CN103664276B - A kind of Multi-element active silicon fertilizer based on oil shale - Google Patents
A kind of Multi-element active silicon fertilizer based on oil shale Download PDFInfo
- Publication number
- CN103664276B CN103664276B CN201210318823.XA CN201210318823A CN103664276B CN 103664276 B CN103664276 B CN 103664276B CN 201210318823 A CN201210318823 A CN 201210318823A CN 103664276 B CN103664276 B CN 103664276B
- Authority
- CN
- China
- Prior art keywords
- oil shale
- fertilizer
- active silicon
- element active
- oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000003337 fertilizer Substances 0.000 title claims abstract description 70
- 239000004058 oil shale Substances 0.000 title claims abstract description 54
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 title claims abstract description 29
- 229910052710 silicon Inorganic materials 0.000 title claims abstract description 29
- 239000010703 silicon Substances 0.000 title claims abstract description 29
- 239000003077 lignite Substances 0.000 claims description 8
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims description 7
- 229960001763 zinc sulfate Drugs 0.000 claims description 7
- 229910000368 zinc sulfate Inorganic materials 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 6
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 4
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 claims description 4
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 claims description 4
- 239000004202 carbamide Substances 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 235000019837 monoammonium phosphate Nutrition 0.000 claims description 4
- 239000006012 monoammonium phosphate Substances 0.000 claims description 4
- 239000003895 organic fertilizer Substances 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 4
- 235000019353 potassium silicate Nutrition 0.000 claims description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 3
- 240000007594 Oryza sativa Species 0.000 abstract description 14
- 235000007164 Oryza sativa Nutrition 0.000 abstract description 14
- 235000009566 rice Nutrition 0.000 abstract description 14
- 239000003921 oil Substances 0.000 abstract description 13
- 240000008042 Zea mays Species 0.000 abstract description 8
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 abstract description 8
- 235000002017 Zea mays subsp mays Nutrition 0.000 abstract description 8
- 235000005822 corn Nutrition 0.000 abstract description 8
- 239000002689 soil Substances 0.000 abstract description 8
- 235000017060 Arachis glabrata Nutrition 0.000 abstract description 5
- 244000105624 Arachis hypogaea Species 0.000 abstract description 5
- 235000010777 Arachis hypogaea Nutrition 0.000 abstract description 5
- 235000018262 Arachis monticola Nutrition 0.000 abstract description 5
- 241000607479 Yersinia pestis Species 0.000 abstract description 5
- 235000013339 cereals Nutrition 0.000 abstract description 5
- 235000020232 peanut Nutrition 0.000 abstract description 5
- 239000002994 raw material Substances 0.000 abstract description 5
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 238000012360 testing method Methods 0.000 abstract description 4
- 241000238631 Hexapoda Species 0.000 abstract description 3
- 238000011161 development Methods 0.000 abstract description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 241000196324 Embryophyta Species 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 239000011573 trace mineral Substances 0.000 description 6
- 235000013619 trace mineral Nutrition 0.000 description 6
- 238000005469 granulation Methods 0.000 description 5
- 230000003179 granulation Effects 0.000 description 5
- 239000002893 slag Substances 0.000 description 5
- 230000008635 plant growth Effects 0.000 description 4
- 239000000377 silicon dioxide Substances 0.000 description 4
- 235000012239 silicon dioxide Nutrition 0.000 description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- 241000209140 Triticum Species 0.000 description 3
- 235000021307 Triticum Nutrition 0.000 description 3
- 201000010099 disease Diseases 0.000 description 3
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000003306 harvesting Methods 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 239000000618 nitrogen fertilizer Substances 0.000 description 3
- 239000011574 phosphorus Substances 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
- 238000009331 sowing Methods 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 description 2
- 244000020518 Carthamus tinctorius Species 0.000 description 2
- 235000003255 Carthamus tinctorius Nutrition 0.000 description 2
- 244000241257 Cucumis melo Species 0.000 description 2
- 244000068988 Glycine max Species 0.000 description 2
- 235000010469 Glycine max Nutrition 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 239000000378 calcium silicate Substances 0.000 description 2
- 229910052918 calcium silicate Inorganic materials 0.000 description 2
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 2
- 229910052681 coesite Inorganic materials 0.000 description 2
- 229910052906 cristobalite Inorganic materials 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 230000012010 growth Effects 0.000 description 2
