CN1183167C - 降低聚乙烯和聚乙烯产物的重均分子量和熔体指数比率的方法 - Google Patents
降低聚乙烯和聚乙烯产物的重均分子量和熔体指数比率的方法 Download PDFInfo
- Publication number
- CN1183167C CN1183167C CNB008184100A CN00818410A CN1183167C CN 1183167 C CN1183167 C CN 1183167C CN B008184100 A CNB008184100 A CN B008184100A CN 00818410 A CN00818410 A CN 00818410A CN 1183167 C CN1183167 C CN 1183167C
- Authority
- CN
- China
- Prior art keywords
- polyethylene
- mixture
- ethylene copolymer
- multipolymer
- molecular weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/50—Partial depolymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2810/00—Chemical modification of a polymer
- C08F2810/10—Chemical modification of a polymer including a reactive processing step which leads, inter alia, to morphological and/or rheological modifications, e.g. visbreaking
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S525/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S525/938—Polymer degradation
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US44169299A | 1999-11-16 | 1999-11-16 | |
| US09/441,692 | 1999-11-16 | ||
| US09/698,749 US6433133B1 (en) | 1999-11-16 | 2000-10-27 | Process for reducing the weight average molecular weight and melt index ratio of polyethylenes and polyethylene products |
| US09/698,749 | 2000-10-27 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1423663A CN1423663A (zh) | 2003-06-11 |
| CN1183167C true CN1183167C (zh) | 2005-01-05 |
Family
ID=27032910
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB008184100A Expired - Lifetime CN1183167C (zh) | 1999-11-16 | 2000-11-16 | 降低聚乙烯和聚乙烯产物的重均分子量和熔体指数比率的方法 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US6433133B1 (enExample) |
| EP (1) | EP1237947B1 (enExample) |
| JP (1) | JP5390054B2 (enExample) |
| CN (1) | CN1183167C (enExample) |
| BR (1) | BR0015594B1 (enExample) |
| DE (1) | DE60023546T2 (enExample) |
| MX (1) | MXPA02004888A (enExample) |
| WO (1) | WO2001036495A1 (enExample) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6649694B2 (en) | 2001-12-21 | 2003-11-18 | Eastman Chemical Company | Process for producing ethylene-α-olefin interpolymer films |
| US20050288447A1 (en) * | 2002-09-09 | 2005-12-29 | Idemitsu Kosan Co., Ltd. | Modified propylene based polymer and polyolefin resin composition |
| FR2879619B1 (fr) | 2004-12-16 | 2007-07-13 | Arkema Sa | Composition adhesive a base de copolymeres ethyleniques, utilisable pour extrusion-couchage et extrusion-lamination sur divers supports |
| US7776401B2 (en) * | 2005-06-21 | 2010-08-17 | E.I. Du Pont De Nemours And Company | Method for treating fabric with viscous liquid polymers |
| US7456244B2 (en) * | 2006-05-23 | 2008-11-25 | Dow Global Technologies | High-density polyethylene compositions and method of making the same |
| CA2805045C (en) * | 2010-07-27 | 2018-08-21 | Henkel Ag & Co. Kgaa | Process for manufacturing an adhesive by means of extrusion |
| US10053574B2 (en) | 2014-08-15 | 2018-08-21 | Westlake Longview Corporation | Maleic anhydride grafted LLDPE having high melt index |
| DE102014117307A1 (de) * | 2014-11-26 | 2016-06-02 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Mittels eines Modifizierungsreagenzes modifizierte Polymere und Verfahren zu deren Herstellung |
| CN106349409B (zh) * | 2015-07-20 | 2018-02-13 | 中国石油化工股份有限公司 | 一种降低聚合物分子量的方法 |
