JP2002003291A - Compost-mixed fertilyzer and grain - Google Patents

Compost-mixed fertilyzer and grain

Info

Publication number
JP2002003291A
JP2002003291A JP2000182476A JP2000182476A JP2002003291A JP 2002003291 A JP2002003291 A JP 2002003291A JP 2000182476 A JP2000182476 A JP 2000182476A JP 2000182476 A JP2000182476 A JP 2000182476A JP 2002003291 A JP2002003291 A JP 2002003291A
Authority
JP
Japan
Prior art keywords
parts
fertilizer
compost
mixed
acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2000182476A
Other languages
Japanese (ja)
Inventor
Tatsuo Okada
達雄 岡田
Iwao Takeda
巌 竹田
Hiroshi Tamiya
弘志 田宮
Kaori Harada
かおり 原田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
MI TEC KK
Mitech KK
Original Assignee
MI TEC KK
Mitech KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by MI TEC KK, Mitech KK filed Critical MI TEC KK
Priority to JP2000182476A priority Critical patent/JP2002003291A/en
Publication of JP2002003291A publication Critical patent/JP2002003291A/en
Pending legal-status Critical Current

Links

Landscapes

  • Cultivation Of Plants (AREA)
  • Fertilizers (AREA)

Abstract

PROBLEM TO BE SOLVED: To improve the aroma and taste of grain by sure absorption of metallic components from roots. SOLUTION: The compost-mixed fertilizer of the present invention contains a compost of 10-100 wt. parts, aerobic microorganisms of 0.1-10 wt. parts, anaerobic microorganisms of 0.05-10 wt. parts and a fertilizer containing a chelated compound 1-50 wt. parts. The metallic components are surely absorbed from the roots of the grain without receiving the influence by the microorganisms, and the grain which is aromatic and tasty and has a preservative effect and an antifungul effect can be grown.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、肥料、特に堆肥、
好気性微生物、嫌気性微生物及びキレート化合物含有肥
料を含む堆肥混合肥料及び堆肥混合肥料を施肥して生育
させた穀類に属する。
TECHNICAL FIELD The present invention relates to a fertilizer, especially a compost,
It belongs to a compost mixed fertilizer containing an aerobic microorganism, an anaerobic microorganism and a fertilizer containing a chelate compound, and a cereal grown by applying the compost mixed fertilizer.

【0002】[0002]

【従来の技術】農作物に養分を与え、収穫率を上げると
共に、地力の衰退を防ぐために土壌には肥料が施され
る。肥料の必要成分は植物の生育に必要でかつ特に大量
補給を要する窒素(N)、リン(P)、カリウム(K)を
主要な3要素とする。窒素は、植物の蛋白質合成、細胞
の分裂及び増殖、根の発育、葉茎の繁茂を促進し、ま
た、養分の吸収、同化作用を促進する。リンは、根の発
育を促進して根の養分吸収面を増大し、発芽を活発化す
る。また、植物の成熟を促進して子実の収量を増大す
る。更に、デンプン生成、酵素及び微生物の活動を促進
し、害虫を防止すると共に、収穫物を良質化する。カリ
ウムは、炭水化物及び窒素化合物を合成し、同化作用、
根の発育、開花及び結実を促進する。また、水分を供給
し、蒸発作用の調整をする。更に、冷害又は病虫害への
抵抗力を増加する。
2. Description of the Related Art Fertilizer is applied to soil in order to provide nutrients to crops, increase the yield, and prevent the decline of soil strength. The main components of the fertilizer are nitrogen (N), phosphorus (P), and potassium (K), which are necessary for plant growth and especially require large-scale replenishment. Nitrogen promotes plant protein synthesis, cell division and proliferation, root development, leaf stem overgrowth, and promotes nutrient uptake and assimilation. Phosphorus promotes root development, increases the nutrient absorption surface of the root, and activates germination. It also promotes plant maturation and increases grain yield. In addition, it promotes starch production, enzyme and microbial activity, prevents pests and improves the quality of the harvest. Potassium synthesizes carbohydrates and nitrogen compounds, assimilating,
Promotes root development, flowering and fruit set. In addition, water is supplied to adjust the evaporation action. In addition, it increases resistance to cold or pest damage.

【0003】金属は、水銀(Hg)、カドミウム(Cd)等
の公害の原因となる重金属の混入は避けなければならな
いが、肥料として有効な金属もある。例えば、カルシウ
ム(Ca)は、有毒物質の中和、葉緑素の生成、根の発育
促進等の作用を示し、マグネシウム(Mg)は葉緑素の生
成、油脂類の合成、酵素の活性化等に関与する。また、
マンガン(Mn)は、呼吸作用、酸化酵素作用の促進を図
り、銅(Cu)は酸化酵素に含まれ、モリブデン(Mo)
は、ビタミンCの合成、空中窒素の固定に関与する酵素
に含まれ、鉄(Fe)は、葉緑素形成、根の保護作用に関
与する。
As for metals, it is necessary to avoid contamination of heavy metals such as mercury (Hg) and cadmium (Cd) which cause pollution, but some metals are effective as fertilizers. For example, calcium (Ca) exhibits actions such as neutralization of toxic substances, production of chlorophyll, promotion of root growth, and magnesium (Mg) is involved in production of chlorophyll, synthesis of oils and fats, activation of enzymes, and the like. . Also,
Manganese (Mn) promotes respiratory action and oxidase activity, and copper (Cu) is included in oxidase and molybdenum (Mo)
Is included in enzymes involved in the synthesis of vitamin C and fixation of air nitrogen, and iron (Fe) is involved in chlorophyll formation and root protective action.

【0004】[0004]

【発明が解決しようとする課題】前記のように、金属成
分は穀類等の農作物の生育上、重要な栄養分として働
き、根から確実に吸収されることが好ましい。しかし、
金属を堆肥等の肥料に混合しても、金属は堆肥中の微生
物による分解や他の物質と反応し化合物として析出する
ことにより、農作物に吸収されないことが多い。そこ
で、本発明は、金属等の肥効成分を農作物へ確実に吸収
させる堆肥混合肥料を提供することを目的とする。ま
た、味、香りが良く、防腐及び防黴作用を有する穀類を
提供することを目的とする。
As described above, it is preferable that the metal component functions as an important nutrient for the growth of crops such as cereals and is surely absorbed from the root. But,
Even when metal is mixed with fertilizer such as compost, the metal is often not absorbed by agricultural crops due to decomposition by microorganisms in the compost or reaction with other substances and precipitation as a compound. Therefore, an object of the present invention is to provide a compost-mixed fertilizer that reliably absorbs fertilizing components such as metals into agricultural products. It is another object of the present invention to provide a cereal having good taste and aroma and having an antiseptic and antifungal action.

【0005】[0005]

【課題を解決するための手段】本発明による堆肥混合肥
料は、重量基準で堆肥10〜1000部と、好気性微生
物0.1〜10部と、嫌気性微生物0.05〜10部と、
キレート化合物含有肥料1〜50部とを含む。キレート
化合物含有肥料のキレート化合物は、2個以上の配位原
子をもつ多座配位子が中心金属と環を形成した非常に安
定な錯体である。キレート化合物含有肥料を堆肥に混合
すると、キレート化合物は堆肥中の微生物による分解及
び他の物質との化学反応による析出が起こらず、農作物
は根から金属成分をキレート化合物の状態で確実に吸収
する。微生物等により金属成分が堆肥中で変性しないの
で、堆肥に好気性微生物及び嫌気性微生物を加えて、更
に堆肥の活性を高めることができる。これにより、土壌
の良質化を図り、土壌中の養分を吸収する農作物の生育
を促進することができる。
The mixed fertilizer of the present invention comprises 10 to 1000 parts by weight of compost, 0.1 to 10 parts of aerobic microorganisms, 0.05 to 10 parts of anaerobic microorganisms, and
1 to 50 parts of a fertilizer containing a chelate compound. The chelate compound of the chelate compound-containing fertilizer is a very stable complex in which a polydentate ligand having two or more coordination atoms forms a ring with a central metal. When a fertilizer containing a chelate compound is mixed with compost, the chelate compound is not decomposed by microorganisms in the compost or precipitated by a chemical reaction with other substances, and the crop reliably absorbs metal components from the roots in the form of a chelate compound. Since the metal component is not denatured in the compost by microorganisms or the like, the activity of the compost can be further enhanced by adding an aerobic microorganism and an anaerobic microorganism to the compost. This makes it possible to improve the quality of the soil and promote the growth of agricultural crops that absorb nutrients in the soil.

