nitrocalcite 15; (16) titanium dioxide TiO2 2;
(7) ammonium nitrate 7; (17) potassium primary phosphate 3;
(8) saltpetre 4; (18) silicon-dioxide SiO2 0.6;
(9) sal epsom 5; (19) water adds to 100%;
(10) ferric sulfate 5;
Above component sum is 100%;
Illustrate:
Fresh garlic class selenium content ranks the first in vegetables, up to every kg selenium content 278mg, and the general every kg of vegetables is not 10mg even does not have, simultaneously garlic has antibiotic, antiviral, hypotensive, anti-platelet aggregation, reducing blood-fat, atherosclerosis, antitumor, multiple specific function such as health care is anti-ageing, China's garlic resource is abundant especially, and annual production accounts for 1/4 of the world.Can increase the content of selenium in the garlic with the embodiment of the invention one.
Method for making:
(1) material of above-described embodiment 1-3 is put with the makeup of nano level particle diameter superfine handled the back mixing fine powders and cross nano-powder that 800-1200 mesh sieve medium particle diameter reaches 0.5-10 μ m and fully dissolve with 50 ℃ warm water 100ml, and then add deionized water gradually while stirring and reach 100ml as stoste, pH value is adjusted between the 5.5-6.5, soaked seed 6-12 hour with this stoste, its seed is soaked into dry the back sowing, or above-mentioned each component is organized proportion by weight by each mixes compacting in flakes, every 1g, per 4 are dissolved in the 100ml water and can be used for balcony, the gourd, fruit and vegetable of garden cultivation is used for the medium-sized flowerpot 8-12 box that root is executed foliage-spray.
(2) soak among the solution 1000ml of 0.1-0.5 with the seeds of food crop such as 500g paddy rice, wheat, corn and soaked into 6-12 as a child, rise and kind dry the back sowing, root imposes outward and adds pure water 1000ml with stoste 3ml and be 0.3% solution as foliage top dressing.Seedling stage is with 0.2% solution foliage application.Once in a week, continuous four times, per 10 days of crop growth stage with 0.2% solution foliage application once, in results preceding 10 days, stop to spray under the situation that does not cause vegetation to wilt and can reduce water supply as far as possible, accumulation and raising storage tolerance to guarantee the fruit sugar reduce dehiscent fruit.
Claims (1)
1. nano rare earth selenium silicon titanium macro micro element compound nutritional fertilizer is characterized in that:
(1) nano rare earth selenium silicon titanium macro micro element compound nutritional fertilizer is formed % by following proportion by weight
1. organoselenium or nanometer selenium 0.2-1.0%;
Ammonium phosphate 3-13%;
2. organic germanium Ge-132 0.1-0.7%;
Potassium silicate 1-11%;
3. medical stone nano powder 1-11%;
Lime acetate 3-13%;
4. tourmalinite nano powder 1-7%;
Magnesium chloride 1-11%;
5. rare earth nano powder 1-3%;
Ferric sulfate 0.1-0.3%;
6. calcium nitrate tetrahydrate 13-21;
Zinc sulfate 0.2-0.6%;
7. saltpetre 5-15%;
Copper sulfate 0.1-0.3%;
8. potassium primary phosphate 1.8-5.8%;
Boric acid 1-3%;
9. bitter salt 7-17%;
Manganous sulfate 1-7%;
10. urea 3-13%;
Copper acid ammonium 0.1-0.7%;
(2) nano rare earth selenium silicon titanium macro micro element compound nutritional fertilizer is formed % by following proportion by weight
1. Se-rich lucid ganoderma mycelium nano powder 3-9%;
Manganous sulfate 1-7%;
2. Ganoderma rich in germanium mycelium nano powder 1-7%;
Boric acid 3-9%;
3. medical stone nano powder 5-11%;
Sodium orthomolybdate 1-3%;
4. tourmalinite nano powder 3-9%;
Chelated iron 3-9%;
5. rare earth nano powder 1-7%;
Ammonium nitrate 1-7%;
6. nitrocalcite 7-13%;
Silicon-dioxide SiO
22-8%;
7. saltpetre 12-18%;
Copper sulfate 1-3%;
8. potassium primary phosphate 0.5-1.5%;
Urea 5-11%;
9. sal epsom 2-8%;
Ammonium phosphate 1-3%;
10. zinc sulfate 0.5-1.5%;
Sodium metavanadate 0.5-1.5%;
(3) fertile its feature of nano rare earth selenium silicon titanium macro micro element compound nutritional: form % by following proportion by weight
1. biological red selenium 2-8%;
Manganous sulfate 0.3-0.5%;
2. Ganoderma rich in germanium mycelium nano powder 1-7%;
Zinc sulfate 0.4-0.8%;
3. medical stone nano powder 3-9%;
Copper sulfate 0.1-0.3%;
4. very ice stone nano powder 2-8%;
Ammonium molybdate 0.1-0.3%;
5. rare earth nano powder 1-5%;
Boric acid 0.5-1.3%;
6. nitrocalcite 12-18%;
Titanium dioxide TiO
21-3%;
7. ammonium nitrate 4-10%;
Potassium primary phosphate 1-5%;
8. saltpetre 1-7%;
Silicon-dioxide SiO
20.3-0.9%;
9. sal epsom 2-8%;
Add water to 100%;
10. ferric sulfate 2-8%;
Illustrate:
Every group of proportion by weight composition sum was 100%, the higher limit+lower value of certain component≤100, the lower value+higher limit of certain component 〉=100 during aforesaid right required.
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