| KR101995951B1 (ko) * | 2019-03-12 | 2019-07-03 | 주식회사 라이온켐텍 | 폴리올레핀 공중합체의 연속식 제조방법 |
| JP2024526561A (ja) * | 2021-06-22 | 2024-07-19 | イクイスター・ケミカルズ・エルピー | ポリマーリサイクレートプロセスおよび製品 |
| CN118804834A (zh) | 2022-02-10 | 2024-10-18 | 道达尔能源一技术 | 用于注塑的聚乙烯组合物 |
| EP4389782A1 (en) | 2022-12-20 | 2024-06-26 | Basell Polyolefine GmbH | Process for modifiyng the melt flow index of low density polyethylene |
| WO2024132833A1 (en) | 2022-12-19 | 2024-06-27 | Basell Polyolefine Gmbh | Process for modifiyng the melt flow index of low density polyethylene |
| CN120303310A (zh) | 2022-12-19 | 2025-07-11 | 巴塞尔聚烯烃股份有限公司 | 用于改性低密度聚乙烯的熔体流动指数的工艺 |
| EP4389781A1 (en) * | 2022-12-20 | 2024-06-26 | Basell Polyolefine GmbH | Process for modifiyng the melt flow index of low density polyethylene |
| US11976183B1 (en) | 2022-12-19 | 2024-05-07 | Basell Polyolefine Gmbh | Process for modifiyng the melt flow index of low density polyethylene |
| US11976184B1 (en) | 2022-12-19 | 2024-05-07 | Basell Polyolefine Gmbh | Process for modifiyng the melt flow index of low density polyethylene |
Family Cites Families (56)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3412080A (en) | 1957-04-02 | 1968-11-19 | Union Carbide Corp | Thermal treatment of high-density polyolefins |
| US2935502A (en) | 1958-02-05 | 1960-05-03 | Union Carbide Corp | Process for the high temperature, high pressure shear degradation of solid polyethylene |
| US3087922A (en) | 1958-05-13 | 1963-04-30 | Phillips Petroleum Co | Method and apparatus for pyrolyzing polymers |
| US3121070A (en) | 1960-05-03 | 1964-02-11 | Eastman Kodak Co | Thermally modified polymers of polypropylene and other polymers and process for preparing the same |
| US3299181A (en) | 1960-05-03 | 1967-01-17 | Eastman Kodak Co | Thermally modified polyethylene and other polymers and process for preparing the same |
| US3144436A (en) | 1961-01-04 | 1964-08-11 | Du Pont | Process for degrading stereoregular polymers |
| BR6237778D0 (pt) | 1961-04-12 | 1973-01-11 | W Taban | Processo continuo para produzir um poli-etileno modificado por um composto de acido maleico solido e poli-etileno modificado por composto de acido maleico solido |
| US3248469A (en) | 1961-08-28 | 1966-04-26 | Phillips Petroleum Co | High shear visbreaking method and apparatus |
| US3230288A (en) | 1961-09-01 | 1966-01-18 | Phillips Petroleum Co | Method of pyrolyzing, blending and extruding a 1-olefin polymer |
| NL297178A (enExample) | 1962-08-31 | 1900-01-01 | ||
| US3345352A (en) | 1964-02-21 | 1967-10-03 | Allied Chem | Catalytic process for the thermal degradation of polyolefins |
| US3243405A (en) | 1964-12-02 | 1966-03-29 | Sun Oil Co | Processing of ethylene-propylene copolymer |
| NL6607078A (enExample) | 1966-05-24 | 1967-11-27 | ||
| US3551943A (en) | 1966-12-19 | 1971-01-05 | Exxon Research Engineering Co | Controlled degradation |
| US3519609A (en) | 1967-06-07 | 1970-07-07 | Eastman Kodak Co | Method for making polyolefin waxes by thermal degradation of higher molecular weight polyolefins in the presence of organic acids and anhydrides |
| US3562788A (en) | 1967-06-08 | 1971-02-09 | Eastman Kodak Co | Thermal degradation of polyolefins |
| US3634381A (en) | 1968-04-27 | 1972-01-11 | Basf Ag | Degradation of high molecular weight polyisobutylene in extruders |