- 239000004021 humic acid Substances 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000005416 organic matter Substances 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 229960001866 silicon dioxide Drugs 0.000 description 2
- 238000004088 simulation Methods 0.000 description 2
- 230000004936 stimulating effect Effects 0.000 description 2
- 229910052682 stishovite Inorganic materials 0.000 description 2
- 229910052905 tridymite Inorganic materials 0.000 description 2
- 241000251468 Actinopterygii Species 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 244000036905 Benincasa cerifera Species 0.000 description 1
- 235000011274 Benincasa cerifera Nutrition 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 244000241235 Citrullus lanatus Species 0.000 description 1
- 235000012828 Citrullus lanatus var citroides Nutrition 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 241000195493 Cryptophyta Species 0.000 description 1
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 1
- 235000009847 Cucumis melo var cantalupensis Nutrition 0.000 description 1
- 240000008067 Cucumis sativus Species 0.000 description 1
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 1
- 229910000616 Ferromanganese Inorganic materials 0.000 description 1
- 240000006927 Foeniculum vulgare Species 0.000 description 1
- 235000004204 Foeniculum vulgare Nutrition 0.000 description 1
- 235000016623 Fragaria vesca Nutrition 0.000 description 1
- 240000009088 Fragaria x ananassa Species 0.000 description 1
- 235000011363 Fragaria x ananassa Nutrition 0.000 description 1
- 241000219146 Gossypium Species 0.000 description 1
- 240000005979 Hordeum vulgare Species 0.000 description 1
- 235000007340 Hordeum vulgare Nutrition 0.000 description 1
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 244000046052 Phaseolus vulgaris Species 0.000 description 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
- 240000003768 Solanum lycopersicum Species 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 1
- 238000002679 ablation Methods 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 239000002956 ash Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000010883 coal ash Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 235000005489 dwarf bean Nutrition 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 230000004720 fertilization Effects 0.000 description 1
- 244000037666 field crops Species 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000003317 industrial substance Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- DALUDRGQOYMVLD-UHFFFAOYSA-N iron manganese Chemical compound [Mn].[Fe] DALUDRGQOYMVLD-UHFFFAOYSA-N 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 239000010977 jade Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 235000008935 nutritious Nutrition 0.000 description 1
- 238000009329 organic farming Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 229940072033 potash Drugs 0.000 description 1
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 1
- 235000015320 potassium carbonate Nutrition 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Abstract
A kind of Multi-element active silicon fertilizer based on oil shale provided by the invention, uses the oil shale of low oil content to prepare as main raw material.The oil shale solving a large amount of low oil contents is idle, the problem that precious resources is wasted.The oil shale of low oil content is utilized to manufacture siliceous fertilizer, not only significant for reasonable development oil shale, and, for raising grain yield and quality, realize the meaning that modern agriculture is very important again.Through the test for many years different areas and crop, the insect pest of crop reduces, and quality-improving, output increased, Soil structure is improved.Corn is than control group increase yield 20-35%.Paddy rice is than control group increase yield 20-30%, and peanut is than control group increase yield 20-25%.This has significant contribution to the grain security of China, significant.
Description
Technical field
The invention belongs to siliceous fertilizer technical field, relate to a kind of multielement active based on oil shale
Siliceous fertilizer.
Background technology
Up to the present siliceous fertilizer is not also generally applied and is accepted by peasant.International soil circle row siliceous fertilizer is the fourth-largest element fertilizer after nitrogen, phosphorus, potassium.
According to China's current fertilizer sorting technique (macroelement, moderate-element, trace element
Fertilizer), siliceous fertilizer belongs to secondary nutrients with calcareous fertilisers etc.
At present, the siliceous fertilizer that China uses is slag siliceous fertilizer mainly, comprises slag calcium silicate fertilizer, powder
Coal ash calcium silicate fertilizers etc., normally utilize industrial residue, as blast-furnace slag, electric furnace iron blast furnace slag, ferro-manganese alloy furnace slag etc. are produced.These raw materials are all by high temperature sintering, except containing silicon-dioxide, and other trace element and organic matter all ablations.Various trace element needed for plant-growth cannot be provided.These raw materials are also containing a lot of heavy metal and other pollutents, and limited amount.
