CN1267009C - Process for preparing crop growth promoting biological preparation for reducing pesticide residue - Google Patents
Process for preparing crop growth promoting biological preparation for reducing pesticide residue Download PDFInfo
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- CN1267009C CN1267009C CN 200410023954 CN200410023954A CN1267009C CN 1267009 C CN1267009 C CN 1267009C CN 200410023954 CN200410023954 CN 200410023954 CN 200410023954 A CN200410023954 A CN 200410023954A CN 1267009 C CN1267009 C CN 1267009C
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- rare earth
- biologic product
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- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- 239000000447 pesticide residue Substances 0.000 title claims description 7
- 230000012010 growth Effects 0.000 title abstract description 3
- 230000001737 promoting effect Effects 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title description 8
- 229910052761 rare earth metal Inorganic materials 0.000 claims abstract description 33
- 239000007788 liquid Substances 0.000 claims abstract description 31
- 150000002910 rare earth metals Chemical class 0.000 claims abstract description 23
- 238000012545 processing Methods 0.000 claims abstract description 15
- 239000012141 concentrate Substances 0.000 claims abstract description 14
- 239000002699 waste material Substances 0.000 claims abstract description 12
- -1 rare earth nitrate Chemical class 0.000 claims abstract description 8
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims abstract description 7
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 claims abstract description 7
- 229930195725 Mannitol Natural products 0.000 claims abstract description 7
- 239000000594 mannitol Substances 0.000 claims abstract description 7
- 235000010355 mannitol Nutrition 0.000 claims abstract description 7
- 235000010413 sodium alginate Nutrition 0.000 claims abstract description 7
- 239000000661 sodium alginate Substances 0.000 claims abstract description 7
- 229940005550 sodium alginate Drugs 0.000 claims abstract description 7
- 229910017604 nitric acid Inorganic materials 0.000 claims description 13
- 230000008635 plant growth Effects 0.000 claims description 9
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 7
- 230000003247 decreasing effect Effects 0.000 claims description 7
- 125000005461 organic phosphorous group Chemical group 0.000 claims description 7
- 238000004090 dissolution Methods 0.000 claims description 5
- 238000012546 transfer Methods 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 3
- 239000003513 alkali Substances 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 2
- 150000004676 glycans Chemical class 0.000 abstract description 19
- 229920001282 polysaccharide Polymers 0.000 abstract description 19
- 239000005017 polysaccharide Substances 0.000 abstract description 19
- 241001122767 Theaceae Species 0.000 abstract description 17
- 239000000575 pesticide Substances 0.000 abstract description 13
- RYYVLZVUVIJVGH-UHFFFAOYSA-N caffeine Chemical compound CN1C(=O)N(C)C(=O)C2=C1N=CN2C RYYVLZVUVIJVGH-UHFFFAOYSA-N 0.000 abstract description 10
- 238000000034 method Methods 0.000 abstract description 8
- 150000008442 polyphenolic compounds Chemical class 0.000 abstract description 7
- 235000013824 polyphenols Nutrition 0.000 abstract description 7
- 239000003337 fertilizer Substances 0.000 abstract description 6
- 239000002994 raw material Substances 0.000 abstract description 6
- LPHGQDQBBGAPDZ-UHFFFAOYSA-N Isocaffeine Natural products CN1C(=O)N(C)C(=O)C2=C1N(C)C=N2 LPHGQDQBBGAPDZ-UHFFFAOYSA-N 0.000 abstract description 5
- 229960001948 caffeine Drugs 0.000 abstract description 5
- VJEONQKOZGKCAK-UHFFFAOYSA-N caffeine Natural products CN1C(=O)N(C)C(=O)C2=C1C=CN2C VJEONQKOZGKCAK-UHFFFAOYSA-N 0.000 abstract description 5
- 230000015556 catabolic process Effects 0.000 abstract description 3
