CN106008059B - A kind of method that cadmium application drops in acidic soil conditioner on rice - Google Patents

A kind of method that cadmium application drops in acidic soil conditioner on rice Download PDF

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Publication number
CN106008059B
CN106008059B CN201610314640.9A CN201610314640A CN106008059B CN 106008059 B CN106008059 B CN 106008059B CN 201610314640 A CN201610314640 A CN 201610314640A CN 106008059 B CN106008059 B CN 106008059B
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China
Prior art keywords
rice
soil conditioner
cadmium
slag
cyanogen ammonia
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Expired - Fee Related
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CN201610314640.9A
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Chinese (zh)
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CN106008059A (en
Inventor
朱振林
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NINGXIA DARONG CHEMICAL AND METALLURGY CO Ltd
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NINGXIA DARONG CHEMICAL AND METALLURGY CO Ltd
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/80Soil conditioners
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05DINORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
    • C05D3/00Calcareous fertilisers
    • C05D3/02Calcareous fertilisers from limestone, calcium carbonate, calcium hydrate, slaked lime, calcium oxide, waste calcium products
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K17/00Soil-conditioning materials or soil-stabilising materials
    • C09K17/40Soil-conditioning materials or soil-stabilising materials containing mixtures of inorganic and organic compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2109/00MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE pH regulation

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Soil Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Pest Control & Pesticides (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Fertilizers (AREA)
  • Soil Conditioners And Soil-Stabilizing Materials (AREA)

Abstract

A kind of method that cadmium application drops in acidic soil conditioner on rice, belongs to soil conditioner field.Described soil conditioner includes cyanogen ammonia slag and regulus, and cyanogen ammonia slag and regulus proportioning are respectively 40:60 or 50:50.Every mu of rice terrace is 70 80 Kg from soil conditioner, is uniformly spread fertilizer over the fields within 5 days in transplanting rice before seedling, and every mu of late July imposes the Kg of urea 11, treats rice maturity in October, investigation drop cadmium situation.This method can effectively reduce the content of beary metal such as cadmium ion, reach increasing crop yield, improve agricultural product quality, and safely, green.

Description

A kind of method that cadmium application drops in acidic soil conditioner on rice
Technical field
The invention belongs to soil conditioner technical field, cadmium drops in more particularly to a kind of acidic soil conditioner on rice should Method.
Background technology
Rice is one of China and the most important crops of world's most area, as China the first generalized grain crop, There is larger cultivated area in the whole nation, played a significant role in China's grain security.Rice because its plant it is with a long history and Cultivation it is intensive etc., fertilising and miscarriage turn into an important factor for influenceing Rice Production.The wherein weight such as soil cadmium ion Tenor height is one of factor for influenceing paddy soil and rice yield.At present, paddy field application by throwing them is Common compound fertilizer, right It is very undesirable that cadmium effect drops.
The content of the invention
The purpose of the present invention is that the content of beary metal height such as cadmium ion is good for human body in soil and rice for existing rice The weak point of Kang Buli situation, there is provided a kind of application of acidic soil conditioner on rice reduces the technical side of cadmium ion Case.
A kind of method that cadmium application drops in acidic soil conditioner on rice, described acidic soil conditioner include cyanogen ammonia Slag and metal magnesium slag, cyanogen ammonia slag and metal magnesium slag proportioning are respectively 40:60 or 50:50.
The species and scope of described cyanogen ammonia slag, including but not limited to dicyandiamide, single cyanogen ammonia, thiocarbamide, carbendazim and cyanogen ammonia Change all solids thing after calcium hydrolysis solid and liquid separation.
The composition of described cyanogen ammonia slag includes calcium carbonate, organic carbon, silica, alundum (Al2O3) and di-iron trioxide, The ratio of above-mentioned constituent each component is:Calcium carbonate 80-85%, organic carbon 9-10%, silica 2-3.5%, alundum (Al2O3) 1- 1.5%, di-iron trioxide 0.6-0.9%, micro- magnesia, calcium hydroxide, chlorine, sodium are no more than 1%, and the pH value of cyanogen ammonia slag exists Between 9-10.
The composition of described metal magnesium slag includes calcium oxide, silica, magnesia, alundum (Al2O3) and three oxidations two Iron, the ratio of above-mentioned constituent each component are:Calcium oxide 53-56%, silica 29-31%, magnesia 7-8%, di-iron trioxide 5-6.5%, alundum (Al2O3) 1-2.5%, trace element, potassium, chlorine, sodium, boron, molybdenum are no more than 1%, and the pH value of metal magnesium slag is in 11-12 Between.
A kind of method that cadmium application drops in acidic soil conditioner on rice.Soil conditioner is applied in rice terrace for every mu 70-80 Kg。
Application process:Uniformly spread fertilizer over the fields within 5 days in transplanting rice before seedling, every mu of late July imposes the Kg of urea 11, treats 10 Month rice maturity, investigation rice is to the uptake situation of cadmium ion.
Cadmium ion in the later paddy soil of mugineic acid soil conditioner and harvest rice is respectively than without using acidity The total cadmium content rate of descent of paddy soil and rice of soil conditioner is between 55-75%.
The present invention has following remarkable result:
1st, the present invention in soil conditioner contain cyanogen ammonia slag, metal magnesium slag can be used as soil conditioner and in micro member Fertilizer, the middle trace quantity mineral substance element needed for improved soil, supplement plant growth, improves the pH value of acid soil, improves it The utilization rate of its fertilizer.
2nd, product of the present invention and method can effectively reduce cadmium pollution in rice terrace and rice, improve agricultural product quality and Effect of increasing production, and safely, green.
Embodiment
The embodiment of the present invention is with reference to embodiment.
Every mu of rice terrace of the embodiment of the present invention is 75Kg and 80Kg from soil conditioner, common with general paddy field application by throwing them Composite fertilizer contrasts.
Embodiment 1:
Test site is in hengyang, hunan province Liao Tian Town rice terrace, from excellent No. 59 kinds of late rice gold, in transplanting rice before seedling 5 My god, mid-July per it is per mu it is even spread fertilizer over the fields 75Kg soil conditioners, every mu of late July, which imposes, builds the Kg of peak urea 11, treats water in October The rice maturity period, investigation drop cadmium situation, the later paddy soil of rice application acidic soil conditioner and harvest rice in cadmium from Son is respectively than the paddy soil without using acidic soil conditioner and the total cadmium content rate of descent of rice 60%.P in soil H values by 5.02 bring up to 6.27, and every mu of increasing production of rice 16.19%, every mu increases income 112 yuan.
Embodiment 2:
Test site is in hengyang, hunan province Liao Tian Town rice terrace, from excellent No. 59 kinds of late rice gold, in transplanting rice before seedling 5 My god, mid-July per it is per mu it is even spread fertilizer over the fields 85Kg soil conditioners, every mu of late July, which imposes, builds the Kg of peak urea 11, treats water in October The rice maturity period, investigation drop cadmium situation, the later paddy soil of rice application acidic soil conditioner and harvest rice in cadmium from Son respectively than the paddy soil without using acidic soil conditioner and the total cadmium content rate of descent of rice 72%, P in soil H values by 5.02 bring up to 6.29, and every mu of increasing production of rice 18.50%, every mu increases income 132 yuan.
Ningxia Daiei Chemical Co., Ltd. be it is domestic first cyanogen ammonolysis product is registered as agricultural chemicals and plant growth regulation Enterprise, according to experiment, the demonstration in agriculture application field for many years, it was found that cyanogen ammonia is in soil improvement and Effects on Plant Growth, work( Effect and mechanism, thus have studied cyanogen ammonia slag, the composition of regulus, can be used as soil conditioner and secondary and micro-element fertilizers.Should With practice have shown that the present invention can be efficiently using needed for cyanogen ammonia slag and other trade waste improved soils, supplement plant growth Middle trace quantity mineral substance element, improve the utilization rate of other fertilizer, can effectively reduce the content of beary metal such as cadmium ion, reach crops Volume increase, improve agricultural product quality, and safely, green.

