CN103120107B - Nutrient enrichment selenium-enriched rice and cultivation method thereof - Google Patents
Nutrient enrichment selenium-enriched rice and cultivation method thereof Download PDFInfo
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- CN103120107B CN103120107B CN201310061120.8A CN201310061120A CN103120107B CN 103120107 B CN103120107 B CN 103120107B CN 201310061120 A CN201310061120 A CN 201310061120A CN 103120107 B CN103120107 B CN 103120107B
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D9/00—Other inorganic fertilisers
- C05D9/02—Other inorganic fertilisers containing trace elements
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
- A01G22/00—Cultivation of specific crops or plants not otherwise provided for
- A01G22/20—Cereals
- A01G22/22—Rice
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F11/00—Other organic fertilisers
- C05F11/10—Fertilisers containing plant vitamins or hormones
Abstract
The invention relates to nutrient enrichment selenium-enriched rice and a cultivation method of the nutrient enrichment selenium-enriched rice. A nutrient solution which is adopted comprises a selenium material, protein, amino acid, microelement, an energy accelerator, an enhancer, a reaction accelerator, active water, a penetrating agent, a protective agent, a buffer agent, emulgator and the like, during a rice seedling period, a heading to flowering period and a grouting fructicative period, the diluted selenium nutrient solution is evenly sprinkled on leaf surfaces of paddies. After the process, the selenium content of the nutrient enrichment selenium-enriched rice can be 189 micrograms per kilogram, and the yield per mu can be improved by about 5% to 10%.
Description
Technical field
The present invention relates to a kind of fortification selenium-rich rice, utilize specifically the fortification selenium-rich rice of cultivating containing peptide albumen selenium, energy promoter and other micro-high energy complex peptides albumen selenium nutrient solutions and the cultivation method of this rice.
Background technology
Selenium is respectfully called " kindling material of life " by domestic and international the world of medicine and nutrition educational circles, enjoys the good reputations such as " long-lived element ", " anticancer king ", " heart patron saint " " natural antipoison ".Selenium is one of trace element of needed by human, and it is glutathione peroxidase (GSH-Px) activated centre, has the free radical of removing, anti-aging effects, and in addition, selenium can improve body immunity, and heavy metal is had to antagonism.
Selenium is 1/10000000th at tissue intensive amount, but it has determined the existence of life, to the great function of human health, is that other materials are irreplaceable.Scarce selenium can directly cause human immunological competence to decline, clinical medicine proves, threaten 40 various diseases of human health and life all relevant with the scarce selenium of human body, as cancer, cardiovascular disease, hepatopathy, cataract, endocrine metabolism disease, pancreas disease, diabetes, atonic constipation, genital system diseases etc.
It is 50～250 micrograms that daily intaking amount is recommended by Chinese Soclety of Nutrition.But China adult's selenium intake every day only has 26～50 micrograms.According to geologist, investigate: the area of China 72% belongs to and lacks selenium area, and the natural food Se contents such as grain are lower; The big and medium-sized cities such as North China, northeast, northwest all belong to and lack selenium area, the wide geographic area of Shi Erge provinces and cities of middle state-two, and approximately 700,000,000 people live in low scarce selenium area.
The data that WHO announces shows, the whole world has more than 40 country to belong to low selenium or scarce selenium area.Rich selenium agricultural byproducts are human body Selenium Supplement element effective ways, and therefore, technique of enriched selenium is the hot fields of scientists study exploitation.
Lower than recommendation.According to expert's textual criticism, people needs to mend throughout one's life selenium.No matter be zoopery or clinical practice, all illustrated and constantly from diet, obtain the selenium of q.s, can not supplement in time, will reduce the ability of getting rid of illness.People should be the same as absorbing starch, protein and vitamin every day, and must take in the selenium of q.s every day.Therefore, mending selenium has become a kind of trend that we pursue health, is also imperative healthy mission.