- 238000006731 degradation reaction Methods 0.000 abstract description 3
- 239000007787 solid Substances 0.000 abstract description 3
- 230000009466 transformation Effects 0.000 abstract description 2
- 239000002912 waste gas Substances 0.000 abstract description 2
- 239000002351 wastewater Substances 0.000 abstract description 2
- 241000512259 Ascophyllum nodosum Species 0.000 abstract 2
- 241000199919 Phaeophyceae Species 0.000 abstract 2
- 229920002307 Dextran Polymers 0.000 abstract 1
- 229910002651 NO3 Inorganic materials 0.000 abstract 1
- 239000003124 biologic agent Substances 0.000 abstract 1
- 229920001542 oligosaccharide Polymers 0.000 abstract 1
- 239000003987 organophosphate pesticide Substances 0.000 abstract 1
- 235000013305 food Nutrition 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 3
- 241000238631 Hexapoda Species 0.000 description 3
- 241000607479 Yersinia pestis Species 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000003814 drug Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- GUBGYTABKSRVRQ-PICCSMPSSA-N D-Maltose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 description 2
- 239000003905 agrochemical Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 230000000813 microbial effect Effects 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 229920001503 Glucan Polymers 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000000853 biopesticidal effect Effects 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 239000003446 ligand Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000003993 organochlorine pesticide Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002728 pyrethroid Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 235000013619 trace mineral Nutrition 0.000 description 1
- 239000011573 trace mineral Substances 0.000 description 1
- 230000009261 transgenic effect Effects 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Landscapes
- Fertilizers (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
- Medicines Containing Plant Substances (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Cultivation Of Seaweed (AREA)
Abstract
一种降有机磷农药残留促作物生长的生物制剂制备方法，利用茶叶加工茶多酚及咖啡碱后的含茶多糖废液或利用海带加工甘露醇、褐藻酸钠后的含褐藻寡糖废液浓缩后直接或添加稀土调节pH值，浓缩得液态叶面肥，干燥得固态叶面肥；也可将固态的茶多糖、海带废弃物或葡聚糖溶解后加入农用硝酸稀土得到。由上述方法制备的生物制剂可使作物内有机磷农药在数天后降解率达80%以上，作物增产率在3～20%。该生物制剂是一种天然制剂或含较少量的稀土，从而不仅极大地减少了稀土的使用量，提高了稀土农用的安全性，且使我国丰富的茶叶及褐藻资源得到充分高值化利用。且无废气、废水污染环境、原料易得、工艺简单、投资小，适合褐藻加工企业提高效益技改需要。A method for preparing biological preparations for reducing organophosphorus pesticide residues and promoting crop growth, using tea polysaccharide-containing waste liquid after processing tea polyphenols and caffeine, or using kelp to concentrate fucoidan-oligosaccharide-containing waste liquid after processing mannitol and sodium alginate Then directly or add rare earth to adjust the pH value, concentrate to obtain liquid foliage fertilizer, and dry to obtain solid foliage fertilizer; it can also be obtained by dissolving solid tea polysaccharide, kelp waste or dextran and adding agricultural rare earth nitrate. The biological agent prepared by the above method can make the degradation rate of organophosphorus pesticides in crops reach more than 80% after a few days, and increase the yield of crops by 3-20%. The biological preparation is a natural preparation or contains a small amount of rare earths, which not only greatly reduces the use of rare earths, improves the safety of rare earths in agriculture, but also makes full and high-value utilization of my country's rich tea and brown algae resources . And there is no waste gas, waste water polluting the environment, raw materials are easy to obtain, the process is simple, and the investment is small, which is suitable for the technical transformation needs of brown algae processing enterprises to improve efficiency.
Description
Technical field
The present invention relates to the short plant growth biologic product preparation method of a kind of decreasing organic phosphorous pesticide residue.