【0006】根から吸収されたキレート化合物は、農作
物内で葉緑素の生成、呼吸作用及び酸化酵素作用の促
進、ビタミンの合成、空中窒素固定酵素の生成、根の保
護作用等農作物生育上重要な役割を担う。また、防黴及
び防腐作用を有し農作物の品質を長期間維持すると共
に、農作物の味及び香りを向上する。
[0006] Chelate compounds absorbed from the roots play important roles in the growth of agricultural crops, such as the production of chlorophyll, the promotion of respiratory and oxidase activities, the synthesis of vitamins, the formation of air-nitrogen fixing enzymes, and the protection of roots in crops. Carry. In addition, it has an antifungal and antiseptic action, maintains the quality of agricultural products for a long time, and improves the taste and aroma of agricultural products.

【0007】更に、堆肥と混合したキレート化合物含有
肥料を施肥した農作物をヒトの体内に摂取すると、体内
でグルタチオンS−トランスフェラーゼ(GST)分子種及
びグルタチオンペルオキシダーゼ(GPx)等の酵素が生
成されると共に、解毒酵素が高収率に内臓で生成され
る。前記酵素は、解毒作用、抗酸化作用、活性酸素を還
元する触媒作用があり、活性酸素、過酸化水素水、有機
過酸化物等の反応性に富む親電子性化合物を水又はアル
コール類に変換する還元反応の触媒として作用するの
で、親電子性化合物がDNA又は蛋白質の求核部分と共有
結合した結果生じる突然変異、発癌、細胞毒性等の発現
を抑制する。
[0007] Furthermore, when a crop that has been fertilized with a fertilizer containing a chelate compound mixed with compost is ingested into the human body, enzymes such as glutathione S-transferase (GST) molecular species and glutathione peroxidase (GPx) are produced in the body. In addition, detoxification enzymes are produced in the organs in high yield. The enzyme has a detoxifying action, an antioxidant action, and a catalytic action to reduce active oxygen, and converts a reactive electrophilic compound such as active oxygen, aqueous hydrogen peroxide, and organic peroxide into water or alcohols. Since it acts as a catalyst for the reduction reaction, it suppresses the occurrence of mutation, carcinogenesis, cytotoxicity, etc. resulting from the covalent bond of the electrophilic compound to the nucleophilic portion of DNA or protein.

【0008】重量基準で堆肥10〜1000部に対し、
好気性微生物0.1〜10部と、嫌気性微生物0.05〜
10部と、キレート化合物含有肥料1〜50部とを添加
する。好気性微生物が0.1部未満及び嫌気性微生物が
0.05部未満であると、微生物が繁殖するために十分
な量ではなく、土壌を活性化することができない。好気
性微生物及び嫌気性微生物が10部を超えると、微生物
の含有量が多く、農作物に害を及ぼす菌類が発生して好
ましくない。キレート化合物含有肥料が1部未満である
と、農作物へのキレート化合物の吸収量が不足し、防黴
及び防腐作用と共に農作物の味及び香りを向上する作用
効果を得ることができない。キレート化合物含有肥料が
50部を超えると、堆肥中に含有するキレート化合物が
多すぎて、吸収されない金属成分が土壌中に残留して蓄
積する。
For 10 to 1000 parts of compost on a weight basis,
0.1 to 10 parts of aerobic microorganisms and 0.05 to anaerobic microorganisms
10 parts and 1 to 50 parts of a chelate compound-containing fertilizer are added. If the amount of the aerobic microorganisms is less than 0.1 part and the amount of the anaerobic microorganisms is less than 0.05 part, the amount is not sufficient for the microorganisms to propagate, and the soil cannot be activated. When the amount of the aerobic microorganisms and the anaerobic microorganisms exceeds 10 parts, the content of the microorganisms is large, and fungi that harm agricultural products are generated, which is not preferable. When the amount of the chelate compound-containing fertilizer is less than 1 part, the amount of the chelate compound absorbed into the crop is insufficient, and the effect of improving the taste and aroma of the crop along with the fungicidal and antiseptic effects cannot be obtained. When the amount of the chelate compound-containing fertilizer exceeds 50 parts, the amount of the chelate compound contained in the compost is too large, and unabsorbed metal components remain and accumulate in the soil.

【0009】また、本発明による穀類は、重量基準で堆
肥10〜1000部と、好気性微生物0.1〜10部
と、嫌気性微生物0.05〜10部と、キレート化合物
含有肥料1〜50部とを含む堆肥混合肥料を施肥して生
育させる。堆肥混合肥料を施肥して生育させた穀類は、
小麦、米、大豆又はそばである。
The cereal according to the present invention comprises 10 to 1000 parts by weight of compost, 0.1 to 10 parts of aerobic microorganisms, 0.05 to 10 parts of anaerobic microorganisms, and 1 to 50 parts of a fertilizer containing a chelate compound. And fertilize with a compost mixed fertilizer containing Grains grown with fertilizer mixed with fertilizer
Wheat, rice, soy or buckwheat.

【0010】[0010]

【発明の実施の形態】以下、本発明による堆肥混合肥料
及び穀類の実施の形態を説明する。本発明による堆肥混
合肥料は、重量基準で堆肥10〜1000部と、好気性
微生物0.1〜10部と、嫌気性微生物0.05〜10部
と、キレート化合物含有肥料1〜50部とを含む。堆肥
は、イナワラ、ヨシ、マコモ、ムギワラ、山野草、落葉
落枝、作物残渣、生ゴミ及び糞尿の1種又は2種以上で
ある。好気性微生物は、酵母、放線菌、酢酸菌、グルコ
ン酸菌、糸状菌及び麹菌の1種又は2種以上であり、嫌
気性微生物は、乳酸菌、グラム陽性発酵性細菌及びグラ
ム陰性発酵性細菌の1種又は2種以上である。好気性及
び嫌気性微生物を堆肥中に混合して繁殖させると、イナ
ワラ、ヨシ、マコモ、ムギワラ、山野草、落葉落枝、作
物残渣、生ゴミ、糞尿等の分解及び発酵が促進され、肥
料として栄養分の高い堆肥が得られる。
BEST MODE FOR CARRYING OUT THE INVENTION Embodiments of a mixed fertilizer and cereal according to the present invention will be described below. The compost mixed fertilizer according to the present invention comprises 10 to 1000 parts of compost on a weight basis, 0.1 to 10 parts of aerobic microorganisms, 0.05 to 10 parts of anaerobic microorganisms, and 1 to 50 parts of a fertilizer containing a chelate compound. Including. The compost is one or more of rice straw, reed, makomo, wheat straw, wild grass, litter, crop residue, garbage, and manure. Aerobic microorganisms are one or more of yeast, actinomycetes, acetic acid bacteria, gluconic acid bacteria, filamentous fungi and koji molds, and anaerobic microorganisms are lactic acid bacteria, gram-positive fermentative bacteria and gram-negative fermentative bacteria. One or two or more. When aerobic and anaerobic microorganisms are mixed and propagated in compost, the decomposition and fermentation of rice straw, reed, makomo, wheat straw, wild grass, litter, crop residues, garbage, manure, etc. are promoted, and nutrients as fertilizer. High compost yield.