Oil shale is the Mineral resources that a kind of standing stock are very abundant.The female page of oil of floorboard with high oil content
Rock not only can extract fuel oils, but also can refine out synthetic gas and industrial chemicals, attached
Product also can be used for the material of construction such as brickmaking, cement.China's oil shale occupies the 4th, the world.
(below 5-6%'s) oil shale of low oil content is not also utilized because oleaginousness is low.
(below 5-6%'s) oil shale of low oil content is not also used to manufacture the report of siliceous fertilizer so far.(below 5-6%'s) oil shale of a large amount of low oil contents is idle, and precious resources is wasted.How this part resource is fully utilized, (below 5-6%'s) oil shale of low oil content is utilized to manufacture siliceous fertilizer, not only significant for reasonable development oil shale, and, for raising grain yield and quality, improvement soil, save Fertilizer resources, reduce environmental pollution, realize agricultural modernization, the meaning that Organic farming is very important again.
Summary of the invention
In order to solve siliceous fertilizer technology of preparing Problems existing, in order to solve (the 5-6% of low oil content
Following) oil shale is low due to oleaginousness, also well do not utilized, a large amount of preciousness money
The problem that source is wasted, the invention provides a kind of Multi-element active silicon fertilizer based on oil shale, uses oil shale to prepare siliceous fertilizer as main raw material.
Oil shale is marine algae, fish, and other animals and plants remains were through 1 years
Rot, deposition, mineralising, formation.It is based on element silicon, containing various moderate-element needed for plant-growth, and trace element.The China oil shale reserves whole world the 4th, and have a large amount of storage within the border in Jilin Province.
According to surveying and determination: silicon-dioxide (sio in oil shale
2) content is 46.25%, ferric oxide
(fe
2o
3) content 7.25%, aluminium sesquioxide (AL
20
3) content: 17.82%, calcium oxide (CaO) content: 4.00%, magnesium oxide (MgO) content: 0.6%.Also multiple macroelement and trace element needed for plant-growth is contained, rare elements in oil shale.These elements to plant disease and pest resistance and human health highly beneficial.Oil shale pollutes because be not subject to any industry, can not to environment in being therefore manured into soil.Containing directly being absorbed growth required silicon, various trace element and organic matter by food crop in the middle of oil shale, nutritious with the food crop of its plantation, strengthen diseases and insect pests resistance, mouthfeel is good, and melon and fruit is fragrant and sweet, storage endurance, and output is high.
All need silicon in plant growing process, silicon is the important component part in plant materials.
Siliceous fertilizer is mainly used in the happiness silicon crops such as paddy rice, wheat, corn, especially the most responsive to silicon with paddy rice.
In paddy rice, wheat, barley, soybean, French beans, fennel six kinds of crop ash contents, silicon oxidation
Thing accounts for 14.2--61.4%.
The Ministry of Agriculture of the People's Republic of China, MOA, on April 16th, 2004, issues siliceous fertilizer country and presses
Standard NY/T797-2004.The standard specifies the technical requirements of siliceous fertilizer, test method,
Inspection rule and mark, packaging, transport and storage.The technical requirements that the standard specifies siliceous fertilizer is as follows: the content of silicon is in SiO2, SiO2 >=20%, and granularity is content >=80% of 25 below μ.
A. a kind of Multi-element active silicon fertilizer based on oil shale provided by the invention, composition and the weight percent of its formula are as follows:
Oil shale: 69-99%,
Brown coal: 0-30%,
Zinc sulfate: 0.2-0.5%,
Water glass: 0.3-0.5%.
Humic acid energy stimulating plant contained by brown coal is produced, and is good fertilizer.Organic mass-energy contained by it increases soil water-retaining, fertilizer-preserving ability.Slow release effect is had to nitrogenous fertilizer.Zinc sulfate provides the zinc element of plant-growth.Water glass increases the crumb structure of granulation process, shortens drying time, and after incorporation of fertilizerin the soil, water suction is dissolved rapidly.
Also Bulk Blending Fertilizer (being called for short BB fertile) can be done by a kind of Multi-element active silicon fertilizer based on oil shale provided by the invention.
