CN103254016A - Production process of hydrolysis-resistant stable titanium ions - Google Patents
Production process of hydrolysis-resistant stable titanium ions Download PDFInfo
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- CN103254016A CN103254016A CN2013102268301A CN201310226830A CN103254016A CN 103254016 A CN103254016 A CN 103254016A CN 2013102268301 A CN2013102268301 A CN 2013102268301A CN 201310226830 A CN201310226830 A CN 201310226830A CN 103254016 A CN103254016 A CN 103254016A
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Abstract
The invention discloses a production process of hydrolysis-resistant stable titanium ions, relating to the field of water-soluble fertilizers containing hydrolysis-resistant stable titanium-ion trace elements in fertilizers. The production process comprises the following steps of: (1) performing a dissolution reaction on a first chelating agent, namely, adding the first chelating agent into deionized water to dissolve, and blending; (2) performing a chelation reaction for the first time, namely, adding a titanium raw materials into the chelating agent solution, and performing mass transfer; (3) performing a dissolution reaction on the trace elements, namely, adding the trace elements into deionized water to dissolve, and blending; (4) performing a chelation reaction for the second time; (5) performing a neutralization reaction; (6) adding the first trace element; and (7) adding the second trace element, namely, adding the second trace element into the solution obtained by the reaction in the step (6), performing surface activation to finally obtain the product containing hydrolysis-resistant stable titanium-ion trace elements. According to the production process disclosed by the invention, via continuous production, the production capacity is improved; and moreover, via the optimized production process, no wastewater, waste gas and environmental pollution during the production are guaranteed.
Description
Technical field
What the present invention relates to is anti-hydrolysis-stable ion titanium trace element water-soluble fertilizer field, is specifically related to a kind of production technique of anti-hydrolysis-stable ion titanium
Background technology
Chemical Manufacture typically uses the batch production of reactor, and intensity of workers is big, and human factor is many, can not accurately control correlation parameter, reduce reliability of products, and it is harmful directly to contact industrial chemicals.The production method of producing the at present anti-hydrolysis-stable ion titanium part that comes with some shortcomings: adopt step production to make anti-hydrolysis-stable ion titanium cascade stochastic system can not accurately control reaction conditions, thereby can not guarantee quality product.And be easy to generate waste water, waste gas in the production process of traditional anti-hydrolysis-stable ion titanium, severe contamination environment.
Summary of the invention
At the deficiency that exists on the prior art, the present invention seeks to be to provide a kind of production technique of anti-hydrolysis-stable ion titanium, the employing serialization is produced, anti-hydrolysis-stable ion titanium cascade stochastic system can not accurately be controlled reaction conditions, make the flow of each material follow principal goods materials flow variation with very high follow up speed, improved throughput, and the production technique of optimizing guaranteed that production process do not have waste water, waste gas, do not produced environmental pollution.
To achieve these goals, the present invention realizes by the following technical solutions: the production technique of anti-hydrolysis-stable ion titanium may further comprise the steps: (1) first sequestrant solubilizing reaction: first sequestrant is added deionized water dissolving, and be in harmonious proportion; (2) chelatropic reaction for the first time: will add titanium material in the chelating agent solution, and carry out mass transfer; (3) micro-solubilizing reaction: trace element is added deionized water dissolve, and be in harmonious proportion; (4) chelatropic reaction for the second time: the solution, second chelating agent solution and the trace element solution that obtain of chelatropic reaction carries out the secondary chelatropic reaction for the first time, and carries out mass transfer; (5) neutralization reaction: neutralization reagent is added deionized water dissolve, and carry out neutralization reaction with above-mentioned solution; (6) add first trace element: the solution that above-mentioned neutralization reaction is obtained adds trace element, carries out the stable equilibrium; (7) add second trace element: the solution that reaction in (6) is obtained adds second trace element, carries out surface active, finally obtains anti-hydrolysis-stable ion titanium microelement product.
According to the production technique of above-mentioned anti-hydrolysis-stable ion titanium, wherein, described first sequestrant and second sequestrant are hydroxyl carboxyl class organic compound; Can form relatively stable complex compound with titanium ion, can protect the stability of titanium ion in the solution, can in use guarantee the activity of titanium ion again.
According to the production technique of above-mentioned anti-hydrolysis-stable ion titanium, wherein, described first trace element and second trace element are in calcium, magnesium, zinc, manganese, copper, molybdenum, the boron two kinds or above elementary composition, and these elements are the necessary nutritive element of plant.
According to the production technique of above-mentioned anti-hydrolysis-stable ion titanium, wherein, titanium ion content is not less than 3.5g/kg in the described anti-hydrolysis-stable ion titanium microelement product, dilutes in accordance with regulations according to plant variety during use.
Digitizing automatic production line and Controlling System are adopted in anti-hydrolysis-stable ion titanium production of the present invention; Controlling System is made up of two large servers, hyperchannel PLC and 88 o'clock projection touch-screens, automatic production line is made up of various reaction units, performer, sensor, the full Weighing type feed proportioning system that batching adopts ladder time difference weighting method weight-loss method to combine guarantees the precision of preparing burden.