【0011】キレート化合物の原料は、重量基準で金属
化合物0.01〜4部と、アミノ酸混合物0.1〜5部
と、カリ肥料2〜8部と、窒素肥料0.1〜1部と、リ
ン肥料0.01〜2部とを含み、水と混合したときにpH
が6.0〜7.5である。アミノ酸混合物は、糖酸及びア
ミノ酸の混合物、脂肪酸及びアミノ酸の混合物又は糖
酸、脂肪酸及びアミノ酸の混合物である。具体的には、
三酸化セレン0.03〜2部と、アミノ酸0.5〜1.5
部と、ペンタル酸0.5〜1.5部と、酢酸0.5〜1.5
部と、カリ肥料3〜5部と、窒素肥料0.3〜0.8部
と、リン肥料0.5〜1部とを含み、水と混合したときp
Hが6.3〜7.0である。また、酢酸ゲルマニウム0.0
5〜2部と、グリセリン酸1.5〜2.5部と、カリ肥料
3〜5部と、窒素肥料0.3〜0.8部と、リン肥料0.
5〜1部とを含み、水と混合したときpHが6.3〜7.0
である。
The raw materials of the chelate compound are 0.01 to 4 parts by weight of a metal compound, 0.1 to 5 parts of an amino acid mixture, 2 to 8 parts of potassium fertilizer, 0.1 to 1 part of nitrogen fertilizer, phosphorus Contains 0.01 to 2 parts of fertilizer, pH when mixed with water
Is 6.0 to 7.5. An amino acid mixture is a mixture of sugar acids and amino acids, a mixture of fatty acids and amino acids or a mixture of sugar acids, fatty acids and amino acids. In particular,
0.03 to 2 parts of selenium trioxide and 0.5 to 1.5 amino acids
Parts, 0.5 to 1.5 parts of pentanoic acid and 0.5 to 1.5 parts of acetic acid.
Parts, 3-5 parts of potassium fertilizer, 0.3-0.8 parts of nitrogen fertilizer, and 0.5-1 parts of phosphorus fertilizer, when mixed with water p
H is 6.3 to 7.0. Also, germanium acetate 0.0
5 to 2 parts, 1.5 to 2.5 parts of glyceric acid, 3 to 5 parts of potassium fertilizer, 0.3 to 0.8 part of nitrogen fertilizer, and 0.5 part of phosphorus fertilizer.
5 to 1 part, and when mixed with water, the pH is 6.3 to 7.0.
It is.

【0012】金属化合物の金属は、カルシウム(Ca)、
マグネシウム(Mg)、マンガン(Mn)、亜鉛(Zn)、銅
(Cu)、モリブデン(Mo)、鉄(Fe)、アルミニウム
(Al)、ニッケル(Ni)、コバルト(Co)、チタン(T
i)、ガリウム(Ga)、セレン(Se)、ゲルマニウム(G
e)、バナジウム(V)、クロム(Cr)、銀(Ag)、スト
ロンチウム(Sr)、インジウム(In)、錫(Sn)、金
(Au)及びジルコニウム(Zr)の1種又は2種以上であ
る。これらの金属成分がキレート化合物によって、穀類
等の農作物に確実に吸収される。
The metal of the metal compound is calcium (Ca),
Magnesium (Mg), manganese (Mn), zinc (Zn), copper (Cu), molybdenum (Mo), iron (Fe), aluminum (Al), nickel (Ni), cobalt (Co), titanium (T
i), gallium (Ga), selenium (Se), germanium (G
e), one or more of vanadium (V), chromium (Cr), silver (Ag), strontium (Sr), indium (In), tin (Sn), gold (Au) and zirconium (Zr) is there. These metal components are surely absorbed by crops such as cereals by the chelate compound.

【0013】キレート化合物の中心金属を形成する金属
化合物の原料は、塩化物塩、硫酸塩、硝酸塩、リン酸
塩、酢酸塩、炭酸塩、珪酸塩及び硼酸塩の金属塩、金属
酸化物並びに金属水酸化物である。アミノ酸は、グリシ
ン、アラニン、ヴァリン、アルギニン、リジン、アスパ
ラギン酸、グルタミン酸、セリン、スレオニン、チロシ
ン、メチオニン及びシスティンの1種又は2種以上を使
用できる。糖酸は、ペンタル酸及びヘキサル酸(グルコ
ン酸も含む)の1種又は2種以上である。脂肪酸は、ギ
酸、酢酸、プロピオン酸、ラウリン酸、ミリスチン酸、
パルミチン酸及びステアリン酸の飽和脂肪酸並びにアク
リル酸、クロトン酸、オレイン酸、ソルビン酸、リノー
ル酸及びリノレン酸の不飽和脂肪酸の1種又は2種以上
から選択される。
The starting materials for the metal compound forming the central metal of the chelate compound include chlorides, sulfates, nitrates, phosphates, acetates, carbonates, silicates and borates, metal oxides and metals. Hydroxide. As the amino acid, one or more of glycine, alanine, valine, arginine, lysine, aspartic acid, glutamic acid, serine, threonine, tyrosine, methionine, and cysteine can be used. The sugar acid is one or more of pentalic acid and hexalic acid (including gluconic acid). Fatty acids are formic, acetic, propionic, lauric, myristic,
It is selected from one or more of saturated fatty acids of palmitic acid and stearic acid and unsaturated fatty acids of acrylic acid, crotonic acid, oleic acid, sorbic acid, linoleic acid and linolenic acid.

