CN102701844B

CN102701844B - Rich-selenium-germanium trace element nanometer nutrition fertilizer for vegetable and fruit soilless culture

Info

Publication number: CN102701844B
Application number: CN201210168960.XA
Authority: CN
Inventors: 成进学; 成钢
Original assignee: Individual
Current assignee: ANHUI JIAFENG FERTILIZER INDUSTRY Co Ltd
Priority date: 2012-05-21
Filing date: 2012-05-21
Publication date: 2014-06-18
Anticipated expiration: 2032-05-21
Also published as: CN102701844A

Abstract

The invention provides a rich-selenium-germanium trace element nanometer nutrition fertilizer for vegetable and fruit soilless culture, belongs to a pollution-free green agricultural product and relates to the technical field of the preparation and production of trace element nanometer nutrition fertilizers for vegetable and fruit soilless culture in courtyards or balconies. The trace element nanometer nutrition fertilizers is applied to the domestic courtyards or balconies, the capability of crop products for containing rich necessary trace elements for human bodies is effectively improved, the active movement of bodies is promoted, trace elements and negative ions in air are continuously generated and released, the air is improved and purified, more importantly, vegetables and fruits produced and planed hard by selves can be used and eaten at ease, and especially, people uptake food such as fresh vegetables, melons and fruits and the like in daily life, so elements in bodies are balanced, and the bodies are healthy. The popularization and the application of the rich-selenium-germanium trace element nanometer nutrition fertilizer for vegetable and fruit soilless culture concerns the important and great event of enriching the country and bringing benefits to the people.

Description

Rich selenium germanium vegetable melon and fruit soilless culture trace element nano nutrient fertilizer

Technical field:

The rich selenium germanium of the present invention vegetable melon and fruit soilless culture trace element nano nutrient fertilizer is to belong to the fertile preparation of nuisanceless green agricultural-food garden balcony soilless culture gourd, fruit and vegetable trace element nano nutrient production technical field.

Background technology:

Improving the content of selenium in agricultural-food by selenium fertilizer, is a Basic Ways.The method of great majority benefit selenium is to adopt Na both at home and abroad ₂seO ₃.Its practice is: by Na ₂seO ₃be mixed with different concentration, release or spray with soaking, make selenium be absorbed, produce the Se-rich farm products of certain content by farm crop.Its crop species comprises: the farm crop such as paddy rice, corn, soybean, tealeaves, tobacco leaf, vegetables, melon and fruit, or with the fertilizer of rich selenium, as rich selenium board full-service fluid fertilizer, rich selenium health, Se-rich agent for promoting growth of crops etc.

Selenium in rich selenium series products production is to enter product by soil application, plant spray approach fertile, that animal is engrossed, can certainly directly admix in feed with selenium element, as being mixed with composite feed additive with selenium salt biologically active substance and stablizer, be formulated in by a certain percentage in chicken feed, just can produce egg rich in selenium; For example in the feed liquid of producing lime-preserved egg, add Na again ₂seO ₃, make selenium content in feed liquid be respectively 21.6ug/g and 11.3ug/g, just can produce the Se-rich lime-preserved eggs that selenium content is 0.4-1.8ug/g.Its lime-preserved egg selenium content becomes positive correlation with the concentration of selenium in soak solution with soak time.

Selenium topmost biological function in animal and human's body is: as the composition of glutathione peroxidase system (GSH-PX), participate in vivo oxidation reduction reaction, remove the free radicals such as lipid peroxide, reduce the peroxidation damage that microbial film etc. is caused; In the process of the metabolism of higher plant body and environment-stress, also produce a large amount of free free radicals, these free radicals can be removed by corresponding enzyme systems such as Superoxide Dismutase (SoD), catalases (CaT), also can be removed by GSH-PX, GSH-PX now in the different tissues of different sorts plant, all detected, and prove to execute selenium and can increase GSH-PX activity in plant tissue, thereby affirm that selenium also has oxidation resistant effect in plant materials.

Exist according to China the soil that big area lacks selenium, boron, zinc, manganese, molybdenum, total trend is: soil manganese deficiency and the zinc in the north, main boron deficiency in the multiple soil in east, the various soil that loess and the Yellow River alluviation become and southern sour earth mainly lack molybdenum, and the whole nation has in the soil on 2/3 territory 72% and lacks selenium.On this basis, according to the situation of Trace Elements in Soil shortcoming, and farm crop consider to study the fertilizer practice of micro-fertilizer to the reaction of Trace Elements in Soil shortcoming, to making good use of trace element fertilizer, increase the content of animals and plants trace element, supplement comprehensively, regulate antagonism people in-vivo element balance, strengthen human body constitution, improve human health level, pick up from source cause close important, available data shows current using in main trace element fertilizer: zinc fertilizer is ZnSO ₄, TH ₂o doing the sowing of base manure or crop, while transplanting row replacement as main, 15 kilograms of amount of application per hectares; Boron fertilizer Na ₂b ₄o ₇10H2O, the foliage top dressing take concentration as 0.2% solution is as main; Molydbenum fertilizer is (NH ₄) ₆m ₀₇o ₂₄4H ₂o, to dress seed as main, per kilogram seed is mixed 2 grams of sheet acid ammoniums.