The setting of manufacturing condition of the present invention and control are by computer the program of working out in advance to be installed to finish, operator only need be by product needed input program code, system just automatic follow procedure carries out material metering, conveying, various raw materials are added proportioning, and temperature of reaction, pressure, acidity, flow are monitored automatically, are regulated.When breaking down or extraneous interim outage, to cut off the water supply, system can realize state protection immediately and start the redemption program, avoids loss.
Various chemistry amounts in the production process of the present invention, physical quantity have all been carried out digitized processing, have increased the transmitting range of status signal, have reduced interference, have improved the speed of response of The whole control system.
The present invention adopts serialization production, anti-hydrolysis-stable ion titanium cascade stochastic system can not accurately be controlled reaction conditions, make the flow of each material follow principal goods materials flow variation with very high follow up speed, improved throughput, and the production technique of optimizing guaranteed that production process do not have waste water, waste gas, do not produce environmental pollution.
Description of drawings
Describe the present invention in detail below in conjunction with the drawings and specific embodiments;
Fig. 1 is technological process of production figure of the present invention.
Embodiment
For technique means, creation characteristic that the present invention is realized, reach purpose and effect is easy to understand, below in conjunction with embodiment, further set forth the present invention.
With reference to Fig. 1, this embodiment by the following technical solutions: the production technique of anti-hydrolysis-stable ion titanium may further comprise the steps (1) first sequestrant solubilizing reaction: first sequestrant is added deionized water dissolving, and be in harmonious proportion; (2) chelatropic reaction for the first time: will add titanium material in the chelating agent solution, and carry out mass transfer; (3) micro-solubilizing reaction: trace element is added deionized water dissolve, and be in harmonious proportion; (4) chelatropic reaction for the second time: the solution, second chelating agent solution and the trace element solution that obtain of chelatropic reaction carries out the secondary chelatropic reaction for the first time, and carries out mass transfer; (5) neutralization reaction: neutralization reagent is added deionized water dissolve, and carry out neutralization reaction with above-mentioned solution; (6) add first trace element: the solution that above-mentioned neutralization reaction is obtained adds trace element, carries out the stable equilibrium; (7) add second trace element: the solution that reaction in (6) is obtained adds second trace element, carries out surface active, finally obtains anti-hydrolysis-stable ion titanium microelement product.
It should be noted that described first sequestrant and second sequestrant are hydroxyl carboxyl class organic compound; Can form relatively stable complex compound with titanium ion, can protect the stability of titanium ion in the solution, can in use guarantee the activity of titanium ion again.
It should be noted that described first trace element and second trace element are two kinds in calcium, magnesium, zinc, manganese, copper, molybdenum, the boron or above elementary composition, these elements are the necessary nutritive element of plant.
In addition, titanium ion content is not less than 3.5g/kg in the described anti-hydrolysis-stable ion titanium microelement product, dilutes in accordance with regulations according to plant variety during use.
Digitizing automatic production line and Controlling System are adopted in the anti-hydrolysis-stable ion titanium production of this embodiment; Controlling System is made up of two large servers, hyperchannel PLC and 88 o'clock projection touch-screens, automatic production line is made up of various reaction units, performer, sensor, the full Weighing type feed proportioning system that batching adopts ladder time difference weighting method weight-loss method to combine guarantees the precision of preparing burden.
Various chemistry amounts in this embodiment production process, physical quantity have all been carried out digitized processing, have increased the transmitting range of status signal, have reduced interference, have improved the speed of response of The whole control system.
The anti-hydrolysis-stable ion titanium of this embodiment is when being diluted to finite concentration, to people, animal, plant toxicological harmless effect.When the anti-hydrolysis-stable ion titanium of this embodiment is applied to leaf dressing, it can make nutritive substance implant in the plant materials from leaf portion, participated in metabolism and the organic building-up process of crop directly, facts have proved that effect is more rapider effectively than soil application.Therefore, Chang Zuowei in time treats the effective measure of crop nutritional deficiency disease, when fertilising, can also spray to mend by the fat border of the confession situation of each breeding time of crop and the growth of cereal crop seedlings and soil by stages and execute, give full play to the willing characteristics of leaf dressing, to guarantee that crop is under suitable fertilizer and water condition, grow normally, reach the purpose of high yield and high quality.
This embodiment adopts serialization production, anti-hydrolysis-stable ion titanium cascade stochastic system can not accurately be controlled reaction conditions, make the flow of each material follow principal goods materials flow variation with very high follow up speed, improved throughput, and the production technique of optimizing guaranteed that production process do not have waste water, waste gas, do not produce environmental pollution.