【0014】カリ肥料は、塩化カリウム、硫酸カリウ
ム、カーナライト(KCl・MgCl2・6H2O)、鉱石カリ肥料
(KCl又はK2SO4を含む)、ニガリカリ塩(KCl(+NaCl+Mg
SO4))、草木灰(K2CO3、KHCO3)、海ソウ灰(KCl、K2S
O4)、セメントダスト(硫酸塩、炭酸塩、ケイ酸塩)、
溶鉱炉ダスト(炭酸塩、硫酸塩)等を使用できる。窒素
肥料は、硫安((NH4)2SO4)、塩安(NH4Cl)、硝安(NH
4NO3)、リン安((NH4)2HPO4、NH4H2PO4)、アンモニア
水肥料(NH4OH)、アンモニア化デイ炭(有機酸のアン
モニウム塩)、アンモニア化過リン酸石灰(NH4H2PO4
(NH4)2SO4)、硫硝安((NH4)2SO4+NH4NO3)、アンモホ
ス((NH4)2SO4+(NH4)2HPO4)、硫リン安((NH4)2SO4+(N
H4)2HPO4)、下肥(アンモニウム塩)、ウマヤ肥(アン
モニウム塩)等のアンモニア系窒素、硝安(NH4NO3)、
チリ硝石(NaNO3)、硝酸石灰(Ca(NO3)2)、硝酸カリ
(KNO3)、硫硝安((NH4)2SO4+NH4NO3)、硝安石灰(NH
4NO3+CaCO3)カルウレア(Ca(NO3)2・4CO(NH2)2)等の
硝酸窒素、石灰窒素(CaCN2)等のシアナミド系窒素、
尿素(CO(NH2)2)、カルウレア(Ca(NO3)2・4CO(N
H2)2)等の尿素系窒素、尿素樹脂化肥料(ウラホルム)
(CO(NH2)2-HCHO縮合物)、オキザマイド(NH2・CO・CO
・NH2)、グアニル尿素塩([NH2・C(NH)・NH・CO・NH2]
・X)、グアニジン塩([NH2・C(NH)・NH2]・X)、アン
モニア化デイ炭(CO(NH2)2含有)等のアミノ系窒素及び
魚肥(NH2、NH含有)、大豆かす(NH2、NH含有)等の蛋
白系窒素を使用できる(X:HCl、H2SO4、HNO3、H3P
O4)。リン肥料は、過リン酸石灰(Ca(H2PO4)2+CaS
O4)、重過リン酸石灰(Ca(H2PO4)2)、苦土過リン酸
(過リン酸石灰+ジャ紋岩)、溶成リン肥(CaO-MgO-P2
O5-SiO2ガラス)、焼リン肥(Ca3(PO4)2-CaNaPO4固溶
体)、混合リン肥(過(重過)リン酸石灰+溶成リン
肥)、リン鉱石粉末肥料(Ca3(PO4)2)、沈殿リン酸石
灰(CaHPO4)、硫リン安((NH4)2SO4+NH4H2PO4)、硫化
リン安((NH4)2SO4+NH4H2PO4+K2SO4)、固形肥料(硫安
+過リン酸石灰+カリ塩+デイ炭、リン酸塩の形はCa(H
2PO4)2)、化成肥料類(CaHPO4、Ca3(PO4)2)等を使用
できる。
Potassium fertilizers include potassium chloride, potassium sulfate, carnalite (KCl.MgCl 2 .6H 2 O), ore potassium fertilizer (including KCl or K 2 SO 4 ), and bitter potassium salt (KCl (+ NaCl + Mg
SO 4 )), plant ash (K 2 CO 3 , KHCO 3 ), sea ash (KCl, K 2 S
O 4 ), cement dust (sulfate, carbonate, silicate),
Blast furnace dust (carbonate, sulfate) and the like can be used. Nitrogen fertilizers include ammonium sulfate ((NH 4 ) 2 SO 4 ), salt ammonium (NH 4 Cl), and ammonium nitrate (NH
4 NO 3 ), low phosphorus ((NH 4 ) 2 HPO 4 , NH 4 H 2 PO 4 ), aqueous ammonia fertilizer (NH 4 OH), ammoniated de charcoal (an ammonium salt of organic acid), ammoniated superphosphate Lime (NH 4 H 2 PO 4 ,
(NH 4) 2 SO 4) ,硫硝weaker ((NH 4) 2 SO 4 + NH 4 NO 3), Anmohosu ((NH 4) 2 SO 4 + (NH 4) 2 HPO 4), sulfate phosphate weaker (( NH 4 ) 2 SO 4 + (N
H 4 ) 2 HPO 4 ), ammonia nitrogen such as manure (ammonium salt), Umaya manure (ammonium salt), ammonium nitrate (NH 4 NO 3 ),
Nitratine (NaNO 3), nitrate of lime (Ca (NO 3) 2) , potassium nitrate (KNO 3),硫硝weaker ((NH 4) 2 SO 4 + NH 4 NO 3), ammonium nitrate of lime (NH
4 NO 3 + CaCO 3 ) Carurea (Ca (NO 3 ) 2 .4CO (NH 2 ) 2 ) and other nitrogen nitrates, lime nitrogen (CaCN 2 ) and other cyanamide nitrogen,
Urea (CO (NH 2) 2) , Karuurea (Ca (NO 3) 2 · 4CO (N
H 2) 2) urea nitrogen such as urea resin of fertilizers (Urahorumu)
(CO (NH 2 ) 2 -HCHO condensate), oxamide (NH 2・ CO ・ CO
・ NH 2 ), guanylurea salt ([NH 2 · C (NH) · NH · CO · NH 2 ]
・ X), amino nitrogen such as guanidine salt ([NH 2 .C (NH) .NH 2 ] .X), ammoniated day coal (containing CO (NH 2 ) 2 ) and fish manure (containing NH 2 and NH) And protein-based nitrogen such as soybean meal (containing NH 2 and NH) (X: HCl, H 2 SO 4 , HNO 3 , H 3 P)
O 4 ). Phosphorus fertilizer is lime superphosphate (Ca (H 2 PO 4 ) 2 + CaS
O 4 ), heavy superphosphate (Ca (H 2 PO 4 ) 2 ), magnesia superphosphate (superphosphate + jadeite), fused phosphorus fertilizer (CaO-MgO-P 2)
O 5 -SiO 2 glass), burnt phosphorus fertilizer (Ca 3 (PO 4 ) 2 -CaNaPO 4 solid solution), mixed phosphorus fertilizer (hyperphosphate lime + fused phosphorus fertilizer), phosphate rock powder fertilizer (Ca 3 (PO 4 ) 2 ), precipitated lime phosphate (CaHPO 4 ), ammonium phosphate ((NH 4 ) 2 SO 4 + NH 4 H 2 PO 4 ), ammonium phosphate sulfide ((NH 4 ) 2 SO 4 + NH 4 H 2 PO 4 + K 2 SO 4 ), solid fertilizer (ammonium sulfate + lime superphosphate + potassium salt + day coal, the form of phosphate is Ca (H
2 PO 4 ) 2 ) and chemical fertilizers (CaHPO 4 , Ca 3 (PO 4 ) 2 ) can be used.

【0015】前記原料を混合して生成されたキレート化
合物と、堆肥と、好気性微生物と、嫌気性微生物とを混
合し、2〜4ヶ月放置して分解及び発酵させることによ
り堆肥混合肥料が得られる。堆肥混合肥料を土壌に施肥
して生育させた小麦、米、大豆又はそば等の穀類は、香
り、味が良く、防腐及び防黴作用を有する。また、これ
を食べ体内に摂取すると、活性酸素、過酸化水素水、有
機過酸化物、癌等の解毒、抗酸化作用をもつ酵素を生成
することできる。この酵素は、癌等の解毒作用及び抗酸
化作用を有し、グルタチオンS−トランスフェラーゼ(G
ST)分子種が腎臓、肝臓で強く誘導され、グルタチオン
ペルオキシダーゼ(GPx)が腎臓で強く誘導される。
A mixed fertilizer is obtained by mixing a chelate compound produced by mixing the above-mentioned raw materials, a compost, an aerobic microorganism and an anaerobic microorganism, and leaving them for 2 to 4 months to decompose and ferment. Can be Grains such as wheat, rice, soybeans or buckwheat grown by applying a compost mixed fertilizer to soil have good aroma and taste, and have an antiseptic and antifungal action. Also, when this is taken into the body of a food, it can produce an enzyme having detoxification and antioxidant action of active oxygen, hydrogen peroxide solution, organic peroxide, cancer and the like. This enzyme has a detoxifying effect on cancer and the like and an antioxidant effect, and has a glutathione S-transferase (G
ST) is strongly induced in kidney and liver, and glutathione peroxidase (GPx) is strongly induced in kidney.

【0016】[0016]

【実施例】以下、本発明による堆肥混合肥料及び堆肥混
合肥料を施肥して生育させた穀類の実施例を説明する。
部数は全て重量部とする。
DESCRIPTION OF THE PREFERRED EMBODIMENTS Hereinafter, embodiments of the mixed fertilizer and the cereals grown by applying the mixed fertilizer according to the present invention will be described.
All parts are by weight.

【0017】[実施例1]重量基準で三酸化セレン(Se
O3)0.07部を水3部に溶解させた液と、アミノ酸1
部、ペンタル酸1部、酢酸1部を水3部に溶解させた液
とを混合し、30〜60分間撹拌して完全に溶解させ
た。次に、カリ肥料として草木灰(K2CO3、KHCO3)4部
を加え60分間撹拌した。更に、窒素肥料として硫安
((NH4)2SO4)0.5部と、リン肥料として過リン酸石灰
(Ca(H2PO4)2+CaSO4)1部を加え、pHを6.6に調整し
たキレート化合物含有肥料を得た。得られたキレート化
合物含有肥料10部と、イナワラに糞尿を加えた堆肥1
00部と、好気性微生物として酵母0.5部及び放線菌
0.5部と、嫌気性微生物として乳酸菌1部とを混合
し、約2ヶ月半放置して堆肥混合肥料を得た。得られた
堆肥混合肥料0.8トン/10a(0.8kg/m2)を苗床に
散布し、種を蒔き育苗する。また、田おこし・代掻き時
に水田に堆肥混合肥料1.0トン/10a(1.0kg/m2
を散布し、トラクターで田面を掘り起こし水を張り平ら
にした。田植えをして稲を生育させて、溝掘り、中干し
をした後、稲刈りをした。刈った稲を脱穀し精米して米
が得られた。
[Example 1] Selenium trioxide (Se) on a weight basis
O 3 ) A solution prepared by dissolving 0.07 parts in 3 parts of water and amino acid 1
And 1 part of pentanoic acid and 1 part of acetic acid dissolved in 3 parts of water were mixed and stirred for 30 to 60 minutes to completely dissolve. Next, 4 parts of plant ash (K 2 CO 3 , KHCO 3 ) was added as a potash fertilizer and stirred for 60 minutes. Further, 0.5 part of ammonium sulfate ((NH 4 ) 2 SO 4 ) as a nitrogen fertilizer and 1 part of lime superphosphate (Ca (H 2 PO 4 ) 2 + CaSO 4 ) as a phosphorus fertilizer were added, and the pH was adjusted to 6.5. A chelate compound-containing fertilizer adjusted to 6 was obtained. 10 parts of the obtained chelate compound-containing fertilizer and compost 1 obtained by adding manure to rice straw
Then, 0.5 part of yeast and 0.5 part of actinomycete as an aerobic microorganism and 1 part of lactic acid bacterium as an anaerobic microorganism were mixed and left for about two and a half months to obtain a compost mixed fertilizer. The obtained compost mixed fertilizer (0.8 ton / 10a (0.8 kg / m 2 )) is sprayed on a nursery, and seeds are sown and raised. In addition, compost mixed fertilizer 1.0 ton / 10a (1.0 kg / m 2 ) on rice paddy when rice is raised or replaced
Was spread, and a tractor was used to dig up the rice field, fill it with water, and level it. After planting rice, growing the rice, digging and drying, the rice was harvested. The cut rice was threshed and milled to obtain rice.