The approach of mending selenium has three kinds: clinical selenium-complementing salt, and dosage is difficult to be grasped, and toxic and side effect is large, is difficult to apply; Take containing selenium health products, as rich selenium health, gold partner, the prosperous capsule of selenium etc., price is high, and numerous residents and wage-earners are difficult to bear economically; Food is mended selenium, by people often edible fruit, grain etc. carry out Selenium Supplement, be a kind of economy, safety, mend selenium approach efficiently, easily.
On market, oneself has rich selenium grain now, but most inorganic selenium and complexing selenium preparation of adopting, its absorption ratio is low, and production capacity is little.As the topmost cereal crops rice of China, the conventional staple food raw material of the most of Area Inhabitants of Ye Shi China, adopts nutrition reinforced type selenium-rich rice, by the health to numerous residents, provides sound assurance.
Summary of the invention
For the demand in above-mentioned field, the invention provides a kind of fortification selenium-rich rice, meet national regulation selenium tolerance limit (GB13105-91) grain oil plant and goods 100-300 microgram thereof/kilogram, be good se-rich health food products.
The present invention simultaneously also provides the cultivation method of this rice.
The cultivation method of fortification selenium-rich rice, it is characterized in that: high energy complex peptides albumen selenium nutrient solution is added to small molecule active water dilution 6000-8000 doubly, adopt the mode of foliage-spray, spray 3 times, 30～50 kilograms of nutrient solutions that diluted of each every mu of needs, described high energy complex peptides albumen selenium nutrient solution is by containing selenium raw material, the enzymolysis product of protein, natural crystal raw material, acetic acid, EDTA, bleeding agent, mineral additive, vitamin additive, organosilicon, solubility modified starch, emulsifier, small molecule active water forms, its raw material weight percentage is: (1) is containing selenium raw material 1-3%, (2) natural crystal raw material 0.5 ‰, (3) protein raw material 2-3%, (4) acetic acid 1～5 ‰, (5) EDTA0.5～1 ‰, (6) bleeding agent 1 ‰, (7) microelement additive 6-10 ‰, (8) vitamin additive 0.2-0.3 ‰ .(9) organosilicon 1 ‰.(10) solubility modified starch 1%, (11) emulsifier 1.5%-5%, (12) small molecule active water: 87-93%.
During described spraying, be respectively: spray for the first time, in rice seedling seedling stage, dilution is sprayed in the rice shoot page; Spray for the second time, at full heading time, be sprayed on rice leaf; Spray for the third time, at During Grain-filling, be sprayed on rice leaf.
Describedly be chosen in illumination while spraying for the second time when weak or afternoon, at dusk.
Described spraying as machinery or artificial vaporific spraying.
Described is one or more in selenium element (SE), selenium oxide, sodium selenite, selenium salt, Organic Selenium containing selenium raw material.
Described natural crystal raw material is one or more in medical stone, nanoscale magnetic, tourmaline, volcanic rock, volcanic ash.
Described emulsifier is mono-stearin: and single 18 (alkane) sour glycerine ester (English name Glycerin monostearate is called for short: GMS), and stearoyl lactate (ssl), CSL (csl), diacetyl tartarate monoglyceride (datem), sucrose fatty ester (se) or distillation monoglyceride (dmg).
Described bleeding agent is methyl alcohol or ethylene glycol.
Described protein is animal/vegetable protein, microprotein or peptide compound.
Described microelement additive consist of zinc: 1-3 ‰; Magnesium: 1-2 ‰; Manganese: 1-2.5 ‰; Molybdenum: 0.1-0.15 ‰; Boron: 2-3 ‰.
Described vitamin additive consist of VC:0.1 ‰; VB1, VD are total up to 0.1.-0.2 ‰.
The rice that adopts said method cultivation to obtain.
The cultivation method of fortification selenium-rich rice of the present invention, adopts homemade high energy complex peptides albumen selenium nutrient solution, divides and sprays the rice seedling page three times, obtains standard compliant fortification selenium-rich rice.
The using method of high energy complex peptides albumen selenium nutrient solution.Foliage-spray: high energy complex peptides albumen selenium nutrient solution mother liquor is added to 100 times of active water dilutions, be mixed with stoste.Get stoste and add again in right amount 60～80 times of active water dilutions, 30～50 kilograms of nutrient solutions that diluted of every mu of needs.With machinery or manually sparge Rice Leaf page, until dilution uses until exhausted.