Summary of the invention:

Trace element is applied to farm crop and has obtained good effect, not only effectively improves crop yield, promotes the output value, is conducive to increasing peasant income volume increase, reasonably improves the trace element supplementing in human body; Prevent and cure diseases, be conducive to the lifting of peasant health level.For example use boron fertilizer in the year's harvest of rape normal growth, rape can increase production 42%; Bloom not that result, grain yield of rapeseed significantly reduce or seed deformity, oleaginousness decline and use boron fertilizer, rape yield increasing 76% be not very serious in the situation that at " colored and unreal "; In serious situation, use boron fertilizer, can increase production 218%; The only 41.1kg of control group per mu yield vegetable seed that does not execute boron fertilizer, at the rape per mu yield 110.2kg of sprayed boric fertilizer, boron fertilizer base is executed rape per mu yield up to 156.6kg.The tool of boron fertilizer is stopped spraying method: seedling stage (under test conditions, being annual November 15) and tongue phase (under test conditions, being annual February 28) respectively spray once each 0.25% borax soln 50kg for mu; Twice consumption adds up to every mu of borax 0.25kg.The way that boron fertilizer base is executed is: after borax is smashed to pieces, first mix and stir with fine sand, then mix ditch spread thoroughly with the thin fertilizer that other bases are executed; The consumption of every mu of borax is 0.25kg, as more and more higher in yield of rape, just increasing to the requirement of boron fertilizer, and every mu need to increase 1 times with boron fertilizer, and every mu of consumption of boron fertilizer is borax 0.5kg.

Yield-increasing Baallus In Maize zinc fertilizer effect of increasing production is fine.In salt affected soil, test-results shows: blade face spray zinc and sulphur ammonium+zinc effect of increasing production are best, and amount of increase in production is respectively 86.5% and 97.3%.Every mu of each spray 0.25% sulfuric acid liquid 50kg of blade face spray zinc.Respectively at seedling stage, jointing, tell tassel and spray for three times, the contrast of per mu yield 322kg foliar spray is per mu yield 172kg; Sulphur ammonium+zinc-base is executed as mu sulphur ammonium 16.5kg+ zinc 1.5kg, per mu yield 406.5kg; Sulphur ammonium is executed contrast mu and is executed sulphur ammonium 16.5kg, per mu yield 210kg.

Be rich in the ability of various trace elements in order effectively to improve crop products, in the soil of producing farm crop, come up vegetative period, jointing, tell tassel and notice that trace element uses, not only can make us obtain many rich zinc, the green health agricultural-food such as rich selenium, the agricultural-food of this rich trace elements can comprise plant, gourd, fruit and vegetable, domestic animal, fish, milk, wine, tea, honey, feed, rice, wheat, flour, soybean, red beans etc. are varied, both for people have supplemented trace element, strengthen people's physique, promote again the economic benefit of crop products, strengthen the interests guarantee that vast farmers is shaken off poverty and set out on the road to prosperity.

Paddy rice, wheat, large cereal product such as corn is in most of rural area, always along constant old road in thousand, although increase production by every means increment, but not from the micro-rich selenium of grain itself, zinc, on germanium key technical problem, make an effort, so provision price is not high, benefit is low, the person between twenty and fifty in vast rural area always like going out doing manual work, abandon the production of grain, the rich selenium of enshi dependence soil and the abundant weather of rainfall are moistening, mist is around hills and mountains, the natural advantage that streams spreads all over, the selenium content of producing has " bestowing favour beautiful revealing " at the tea rich in selenium of 0.3-5mg/kg, " the beautiful milli of Venus tea ", " Venus sword milli tea ", national well-known teas such as " the beautiful millis of bajiao banana ".Every gram of the beautiful milli of bajiao banana wherein price exceedes more than a times of the price of gold, and this just absolutely proves the personal value and the glamour of the tea rich in selenium of bestowing favour.And for example always supply falls short of demand for the selenium-rich rice on market, the rich selenium scented rice that Anhui, Heilungkiang produce has been sold fire, the rich selenium scented rice of " Sai Tai " board wholesale price that Hongchehu Lake, Jiangsu produces exceeds 40% than common rice, selenium-rich rice, tea rich in selenium, rich selenium watermelon, the maize rich in selenium outlet Italy that Se-rich farm products group company produces is looked far into the distance in Nanjing, the easily first lotus flower supermarket and domestic several hundred supermarkets that enter Wal-Mart of U.S. supermarket, Thailand, sales situation is very prosperous.

The potentiality of the rich selenium of development of agricultural products, zinc, germanium are very large, have very large DEVELOPMENT PROSPECT.Routine garlicky selenium rich ability is strong again, and fresh head of garlic selenium content ranks the first in vegetables, and up to 278mg/kg, and general vegetables are only 10mg/kg; And that garlic has is antibacterial, antiviral, hypotensive, reducing blood-fat, anti-platelet aggregation, arteriosclerosis, have stronger to multiple effects such as anti-ageing, prophylaxis of tumours.And China's garlic resource is abundant especially, annual production accounts for 1/4 of the world, therefore garlic is carried out to very promising, the huge profit margin of rich selenium research enrichment culture.Carry out garlic water planting, with lotus lattice solution, blue moral nutritive medium, control group adds selenium, processes and presses 1mmol/L Na ₂seO ₃add, culture temperature is at 10-15 ℃, and result garlic selenium content reaches 5530mg/kg; Organic selenizing degree is the highest, reaches 78.24%; And garlic weight increases and reaches 61.68%; Protein, soluble sugar etc. all have raising more significantly.Find after deliberation major element potassium K, the sodium Na, calcium Ca, the magnesium Mg that in garlic, contain human body, also have 16 kinds of elements such as trace elements iron Fe, zinc Zn, copper Cu, molybdenum Mo, manganese Mn, aluminium Al, silicon Si, phosphorus P, chromium Cr, barium Ba, vanadium V, selenium Se, germanium Ge, cadmium Cd, plumbous Pb, arsenic As; That wherein content is the highest is phosphorus P, selenium Se, germanium Ge content are also all very high, have high physiologically active in human body, are anti-cancer, the important bioelement that anticancer, health care lengthens one's life, and harmful element arsenic As, cadmium Cd, plumbous Pb content in garlic are very low, can not damage human body.