B. a kind of Multi-element active silicon fertilizer based on oil shale provided by the invention, is characterized in that, it is Chemical Mixed Fertilizer, and composition and the weight percent of its formula are as follows:
Oil shale: 10--40%,
Brown coal: 20--30%,
Zinc sulfate: 0-0.5%,
Urea: 15---20%,
Monoammonium phosphate; 15---25%,
Repone K; 10---15%.
Described Chemical Mixed Fertilizer provided by the invention, meets country by standard GB15063-2009, is applicable to corn, the land for growing field crops farm crop such as paddy rice.Humic acid energy stimulating plant contained by brown coal is produced, and is good fertilizer.Contained organic mass-energy increases soil water-retaining, fertilizer-preserving ability.Slow release effect is had to nitrogenous fertilizer.
C. a kind of Multi-element active silicon fertilizer based on oil shale provided by the invention, is characterized in that, it is compound organic and inorganic fertilizer, and composition and the weight percent of its formula are as follows:
Oil shale: 10--40%,
Brown coal: 25-40%,
Zinc sulfate: 0--1%,
Urea: 10---15%,
Monoammonium phosphate: 15---20%,
Repone K: 10---14%.
Described compound organic and inorganic fertilizer provided by the invention, meets country by standard GB18877-2009, is applicable to various farm crop.Because fertilizer amount is few, the little crops quality of environmental pollution is good, developing direction after being.
The method for making of a kind of Multi-element active silicon fertilizer based on oil shale provided by the invention, step and condition as follows:
(1) oil shale is pulverized: in high-pressure overhang roll abrasive dust machine, oil shale is ground into powder, crosses 120 mesh sieves;
(2) granulation: by proportioning, by the traditional granulating disc mixing granulation of a kind of all the components of the Multi-element active silicon fertilizer based on oil shale;
(3) sieve: sieve, obtain 2-3.5 mm granules;
(4) dry: be placed in dryer and dry;
(5) be cooled to room temperature, obtain a kind of Multi-element active silicon fertilizer based on oil shale.
The method for making of described Chemical Mixed Fertilizer provided by the invention, compound organic and inorganic fertilizer, step (2) granulation wherein: respectively according to described proportioning, uses conventional rollers tablets press mixing granulation; Remaining is all with step and the condition of the method for making of a kind of Multi-element active silicon fertilizer based on oil shale provided by the invention.
A kind of Multi-element active silicon fertilizer based on oil shale provided by the invention, by national standard NY/T797-2004, must with other fertile compounding application.Siliceous fertilizer can not replace nitrogen, phosphorus, potash fertilizer.Nitrogen, phosphorus, potassium, siliceous fertilizer scientific matching are used, and could obtain good effect.
A kind of Multi-element active silicon fertilizer based on oil shale provided by the invention makees base fertilizer.Be applicable to the gramineous crops such as paddy rice, wheat, corn (wherein, paddy rice belongs to typical happiness silicon crop); Soybean, peanut; The crops such as the Curcurbitaceaes such as cucumber, wax gourd, watermelon, muskmelon and tomato, strawberry, cotton.
Use consumption: do that base fertilizer is disposable to be applied, paddy rice per hectare 400-500 kilograms
.when paddy field application by throwing them, amount of application of nitrogen fertilizer be reduced, to avoid excessive growth.Other crop per hectares 200-400 kilograms.
beneficial effect:a kind of Multi-element active silicon fertilizer based on oil shale provided by the invention,
(below 5-6%'s) oil shale of low oil content is used to prepare as main raw material.The oil shale solving a large amount of low oil contents is idle, the problem that precious resources is wasted.The oil shale of low oil content is utilized to manufacture siliceous fertilizer, not only significant for reasonable development oil shale, and, for raising grain yield and quality, realize the meaning that modern agriculture is very important again.Through the test for many years different areas and crop, the insect pest of crop reduces, and quality-improving, output increased, Soil structure is improved.Corn is than control group increase yield 20--35%.Paddy rice is than control group increase yield 20---30%, and peanut is than control group increase yield 20---25%.This has significant contribution to the grain security of China, significant.
Embodiment
embodiment 1: within 2009, dry year carries out corn fertilizing simulation experiments in Hua Jiqiao village, Hua Jia town, Nongan County.Same plot, does simultaneous test under identical conditions.