Background technology
China has a large population in a small area, and how to guarantee that size of food safety and quality safety are long-term and difficult task.With regard to plant resource food, no matter be large grain-production, or the production of vegetable and fruit, their growth busy season is also mostly to be that the busy season takes place in insect pest.Present stage, the peasant also needed to use the chemical pesticide control insect pest in order to improve their output and quality.Along with the complete prohibition use and the pyrethroid pesticide of organo-chlorine pesticide easily makes insect develop immunity to drugs, organophosphorous pesticide has accounted for 70% of insecticide total amount at present.But long-term large-scale production and use organophosphorous pesticide not only causes severe contamination to environment, residual in food and feed people and cultivated animals is also seriously influenced.And the superseded use or reach in food hygienic standard of construction, biopesticide and organophosphorous pesticide development of substitutes and some organophosphorous pesticide of carrying out research, the pollution-free food production base of transgenic pest-resistant, disease-resistant crop does not have and detects requirement etc. and all need very strong science and technology and funds support, apply from developing to as a kind of agricultural chemicals, need multi-disciplinary cooperations such as chemistry, agronomy, medical science and environment, go through 10 surplus year.According to the national conditions of China, present stage is the use of impossible total ban organophosphorous pesticide also.Therefore, develop a kind of can the degraded and do the residual of the interior organophosphorous pesticide of object, the biologic product that can promote plant growth again is current and presses for from now on.
Rare earth application is China's initiative, and has become one of major measure of agricultural production and income.At present relevant RE microbial fertilizer (as " Chang Le ") and relevant patent (as: 96109036.7, manufacture method of solvay-type RE microbial fertilizer and products thereof; 96117083.2, serial compound rare-earth trace element fertilizer and production method thereof; 98103155.2, a kind of solubility compound powder as fertile medicine) and the main purpose of its developments such as other foliage fertilizers and biologic product be to promote plant growth and raising quality, and existing promotion plant growth has the product for agriculture of decreasing organic phosphorous agricultural chemicals to have not yet to see patent report.We find to the physiological and biochemical research of rare earth, sea-tangle and tealeaves isoreactivity composition the time, natural tea polysaccharide and algal polysaccharide are combined with rare earth element, this natural malt sugar soil compound and tea polysaccharide, brown alga oligose class and glucan are that part and rare earth element ligand complex are prepared the polysaccharide RE composite, and the phosphide key is all had very strong splitting action.Organophosphorous pesticide contains the phosphide key mostly, and therefore, the polysaccharide RE composite has degradation to organophosphorous pesticide theoretically, but has not yet to see the patent of invention report.
Summary of the invention
One of purpose of the present invention is to overcome the deficiency of prior art, and the preparation method of the short plant growth biologic product of a kind of decreasing organic phosphorous pesticide residue is provided.
Another object of the present invention is to promote the higher value application of tealeaves and brown alga industrial enterprise discarded object.
The preparation method 1: do not add the preparation method that rare earth directly utilizes tealeaves and brown alga industrial enterprise discarded object (often including rare earth usually): A, directly utilize contain tea polysaccharide waste liquid and B behind Tea Processing Tea Polyphenols and the caffeine to utilize the brown alga oligose waste liquid that contains behind sea-tangle processing mannitol, the sodium alginate to concentrate the back and regulate pH value to 4～7, filter, and further concentrate liquid biologic product, dry solid-state biologic product
The preparation method 2: add the preparation method that rare earth utilizes tealeaves or brown alga industrial enterprise discarded object: A, utilize behind Tea Processing Tea Polyphenols and the caffeine contain the tea polysaccharide waste liquid and B utilizes sea-tangle processing mannitol, contain the brown alga oligose waste liquid behind the sodium alginate, after concentrating, add in advance with the rare earth of dilute nitric acid dissolution or directly use agricultural nitric acid rare earth, the percentage that rare earth adding quantity accounts for tea polysaccharide or sea-tangle discarded object weight is controlled at 0.00%～0.5%, react 5～24h down at 10～35 ℃, transfer reacting liquid pH value to 4～7 with acid or alkali, filtering and concentrating gets liquid biologic product, or dry solid-state biologic product.
The preparation method 3: add in advance solid-state tea polysaccharide or the sea-tangle discarded object dissolving back that contains brown alga oligose with the rare earth of dilute nitric acid dissolution or directly use agricultural nitric acid rare earth, the percentage that rare earth adding quantity accounts for tea polysaccharide or sea-tangle discarded object weight is controlled at 0.00%～0.5%, react 5～24h down at 10～35 ℃, transfer reactant liquor pH value to 4～7, filter, concentrate liquid biologic product, or dry solid-state biologic product.
