CN103664276A - Multi-element active silicon fertilizer based on oil shale - Google Patents

Multi-element active silicon fertilizer based on oil shale Download PDF

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CN103664276A
CN103664276A CN201210318823.XA CN201210318823A CN103664276A CN 103664276 A CN103664276 A CN 103664276A CN 201210318823 A CN201210318823 A CN 201210318823A CN 103664276 A CN103664276 A CN 103664276A
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oil shale
fertilizer
yield
silicon fertilizer
element active
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CN103664276B (en
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焦伸
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Jiao Kebei
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Abstract

The invention provides multi-element active silicon fertilizer based on oil shale, which is prepared by using the oil shale with low oil content as a main raw material. The problems that a large amount of oil shale with low oil content is idle and precious resources are wasted are solved. The way of utilizing the oil shale with low oil content to manufacture the silicon fertilizer has important significance for reasonable development of the oil shale and further has very important significance for improving grain yield and quality and realizing modern agriculture. After years of tests of different crops in different regions, the multi-element active silicon fertilizer is proved to be capable of reducing insect pests of the crops, upgrading the quality, improving the yield and improving the soil structure. The yield of corn is increased by 20-35% in comparison with that of a control group. The yield of rice is increased by 20-30% in comparison with that of the control group, and the yield of peanut is increased by 20-25% in comparison with that of the control group. The multi-element active silicon fertilizer makes important contribution to safety of grains in China and has significance.