Experimental plot and contrast each 5 hectares of field.Corn variety is: first jade 335.Fertilizer adopts row replacement mode, adopts usual manner sowing.Contrast field adopts usual manner fertilising.
Experimental plot a kind of Multi-element active silicon fertilizer based on oil shale provided by the invention makes base fertilizer.Amount of application per hectare 400 kilograms, the sowing time is April 20, and other kind fertilizer are identical with contrast field, adopts usual manner fertilising.
Corn bar alive in experimental plot is sturdy, and bar of living is ripe, full seed.Harvest time is October 10.The average output per hectare in experimental plot 13500 kilograms.The average output per hectare 10000 kilograms in contrast field.Experimental plot volume increase 35%
.
embodiment 2:within 2009, on farm, Heilungkiang 859, carry out fertilization of rice volume increase examination
Test.Experimental plot and contrast each 5 hectares of field.Employing usual manner is broadcast.Transplanting time is May 20, early maturing variety paddy rice.Contrast field adopts usual manner fertilising.
Experimental plot a kind of Multi-element active silicon fertilizer based on oil shale provided by the invention makes base fertilizer.Experimental plot per hectare applies fertilizer 500 kilograms.Other kind fertilizer are identical with contrast field, adopt usual manner fertilising.
Experimental plot, rice seedlings are dark green, full seed, do not have various disease and pest to occur.Harvest time is October 5.The average hectare output 9000 kilograms in experimental plot.The average hectare output 7000 kilograms in contrast field.Experimental plot volume increase 30%
.
embodiment 3:2010, in Mo-tse village of Zan Zi township, Qianan County, area, Songyuan City of Jilin Province,
Carry out peanut fertilising simulation experiments.
Experimental plot and contrast each 1 hectare of field.Peanut varieties is safflower life and white sand popped rice raw half and half.Sowing time is May 10.Contrast field adopts usual manner fertilising.
Experimental plot a kind of Multi-element active silicon fertilizer based on oil shale provided by the invention makes base fertilizer.Rate of fertilizer application per hectare 300 kilograms.Other kind fertilizer are identical with contrast field, adopt usual manner fertilising.
Harvest time: October 10, the raw per hectare mean yield 2500 kilograms of safflower.Contrast field per hectare mean yield 2000 kilograms.Experimental plot volume increase 25%
The raw per hectare mean yield 4500 kilograms of white sand popped rice, contrast field per hectare mean yield 3600 kilograms.Experimental plot volume increase 25%.
Claims (4)
1. based on a Multi-element active silicon fertilizer for oil shale, it is characterized in that, composition and the weight percent of its formula are as follows:
Oil shale: 69-99%,
Brown coal: 0-30%,
Zinc sulfate: 0.2-0.5%,
Water glass: 0.3-0.5%.
2. based on a Chemical Mixed Fertilizer of planting based on oil shale, it is characterized in that, composition and the weight percent of its formula are as follows:
Oil shale: 10--40%,
Brown coal: 20--30%,
Zinc sulfate: 0-0.5%,
Urea: 15---20%,
Monoammonium phosphate; 15---25%,
Repone K; 10---15%.
3., based on a compound organic and inorganic fertilizer for oil shale, composition and the weight percent of its formula are as follows:
Oil shale: 10--40%,
Brown coal: 25-40%,
Zinc sulfate: 0--1%,
Urea: 10---15%,
Monoammonium phosphate: 15---20%,
Repone K: 10---14%.