The high energy complex peptides albumen selenium nutrient solution first step that the present invention adopts is by protein digestion, to be amino protein peptide by enzymolysis; this protein peptides and selenium raw material are under the protection of organosilyl protective agents; the synthetic peptide of having an effect albumen selenium compound; by energy promoter, it is natural energy ore; product energy is further promoted; by adding nutrition that vitamin, mineral additive makes Crop more comprehensively, bleeding agent, small molecule active water can absorb each active ingredient faster and betterly.This high energy complex peptides albumen selenium nutrient solution not only makes crop selenium rich ability greatly improve, and the nutritive value of crop, diseases and insect pests resistance, anti-corrupt ability all improve greatly, and every mu can be improved output 5-10% left and right.
In its formula, proteins,vitamins,minerals, energy promoter etc. have been added simultaneously, greatly improved the content of the mineral element zinc of needed by human, magnesium, Meng, Molybdenum, boron and Cobastab, C, D in crop, make selenium-rich rice mass color fine and smooth, mouthfeel is excellent, anti-oxidant, press down germ ability and improve, make the resistance to fortune of the resistance to storage of Se-rich farm products.
Selenium in its formula and boron element etc. are converted into nutrient for plants, can resist germ and insect, even the malignant diseases insect pests such as nematode, fragrant-flowered garlic maggot and fruit tree putrefaction disease are also had to remarkable result, can partly replace agricultural chemicals, pesticide dosage and residue of pesticide are reduced, make Se-rich farm products more easily reach green standard.
Described small molecule active water, be exactly by common drinking water after the multiple filtrations such as sand filtration, charcoal filter, membrane filtration, again through thering is the raw ion-exchange unit of electricity of nanometer technology, acidic materials harmful in water are separated, and mineral ion in reservation water is the water with alkalescent, subset feature.Micromolecular water contributes to the abundant dissolving of said components and the quick absorption of crop, improves the absorption ratio of material to nutrient solution, makes crop alimentary general equilibrium.
Utilize selenium-rich nutritive liquid of the present invention not only for crop provides selenium, the needed various trace elements of crops normal growth and energy promoter also can be provided, can promote growth and the resistance against diseases of crops, resist harmful substance, improve and make amount and output.
Adopt above-mentioned cultivation method, in Shandong Tancheng county, cultivate and be rich in selenium element and other micro-fortification selenium-rich rices, after rice seedling ripe and harvested, through processing, get product.The Se content of selenium-rich rice detects (GB5009.93-2010) through Shandong Forecasting and Analysis Center, and submitted sample Se content is 189 micro-gs/kg.Complete compound national regulation selenium in food tolerance limit (GB13105-91) grain oil plant and goods 100-300 microgram thereof/kilogram.
Embodiment
Below by embodiment, the invention will be further described.
The high energy complex peptides albumen selenium nutrient solution of mentioning in the present invention, by containing selenium raw material, the enzymolysis product of protein, natural crystal raw material, acetic acid, EDTA, bleeding agent, mineral additive, vitamin additive, organosilicon, solubility modified starch, emulsifier, small molecule active water forms, its raw material weight percentage is: (1) is containing selenium raw material 1-3%, (2) natural crystal raw material 0.5 ‰, (3) protein raw material 2-3%, (4) acetic acid 1～5 ‰, (5) EDTA0.5～1 ‰, (6) bleeding agent 1 ‰, (7) microelement additive: 6-10 ‰, (8) vitamin component: 0.2-0.3 ‰ .(9) organosilicon 1 ‰.(10) solubility modified starch 1%.(11) emulsifier: 1.5%-5%.(12) small molecule active water: 87-93%.