Description

A kind of multielement active siliceous fertilizer based on oil shale
Technical field
The invention belongs to siliceous fertilizer technical field, relate to a kind of multielement active based on oil shale
Siliceous fertilizer.
Background technology
Up to the present siliceous fertilizer is not also generally applied and is accepted by peasant.International soil circle row siliceous fertilizer is the fourth-largest first fertilizer after nitrogen, phosphorus, potassium.
According to China's current fertilizer sorting technique (macroelement, moderate-element, trace element
Fertilizer), siliceous fertilizer is to belong to secondary nutrients with calcareous fertilisers etc.
At present, the siliceous fertilizer that China uses is mainly slag siliceous fertilizer, comprises slag calcium silicate fertilizer, powder
Coal ash calcium silicate fertilizers etc., normally utilize industrial residue, as blast-furnace slag, electric furnace iron blast furnace slag, manganeseirom slag etc. are produced.These raw materials are all by high temperature sintering, except containing silicon-dioxide, and other trace element and all ablations of organic matter.Cannot provide plant-growth required various trace elements.These raw materials also contain a lot of heavy metals and other pollutents, and limited amount.
Oil shale is the Mineral resources that a kind of standing stock are very abundant.The female page of oil of floorboard with high oil content
Rock not only can extract fuel oils, but also can refine out synthetic gas and industrial chemicals, attached
Product also can be used for the material of construction such as brickmaking, cement.China's oil shale occupies the 4th, the world.
(below 5-6%) oil shale of low oil content is not also utilized because oleaginousness is low.
Also do not use so far (below 5-6%) oil shale of low oil content to manufacture the report of siliceous fertilizer.(below 5-6%) oil shale of a large amount of low oil contents is idle, and precious resources is wasted.How this part resource is fully utilized, utilize (below 5-6%) oil shale of low oil content to manufacture siliceous fertilizer, not only significant for reasonable development oil shale, and, for improving grain yield and quality, improvement soil, save chemical fertilizer resource, reduce environmental pollution, realize agricultural modernization, Organic farming is very important meaning again.
Summary of the invention
The problem existing in order to solve siliceous fertilizer technology of preparing, in order to solve (the 5-6% of low oil content
Following) oil shale is because oleaginousness is low, also well do not utilized a large amount of preciousness money
The problem that source is wasted, the invention provides a kind of multielement active siliceous fertilizer based on oil shale, with oil shale, as main raw material, prepares siliceous fertilizer.
Oil shale is marine algae, fish, and other animals and plants remains were through 1 years
Rot, deposition, mineralising, formation.It take element silicon as main body, contains the required various moderate-elements of plant-growth, trace element.The China's oil shale reserves whole world the 4th, Bing Jilin Province has a large amount of storages within the border.
According to surveying and determination: silicon-dioxide (sio in oil shale 2) content is 46.25%, ferric oxide
(fe 2o 3) content 7.25%, aluminium sesquioxide (AL 20 3) content: 17.82%, calcium oxide (CaO) content: 4.00%, magnesium oxide (MgO) content: 0.6%.In oil shale, also contain the required multiple macroelement of plant-growth and trace element, rare elements.These elements are highly beneficial to plant disease and pest resistance and human health.Oil shale, can be to environment in being therefore manured into soil because not being subject to any industry pollutes.In the middle of oil shale, contain and can directly by food crop, be absorbed growth required silicon, various trace element and organic matter, nutritious with the food crop of its plantation, strengthen diseases and insect pests resistance, mouthfeel is good, and melon and fruit is fragrant and sweet, storage endurance, output is high.
In plant growing process, all need silicon, silicon is the important component part in plant materials.
Siliceous fertilizer is mainly used in the happiness silicon crops such as paddy rice, wheat, corn, especially the most responsive to silicon with paddy rice.
In paddy rice, wheat, barley, soybean, French beans, six kinds of crop ash contents of fennel, silicon oxidation
Thing accounts for 14.2--61.4%.
The Ministry of Agriculture of the People's Republic of China, MOA was on April 16th, 2004, and issue siliceous fertilizer country presses
Standard NY/T 797-2004.This standard stipulated siliceous fertilizer technical requirements, test method,
Inspection rule and sign, packing, transportation and storage.This standard has stipulated that the technical requirements of siliceous fertilizer is as follows: the content of silicon is in SiO2, SiO2 >=20%, and granularity is content >=80% below 25 μ.
A. a kind of multielement active siliceous fertilizer based on oil shale provided by the invention, composition and the weight percent of its formula are as follows:
Oil shale: 69-99%,
Brown coal: 0-30%,
Zinc sulfate: 0.2-0.5%,
Water glass: 0.3-0.5%.
The contained humic acid energy of brown coal stimulating plant is produced, and is good fertilizer.Its contained organic mass-energy increases soil water-retaining, fertilizer-preserving ability.Nitrogenous fertilizer is had to slow release effect.Zinc sulfate provides the zinc element of plant-growth.Water glass increases the crumb structure of granulation process, shortens drying time, and after incorporation of fertilizerin the soil, water suction is dissolved rapidly.
With a kind of multielement active siliceous fertilizer based on oil shale provided by the invention, also can do Bulk Blending Fertilizer (being called for short BB fertile).
B. a kind of multielement active siliceous fertilizer based on oil shale provided by the invention, is characterized in that, it is Chemical Mixed Fertilizer, and composition and the weight percent of its formula are as follows:
Oil shale: 10--40%,
Brown coal: 20--30%,
Zinc sulfate: 0-0.5%,
Urea: 15---20%,
Monoammonium phosphate; 15---25%,
Repone K; 10---15%.
Described Chemical Mixed Fertilizer provided by the invention, meets country by standard GB 15063-2009, is applicable to corn, the land for growing field crops farm crop such as paddy rice.The contained humic acid energy of brown coal stimulating plant is produced, and is good fertilizer.Contained organic mass-energy increases soil water-retaining, fertilizer-preserving ability.Nitrogenous fertilizer is had to slow release effect.