【0018】[実施例2]重量基準で酢酸ゲルマニウム
0.1部を水3部に溶解させた液と、グリセリン酸2部
を水3部に溶解させた液とを混合し60分間撹拌した。
次に、カリ肥料として海ソウ灰6部を加え60分間撹拌
した。更に、窒素肥料としてアンモニア水肥料0.2部
と、リン肥料としてリン鉱石粉末肥料0.06部とを加
え撹拌し、pHを7.1に調整したキレート化合物含有肥
料を得た。得られたキレート化合物含有肥料15部と、
ムギワラに生ゴミを加えた堆肥100部と、好気性微生
物として酢酸菌1.5部と、嫌気性微生物としてグラム
陽性発酵性細菌0.5部とを混合し、約3ヶ月間放置し
て堆肥混合肥料を得た。畑に堆肥混合肥料10kg/10a
(0.01kg/m2)を散布し、種を蒔き生育させたそばの
木からそばの実を採取し、そば粉を得てそばを製造し
た。
Example 2 A liquid in which 0.1 part of germanium acetate was dissolved in 3 parts of water and a liquid in which 2 parts of glyceric acid were dissolved in 3 parts of water were mixed and stirred for 60 minutes.
Next, 6 parts of sea ash was added as potash fertilizer and stirred for 60 minutes. Further, 0.2 part of an aqueous ammonia fertilizer as a nitrogen fertilizer and 0.06 part of a phosphate rock fertilizer as a phosphorus fertilizer were added and stirred to obtain a chelate compound-containing fertilizer whose pH was adjusted to 7.1. 15 parts of the obtained chelate compound-containing fertilizer,
100 parts of compost obtained by adding garbage to wheat straw, 1.5 parts of acetic acid bacterium as an aerobic microorganism, and 0.5 part of gram-positive fermentative bacteria as an anaerobic microorganism are mixed and left for about 3 months to compost. A mixed fertilizer was obtained. Compost mixed fertilizer 10kg / 10a in the field
(0.01 kg / m 2 ), buckwheat seeds were collected from a buckwheat tree sown and grown, and buckwheat flour was obtained to produce buckwheat.

【0019】[試験方法]得られた米及びそばを、下記
(1)〜(3)の方法により、色、香り、味、防腐及び
防黴作用、癌等の解毒、抗酸化作用をもつ発生酵素の量
について比較した。 (1)穀類の色、香り及び味をみる。 (2)穀類を小さく刻み、水を入れた容器に入れて常温
で静置し、防腐及び防黴作用をみる。 (3)穀類をF344雌ラット(7週令)に3週間与え
た後、肝臓、腎臓を摘出し、これらの臓器に含まれる癌
等の解毒、抗酸化作用をもつ酵素、例えばグルタチオン
S−トランスフェラーゼ(GST)分子種と、グルタチオン
ペルオキシダーゼ(GPx)の量を測定した。グルタチオ
ンS−トランスフェラーゼ(GST)分子種の測定方法は次
の通りである。 <電気泳動用サンプルの調整>摘出した臓器に重量の3
倍量の0.25Mスクロース−10mMリン酸塩緩衝液(pH
7.4)を加えてホモジナイズした。ホモジナイズした
サンプル20μlに20%SDS50μl及びPBS275μl加
えたものを水で10倍に希釈し、ローリー(Lowry)法
により総蛋白量を測定した。蛋白濃度1mg/mlとなるよ
うにサンプル希釈液で調整し、沸騰水で2分間煮沸した
後、0.1%BPB50μlを加えた。 <電気泳動>12.5%SDS−ポリアクリルアミドゲル
(電気泳動SDS-PAGE)を用い、スタッキングジェルは2
8mAでスタッキングジェルを通過するまで、セパレーテ
ィングジェルは36mAで1時間泳動した。 <転写(Western Blot)>バイオラート(BIO RAD)社
製トランスブロットセル(TRANS-BLOT CELL)を用いて
80Vで2時間通過し、電気泳動により分離した蛋白を
ニトロセルロース膜上に転写した。 <免疫染色(Immunostaining)> (a)ブロッキング処理 ニトロセルロース膜を3%スキムミルクTBS緩衝液(pH
7.4)で1時間ブロッキング処理した。 (b)一次抗体 rGSTA1(Ya)、rGSTA3(Yc)、rGSTA4(Yk)、rGSTM
1(Yb1)、rGSTM2(Yb2)、rGSTP1(Yp)の各々に
対するバイオトリン・インターナショナル・リミテッド
(Biotrin International Limited)社製ウサギポリク
ローナ抗体を3%ウシアルブミン(BSA)を含むTBS緩衝
液で5分、0.05%トウィーン(Tween)20を含むTBS
緩衝液で5分を2回、更にTBS緩衝液で5分洗浄した。 (c)二次抗体 ジャクソン・イムノ・リサーチ・ラボラトリーズ・イン
コーポレイテッド(Jacson Immuno Research Laborator
ies, Inc.)社製アルカリフォスファターゼ標識抗ウサ
ギIgGヤギ抗体をTBS緩衝液(pH7.4)で5000倍に
希釈し、室温で1時間反応させた後、一次抗体と同様に
洗浄した。 (d)発色 ピアス(Pierce)社製ニトロブルーテトラ(Nitro Blue
Tetra)を発色試薬として発色反応させた。
[Test Method] The obtained rice and buckwheat are produced by the following methods (1) to (3) to have color, fragrance, taste, antiseptic and antifungal action, detoxification of cancer and the like, and antioxidant action. The amount of enzyme was compared. (1) Check the color, aroma, and taste of cereals. (2) Chop the cereal into small pieces, put them in a container filled with water, and leave them at room temperature to observe their antiseptic and antifungal effects. (3) After giving cereals to F344 female rats (7-week-old) for 3 weeks, the liver and kidneys are removed, and enzymes contained in these organs that have antitoxin and antioxidant effects on cancer and the like, for example, glutathione
The amounts of S-transferase (GST) species and glutathione peroxidase (GPx) were measured. The method for measuring glutathione S-transferase (GST) molecular species is as follows. <Preparation of the sample for electrophoresis>
Double volume of 0.25 M sucrose-10 mM phosphate buffer (pH
7.4) was added and homogenized. 20 μl of the homogenized sample, 50 μl of 20% SDS and 275 μl of PBS, were diluted 10-fold with water, and the total protein content was measured by the Lowry method. The mixture was adjusted to a protein concentration of 1 mg / ml with a sample diluent, boiled with boiling water for 2 minutes, and then 50 μl of 0.1% BPB was added. <Electrophoresis> 12.5% SDS-polyacrylamide gel (electrophoresis SDS-PAGE) was used, and the number of stacking gels was 2
The separating gel ran at 36 mA for 1 hour until it passed through the stacking gel at 8 mA. <Transfer (Western Blot)> The protein separated by electrophoresis was transferred onto a nitrocellulose membrane by passing through a trans-blot cell (TRANS-BLOT CELL) manufactured by Bio RAD at 80 V for 2 hours. <Immunostaining> (a) Blocking treatment The nitrocellulose membrane was coated with 3% skim milk TBS buffer (pH
Blocking treatment was performed for 1 hour in 7.4). (B) Primary antibodies rGSTA1 (Ya), rGSTA3 (Yc), rGSTA4 (Yk), rGSTM
1 (Yb1), rGSTM2 (Yb2), and rGSTP1 (Yp) were treated with a rabbit polyclonal antibody (Biotrin International Limited) for 5 minutes in a TBS buffer containing 3% bovine albumin (BSA). TBS containing 0.05% Tween 20
The plate was washed twice with a buffer for 5 minutes, and further washed with a TBS buffer for 5 minutes. (C) Secondary antibody Jackson Immuno Research Laboratories, Inc. (Jacson Immuno Research Laborator)
ies, Inc.) was diluted 5,000-fold with a TBS buffer (pH 7.4) labeled with an alkaline phosphatase-labeled anti-rabbit goat antibody, reacted at room temperature for 1 hour, and then washed in the same manner as the primary antibody. (D) Color development Nitro Blue Tetra (Pierce)
Tetra) was used as a coloring reagent to carry out a coloring reaction.