With the biologic product of said method processing, application can make organophosphorous pesticide reach more than 80% at degradation rate after a couple of days on the crop that has sprayed organophosphorous pesticide, and the crop yield rate is 3～20%, and the crop yield probability is about 85%.In addition, this biologic product is a kind of natural medicine or contains more a spot of rare earth, thereby not only greatly reduced the usage amount of rare earth, improved the safety of rare earth application, and made the tealeaves of China's abundant and brown alga resource obtain abundant higher value application.
The present invention also has production process not have distinguishing features such as waste gas, contaminated wastewater environment, raw material are easy to get, technology is simple, investment is very little, therefore the technological transformation needs that not only are fit to existing Tea Polyphenols factory and brown alga processing enterprise, improve its benefit, and can produce and be applicable in rural area medium-sized and small enterprises, be a kind of new technology that current pollution-free food production presses for.
Embodiment
Tea polysaccharide or sea-tangle discarded object with warm water dissolving (when producing in Tea Polyphenols factory or in brown alga processing enterprise, can be directly with the liquid that contains tea polysaccharide and brown alga oligose, needn't dissolve), solvability is controlled at 2%～35%, slowly add in advance with the rare earth of dilute nitric acid dissolution then or directly use nitric acid rare earth, rare earth adding quantity is controlled at 0.00%～0.5% (accounting for the percentage of tea polysaccharide or sea-tangle discarded object weight), pH is controlled at 2～6, and after remaining on 25 ℃～35 ℃ reaction 24h, with acid, alkali fine setting reacting liquid pH value to 4～7.Filter the back concentrate liquid biologic product, or dry solid-state biologic product.No matter the final products of preparation are liquid state or solid-state shape, all should include the active ingredient carbohydrate in their every mu of usage amount is 30g～150g (by dropping into raw material), and rare earth is 0.0001g～20g (by dropping into raw material).Used rare earth can directly be planted element (the little fertile factory in Shangqiu produces) or other agricultural nitric acid rare earth with " Chang Le " board benefit among the above-mentioned preparation method, and this biologic product field using method is with conventional biologic product using method.
Embodiment 1
Be dissolved in the 1000ml water with prepared tea polysaccharide 50g behind Tea Processing Tea Polyphenols and the caffeine, slowly add 0.2g " Chang Le " board benefit and plant element, after remaining on 25 ℃ of reaction 24h, with carbonic hydroammonium fine setting reacting liquid pH value to 6.5, filter the back concentrate liquid biologic product, or dry solid-state biologic product.No matter be liquid biologic product, or solid-state biologic product, tea polysaccharide content 500g in every mu of usage amount (, as follows), content of rare earth 2g (, as follows) by dropping into raw material by dropping into raw material.
Embodiment 2
The waste liquid thing 50g that processes behind mannitol, the sodium alginate with sea-tangle is dissolved in the 1000ml water, slowly add 0.3g " Chang Le " board benefit and plant element, after remaining on 25 ℃ of reaction 24h, with nitric acid fine setting reacting liquid pH value to 6.5, filter the back concentrate liquid biologic product, or dry solid-state biologic product.No matter be liquid biologic product, or solid-state biologic product, sea-tangle discarded object content 500g in every mu of usage amount, content of rare earth 3g.
Embodiment 3
With after containing the tea polysaccharide waste liquid and concentrate behind Tea Processing Tea Polyphenols and the caffeine, leave standstill 24h after, the biologic product that filters liquidly, and then dry solid-state biologic product.Contain tea polysaccharide solid content 500g in every mu of usage amount.
Embodiment 4
After processing waste liquid behind mannitol, the sodium alginate and concentrate with sea-tangle, with the little adjust pH to 6 of nitric acid, the biologic product that filters liquidly, and then dry solid-state biologic product.Thallus Laminariae (Thallus Eckloniae) extract content 500g in every mu of usage amount.