C. a kind of multielement active siliceous fertilizer based on oil shale provided by the invention, is characterized in that, it is compound organic and inorganic fertilizer, and composition and the weight percent of its formula are as follows:
Oil shale: 10--40%,
Brown coal: 25-40%,
Zinc sulfate: 0--1%,
Urea: 10---15%,
Monoammonium phosphate: 15---20%,
Repone K: 10---14%.
Described compound organic and inorganic fertilizer provided by the invention, meets country by standard GB 18877-2009, is applicable to various farm crop.Because fertilizer amount is few, the little crops quality of environmental pollution is good, be after developing direction.
The method for making of a kind of multielement active siliceous fertilizer based on oil shale provided by the invention, step and condition are as follows:
(1) oil shale is pulverized: in high-pressure overhang roll abrasive dust machine, oil shale is ground into powder, crosses 120 mesh sieves;
(2) granulation: by proportioning, a kind of all the components of the multielement active siliceous fertilizer based on oil shale is mixed to granulation with traditional granulating disc;
(3) screening: sieve, obtain 2-3.5 mm granules;
(4) dry: be placed in dryer and dry;
(5) be cooled to room temperature, obtain a kind of multielement active siliceous fertilizer based on oil shale.
Described Chemical Mixed Fertilizer provided by the invention, the method for making of compound organic and inorganic fertilizer, step wherein (2) granulation: respectively according to described proportioning, use conventional rollers tablets press to mix granulation; Remaining is all with step and the condition of the method for making of a kind of multielement active siliceous fertilizer based on oil shale provided by the invention.
A kind of multielement active siliceous fertilizer based on oil shale provided by the invention, by national standard NY/T 797-2004, must with other fertile compounding application.Siliceous fertilizer can not replace nitrogen, phosphorus, potash fertilizer.Nitrogen, phosphorus, potassium, siliceous fertilizer scientific matching are used, and could obtain good effect.
A kind of multielement active siliceous fertilizer based on oil shale provided by the invention is made base fertilizer.Be applicable to the gramineous crops (wherein, paddy rice belongs to typical happiness silicon crop) such as paddy rice, wheat, corn; Soybean, peanut; The crops such as the Curcurbitaceaes such as cucumber, wax gourd, watermelon, muskmelon and tomato, strawberry, cotton.
Use consumption: do that base fertilizer is disposable to be applied, 400-500 kilograms of paddy rice per hectares .when paddy field application by throwing them, reduce amount of application of nitrogen fertilizer, to avoid excessive growth.200-400 kilograms of other crop per hectares.
beneficial effect:a kind of multielement active siliceous fertilizer based on oil shale provided by the invention,
Use (below 5-6%) oil shale of low oil content to prepare as main raw material.The oil shale that has solved a large amount of low oil contents is idle, the problem that precious resources is wasted.Utilize the oil shale of low oil content to manufacture siliceous fertilizer, not only significant for reasonable development oil shale, and, for improving grain yield and quality, realize modern agriculture very important meaning again.Through for many years, in the test of different areas and crop, the insect pest of crop reduces, quality-improving, and output improves, and Soil structure is improved.Corn increases output 20--35% than control group.Paddy rice increases output 20---30% than control group, and peanut increases output 20---25% than control group.This has significant contribution to Chinese grain security, significant.
Embodiment
embodiment 1: within 2009, dry year carries out corn fertilizing volume increase test in Hua Jiqiao village, Hua Jia town, Nongan County.Same plot, does simultaneous test under identical conditions.
Each 5 hectares, experimental plot and contrast field.Corn variety is: first beautiful 335.Fertilizer adopts row replacement mode, adopts usual manner sowing.Contrast field adopts usual manner fertilising.
Base fertilizer is made with a kind of multielement active siliceous fertilizer based on oil shale provided by the invention in experimental plot.400 kilograms of amount of application per hectares, the sowing time is April 20, other kind fertilizer are identical with contrast field, adopt usual manner fertilising.
Corn bar alive in experimental plot is sturdy, and the bar of living is ripe, full seed.Harvest time is October 10.13500 kilograms of the average output per hectares in experimental plot.10000 kilograms of the average output per hectares in contrast field.Experimental plot volume increase 35% .
embodiment 2:2009 in Heilungkiang 859 farms, carry out fertilization of rice volume increase examination
Test.Each 5 hectares, experimental plot and contrast field.Employing usual manner is broadcast.Transplanting time is May 20, early maturing variety paddy rice.Contrast field adopts usual manner fertilising.
Base fertilizer is made with a kind of multielement active siliceous fertilizer based on oil shale provided by the invention in experimental plot.500 kilograms of experimental plot per hectare fertilisings.Other kind fertilizer are identical with contrast field, adopt usual manner fertilising.
Experimental plot, rice seedlings are dark green, and full seed does not have various disease and pests to occur.Harvest time is October 5.9000 kilograms of the average hectare output in experimental plot.7000 kilograms of the average hectare output in contrast field.Experimental plot volume increase 30% .
embodiment 3:2010, in Mo-tse village, Zan Zi township, Qianan County, area, Songyuan City, Jilin Province,
Carry out peanut fertilising volume increase test.
Each 1 hectare, experimental plot and contrast field.Peanut varieties is safflower life and white sand popped rice raw half and half.Sowing time is May 10.Contrast field adopts usual manner fertilising.
Base fertilizer is made with a kind of multielement active siliceous fertilizer based on oil shale provided by the invention in experimental plot.300 kilograms of rate of fertilizer application per hectares.Other kind fertilizer are identical with contrast field, adopt usual manner fertilising.
Harvest time: October 10,2500 kilograms of the raw per hectare mean yields of safflower.2000 kilograms of contrast field per hectare mean yields.Experimental plot volume increase 25%
4500 kilograms of the raw per hectare mean yields of white sand popped rice, 3600 kilograms of contrast field per hectare mean yields.Experimental plot volume increase 25%.