【0020】各サンプルの発色バンドをフォトレタッチ
ソフトのアドピフォトショップに取り込み、NIHイメー
ジアナライザーによって発色バンドの強度を測定した。
得られた結果を比較し、有意差検定(t−検定)よりの
グルタチオンS−トランスフェラーゼ(GST)分子種の誘
導状況を調べた。グルタチオンS−トランスフェラーゼ
(GST)分子種の測定値は、カイワレ大根の代わりに通
常の市販固形飼料を3週間与えたF344雌ラット(7
週令)の肝臓、腎臓についての発色バンドの強度を1と
した場合の強度比(単位なし)として算出した。
The color band of each sample was loaded into Adpi Photoshop of photo retouching software, and the intensity of the color band was measured by an NIH image analyzer.
The obtained results were compared, and the state of induction of glutathione S-transferase (GST) molecular species by a significant difference test (t-test) was examined. Glutathione S-transferase (GST) molecular species were measured based on F344 female rats (7
The intensity ratio (without unit) was calculated assuming that the intensity of the coloring band for the liver and kidney at 1 week) was 1.

【0021】[試験結果]試験結果を表1に示す。表1に
示す実施例1は、セレンを含有させた米であり、実施例
2は、ゲルマニウムを含有させたそばである。比較例は
キレート化合物を含まない米である。*印は比較例と比
べて有意差があることを示す。表1に示す通り、色、香
り、味、防腐及び防黴作用について、比較例に対し、実
施例1及び2では顕著な効果が現れた。また、癌等の解
毒、抗酸化作用を持つ発生酵素の量について、比較例に
対し、実施例1及び2では、グルタチオンS−トランス
フェラーゼ(GST)分子種が腎臓、肝臓において有意差
が現れた。グルタチオンペルオキシダーゼ(GPx)は、
腎臓において有意差が現れた。この結果、本実施例の堆
肥混合肥料を施肥して生育させた穀類は、体内で癌等の
解毒、抗酸化作用を持つ酵素を発生させることが判明し
た。
[Test Results] Table 1 shows the test results. Example 1 shown in Table 1 is rice containing selenium, and Example 2 is buckwheat containing germanium. The comparative example is rice without a chelate compound. An asterisk indicates that there is a significant difference compared with the comparative example. As shown in Table 1, with respect to the color, aroma, taste, antiseptic and antifungal effects, Examples 1 and 2 showed remarkable effects as compared with Comparative Examples. In Examples 1 and 2, the glutathione S-transferase (GST) molecular species showed significant differences in kidney and liver in Examples 1 and 2 with respect to the amount of the generated enzyme having detoxification and antioxidant effects on cancer and the like. Glutathione peroxidase (GPx)
A significant difference appeared in the kidney. As a result, it was found that cereals grown by applying the compost-mixed fertilizer of this example and producing enzymes having a detoxifying effect on cancer and the like and an antioxidant action in the body.

【0022】[0022]

【表1】 [Table 1]

【0023】[0023]

【発明の効果】前記のように、本発明による堆肥混合肥
料は、金属等の肥効成分を穀類等の農作物へ確実に吸収
させて、穀類の香り及び味を向上すると共に、防腐及び
防黴作用を有するため、長期間新鮮な状態を保持し品質
の低下を防ぐ。また、堆肥混合肥料を施肥して生育させ
た穀類を体内に摂取すると、癌等の解毒作用及び抗酸化
作用を有する酵素を発生させるため、健康の増進を図る
ことができる。
As described above, the compost-mixed fertilizer according to the present invention ensures that fertilizers such as metals are absorbed into agricultural crops such as cereals, thereby improving the aroma and taste of the cereals, as well as preserving and fungicidal. Since it has an effect, it keeps it fresh for a long period of time and prevents deterioration in quality. In addition, when cereals grown by applying a compost-mixed fertilizer are ingested into the body, an enzyme having a detoxifying action against cancer and the like and an antioxidant action is generated, so that health can be improved.

フロントページの続き (72)発明者 原田 かおり 長野県上伊那郡辰野町大字赤羽664−92 Fターム(参考) 2B022 AB20 EA01 4H061 AA01 BB01 BB21 BB51 CC41 CC47 CC60 DD20 EE07 EE11 EE12 EE13 EE14 EE15 EE16 EE17 EE18 EE19 EE25 EE66 EE70 FF24 GG49 GG50 KK01 KK02 LL22 LL25 Continued on the front page. EE66 EE70 FF24 GG49 GG50 KK01 KK02 LL22 LL25

Claims (10)