Compound method:
1) protein digestion: protein raw material is carried out to Peptides processing, and obtaining protein purification zymolyte is amino protein peptide; Described protein digestion is for adopting neutral protease enzymolysis, concentration of substrate 3%, neutral protein enzyme concentration 4.5%, phosphate buffered solution pH value 7.0, temperature 50 C, enzymolysis 1～2 hour, centrifugation is enzymolysis protein matter not, obtains protein purification zymolyte, i.e. amino protein peptide;
2) synthetic peptide albumen selenium compound: in the material generating, add organosilyl protective agents in step 1), add selenium raw material, in 55 ℃ of situations, uniform stirring 1.5h;
3) energy quantification treatment: natural crystal raw material, microelement additive, acetic acid, solubility modified starch are mixed, in 42～70 ℃ of situations, uniform stirring 1h;
4) complex reaction: step 2), in product, add EDTA,, in 50～85 ℃ of situations, reaction 2.5h;
5) intensive treatment: in step 3) product, add bleeding agent, vitamin additive, stir at normal temperatures 1h;
6) emulsification pretreatment: emulsifier is placed in container, and heat fused becomes liquid; 4-5 is doubly added to homogenizer to the small molecule active water of approximately 70 ℃ of emulsifier weight portion, start agitator, by the fierce stirring of hot water; To be fused into the emulsifier of liquid, slowly add in the hot water being stirred and beat and mix, can generate milky white hydrate lotion, rear cool to room temperature is stand-by;
7) emulsification treatment: step 4), step 5) and step 6) product are mixed, add appropriate all the other small molecule active water, stirring at room 1h;
8) be up to the standards, after sterilizing, be made into qualified high energy complex peptides albumen selenium nutrient solution mother liquor and store.
Following examples are only for setting forth the present invention, and protection scope of the present invention is not only confined to following examples.The those of ordinary skill of described technical field, according to above disclosure of the present invention, all can be realized object of the present invention.
Embodiment 1
1,1 feed proportioning
(1) containing selenium raw material 2KG, (2) natural crystal raw material 0.05KG, (3) protein raw material 2KG, (4) acetic acid 0.3KG, (5) EDTA0.1KG, (6) bleeding agent 0.1KG, (7) microelement additive, zinc: 0.1KG; Magnesium: 0.1KG; Manganese: 0.2KG; Molybdenum: 0.01KG; Boron: 0.21KG, (8) vitamin additive, VC:0.01KG; VB1, VD are total up to 0.02KG, (9) organosilicon 0.1KG, and (10) solubility modified starch 1KG, (11) emulsifier 3KG, (12) small molecule active water is about 90.7KG, and batching is total up to 100KG.
Prepare as stated above high energy complex peptides albumen selenium nutrient solution.
1,2 carry out the cultivation of fortification selenium-rich rice
The present invention, by following processing step, cultivates and is rich in selenium element and other micro-fortification selenium-rich rices in Shandong Tancheng county.Specific as follows:
1, first prepare foliage-spray nutritious liquor: utilize the high energy complex peptides albumen selenium nutrient solution of mentioning in summary of the invention, add 100 times of small molecule active water dilutions, be mixed with stoste.Get stoste and add again in right amount 60～80 times of active water dilutions, the high energy complex peptides albumen selenium nutrient solution having diluted.
2, in rice seedling seedling stage, spray for the first time, the high energy complex peptides albumen selenium nutrient solution configuring is sprayed on rice shoot blade face.Consumption 10～20kg/100 the ㎡ spraying;
3, at full heading time, spray for the second time, be sprayed on rice leaf, every mu of ground sprays nutrient solution 30-50kg; The selection of time of spraying is when illumination is weak or afternoon, at dusk.
4, at During Grain-filling, within namely interval 5-7 days after spraying for the second time, spray for the third time, every mu of needs 30～50kg, can gather in after 15-20 days.
After above steps is processed, after rice seedling ripe and harvested, through processing, get product.The Se content of selenium-rich rice detects (GB5009.93-2010) through Shandong Forecasting and Analysis Center, and submitted sample Se content is 189 micro-gs/kg.Complete compound national regulation selenium in food tolerance limit (GB13105-91) grain oil plant and goods 100-300 microgram thereof/kilogram.