| US3598885A (en) | 1968-07-11 | 1971-08-10 | Standard Oil Co | Process for preparation of low molecular weight polymers |
| DE1904739C3 (de) | 1969-01-31 | 1980-12-18 | Basf Ag, 6700 Ludwigshafen | Verfahren zum Nachbehandeln von Hochdruck-Polyäthylen in einem Scheraggregat |
| US3842153A (en) | 1969-07-23 | 1974-10-15 | Midland Silicones Ltd | Polypropylene |
| GB1311855A (en) | 1969-07-23 | 1973-03-28 | Dow Corning Ltd | Polypropylene |
| US3608001A (en) | 1969-08-26 | 1971-09-21 | Exxon Research Engineering Co | Controlled degradation of polypropylene in extruder-reactor |
| US3563972A (en) | 1969-10-15 | 1971-02-16 | Exxon Research Engineering Co | Low melt elasticity composition of polypropylene |
| JPS506020B1 (enExample) * | 1970-05-04 | 1975-03-10 | ||
| US3803080A (en) | 1970-05-22 | 1974-04-09 | Huels Chemische Werke Ag | Process for the defined increase of the molecular weight of solid,unsaturated elastomers |
| US3862265A (en) | 1971-04-09 | 1975-01-21 | Exxon Research Engineering Co | Polymers with improved properties and process therefor |
| US3953655A (en) | 1972-04-03 | 1976-04-27 | Exxon Research And Engineering Company | Polymers with improved properties and process therefor |
| US4001172A (en) | 1972-04-03 | 1977-01-04 | Exxon Research And Engineering Company | Polymers with improved properties and process therefor |
| US3940379A (en) | 1973-05-21 | 1976-02-24 | Dart Industries, Inc. | Process for controlled degradation of propylene polymers |
| US3898209A (en) | 1973-11-21 | 1975-08-05 | Exxon Research Engineering Co | Process for controlling rheology of C{HD 3{B {30 {0 polyolefins |
| DE3003768A1 (de) | 1980-02-01 | 1981-08-06 | Ljudmila Konstantinovna Ašichmina | Verfahren zur kontinuierlichen herstellung von polyolefinwachs |
| US4720540A (en) | 1983-02-24 | 1988-01-19 | Amoco Corporation | Process for treating thermoplastic polymers |
| US4632977A (en) | 1984-06-01 | 1986-12-30 | The Hygenic Corporation | Method of plasticizing thermoplastic polymers |
| US4632962A (en) * | 1984-12-24 | 1986-12-30 | General Electric Company | Hydroxyl group graft modified polyolefins |
| US4749505A (en) | 1985-07-08 | 1988-06-07 | Exxon Chemical Patents Inc. | Olefin polymer viscosity index improver additive useful in oil compositions |
| US4707524A (en) | 1986-05-06 | 1987-11-17 | Aristech Chemical Corporation | Controlled-rheology polypropylene |
| US5324816A (en) | 1987-06-22 | 1994-06-28 | Allied-Signal Inc. | Process for improving the properties of polymers |
| DE3869593D1 (de) | 1988-01-21 | 1992-04-30 | Idemitsu Petrochemical Co | Verfahren zur herstellung von modifizierten polyaethylenen. |
| US5478906A (en) | 1988-12-02 | 1995-12-26 | E. I. Du Pont De Nemours And Company | Ultrahigh molecular weight linear polyethylene and articles thereof |
| JP2957632B2 (ja) * | 1990-04-04 | 1999-10-06 | 三井化学株式会社 | α−オレフィン系共重合体の熱分解物およびその製造方法 |
| EP0474889B1 (en) | 1990-04-10 | 1998-01-07 | Mitsui Petrochemical Industries, Ltd. | Process for thermal degradation of polymer |
| JPH03292305A (ja) * | 1990-04-10 | 1991-12-24 | Mitsui Petrochem Ind Ltd | ポリマーの熱減成方法 |
| JP3051484B2 (ja) * | 1991-04-02 | 2000-06-12 | 三井化学株式会社 | 熱分解ワックスの製造方法 |