The inorganic elementss such as selenium Se, the germanium Ge in garlic and calcium Ca, copper Cu, iron Fe, potassium K, magnesium Mg, zinc Zn, lengthen one's life and many physiology and the pharmacological function such as enhancing body immunity in anticoagulation, hypotensive, reducing blood-fat, liver detoxification, anticancer anti-oxidant, health care, so the clinical application of the exploitation of rich selenium germanium garlic has wide social prospect.

The essential trace element relevant with plant-growth of generally acknowledging at present has 7 kinds of boron, manganese, molybdenum, zinc, copper, iron, chlorine, and easily for animals and plants absorb be the organic of Trace Elements in Soil, comprise the trace element that can be absorbed and used by plants in water-soluble state, exchange state and part organic, be referred to as Availability of Trace Elements.It depends on potential of hydrogen, redox location, the soil texture, permeability, microbial activities, organic content and the soil absorptive character etc. of soil.Conventionally Acid soil organic content is higher, and this is not only conducive to crop yield, also can optimize crop quality, increase the element zinc, iron, the manganese equal size that in doing, are conducive to HUMAN HEALTH.For example use molydbenum fertilizer to soybean, can improve protein and lipid content in seed; Be applied to the paddy rice of zinc fertilizer, can improve protein in paddy kernel, starch, sugar and potassium magnesium copper equal size; The corn of application of zinc fertilizer, can also improve the amino acid whose total amount of corn; Winter wheat is used zinc-manganese fertilizer, can increase gliadin and alcohol glutelin content in seed; Manganese and copper fertilizer can improve the content of mucedin in winter rye seed; Tea tree application of zinc fertilizer can improve the formation condition of plant young shoot, promotes the accumulation of catechol in tealeaves, uses boron fertilizer and can also improve amino acid whose content in tealeaves, uses manganese fertilizer and can improve ascorbic content in tealeaves.Because micro-content is directly connected to the yield and quality of crop, therefore environment is extremely important on soil quality impact; But exceedingly use chemical fertilizer can cause salting of soil, not only reduce soil trace element available state content, simultaneously, because phosphorus in fertilizer and calcium have antagonistic action to trace elements such as zinc, suppressed widely the absorption of zinc, this is obviously disadvantageous to producing the green food of being rich in nutrition value.So the use of trace element fertilizer will be got hold of size, key is the pollution of restriction harmful element to green food.About rationally using selenium fertilizer and zinc fertilizer in green food, output be can not only improve, selenium, zinc content in crop optimized, can utilize selenium, the antagonistic action of zinc to some harmful element simultaneously, reduce content plumbous in green food, cadmium.Scientific experiment confirms: to using in the vegetable potted soil of selenium, zinc fertilizer, specific absorption plumbous, cadmium has reduced 30-50%, the pea seedlings of cultivating with the composite nutritive solution seed soaking containing selenium, not only make lead content in bean seedlings reduce nearly one times, and selenium is enriched to more than ten times, output is brought up to 17-40%, and height of seedling increases 18-47%, and brown mould variable area is reduced to 0 from 90%.By selenium, the reasonable application of this healthy trace elements with household of zinc in green food, both solved problem of environmental pollution, increase again the micro-picked-up of needed by human, promote HUMAN HEALTH.

The source of mending selenium comprises inorganic selenium and organoselenium, utilize different biologies to there is assimilation inorganic selenium and be converted into the ability of organoselenium, the plant seed that produces organoselenium for enrichment inorganic selenium soaks, and the cultivation foliage application of nutrient solution is produced the various rich selenium foods such as selenium-enriched garlic, Fructus Hordei Germinatus, corn, wheat, rice, beans, tea rich in selenium, bean sprouts rich in selenium.In animal-feed, add the inorganic selenium of certain proportioning by scientific and reasonable formula, can improve the selenium content of meat product, as the selenium content of the brutish class meat products processed such as pig, ox, sheep, chicken, duck, goose; As added the selenium of certain proportioning in chicken feed, can improve organoselenium in egg and reach 8-10 doubly, become genuine Se-enriched egg; Other also has rich selenium cow's milk, Se-enriched honey etc.In woods fruit product, set up selenium-enriched apple in addition, pears, peach, jujube, banana, grape and set up rich selenium vegetables booth, set up rich selenium cucumber, muskmelon, the pollution-free healthy green food of the various rich selenium animal-plant kinds such as watermelon, both improved peasant's income, improve again people's body health quality, change people's sub-health status, the more important thing is the soil to long-term application selenium-enriched fertilizer, can alleviate chemical residual lead in soil, mercury, arsenic, the pollution damage of cadmium harmful element to human body and environment, change soil, activate soil, and there is an effect of vegetable nitrate of reduction.Suitably mend selenium, various nutritive ingredients in soil are tended to balance, naturally improved the absorption rate of crop to fertilizer nutritive element, promoted growth and the volume increase of crop simultaneously; Add after selenium, also can change the composition of trace element in animal and plant body, amino acid, VITAMIN equal size also increase.The rich selenium of this popularization, germanium, zinc increases the technology of trace element in animal and plant body, it not again a numerous tired technology of complicated difficulty, governments at all levels of party and state should put forth strength and extract special agricultural innovation support fund, building a New Socialist Countryside, greatly promote the income of husbandry, change the looks that Chinese agriculture falls behind, promote national health level, break away from Chinese 75% subhealth state health, it is the major action that China makes one's country rich and powerful so that its people can enjoy a prosperous life, there is great applied economics meaning, long-range historic significance, it is the once technological revolution of great change fate of human beings of agricultural.Trace element applies in growth and development of plants and animals food, makes people from the food of daily picked-up, obtain the necessary element of human body, makes people's in-vivo element balance, and healthy is to be related to the great grand occasion of making one's country rich and powerful so that its people can enjoy a prosperous life.