Claims (3)
1, the preparation method of the short plant growth biologic product of a kind of decreasing organic phosphorous pesticide residue, it is characterized in that directly utilizing the brown alga oligose waste liquid that contains behind sea-tangle processing mannitol and the sodium alginate to concentrate the back and regulate pH value to 4～7, concentrate liquid biologic product, dry solid-state biologic product.
2, the preparation method of the short plant growth biologic product of a kind of decreasing organic phosphorous pesticide residue, it is characterized in that directly utilizing the brown alga oligose waste liquid that contains behind sea-tangle processing mannitol and the sodium alginate to concentrate the pH that the back adds in advance with dilute nitric acid dissolution and be 1～3 rare earth or directly use agricultural nitric acid rare earth, the percentage that rare earth adding quantity accounts for sea-tangle discarded object dry weight is controlled at below 0.5%, react 5～24h down at 10～35 ℃, transfer reacting liquid pH value to 4～7 with acid or alkali, filtering and concentrating gets liquid biologic product, or dry solid-state biologic product.
3, the preparation method of the short plant growth biologic product of a kind of decreasing organic phosphorous pesticide residue, it is characterized in that the solid-state brown alga oligose refuse dissolving back adding that contains is 1～3 rare earth or directly uses agricultural nitric acid rare earth with the pH of dilute nitric acid dissolution in advance, rare earth adding quantity accounts for the solid-state percentage that contains brown alga oligose refuse weight and is controlled at below 0.5%, react 5～24h down at 10～35 ℃, transfer reacting liquid pH value to 4～7, filter, concentrate liquid biologic product, or dry solid-state biologic product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410023954 CN1267009C (en) | 2004-04-22 | 2004-04-22 | Process for preparing crop growth promoting biological preparation for reducing pesticide residue |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410023954 CN1267009C (en) | 2004-04-22 | 2004-04-22 | Process for preparing crop growth promoting biological preparation for reducing pesticide residue |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200510129937XA Division CN101120684B (en) | 2004-04-22 | 2004-04-22 | A kind of preparation method of growth-promoting biological agent for reducing organophosphorus pesticide residues |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1561750A CN1561750A (en) | 2005-01-12 |
| CN1267009C true CN1267009C (en) | 2006-08-02 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200410023954 Expired - Fee Related CN1267009C (en) | 2004-04-22 | 2004-04-22 | Process for preparing crop growth promoting biological preparation for reducing pesticide residue |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1267009C (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB0521993D0 (en) * | 2005-10-28 | 2005-12-07 | Plant Impact Plc | Agricultural composition |
| CN101965936B (en) * | 2010-09-15 | 2012-06-27 | 李成保 | Biological agent for degrading pesticide residues and preparation process thereof |
| CN103319621B (en) * | 2013-07-02 | 2016-06-15 | 青岛农业大学 | There is the synthetic method of the rare earth polysaccharide complex of bacteriostatic activity |
| CN104798776B (en) * | 2014-01-28 | 2017-03-15 | 中国科学院大连化学物理研究所 | A kind of method for alleviating crops herbicide damage |
| CN103797955B (en) * | 2014-01-28 | 2015-09-09 | 广西喷施宝股份有限公司 | A kind of method reducing Organo-phosphorus Pesticide Residues in Vegetables |
| CN108525190A (en) * | 2018-04-20 | 2018-09-14 | 佛山推启农业研究院（普通合伙） | A kind of tea polysaccharide RE composite is for the residual method of agriculture of degrading |
| CN108835511A (en) * | 2018-06-04 | 2018-11-20 | 陕西日日新生物科技有限公司 | A kind of fruits and vegetables coloring modifying agent |
| CN112090408B (en) * | 2020-09-16 | 2023-02-17 | 浙江省农业科学院 | A kind of natural fucoidan magnetic material and its preparation method and application |
-
2004
- 2004-04-22 CN CN 200410023954 patent/CN1267009C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN1561750A (en) | 2005-01-12 |
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