Claims (10)
1. the cultivation method of fortification selenium-rich rice, it is characterized in that: high energy complex peptides albumen selenium nutrient solution is added to small molecule active water dilution 6000-8000 doubly, adopt the mode of foliage-spray, spray 3 times, 30～50 kilograms of nutrient solutions that diluted of each every mu of needs, described high energy complex peptides albumen selenium nutrient solution is by containing selenium raw material, the enzymolysis product of protein, natural crystal raw material, acetic acid, EDTA, bleeding agent, mineral additive, vitamin additive, organosilicon, solubility modified starch, emulsifier, small molecule active water forms, its raw material weight percentage is: (1) is containing selenium raw material 1-3%, (2) natural crystal raw material 0.5 ‰, (3) protein raw material 2-3%, (4) acetic acid 1～5 ‰, (5) EDTA0.5～1 ‰, (6) bleeding agent 1 ‰, (7) microelement additive 6-10 ‰, (8) vitamin additive 0.2-0.3 ‰, (9) organosilicon 1 ‰, (10) solubility modified starch 1%, (11) emulsifier 1.5%-5%, (12) small molecule active water: 87-93%,
During described spraying, be respectively: spray for the first time, in rice seedling seedling stage, dilution is sprayed in rice shoot blade face; Spray for the second time, at full heading time, be sprayed on rice leaf; Spray for the third time, at During Grain-filling, be sprayed on rice leaf;
Described natural crystal raw material is one or more in medical stone, nanoscale magnetic, tourmaline, volcanic rock, volcanic ash;
Described microelement additive consist of zinc: 1-3 ‰; Magnesium: 1-2 ‰; Manganese: 1-2.5 ‰; Molybdenum: 0.1-0.15 ‰; Boron: 2-3 ‰.
2. cultivation method according to claim 1, is describedly chosen in afternoon or at dusk while spraying for the second time.
3. cultivation method according to claim 1, described in spray as machinery or artificial vaporific spraying.
4. cultivation method according to claim 1, described is one or more in selenium simple substance, selenium oxide, selenium salt, Organic Selenium containing selenium raw material.
5. cultivation method according to claim 1, described is sodium selenite containing selenium raw material.
6. cultivation method according to claim 1, described emulsifier is mono-stearin: single octadecanoid acid glycerine ester, stearoyl lactate, CSL, diacetyl tartarate monoglyceride, sucrose fatty ester or distillation monoglyceride.
7. cultivation method according to claim 1, described bleeding agent is methyl alcohol or ethylene glycol.
8. cultivation method according to claim 1, described protein is animal/vegetable protein, microprotein or peptide compound.
9. cultivation method according to claim 1, described vitamin additive consist of VC:0.1 ‰; VB1, VD are total up to 0.1.-0.2 ‰.
10. the rice that adopts the cultivation of claim 1-9 either method to obtain.
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| CN201310061120.8A CN103120107B (en) | 2013-02-27 | 2013-02-27 | Nutrient enrichment selenium-enriched rice and cultivation method thereof |
| PCT/CN2013/090597 WO2014131310A1 (en) | 2013-02-27 | 2013-12-26 | Nutrient-strengthened selenium-rich rice and cultivation method thereof |
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| CN103283549B (en) * | 2013-06-28 | 2015-04-01 | 丹寨县黔丹硒业有限责任公司 | Cultivation method of pollution-free high-quality selenium-zinc rice |
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| CN110786215B (en) * | 2019-11-28 | 2021-08-27 | 吉林省辉农粳稻科学技术开发有限公司 | Cultivation method of selenium-rich rice |
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| CN112956380B (en) * | 2021-01-29 | 2022-11-04 | 朱宁 | Planting method of highland barley tolerant to high selenium and cultivation method of highland barley malt |
| CN115353436A (en) * | 2022-08-29 | 2022-11-18 | 佛山市铁人环保科技有限公司 | Silicon-selenium-zinc organic foliar fertilizer and preparation method thereof |
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| WO2014131310A1 (en) | 2014-09-04 |
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