Kingdom of ancient Roman the powerful and prosperous period is defeated ancient Egypt, by predation to a large amount of hard leads forge into various tablewares for Royal Palace noble, result influential officials' infertility, infertility, this has caused the extinction of kingdom of ancient Roman just because of lead element.Not only few, the people but also short and small in for example Japanese territory, resource is poor to be lacked, when the old society, China's southeastern coast is attacked always, always the Japanese pirates that Chinese hate, the period of Cultural Revolution is dragged for Flos Bombacis Malabarici in entrance of Changjiang River, the East Sea and pours into the slag in Jinsha jiang River, by analysis in slag the content of vanadium, titanium, cobalt, nickel than natural crystal exceed a lot of doubly, and Japanese names and buys containing the Sichuan konjaku of selenium, containing the Shaoxing Rice Wine of molybdenum, will buy whole Maifanitum in the Inner Mongol, to transport to Japan; Because the necessary various trace elements of selenium, molybdenum, vanadium, titanium, cobalt, nickel and other people body that these materials are contained, content is many and abundant, so they will remove these valuable resources by fair means or foul; Therefore present Japanese is no longer short and small, Japan's state-of-the-nation call Japanese national will be eaten different types of food for each person every day, kind must not be less than 30 kinds, various elements in human body pickuping food every day are just abundant like this, just can substantially reach the supplementing of people's in-vivo element, adjusting, antagonism, thereby make people's in-vivo element balance, healthy; Therefore, Japan is the most long-lived in the world nationality at present.Element research applies in the daily edible animals and plants food of people widely thus, thereby can make people from the food of these rich selenium, zinc, germanium, absorb the necessary various macro micro elements of human body, reach the object that improves the health, lengthens one's life, builds up a powerful nation and make the people rich.This is the cardinal task that is related to national prosperous and powerful fitness-for-all, trace element can not be in human body synthetic generation voluntarily, in the picked-up of the food that the animal-plant kind that must grow by soil incubation is made, obtain that human body grows, diseases prevention, the required various nutritive elements of curing the disease.

The source of mending selenium comprises inorganic selenium and organoselenium, the conversion of animals and plants and microorganism organoselenium, and microorganism is because fast growth, harvest cycle are short, and it is convenient to cultivate, and various conditions are easy to control; Therefore transform into the main source of biogenic organoselenium with microorganism inorganic selenium.Many microorganisms have good selenium rich ability, as the organoselenium of the total selenium 97% obtaining after yeast assimilation inorganic selenium.Glossy ganoderma is described as the good merchantable brand of promoting longevity, elixir alive for evermore since ancient times, and Ganoderma fungi has long medicinal history in China, is listed in rare Chinese medicine; Glossy ganoderma, except having rich in protein, polysaccharide, vitamin and microelement and other active substance, also has very strong rich selenium, the ability of germanium, and the selenium of institute's enrichment, germanium are mainly the Organic Selenium germanium such as albumen selenium, albumen germanium, polysaccharide selenium, holoside Ge.Use at present fermentation engineering, form organism organic selenium germanium by the microbial transformation of Ganoderma mycelium Enriching Selenium germanium resource, but organoselenium ge content is lower in normal Ganderma lucidum, if access Ganderma lucidum strain in the substratum that is rich in inorganic selenium germanium, utilize the rich selenium germanium ability of Ganderma lucidum that inorganic selenium germanium is transformed into organoselenium germanium, and can be enriched to the organoselenium germanium of high level, the length of melting glossy ganoderma and organoselenium germanium, obtains the medical-care health food of the high quality high-content that is rich in organoselenium germanium.Experimental study is made the organic selenium content of Se-rich lucid ganoderma goods between 279-5600mg/kg, consider that human body takes the factor of the aspect such as significant quantity and security easily and effectively, think that the selenium of 10mg/kg adds the dry product containing selenium 270mg/kg that concentration makes comparatively suitable.

In natural food, the content of selenium all can not meet the normal need of human body, and adult takes the nuisanceless scented rice of rich selenium every day, and containing selenium 0.2-0.4mg/kg, about 300-500g just can reach 60mg or 200mg by every daily ingestion selenium content; Preferably take the photograph selenium amount every day and reach between 200-500ug, so just can effectively prevent developing of 80 various diseases.