Claims (4)

1. the multielement active siliceous fertilizer based on oil shale, is characterized in that, composition and the weight percent of its formula are as follows:
Oil shale: 69-99%,
Brown coal: 0-30%,
Zinc sulfate: 0.2-0.5%,
Water glass: 0.3-0.5%.
2. the Chemical Mixed Fertilizer based on planting based on oil shale, is characterized in that, composition and the weight percent of its formula are as follows:
Oil shale: 10--40%,
Brown coal: 20--30%,
Zinc sulfate: 0-0.5%,
Urea: 15---20%,
Monoammonium phosphate; 15---25%,
Repone K; 10---15%.
3. the compound organic and inorganic fertilizer based on oil shale, composition and the weight percent of its formula are as follows:
Oil shale: 10--40%,
Brown coal: 25-40%,
Zinc sulfate: 0--1%,
Urea: 10---15%,
Monoammonium phosphate: 15---20%,
Repone K: 10---14%.
4. a kind of multielement active siliceous fertilizer based on oil shale claimed in claim 1, is characterized in that, with it, does Bulk Blending Fertilizer.
CN201210318823.XA 2012-09-03 2012-09-03 A kind of Multi-element active silicon fertilizer based on oil shale Active CN103664276B (en)

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Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104261948A (en) * 2014-10-11 2015-01-07 延边遵杰资源开发利用有限公司 Organic and inorganic compound fertilizer prepared from oil-shale waste residues and preparation method thereof
CN106495955A (en) * 2016-11-01 2017-03-15 登封市老拴保肥料有限公司 A kind of sustained-release synergistic strawberry special bulk blended fertilizer that applies in calacareous soil
CN107548648A (en) * 2017-08-12 2018-01-09 佛山推启农业研究院(普通合伙) A kind of implantation methods of Silicon-rich wax gourd
CN108440110A (en) * 2018-04-16 2018-08-24 隋皓为 A kind of oil shale makes organic fertilizer and does organic fertilizer additive
CN108440109A (en) * 2018-04-16 2018-08-24 隋皓为 A kind of production bio-bacterial manure of oil shale and do bio-bacterial manure additive
CN108456040A (en) * 2018-05-28 2018-08-28 隋皓为 A kind of oil shale making siliceous fertilizer technique
CN108485674A (en) * 2018-04-16 2018-09-04 隋皓为 A kind of oil shale making soil conditioner
CN108794254A (en) * 2018-06-13 2018-11-13 隋皓为 A kind of oil shale production composite fertilizer and do additive for compound fertilizer
CN108794156A (en) * 2018-06-13 2018-11-13 隋皓为 A kind of oil shale production Blending Fertilizer and do blending fertilizer additive
CN108794255A (en) * 2018-06-13 2018-11-13 隋皓为 A kind of oil shale makes compound organic and inorganic fertilizer and does compound organic and inorganic fertilizer additive
CN112919977A (en) * 2021-04-12 2021-06-08 兰州交通大学 Modified oil shale semicoke coated slow and controlled release fertilizer and preparation method thereof

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Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104261948A (en) * 2014-10-11 2015-01-07 延边遵杰资源开发利用有限公司 Organic and inorganic compound fertilizer prepared from oil-shale waste residues and preparation method thereof
CN106495955A (en) * 2016-11-01 2017-03-15 登封市老拴保肥料有限公司 A kind of sustained-release synergistic strawberry special bulk blended fertilizer that applies in calacareous soil
CN107548648A (en) * 2017-08-12 2018-01-09 佛山推启农业研究院(普通合伙) A kind of implantation methods of Silicon-rich wax gourd
CN108440110A (en) * 2018-04-16 2018-08-24 隋皓为 A kind of oil shale makes organic fertilizer and does organic fertilizer additive
CN108440109A (en) * 2018-04-16 2018-08-24 隋皓为 A kind of production bio-bacterial manure of oil shale and do bio-bacterial manure additive
CN108485674A (en) * 2018-04-16 2018-09-04 隋皓为 A kind of oil shale making soil conditioner
CN108456040A (en) * 2018-05-28 2018-08-28 隋皓为 A kind of oil shale making siliceous fertilizer technique
CN108794254A (en) * 2018-06-13 2018-11-13 隋皓为 A kind of oil shale production composite fertilizer and do additive for compound fertilizer
CN108794156A (en) * 2018-06-13 2018-11-13 隋皓为 A kind of oil shale production Blending Fertilizer and do blending fertilizer additive
CN108794255A (en) * 2018-06-13 2018-11-13 隋皓为 A kind of oil shale makes compound organic and inorganic fertilizer and does compound organic and inorganic fertilizer additive
CN112919977A (en) * 2021-04-12 2021-06-08 兰州交通大学 Modified oil shale semicoke coated slow and controlled release fertilizer and preparation method thereof

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