| US5346963A (en) | 1993-04-28 | 1994-09-13 | The Dow Chemical Company | Graft-modified, substantially linear ethylene polymers and methods for their use |
| US5391617A (en) | 1993-08-02 | 1995-02-21 | Dsm Copolymer, Inc. | Solid sheared polymer blends and process for their preparation |
| EP0661308B1 (de) * | 1993-12-24 | 1999-06-02 | Ticona GmbH | Cycloolefincopolymere und Verfahren zu ihrer Herstellung |
| FI98916C (fi) | 1994-03-24 | 1997-09-10 | Borealis Polymers Oy | Menetelmä eteenin ja -olefiinin kopolymeroimiseksi |
| US5451630A (en) | 1994-08-02 | 1995-09-19 | Dsm Copolymer, Inc. | Solid sheared polymer blends and process for their preparation |
| FR2723880B1 (fr) | 1994-08-30 | 1997-01-03 | Bp Chemicals Snc | Procede pour modifier un polyethylene dans une extrudeuse |
| DE4437754A1 (de) * | 1994-10-21 | 1996-04-25 | Basf Ag | Verfahren zum thermomechanischen Abbau von Polyolefinen |
| US5541285A (en) * | 1995-01-13 | 1996-07-30 | Exxon Chemical Patents Inc. | Method to process narrow molecular weight distribution polyolefins |
| US5594074A (en) | 1995-02-21 | 1997-01-14 | Shell Oil Company | Process for improving processability of ultra low melt viscosity polymer |
| US5530073A (en) | 1995-06-30 | 1996-06-25 | Amoco Corporation | Process for increased peroxide efficiency in controlled rheology polypropylene resin |
| US5587434A (en) | 1995-10-13 | 1996-12-24 | Union Carbide Chemicals & Plastics Technology Corporation | Process for polymer degradation |
| NO980552D0 (no) | 1998-02-09 | 1998-02-09 | Borealis As | Katalysatorbestandel og katalysator for (ko)polymerisering av etylen, og fremgangsmåte for fremstilling av slik |
| US6060584A (en) * | 1998-05-13 | 2000-05-09 | Eastman Chemical Company | Process for the degradation of polyolefins |
-
2000
- 2000-10-27 US US09/698,749 patent/US6433133B1/en not_active Expired - Lifetime
- 2000-11-16 BR BRPI0015594-2A patent/BR0015594B1/pt not_active IP Right Cessation
- 2000-11-16 EP EP00978754A patent/EP1237947B1/en not_active Expired - Lifetime
- 2000-11-16 DE DE60023546T patent/DE60023546T2/de not_active Expired - Lifetime
- 2000-11-16 WO PCT/US2000/031593 patent/WO2001036495A1/en not_active Ceased
- 2000-11-16 MX MXPA02004888A patent/MXPA02004888A/es not_active Application Discontinuation
- 2000-11-16 CN CNB008184100A patent/CN1183167C/zh not_active Expired - Lifetime
- 2000-11-16 JP JP2001538984A patent/JP5390054B2/ja not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| DE60023546D1 (de) | 2005-12-01 |
| CN1423663A (zh) | 2003-06-11 |
| JP5390054B2 (ja) | 2014-01-15 |
| WO2001036495A1 (en) | 2001-05-25 |
| US6433133B1 (en) | 2002-08-13 |
| EP1237947B1 (en) | 2005-10-26 |
| BR0015594A (pt) | 2002-07-09 |
| MXPA02004888A (es) | 2002-09-18 |
| JP2003514926A (ja) | 2003-04-22 |
| BR0015594B1 (pt) | 2010-06-15 |
| EP1237947A1 (en) | 2002-09-11 |
| DE60023546T2 (de) | 2006-04-20 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: WESTLAKE LONGVIEW CORPORATION Free format text: FORMER OWNER: YISIMAN CHEMICAL COMPANY Effective date: 20070518 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20070518 Address after: American Texas Patentee after: Westlake Longview Corp. Address before: Tennessee Patentee before: Eastman Chem Co. |
|
| CX01 | Expiry of patent term | ||
| CX01 | Expiry of patent term |
Granted publication date: 20050105 |