Ganoderma mycelium enriched germanium forms biological state organic germanium, just knows about by dialysis and detection.After enrichment, mycelia dry powder is measured and is shown that germanium reaches 497-3300ug/g (control group 13.2ug/g), illustrates that inorganic Ge has changed into endobacillary organic germanium.Germanium has the effect that strengthens human immunologic function according to the study, induction body secreting leukocytes mesonium-2, improve T lymphocyte and leukocytic phagocytic activity, strengthen the activity of NK cell, thereby the immunological competence of enhancing body, improves the vigor of antioxidase, regulation of physiological functions, anti-inflammatory, antibacterial, anti-cancer, anticancer, protect liver, protect the liver, health care lengthens one's life, it is also the conditioning agent of plant-growth simultaneously, can promote the growth of cereal, vegetables, melon and fruit etc. and the improvement of variety and quality.Being widely distributed in the living organism of germanium, in the many enzymes in organism, the cortex of human brain and grey matter composition, all contain element Ge in the subcellular component such as cell walls, plastosome, karyomit(e), lysosome; Use Germanium tetraacetate fertilizer in ginseng and can increase the speed of growth of ginseng giving, in ginseng its fragrance is denseer uniquely, the content of Germanium in Ginseng also improves greatly.Selenium, germanium junction close the ability of removing human free radical stronger better, free radical is all constantly producing whenever and wherever possible at human body, free radical has extremely strong oxidizing reaction ability, oxidable destruction protein, lipid or nucleic acid etc., make that cellularstructure, function are impaired, radiation-indued DNA damage transgenation, nucleic acid main chain fracture, hyaluronic acid depolymerization, lipid peroxidation, base degraded, hydrogen bond destroy, and finally destroys the normal function of cell and induced tumor.Current ban on opium-smoking and the opium trade comprehensively does not reach again, often have a suck of cigarette and can produce 100,000 free radicals, therefore manage to reduce the generation of human free radical, selenium germanium has powerful effect of removing human free radical, impel the people can be from ingestion of food selenium element Ge, strengthen the ability of human body resist the disease, maintain the balance of body oxidative and anti-oxidative, effectively reach and prevent, treat the object of tumour with this.

Contained composition silicon-dioxide SiO in medical stone ₂, aluminium sesquioxide Al ₂o ₃, titanium dioxide TiO ₂, ferric oxide Fe ₂o ₃, ferric oxide FeO, magnesium oxide MgO etc. are common far-infrared radiation materials, life science confirms, human body is a far-infrared radiation source, is again a far IR shielding effect source, its emitting far-infrared wavelength 5-25um, optimal absorption wave band is 4-16um; The main component that forms human body cell is water molecules and macromolecular compound, water molecules in blood accounts for 60-70%, if insufficiency of vital energy and blood, water molecules in blood is just assembled and is formed inertia water, i.e. four hydrogen molecules and an oxygen molecule combination, can not produce exchange of substance with human tissue cell by cytolemma, far-infrared engergy gos deep into the subcutaneous 3-5um of human body, automatic heating heats up, activation is organized, enhanced metabolism, produce resonance effect with water molecules, make it become independently water molecules, two hydrogen molecules and an oxygen molecule are combined into H ₂o, improves the oxygen level of health, increases the vigor of cell, makes that people's spirit is more vigorous, brains is more flexible, and then improves human body resistance against diseases, delays senility.And the main component of tourmalinite and medical stone all contains SiO ₂, TiO ₂, Al ₂o ₃, Fe ₂o ₃deng the silicate that is all aluminium take boron as feature, iron, magnesium, lithium ring texture; The medical stone 19 kinds of necessary trace elements of human body such as being easy to stripping calcium Ca, magnesium Mg, potassium K, sodium Na, strontium Sr, selenium Se, zinc Zn, iodine l metasilicic acid that are soaked in water, the content of harmful heavy metal element plumbous Pb, mercury Hg, arsenic As and radioactive element uranium U, thorium Th etc. all the earth's crust with rocks Abundances below, can not produce harm to human body; And strange ice stone, astroies, marine bottom sediment, aethiops vegetabilis etc. are all the inorganic porous class materials forming with the metal oxide of silicates and aluminium, iron, there is permanent spontaneous electrode, be subject to small variation and just can make ambient air ionization, the electronics being hit has the permanent spontaneous utmost point by these, the permanent positive and negative polarity being had as tourmalinite crystalline powder two ends will produce the ionisation effect that sparks after contacting with the water molecules in common water, air and in skin surface, is H by water molecules electrolysis ⁺and OH ^-.H ⁺the electronics discharging with tourmalinite is combined and is neutralized into H atom; And OH ^-with other water molecules, can generate continuously its negative ion of hydrogen H ₃o ₂ ^-.Through the water of this process, it is the weakly alkaline that alkaline water or sour water all can be useful human body.

Now rapid economic development, the huge increasing of private car, the tail gas of vehicle emissions, industrial gaseous waste, dust etc. are seriously polluted, and Air quality constantly declines, and topsoil is serious; The Contamination of Electromagnetic Waves such as urban modernization air-conditioning, mobile phone, computer are serious, not only can spontaneous generation anion fine-purification air in medical stone, tourmalinite composition, but also there is ferrite, the electromagnetic shielding material of fine antagonism Contamination of Electromagnetic Wave: Indian red Fe ₂o ₃, Z 250 Fe ₃o ₄deng, green non-pollution vegetable melon and fruit is on balcony cultivated in plantation and has been used the trace element fertilizer such as medical stone, tourmalinite, although fertilizer cost is higher, but in vegetable melon and fruit, be rich in selenium germanium to the high composition of the constituent content of human body, can effectively promote people's in-vivo element balance, strengthen people's physique, improve human health level.On balcony plant upper a few basin vegetable melon and fruits simultaneously and both beautified the environment, purify air, strengthened again the intensity of body kinematics, more promoted healthyly, make people on balcony with regard in similar forest afield, make people feel clearheaded, happy.The effect of Here it is negative ion.Negative ion is termed " VITAMIN of air ", " long-lived element ".It is the material that HUMAN HEALTH is highly profitable.In the time that people send airborne negative ion to alveolar by absorbing, the system that can excite nerve produces good effect; Through blood circulation, be with electric charge is delivered in systemic cell, can improve myocardial function, strengthen myocardial nutrition and cellular metabolism, improve immunological competence, promotion health, and energy nervous system regulation function, stimulate circulation, can make people energetic, good health and a long life, even asthma, hypertension, neurasthenia, pulmonary emphysema, coronary heart disease etc. are had to positive effect.