4. a kind of Multi-element active silicon fertilizer based on oil shale according to claim 1, is characterized in that, do Bulk Blending Fertilizer with it.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210318823.XA CN103664276B (en) | 2012-09-03 | 2012-09-03 | A kind of Multi-element active silicon fertilizer based on oil shale |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210318823.XA CN103664276B (en) | 2012-09-03 | 2012-09-03 | A kind of Multi-element active silicon fertilizer based on oil shale |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103664276A CN103664276A (en) | 2014-03-26 |
| CN103664276B true CN103664276B (en) | 2015-11-11 |
Family
ID=50303175
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210318823.XA Active CN103664276B (en) | 2012-09-03 | 2012-09-03 | A kind of Multi-element active silicon fertilizer based on oil shale |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103664276B (en) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104261948A (en) * | 2014-10-11 | 2015-01-07 | 延边遵杰资源开发利用有限公司 | Organic and inorganic compound fertilizer prepared from oil-shale waste residues and preparation method thereof |
| CN106495955A (en) * | 2016-11-01 | 2017-03-15 | 登封市老拴保肥料有限公司 | A kind of sustained-release synergistic strawberry special bulk blended fertilizer that applies in calacareous soil |
| CN107548648A (en) * | 2017-08-12 | 2018-01-09 | 佛山推启农业研究院（普通合伙） | A kind of implantation methods of Silicon-rich wax gourd |
| CN108485674A (en) * | 2018-04-16 | 2018-09-04 | 隋皓为 | A kind of oil shale making soil conditioner |
| CN108440109A (en) * | 2018-04-16 | 2018-08-24 | 隋皓为 | A kind of production bio-bacterial manure of oil shale and do bio-bacterial manure additive |
| CN108440110A (en) * | 2018-04-16 | 2018-08-24 | 隋皓为 | A kind of oil shale makes organic fertilizer and does organic fertilizer additive |
| CN108456040A (en) * | 2018-05-28 | 2018-08-28 | 隋皓为 | A kind of oil shale making siliceous fertilizer technique |
| CN108794255A (en) * | 2018-06-13 | 2018-11-13 | 隋皓为 | A kind of oil shale makes compound organic and inorganic fertilizer and does compound organic and inorganic fertilizer additive |
| CN108794156A (en) * | 2018-06-13 | 2018-11-13 | 隋皓为 | A kind of oil shale production Blending Fertilizer and do blending fertilizer additive |
| CN108794254A (en) * | 2018-06-13 | 2018-11-13 | 隋皓为 | A kind of oil shale production composite fertilizer and do additive for compound fertilizer |
| CN112919977B (en) * | 2021-04-12 | 2023-04-28 | 兰州交通大学 | Modified oil shale semicoke coated slow and controlled release fertilizer and preparation method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101054568A (en) * | 2007-04-17 | 2007-10-17 | 周文彩 | Microorganism bacterium composition, special biological organic fertilizer for tobacco containing the same, preparation and use method for the microorganism bacterium composition |
| CN101638345A (en) * | 2009-09-04 | 2010-02-03 | 抚顺矿业集团有限责任公司 | High-efficiency nitrogen-phosphorus-potassium fertilizer containing silicon and calcium and preparation method thereof |
| CN101638346A (en) * | 2009-09-04 | 2010-02-03 | 抚顺矿业集团有限责任公司 | Fertilizer special for soybeans and preparation method thereof |
| CN101905990A (en) * | 2009-06-03 | 2010-12-08 | 抚顺矿业集团有限责任公司 | Nitrogenous and potassic high-efficiency fertilizer containing calcium silicon and preparation method thereof |
| CN101905989A (en) * | 2009-06-03 | 2010-12-08 | 抚顺矿业集团有限责任公司 | Silico-calcium-containing high-efficiency potassic fertilizer and preparation method thereof |
| CN101993313A (en) * | 2009-08-27 | 2011-03-30 | 陈书仁 | Fertilizer for reforming saline soil |
-
2012
- 2012-09-03 CN CN201210318823.XA patent/CN103664276B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101054568A (en) * | 2007-04-17 | 2007-10-17 | 周文彩 | Microorganism bacterium composition, special biological organic fertilizer for tobacco containing the same, preparation and use method for the microorganism bacterium composition |
| CN101905990A (en) * | 2009-06-03 | 2010-12-08 | 抚顺矿业集团有限责任公司 | Nitrogenous and potassic high-efficiency fertilizer containing calcium silicon and preparation method thereof |
| CN101905989A (en) * | 2009-06-03 | 2010-12-08 | 抚顺矿业集团有限责任公司 | Silico-calcium-containing high-efficiency potassic fertilizer and preparation method thereof |
| CN101993313A (en) * | 2009-08-27 | 2011-03-30 | 陈书仁 | Fertilizer for reforming saline soil |
| CN101638345A (en) * | 2009-09-04 | 2010-02-03 | 抚顺矿业集团有限责任公司 | High-efficiency nitrogen-phosphorus-potassium fertilizer containing silicon and calcium and preparation method thereof |