Claims (2)

1. a kind of method that cadmium application drops in acidic soil conditioner on rice, it is characterised in that:Described acid soil conditioning Agent includes cyanogen ammonia slag and metal magnesium slag, and cyanogen ammonia slag and metal magnesium slag proportioning are respectively 40:60 or 50:50;Wherein cyanogen ammonia slag into Dividing includes calcium carbonate, organic carbon, silica, alundum (Al2O3) and di-iron trioxide, and the ratio of above-mentioned constituent each component is: Calcium carbonate 80-85%, organic carbon 9-10%, silica 2-3.5%, alundum (Al2O3) 1-1.5%, di-iron trioxide 0.6-0.9%, Micro- magnesia, calcium hydroxide, chlorine, sodium are no more than 1%, and the pH value of cyanogen ammonia slag is between 9-10;Metal magnesium slag into subpackage Calcium oxide, silica, magnesia, alundum (Al2O3) and di-iron trioxide are included, the ratio of above-mentioned constituent each component is:Oxidation Calcium 53-56%, silica 29-31%, magnesia 7-8%, di-iron trioxide 5-6.5%, alundum (Al2O3) 1-2.5%, micro member Element, potassium, chlorine, sodium, boron, molybdenum are no more than 1%, and the pH value of metal magnesium slag is between 11-12.
2. the method that cadmium application drops in acidic soil conditioner as claimed in claim 1 on rice, it is characterised in that:Rice terrace The soil conditioner of every mu of administration is 70-80kg, and application process is:Uniformly spread fertilizer over the fields within 5 days in transplanting rice before seedling, 7 below the moon Impose the Kg of urea 11 every mu of ten days, treat rice maturity in October, uptake situation of the investigation rice to cadmium ion.
CN201610314640.9A 2016-05-13 2016-05-13 A kind of method that cadmium application drops in acidic soil conditioner on rice Expired - Fee Related CN106008059B (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115029141B (en) * 2022-06-21 2023-03-17 陕西省建筑科学研究院有限公司 Heavy metal contaminated soil remediation agent and preparation method and application thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104232099A (en) * 2014-05-30 2014-12-24 昆明绿色中迅生物有限公司 Modifier for acidic soil
CN104628479A (en) * 2015-02-09 2015-05-20 山西大学 Method for preparing controlled release compound fertilizer through magnesium slag phosphorus acid passivation
CN105432664A (en) * 2015-12-04 2016-03-30 宁夏大荣化工冶金有限公司 Method for increasing yield of garlic by means of modified calcium cyanamide

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104232099A (en) * 2014-05-30 2014-12-24 昆明绿色中迅生物有限公司 Modifier for acidic soil
CN104628479A (en) * 2015-02-09 2015-05-20 山西大学 Method for preparing controlled release compound fertilizer through magnesium slag phosphorus acid passivation
CN105432664A (en) * 2015-12-04 2016-03-30 宁夏大荣化工冶金有限公司 Method for increasing yield of garlic by means of modified calcium cyanamide

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
镁渣的资源利用特性与重金属污染风险;李咏玲等;《环境化学》;20151130(第11期);第2079-2081页 *

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