Chitin and chitosan is all refine a kind of natural biological superpolymer out from the cell walls of the shell of shrimp, crab, insect and mushroom, algae, is the extremely abundant a kind of natural resources of storage on the earth; Also be that occurring in nature is found unique positively charged natural nitrogenous polysaccharide superpolymer up to now.Chitin belongs to polysaccharide, after concentrated base is processed, can slough ethanoyl wherein.When the N-ethanoyl in chitin structural formula is divested 55% when above, become the most important derivative chitosan of solvable fluidity chitin, this is natural antiseptic-germicide.Stipulate according to electron microscope: bacterium is subject to after chitosan effect, quite obvious morphological change, the bright property of gram bacterium-as concentrated in colibacillary bacterial cytoplasm, space obviously expands, visible chitosan has affected the growth of bacterial cell, chitosan is to head mold, subtilis, Candida albicans, pseudomonas, bacstearothermophilus, intestinal bacteria, Mucor, streptococcus aureus, Salmonellas, Haemolysis Vibrio, the various bacteria such as intestines streptobacillus have good inhibition, and its biophase solvent again can to environment produce pollute, so cultivate as crop growth, as fertilizer sources uses, all safe and reliable, it does not belong to chemical fertilizer goods.

The fundamental that pollen contains food, has possessed all the components that human body needs.A large amount of sugar, protein, 21 seed amino acids comprise total free aminoacids, comprising 14 kinds of trace elements and other useful mineral substance of the necessary 8 kinds of total free aminoacidss of human body, 14 kinds of VITAMIN and needed by human, 50 kinds of above natural ferment enzymes and coenzyme, sexual hormoue, growth hormone, antibiotic etc.Bee pollen has the laudatory title of " concentrated VITAMIN ", " miniature nutrition library ".In pollen, contain abundant VITAMIN, exceed 100 times than honey, and kind being very complete, is a kind of natural multivitamin enriched material.Be measured in pollen the content of cobalt high, vitamins B ₁₂structure composition has the composition of cobalt to exist.Vitamins B as everybody knows ₁₂in the biological activity of cobalt be 1000 times of free cobalt.We study trace element cobalt and prove: growth, growth and the human senility of cobalt and human heart, blood vessel, blood all have close relationship.In pollen, contain very high phosphorus; the phosphorus that contains 250-800mg in every 100 grams of pollen; exceed several times of fruit and vegetables, tens times, hundred times even; the effective way of supplementing human body phosphorus, phosphate, phosphatide, be safeguard eubolism in body, improve body energy level, improve immunizing power, anti-ageingly lengthen one's life, clear liver and improve vision, protect human body neuroretina, eyeglass is grown health care remarkable efficacy.The content of calcium is also higher than several times of fruit and vegetables, tens times, hundred times even, and doubly average higher than beef, milk, chicken, egg, Semen arachidis hypogaeae approximately has the calcium of 100-350mg in every 100 grams of pollen.Mg content in pollen is that every 100 grams of pollen contain magnesium 50-500mg, and it is the highest food of Mg content in all food.Magnesium in vivo, is particularly the activator that plurality of enzymes forms in plant materials, for example hexokinase, nucleic acid ribokinase etc.If there is no the participation of magnesium, the anabolism of the activation of these enzymes and function, sugar will be obstructed, DNA and RNA can not constantly form and metabolism, DNA, RNA can not keep stable structure, participate in the formation of various films in cell and the formation of plant growth growth Determination of Chlorophyll, magnesium deficiency affects human body protein, ribose, metabolism of fat, affects the retina of eyes, the function of crystal.In pollen, the content of potassium is that every 100 grams of pollen are containing potassium 100-550mg.Potassium is one of major fertilizer elements of growth and development of plants; Potassium is mainly distributed in the matrix of tenuigenin, nucleus and organoid of plant, makes these full life materials keep the suitable viscosity of colloidal states, moisture, circulation and the elasticity of colloid.Potassium activates many enzymes in photosynthesis, completes specific task, directly affects light compositing, reverse, the storage of carbohydrate, protein, and pollen is a kind of have very high nutritive value and the necessarily good health-care good product of auxiliary therapeutic action in a word.A lot of families have eaten the bee pollen of half because of not knowing its effect, be placed on a limit need not, central bay has been grown and has been lost unfortunately really, not as being used as the fertilizer of household balcony fruit and vegetable, this is a kind of good selection really.Above these are given full play to the effect that it improves the health containing micro-material by the composite the present invention's of making trace element nano nutrient fertilizer of science.

Below in conjunction with examples of implementation, the present invention is further illustrated:

Embodiment mono-: the rich selenium germanium vegetable melon and fruit soilless culture rich selenium element Ge nutritive medium of growing, by following mass component proportioning composition

(1) inorganic selenium Na ₂seO ₃11 account for 0.30%;

(2) organic germanium Ge-132 8 accounts for 0.22%;

(3) nitrogenous 20% ammonium sulfate 38 accounts for 1.05%;

(4) nitrogenous 34% ammonium nitrate 70 accounts for 1.93%;

(5) containing P ₂o ₅a hypophosphite monohydrate calcium dihydrogen 450 of 21% accounts for 12.43%;

(6) account for 1.66% containing the potassium sulfate 60 of potassium 50%;

(7) two Magnesium sulfate heptahydrates 80 account for 2.21%;

(8) calcium sulphate dihydrate 500 accounts for 13.81%;

(9) four anhydrous manganeses 0.6 account for 0.02%;

(10) Salzburg vitriol 0.6 accounts for 0.02%;

(11) Zinc vitriol 0.6 accounts for 0.02%;

(12) seven ferric sulfate hydrates 0.6 account for 0.02%;

(13) ten hydrated sodium borates 0.6 account for 0.02%;

(14) medical stone or strange ice stone nano powder 550 account for 15.19%;

(15) tourmalinite or astroies nano powder 500 account for 13.81%;

(16) chitin or chitosan nano ground rice 650 account for 17.96%;

(17) bee pollen nano powder 700 accounts for 19.38%;

Amount to 3,620 100%.