| CN101638346A (en) * | 2009-09-04 | 2010-02-03 | 抚顺矿业集团有限责任公司 | Fertilizer special for soybeans and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103664276A (en) | 2014-03-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103664276B (en) | A kind of Multi-element active silicon fertilizer based on oil shale | |
| CN101665699B (en) | Nutrient conditioner for acidified soil in orchards, and preparation method | |
| CN102153419B (en) | Special fertilizer for rice | |
| CN101693638B (en) | Preparation method and application method of tomato special fertilizer | |
| CN100462341C (en) | Organic nitrogenous fertilizer | |
| CN103467182A (en) | Granular bio-organic fertilizer and preparation method thereof | |
| CN102503676A (en) | Base fertilizer type eucalyptus ecological fertilizer | |
| CN102503632A (en) | Selenium-rich organic/inorganic fertilizer for producing selenium-rick rice as well as application method thereof | |
| CN105906458A (en) | Soil improvement slow-release compound fertilizer and preparation method thereof | |
| CN106977278A (en) | Potassium polyphosphate sugarcane slow-release fertilizer and its production method | |
| CN103694021A (en) | Gangue-based siliceous fertilizer | |
| CN104496635A (en) | Sweet potato special-purpose fertilizer | |
| CN108929167A (en) | One planting fruit-trees disease and insect resistance increases production organic fertilizer | |
| CN103524199B (en) | Compound fertilizer for green food production | |
| CN106278765A (en) | A kind of organic soil conditioner | |
| CN114716279A (en) | Water-soluble compound fertilizer special for cotton and preparation method thereof | |
| CN103086807B (en) | Bulk blend fertilizer for controlling soil-borne disease and preparation method of bulk blend fertilizer | |
| CN106748561A (en) | A kind of wheat tillering fertilizer and its preparation method and application | |
| CN108782140A (en) | A kind of plantation cucumber organic substrate and preparation method thereof | |
| CN104030858B (en) | A kind of disease prevention desinsection natural mineral fertilizer and preparation method and using method | |
| CN106938954A (en) | A kind of wheat efficient formula fertilizer suitable for Soil Development in Huaibei Plain low yield Shajiang black soil | |
| CN111732480A (en) | Special package fertilizer containing mineral and biological organic components for organic crops and preparation method thereof | |
| CN103804059B (en) | Special fertilizer for culturing Chinese clover | |
| CN106431748A (en) | Activated conditioning agent for repairing soil of salt march and preparation method thereof | |
| CN102060625A (en) | Fertilizer synergist for special paddy and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| CB03 | Change of inventor or designer information |
Inventor after: Jiao Kebei Inventor before: Jiao Shen |
|
| COR | Change of bibliographic data | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20160419 Address after: 130200 Jilin province city Changchun Nong'an county Wang Zheng two world network 7 Tung Road four South Patentee after: Jiao Kebei Address before: The people of 130021 cities in Jilin province Changchun Street No. 7520 Patentee before: Jiao Shen |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| CB03 | Change of inventor or designer information |
Inventor after: Sui Haowei Inventor before: Jiao Kebei |
|
| COR | Change of bibliographic data | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20161017 Address after: 110043 Beihai street, Shenyang, Liaoning, No. 93 Patentee after: Sui Haowei Address before: 130200 Jilin province city Changchun Nong'an county Wang Zheng two world network 7 Tung Road four South Patentee before: Jiao Kebei |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| CB03 | Change of inventor or designer information |
Inventor after: Jiao Kebei Inventor before: Sui Haowei |
|
| COR | Change of bibliographic data | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20161207 Address after: 130200 Jilin province city Changchun Nong'an county Wang Zheng two world network 7 Tung Road four South Patentee after: Jiao Kebei Address before: 110043 Beihai street, Shenyang, Liaoning, No. 93 Patentee before: Sui Haowei |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20170321 Address after: 110043 Beihai street, Shenyang, Liaoning, No. 93 Patentee after: Sui Haowei Address before: 130200 Jilin province city Changchun Nong'an county Wang Zheng two world network 7 Tung Road four South Patentee before: Jiao Kebei |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20170623 Address after: 130200 Jilin province city Changchun Nong'an county Wang Zheng two world network 7 Tung Road four South Patentee after: Jiao Kebei Address before: 110043 Beihai street, Shenyang, Liaoning, No. 93 Patentee before: Sui Haowei |