【特許請求の範囲】[Claims] 【請求項1】 重量基準で堆肥10〜1000部と、好
気性微生物0.1〜10部と、嫌気性微生物0.05〜1
0部と、キレート化合物含有肥料1〜50部とを含むこ
とを特徴とする堆肥混合肥料。
The present invention relates to a compost comprising 10 to 1000 parts of compost, 0.1 to 10 parts of aerobic microorganisms and 0.05 to 1 part of anaerobic microorganisms on a weight basis.
A mixed compost fertilizer comprising 0 part and 1 to 50 parts of a chelate compound-containing fertilizer.
【請求項2】 堆肥は、イナワラ、ヨシ、マコモ、ムギ
ワラ、山野草、落葉落枝、作物残渣、生ゴミ及び糞尿の
1種又は2種以上である請求項1に記載の堆肥混合肥
料。
2. The compost mixed fertilizer according to claim 1, wherein the compost is at least one of rice straw, reed, makomo, barley straw, wild grass, litter, crop residue, garbage, and manure.
【請求項3】 好気性微生物は、酵母、放線菌、酢酸
菌、グルコン酸菌、糸状菌及び麹菌の1種又は2種以上
である請求項1に記載の堆肥混合肥料。
3. The compost mixed fertilizer according to claim 1, wherein the aerobic microorganism is one or more of yeast, actinomycetes, acetic acid bacteria, gluconic acid bacteria, filamentous fungi, and koji molds.
【請求項4】 嫌気性微生物は、乳酸菌、グラム陽性発
酵性細菌及びグラム陰性発酵性細菌の1種又は2種以上
である請求項1に記載の堆肥混合肥料。
4. The compost mixed fertilizer according to claim 1, wherein the anaerobic microorganism is one or more of lactic acid bacteria, gram-positive fermentative bacteria, and gram-negative fermentative bacteria.
【請求項5】 キレート化合物含有肥料は、重量基準で
金属化合物0.01〜4部と、アミノ酸混合物0.1〜5
部と、カリ肥料2〜8部と、窒素肥料0.1〜1部と、
リン肥料0.01〜2部とを含み、水と混合したときにp
Hが6.0〜7.5となり、アミノ酸混合物は、糖酸及び
アミノ酸の混合物、脂肪酸及びアミノ酸の混合物又は糖
酸、脂肪酸及びアミノ酸の混合物である請求項1に記載
の堆肥混合肥料。
5. The fertilizer containing a chelate compound comprises 0.01 to 4 parts by weight of a metal compound and 0.1 to 5 parts of an amino acid mixture.
Part, 2 to 8 parts of potassium fertilizer, 0.1 to 1 part of nitrogen fertilizer,
Contains 0.01 to 2 parts of phosphorus fertilizer, when mixed with water
The compost mixed fertilizer according to claim 1, wherein H is 6.0 to 7.5, and the amino acid mixture is a mixture of sugar acids and amino acids, a mixture of fatty acids and amino acids, or a mixture of sugar acids, fatty acids and amino acids.
【請求項6】 金属化合物の金属は、カルシウム、マグ
ネシウム、マンガン、亜鉛、銅、モリブデン、鉄、アル
ミニウム、ニッケル、コバルト、チタン、ガリウム、セ
レン、ゲルマニウム、バナジウム、クロム、銀、ストロ
ンチウム、インジウム、錫、金及びジルコニウムの1種
又は2種以上である請求項5に記載の堆肥混合肥料。
6. The metal of the metal compound is calcium, magnesium, manganese, zinc, copper, molybdenum, iron, aluminum, nickel, cobalt, titanium, gallium, selenium, germanium, vanadium, chromium, silver, strontium, indium, tin. The compost mixed fertilizer according to claim 5, which is one or more of gold, zirconium, and the like.
【請求項7】 重量基準で三酸化セレン0.03〜2部
と、アミノ酸0.5〜1.5部と、ペンタル酸0.5〜1.
5部と、酢酸0.5〜1.5部と、カリ肥料3〜5部と、
窒素肥料0.3〜0.8部と、リン肥料0.5〜1部とを
含み、水と混合したときpHが6.3〜7.0となる請求項
5又は6に記載の堆肥混合肥料。
7. 0.03 to 2 parts by weight of selenium trioxide, 0.5 to 1.5 parts of amino acid and 0.5 to 1.5 parts of pentanoic acid on a weight basis.
5 parts, 0.5 to 1.5 parts of acetic acid, 3 to 5 parts of potassium fertilizer,
The compost mixture according to claim 5 or 6, comprising 0.3 to 0.8 part of a nitrogen fertilizer and 0.5 to 1 part of a phosphorus fertilizer and having a pH of 6.3 to 7.0 when mixed with water. fertilizer.
【請求項8】 重量基準で酢酸ゲルマニウム0.05〜
2部と、グリセリン酸1.5〜2.5部と、カリ肥料3〜
5部と、窒素肥料0.3〜0.8部と、リン肥料0.5〜
1部とを含み、水と混合したときpHが6.3〜7.0とな
る請求項5又は6に記載の堆肥混合肥料。
8. The germanium acetate 0.05-0.5 on a weight basis
2 parts, 1.5 to 2.5 parts of glyceric acid, and 3 to potassium fertilizer
5 parts, 0.3 to 0.8 parts of nitrogen fertilizer, 0.5 to phosphorus fertilizer
7. The compost mixed fertilizer according to claim 5 or 6, comprising 1 part and having a pH of 6.3 to 7.0 when mixed with water.
【請求項9】 重量基準で堆肥10〜1000部と、好
気性微生物0.1〜10部と、嫌気性微生物0.05〜1
0部と、キレート化合物含有肥料1〜50部とを含む堆
肥混合肥料を施肥して生育させたことを特徴とする穀
類。
9. A composition comprising 10 to 1000 parts of compost, 0.1 to 10 parts of aerobic microorganisms and 0.05 to 1 part of anaerobic microorganisms on a weight basis.
A cereal, wherein the cereal is grown by applying a compost mixed fertilizer containing 0 part and 1 to 50 parts of a fertilizer containing a chelate compound.
【請求項10】 堆肥混合肥料を施肥して生育させた穀
類は、小麦、米、大豆又はそばである請求項9に記載の
穀類。
10. The cereal according to claim 9, wherein the cereal grown by applying the compost mixed fertilizer is wheat, rice, soybean or buckwheat.
JP2000182476A 2000-06-19 2000-06-19 Compost-mixed fertilyzer and grain Pending JP2002003291A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2000182476A JP2002003291A (en) 2000-06-19 2000-06-19 Compost-mixed fertilyzer and grain

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2000182476A JP2002003291A (en) 2000-06-19 2000-06-19 Compost-mixed fertilyzer and grain

Publications (1)

Publication Number Publication Date
JP2002003291A true JP2002003291A (en) 2002-01-09

Family

ID=18683225

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2000182476A Pending JP2002003291A (en) 2000-06-19 2000-06-19 Compost-mixed fertilyzer and grain

Country Status (1)

Country Link
JP (1) JP2002003291A (en)

Cited By (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008081584A1 (en) * 2006-12-27 2008-07-10 Snow Brand Seed Co., Ltd. Bean having high zinc content
US20100212384A1 (en) * 2007-05-31 2010-08-26 National University Corporation Shizuoka University Method for Producing Functional Compost, Functional Compost and Compost for Proliferation of Filamentous Fungus
JP2011505133A (en) * 2007-12-05 2011-02-24 ユン,ウイ−シク Functional agricultural products and their cultivation methods
WO2012075689A1 (en) * 2010-12-09 2012-06-14 苏州硒谷科技有限公司 Se-enriched paddy seedling, cultivating method for se-enriched paddy seedling and organic-selenium-enriched rice
CN102557769A (en) * 2012-01-04 2012-07-11 浙江滕头园林股份有限公司 Plant organic fertilizer and preparation method thereof
CN102584362A (en) * 2012-02-13 2012-07-18 信息产业电子第十一设计研究院科技工程股份有限公司 Leavening agent for poultry excrement
JP2013100192A (en) * 2011-11-08 2013-05-23 Kino Yukinori Amino acid-containing liquid and method of manufacturing the same, fertilizer and harmful insect repellent
CN103120107A (en) * 2013-02-27 2013-05-29 谢超 Nutrient enrichment selenium-enriched rice and cultivation method thereof
CN103254016A (en) * 2013-06-01 2013-08-21 陈静静 Production process of hydrolysis-resistant stable titanium ions
CN103319250A (en) * 2013-06-27 2013-09-25 苏州仁成生物科技有限公司 Microbial fertilizer specially used for magnolia officinalis powdery mildew
CN103319244A (en) * 2013-06-27 2013-09-25 苏州仁成生物科技有限公司 Multielement compound fertilizer for preventing and treating anthracnose of leontopodium smithianum and preparation method thereof
CN103408364A (en) * 2013-07-31 2013-11-27 张东明 Wheat selenium-rich biological water retention organic seed manure and manufacturing method thereof
CN103508770A (en) * 2012-06-18 2014-01-15 湖南农业大学 Fertilizing formula and fertilizing process for naturally increasing fragrance of grains of Huanghuazhan paddy rice
CN104206142A (en) * 2014-08-19 2014-12-17 安徽省富硒香生物食品集团有限公司 Cultivation method for wheat rich in Se, Zn and Fe
CN104230446A (en) * 2014-10-21 2014-12-24 中山市巴斯德农业科技有限公司 Preparation method for selenium-rich organic fertilizer
CN104396486A (en) * 2014-10-27 2015-03-11 山东省农作物种质资源中心 Winter wheat planting method
CN104788144A (en) * 2015-04-09 2015-07-22 青岛即发集团股份有限公司 Preparation method of active probiotic organic fertilizer
CN104838832A (en) * 2015-03-13 2015-08-19 高煜昕 Planting method of selenium-rich rice
CN104860734A (en) * 2015-04-27 2015-08-26 安徽省富硒香生物食品集团有限公司 Rice selenium-zinc-iron-rich microbial fermentation fertilizer, and preparation method as well as application thereof
CN104871844A (en) * 2015-06-03 2015-09-02 长江大学 Screening method of rice variety resource selenium enrichment performance
CN104926457A (en) * 2015-04-27 2015-09-23 亳州师范高等专科学校 Se, Zn and Fe-enriched microbial fermentation fertilizer for potatoes and preparation method and application thereof
CN105104041A (en) * 2015-08-11 2015-12-02 江苏神居硒谷农业开发有限公司 Production method of selenium-enriched rice
CN105103858A (en) * 2015-08-17 2015-12-02 太仓市雅丰农场专业合作社 Planting method of wheat
CN105191646A (en) * 2015-10-26 2015-12-30 和县绿源蔬菜种植有限责任公司 Bitter gourd planting method
CN105461392A (en) * 2015-12-15 2016-04-06 郴州京鑫农业有限责任公司 Planting method of selenium-rich and high-iron paddy rice
CN107673834A (en) * 2017-10-18 2018-02-09 桂东县隆平高科种粮专业合作社 A kind of rice fertilizer
CN108424213A (en) * 2018-03-19 2018-08-21 长沙秋点兵信息科技有限公司 A kind of Rice enriched-Se and preparation method thereof
CN108752096A (en) * 2018-06-12 2018-11-06 安徽云峰农业发展有限公司 A kind of wheat water-soluble fertilizer containing amino acid and preparation method thereof
JP2022534638A (en) * 2019-03-27 2022-08-03 フェルティナグロ バイオテック,エス.エル. Fertilizer composition containing plant absorbable phosphorus and calcium enhancer and use thereof
WO2024106409A1 (en) * 2022-11-14 2024-05-23 株式会社ハイポネックスジャパン Fertilizer composition