The present invention is the nutritive medium inorganic elements fertilizer for the vegetable growth of soilless culture, main component comprises the Trace Elements such as nitrogen, phosphorus, potassium, selenium, germanium, calcium, boron, zinc, manganese, copper, magnesium, sulphur, can promote the necessary multiple macro micro element of vegetable growth, make this vegetables be rich in human body grow prevention and treatment disease needs, make human elementary balance, healthy.

Concrete formulation operations method:

Respectively a granular hypophosphite monohydrate calcium dihydrogen and calcium sulphate dihydrate are pulverized, make it become nanoscale powder shape, again by ammonium sulfate, ammonium nitrate, potassium sulfate, inorganic states selenium, inorganic states germanium, magnesium sulfate adds in container, add water and at 20 ℃-30 ℃, be stirred to above-mentioned material and be all uniformly dissolved, separately by four anhydrous manganeses, Salzburg vitriol, Zinc vitriol, ferrous sulfate, ten hydrated sodium borates are put into another container jointly, add a small amount of boiling water, under agitation make it all dissolve, then whole materials of above-mentioned two kinds of solution and two kinds of nanoscale powders are fully mixed at normal temperatures and stirred, and the PH of the mixture stirring is aligned to 6-7, gained be stoste, be and there is the nutritive medium that maintains the Effects on Plant Growths such as vegetables.In the time using this nutritive medium, 200 times of thin ups, can spray in vegetables blade face.Very applicable city resident's balcony vegetable growing.

Embodiment bis-: balcony gourd, fruit and vegetable soilless culture trace element fertilizer is by following mass component proportioning composition

(1) chelated iron 20%;

(2) nanometer selenium 8%;

(3) lactic acid citric acid germanium 6%;

(4) boric acid or borax 2.68%;

(5) manganous sulfate 1.54%;

(6) zinc sulfate 0.22%;

(7) copper sulfate 0.18%;

(8) ammonium molybdate 0.20%;

(9) medical stone or strange ice stone nano powder 15%;

(10) tourmalinite or astroies nano powder 14%;

(11) chitin or chitosan nano ground rice 17%;

(12) bee pollen nano powder 15%;

Amount to 100%.

Method for making: after above-mentioned material is fully uniformly mixed, cross 1000 mesh sieves with Nano Particle superfine gasifying device nano powder after treatment, medium particle diameter is 0.1-10 μ m.Due to the effect of nanotechnology to material ultra micro granulation; make nanometer particle in plant materials, transport more convenient, absorb more abundant; bioavailability in plant materials is higher, is more conducive to growing of plant, and in plant materials, contained trace element is more more comprehensively many.Above-mentioned material is by every t water material used.First the nanoparticle of above-mentioned ultra micro nanometer is fully stirred mixed, every 100g material 1000ml that adds water stirs and mixed be made into stoste and preserve in dark, face the used time rare aqueous solution of selecting 10 times of water again, levelling pH value is between 5.5-6.5, for the foliage-spray of vegetable melon and fruit and pouring of root system.

Embodiment tri-: fruit tree vegetable hydroponic nutritive medium is by following mass component proportioning composition

(1) organoselenium or Se-rich lucid ganoderma mycelium nano powder 18g account for 1.10%;

(2) organic germanium Ge-132 or Ganoderma rich in germanium mycelium nano powder 15g account for 0.91%;

(3) nitrocalcite 437g accounts for 28.84%;

(4) saltpetre 405g accounts for 24.70%;

(5) potassium primary phosphate 77g accounts for 4.70%;

(6) magnesium sulfate 247g accounts for 15.06%;

(7) manganous sulfate 5g accounts for 0.30%;

(8) zinc sulfate 28g accounts for 1.71%;

(9) copper sulfate 2g accounts for 0.12%;

(10) boric acid 20g accounts for 1.22%;

(11) Sodium orthomolybdate 1g accounts for 0.06%;

(12) chelated iron 15g accounts for 0.91%;

(13) medical stone nano powder 77g accounts for 4.70%;

(14) tourmalinite nano powder 65g accounts for 3.96%;

(15) chitin or chitosan nano ground rice 107g account for 6.52%;

(16) bee pollen nano powder 85g accounts for 5.18%.

Amount to and in water per ton, add 1640 grams of above materials and be mixed with nutritive medium 1640g 100%

The specific conductivity of nutritive medium is controlled at 18ms/cm left and right, and pH value is controlled at 6-6.5.

Method for making: above material, after being fully uniformly mixed, is crossed 1000 mesh sieves with Nano Particle superfine gasifying device nano powder after treatment, and medium particle diameter is 0.1-10 μ m.The every 100g of the above-mentioned material 1000ml that adds water is uniformly mixed and is made into stoste and preserves at dark place, face the aqueous solution that the used time is diluted to 10 times, every day, the nutritive medium 1-1.5L of this dilution was watered in every young plant strain, and the concentration of nutritive medium is controlled at specific conductivity 2.0-2.5ms/cm, and pH value levelling is advisable between 5.5-6.5.