More than show and described ultimate principle of the present invention and principal character and advantage of the present invention.The technician of the industry should understand; the present invention is not restricted to the described embodiments; that describes in above-described embodiment and the specification sheets just illustrates principle of the present invention; without departing from the spirit and scope of the present invention; the present invention also has various changes and modifications, and these changes and improvements all fall in the claimed scope of the invention.The claimed scope of the present invention is defined by appending claims and equivalent thereof.
Claims (6)
1. the production technique of anti-hydrolysis-stable ion titanium is characterized in that, may further comprise the steps: (1) first sequestrant solubilizing reaction: first sequestrant is added deionized water dissolving, and be in harmonious proportion; (2) chelatropic reaction for the first time: will add titanium material in the chelating agent solution, and carry out mass transfer; (3) micro-solubilizing reaction: trace element is added deionized water dissolve, and be in harmonious proportion; (4) chelatropic reaction for the second time: the solution, second chelating agent solution and the trace element solution that obtain of chelatropic reaction carries out the secondary chelatropic reaction for the first time, and carries out mass transfer; (5) neutralization reaction: neutralization reagent is added deionized water dissolve, and carry out neutralization reaction with above-mentioned solution; (6) add first trace element: the solution that above-mentioned neutralization reaction is obtained adds trace element, carries out the stable equilibrium; (7) add second trace element: the solution that reaction in (6) is obtained adds second trace element, carries out surface active, finally obtains anti-hydrolysis-stable ion titanium microelement product.
2. the production technique of anti-hydrolysis-stable ion titanium according to claim 1 is characterized in that, described first sequestrant and second sequestrant are hydroxyl carboxyl class organic compound; Can form relatively stable complex compound with titanium ion, can protect the stability of titanium ion in the solution, can in use guarantee the activity of titanium ion again.
3. the production technique of anti-hydrolysis-stable ion titanium according to claim 1, it is characterized in that, described first trace element and second trace element are in calcium, magnesium, zinc, manganese, copper, molybdenum, the boron two kinds or above elementary composition, and these elements are the necessary nutritive element of plant.
4. the production technique of anti-hydrolysis-stable ion titanium according to claim 1 is characterized in that, titanium ion content is not less than 3.5g/kg in the described anti-hydrolysis-stable ion titanium microelement product, dilutes in accordance with regulations according to plant variety during use.
5. the production technique of anti-hydrolysis-stable ion titanium according to claim 1 is characterized in that, digitizing automatic production line and Controlling System are adopted in described anti-hydrolysis-stable ion titanium production.
6. the production technique of anti-hydrolysis-stable ion titanium according to claim 1 is characterized in that, the full Weighing type feed proportioning system that described anti-hydrolysis-stable ion titanium production batching adopts ladder time difference weighting method weight-loss method to combine.
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| CN2013102268301A CN103254016A (en) | 2013-06-01 | 2013-06-01 | Production process of hydrolysis-resistant stable titanium ions |
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| CN2013102268301A CN103254016A (en) | 2013-06-01 | 2013-06-01 | Production process of hydrolysis-resistant stable titanium ions |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1257054A (en) * | 1999-12-28 | 2000-06-21 | 张玉梅 | Titanium-containing chelate plant nutrient liquid |
| JP2002003291A (en) * | 2000-06-19 | 2002-01-09 | Mi Tec:Kk | Compost-mixed fertilyzer and grain |
| CN101665385A (en) * | 2009-09-16 | 2010-03-10 | 钛谷（天津）科技有限公司 | Process and device for producing hydrolytic stabilizing iron titanium by continuation method |
| CN102503700A (en) * | 2011-11-17 | 2012-06-20 | 天津九策东方高科技有限公司 | Titanium-containing trace element fertilizer |
| CN202322664U (en) * | 2011-11-14 | 2012-07-11 | 中钛农化(天津)科技有限公司 | Device for producing anti-hydrolysis stable ion titanium in continuous method |
-
2013
- 2013-06-01 CN CN2013102268301A patent/CN103254016A/en not_active Withdrawn
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1257054A (en) * | 1999-12-28 | 2000-06-21 | 张玉梅 | Titanium-containing chelate plant nutrient liquid |
| JP2002003291A (en) * | 2000-06-19 | 2002-01-09 | Mi Tec:Kk | Compost-mixed fertilyzer and grain |
| CN101665385A (en) * | 2009-09-16 | 2010-03-10 | 钛谷（天津）科技有限公司 | Process and device for producing hydrolytic stabilizing iron titanium by continuation method |
| CN202322664U (en) * | 2011-11-14 | 2012-07-11 | 中钛农化(天津)科技有限公司 | Device for producing anti-hydrolysis stable ion titanium in continuous method |
| CN102503700A (en) * | 2011-11-17 | 2012-06-20 | 天津九策东方高科技有限公司 | Titanium-containing trace element fertilizer |
Non-Patent Citations (1)
| Title |
|---|
| 邢小军 等: "离子钛对烟苗生长和烟叶产质量的影响", 《中国烟草科学》, vol. 31, no. 6, 15 December 2010 (2010-12-15), pages 38 - 40 * |
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Application publication date: 20130821 |