Cited By (36)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008161099A (en) * 2006-12-27 2008-07-17 Yamamoto Tadanobu Shoten:Kk Bean having high content of zinc
WO2008081584A1 (en) * 2006-12-27 2008-07-10 Snow Brand Seed Co., Ltd. Bean having high zinc content
US9313958B2 (en) 2006-12-27 2016-04-19 Snow Brand Seed Co., Ltd. High zinc-containing legumes
US20100212384A1 (en) * 2007-05-31 2010-08-26 National University Corporation Shizuoka University Method for Producing Functional Compost, Functional Compost and Compost for Proliferation of Filamentous Fungus
US8445252B2 (en) * 2007-05-31 2013-05-21 National University Corporation Shizuoka University Method for producing functional compost, functional compost and compost for proliferation of filamentous fungus
JP2011505133A (en) * 2007-12-05 2011-02-24 ユン,ウイ−シク Functional agricultural products and their cultivation methods
WO2012075689A1 (en) * 2010-12-09 2012-06-14 苏州硒谷科技有限公司 Se-enriched paddy seedling, cultivating method for se-enriched paddy seedling and organic-selenium-enriched rice
JP2013100192A (en) * 2011-11-08 2013-05-23 Kino Yukinori Amino acid-containing liquid and method of manufacturing the same, fertilizer and harmful insect repellent
CN102557769A (en) * 2012-01-04 2012-07-11 浙江滕头园林股份有限公司 Plant organic fertilizer and preparation method thereof
CN102584362A (en) * 2012-02-13 2012-07-18 信息产业电子第十一设计研究院科技工程股份有限公司 Leavening agent for poultry excrement
CN103508770A (en) * 2012-06-18 2014-01-15 湖南农业大学 Fertilizing formula and fertilizing process for naturally increasing fragrance of grains of Huanghuazhan paddy rice
CN103120107A (en) * 2013-02-27 2013-05-29 谢超 Nutrient enrichment selenium-enriched rice and cultivation method thereof
CN103254016A (en) * 2013-06-01 2013-08-21 陈静静 Production process of hydrolysis-resistant stable titanium ions
CN103319244A (en) * 2013-06-27 2013-09-25 苏州仁成生物科技有限公司 Multielement compound fertilizer for preventing and treating anthracnose of leontopodium smithianum and preparation method thereof
CN103319250A (en) * 2013-06-27 2013-09-25 苏州仁成生物科技有限公司 Microbial fertilizer specially used for magnolia officinalis powdery mildew
CN103408364A (en) * 2013-07-31 2013-11-27 张东明 Wheat selenium-rich biological water retention organic seed manure and manufacturing method thereof
CN104206142A (en) * 2014-08-19 2014-12-17 安徽省富硒香生物食品集团有限公司 Cultivation method for wheat rich in Se, Zn and Fe
CN104230446A (en) * 2014-10-21 2014-12-24 中山市巴斯德农业科技有限公司 Preparation method for selenium-rich organic fertilizer
CN104230446B (en) * 2014-10-21 2016-08-24 中山市巴斯德农业科技有限公司 A kind of preparation method of selenium-enriched organic fertilizer
CN104396486A (en) * 2014-10-27 2015-03-11 山东省农作物种质资源中心 Winter wheat planting method
CN104838832A (en) * 2015-03-13 2015-08-19 高煜昕 Planting method of selenium-rich rice
CN104788144A (en) * 2015-04-09 2015-07-22 青岛即发集团股份有限公司 Preparation method of active probiotic organic fertilizer
CN104926457A (en) * 2015-04-27 2015-09-23 亳州师范高等专科学校 Se, Zn and Fe-enriched microbial fermentation fertilizer for potatoes and preparation method and application thereof
CN104860734A (en) * 2015-04-27 2015-08-26 安徽省富硒香生物食品集团有限公司 Rice selenium-zinc-iron-rich microbial fermentation fertilizer, and preparation method as well as application thereof
CN104871844A (en) * 2015-06-03 2015-09-02 长江大学 Screening method of rice variety resource selenium enrichment performance
CN105104041A (en) * 2015-08-11 2015-12-02 江苏神居硒谷农业开发有限公司 Production method of selenium-enriched rice
CN105103858A (en) * 2015-08-17 2015-12-02 太仓市雅丰农场专业合作社 Planting method of wheat
CN105191646A (en) * 2015-10-26 2015-12-30 和县绿源蔬菜种植有限责任公司 Bitter gourd planting method
CN105461392A (en) * 2015-12-15 2016-04-06 郴州京鑫农业有限责任公司 Planting method of selenium-rich and high-iron paddy rice
CN107673834A (en) * 2017-10-18 2018-02-09 桂东县隆平高科种粮专业合作社 A kind of rice fertilizer
CN108424213A (en) * 2018-03-19 2018-08-21 长沙秋点兵信息科技有限公司 A kind of Rice enriched-Se and preparation method thereof
CN108752096A (en) * 2018-06-12 2018-11-06 安徽云峰农业发展有限公司 A kind of wheat water-soluble fertilizer containing amino acid and preparation method thereof
JP2022534638A (en) * 2019-03-27 2022-08-03 フェルティナグロ バイオテック,エス.エル. Fertilizer composition containing plant absorbable phosphorus and calcium enhancer and use thereof
EP3950648A4 (en) * 2019-03-27 2022-11-16 Fertinagro Biotech, S.L. Fertilising composition which includes a plant-assimilable phosphorus and calcium potentiator and use thereof
JP7317980B2 (en) 2019-03-27 2023-07-31 フェルティナグロ バイオテック,エス.エル. Fertilizer composition containing plant absorbable phosphorus and calcium enhancer and use thereof
WO2024106409A1 (en) * 2022-11-14 2024-05-23 株式会社ハイポネックスジャパン Fertilizer composition

Similar Documents

Publication Publication Date Title
JP2002003291A (en) Compost-mixed fertilyzer and grain
US20210078915A1 (en) Organically chelated mineral compositions and methods thereof
KR100918106B1 (en) Cultivation method for farm produce contianing selenium
US6391079B1 (en) Fertilizer with a chelate element
EP1084999B1 (en) Fertilizer with a selenium chelate element
WO2013019933A2 (en) Plant fertilizers derived from organic nitrogen and phosphorus sources
JP2001190154A (en) Method for culturing crop and agent for improving quality of crop
Young Cobalt
JP3288659B2 (en) Manufacturing method of sulfur compound containing food deodorant
JP2002173388A (en) Chelate compound-containing fertilizer
JP2001151589A (en) Chelate compound-containing fertilizer and farm product
JP2001089278A (en) Chelate compound-containing fertilizer
JP2001136832A (en) Coral sand-containing culture medium for artificial cultivation of mushroom
JP3012239B2 (en) Fertilizer containing chelate compounds
JP2001314181A (en) Liquors containing chelate compound
RU2759954C2 (en) Synergistic agricultural composition containing diacyl urea or diaryl urea and at least one mixture of nutrients
JP2011088802A (en) Spraying agent for leaf surface of leaf vegetables or the like
JP2001089279A (en) Chelate compound-containing fertilizer and method for manufacturing the same
CN110204377A (en) A kind of Special fertilizer for potato and preparation method thereof
JP2002212084A (en) Antioxidative substance
KR19990084146A (en) Fertilizer containing chelate compounds
CN1872807A (en) Compound fertilizer dedicated to paddy of containing 14 kinds of mineral nutrition elements in plasma, and preparation method
KR950010005B1 (en) Organic compound fertilizer
Lantos Agrochemistry
Gajbhiye et al. Influence of Iron Nutrition on Soil Properties, Uptake and Yield of Soybean Grown on Iron Deficient Inceptisol

Legal Events

Date Code Title Description
A02 Decision of refusal

Free format text: JAPANESE INTERMEDIATE CODE: A02

Effective date: 20040524