Embodiment tetra-: balcony flower soilless culture nutrient fluid (1) material is by following mg/L quality proportioning composition %; (2) material is by following mmol/L quality proportioning composition

(1) name of material 1. 2. 3.

Calcium nitrate tetrahydrate mg/L 1180 accounts for 46.92%; 945 account for 43.75%; 708 account for 28.99%;

Saltpetre mg/L 506 accounts for 20.12%; 607 account for 28.10%; 1011 account for 41.40%;

Potassium primary phosphate mg/L 136 accounts for 5.41%; 115 account for 5.31%; 230 account for 9.42%;

Bitter salt mg/L 693 accounts for 27.55%; 493 account for 22.82%; 493 account for 20.19%;

Amount to 2515 and account for 100%; 2160 account for 100%; 2442 account for 100%.

(2) name of material 1. 2. 3.

NH ⁺ ₄-N mmol/L 11.7 accounts for 19.40%; 11.0 account for 16.62%; 2.0 account for 2.99%;

NO ^- ₃-N mmol/L 11.7 accounts for 19.40%; 14.0 account for 21.15%; 16.0 account for 23.88%;

Na ₂seO ₃mmol/L 15.0 accounts for 24.87%; 17.50 account for 26.44%; 18.0 account for 26.87%;

Ge-132mmol/L 10.5 accounts for 17.41%; 8.7 account for 13.14%; 12.0 account for 17.91%;

P mmol/L 1.47 accounts for 2.44%; 1.0 account for 1.51%; 2.0 account for 2.99%;

K mmol/L 3.43 accounts for 5.69%; 6.0 account for 9.06%; 10.0 account for 14.93%;

Ca mmol/L 4.88 accounts for 8.09%; 4.0 account for 6.04%; 3.0 account for 4.48%;

Mg mmol/L 0.82 accounts for 136%; 2.0 account for 3.02%; 2.0 account for 2.99%;

S mmol/L 0.82 accounts for 1.36%; 2.0 account for 3.02%; 2.0 account for 2.99%;

Amount to 60.32 and account for 100%; 66.20 account for 100%; 67.0 account for 100%.

Method for making: formula (1), (2) each material are fully uniformly mixed crosses 1000 mesh sieves afterwards with Nano Particle superfine gasifying device nano powder after treatment, and medium particle diameter is 0.1-10 μ m.Due to the effect of nanotechnology to material ultra micro granulation; make nanometer particle in plant materials, transport more convenient, absorb kind with more abundant; bioavailability in plant materials is higher, is more conducive to growing of plant, and trace element contained in plant materials is more more comprehensively many.

More than formula is with reference to the U.S. suddenly on Glan Shi Naide and A Nong formula basis, carries out nanotechnology treatments and the situation that lacks selenium germanium or seriously lack selenium germanium according to the area of China 72% is added Se, Ge element, and object is to increase the composition containing selenium germanium in fruit.This on original basis, all materials are carried out after nanotechnology treatments, there is surprising change in its function, physico-chemical property, the growth of convenient plant trees, the supply of nutrition absorb, have more practicality, substance and progressive significantly, have more the creativeness of the 3rd section of the 22nd article regulation of standby patent law.The constituent content of having listed compound composition, content and contained Se, Ge, N, P, K, Ca, Mg, S in formula is belong to the universal formula of fruit tree growth, that in the fruit tree body according to normal growth, needed various nutrient composition contents are worked out this nutrient composition content, therefore, meet the requirement of fruit tree growth physiological equilibrium.

Claims

1. rich selenium germanium vegetable melon and fruit soilless culture trace element nano nutrient fertilizer, is characterized in that: by following mass component proportioning composition

2. a rich selenium germanium vegetable melon and fruit soilless culture trace element nano nutrient fertilizer, is characterized in that: by following mass component proportioning composition

Method for making: after above-mentioned material is fully uniformly mixed, cross 1000 mesh sieves with Nano Particle superfine gasifying device nano powder after treatment, medium particle diameter is 0.1-10 μ m, due to the effect of nanotechnology to material ultra micro granulation, make nanometer particle in plant materials, transport more convenient, absorb more abundant, bioavailability in plant materials is higher, is more conducive to growing of plant, and in plant materials, contained trace element is more more comprehensively many; Above-mentioned material is by every T water material used; First the nanoparticle of above-mentioned ultra micro nanometer is fully stirred mixed, every 100g material 1000ml that adds water, stir and mixed be made into stoste and preserve in dark, face the used time aqueous solution of 10 times of dilute with waters again, adjusting pH value is between 5.5-6.5, for the foliage-spray of vegetable melon and fruit sapling and pouring of root system.

3. a rich selenium germanium vegetable melon and fruit soilless culture trace element nano nutrient fertilizer, is characterized in that: by following mass component proportioning composition

In every T water, add above material 1640g above, material sum is 100%;

4. a rich selenium germanium vegetable melon and fruit soilless culture trace element nano nutrient fertilizer, is characterized in that: following mass component proportioning composition

(1)

(2)

Method for making: formula (1), (2) each material are fully uniformly mixed crosses 1000 mesh sieves afterwards with Nano Particle superfine gasifying device nano powder after treatment, and medium particle diameter is 0.1-10 μ m; Due to the effect of nanotechnology to material ultra micro granulation; make nanometer particle in plant materials, transport more convenient, absorb kind with more abundant; bioavailability in plant materials is higher, is more conducive to growing of plant, and trace element contained in plant materials is more more comprehensively many.