CN1182797A - Method for preparing agricultural biochemical humic acid compound - Google Patents
Method for preparing agricultural biochemical humic acid compound Download PDFInfo
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- CN1182797A CN1182797A CN 97118762 CN97118762A CN1182797A CN 1182797 A CN1182797 A CN 1182797A CN 97118762 CN97118762 CN 97118762 CN 97118762 A CN97118762 A CN 97118762A CN 1182797 A CN1182797 A CN 1182797A
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- humic acid
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Abstract
The present invention relates to a preparation method of agricultural biochemical humic acid composite. It mainly includes organic nutrients, inorganic nutrients and composite growth promotor, and adds macro-elements, rare-elements and activating preparation. Said invention possesses the main advantages of more sufficient nutrient source, cheap price, rich and complete nutrients, simple and convenient preparation process, extensive application and obvious effects.
Description
The present invention relates to a kind of preparation method of biochemical humic acid compound.
Humic acid substance is the macromolecular organic compound that a class has physiologically active, the humic acid substance of occurring in nature is mainly just formed through very very long time and complicated biochemical action by plant residue and animal residue, mainly is present in the peat composed of rotten mosses, peat, weathered coal and the brown coal.But from wherein obtaining the humic acids complex process, the investment cost height, the active constituent content in the raw material differs greatly, and raw material quantity and originate limited, be difficult to satisfy the big and growing needs of humic acids demand, also existing in the part material and being doped with objectionable impurities needs to remove.So people begin to seek to obtain the novel method of humic acids.
Have to disclose in two pieces of documents and utilize microorganism to carry out the method for biochemical synthetic humic acids, their common essential conditions are bacterial classification, culture material and yeasting.Its bacterial classification all adopts natural wide spectrum bacterial classification, because natural bacterial classification complexity, wherein mixing has harmful microorganism, can not be formed with the bacteria group advantage in early days what ferment especially, has a negative impact to producing effect.Wherein a kind of method has added a large amount of greases in culture material, thereby has increased production cost, lacks inorganic nutrients compositions such as nitrogen, phosphorus, potassium, magnesium again.Though another kind method contains nitrogen, phosphorus, potassium etc., nutrition is incomplete yet.Also have one piece of document to disclose a kind of fermenting process of in multifunctional fermentation tank, finishing in addition, in culture base-material, added the inhibitor that suppresses harmful bacterial strain during fermentation, but it also has restraining effect to useful bacterial strain, the advantage that though fermentation has yeasting to be convenient to control in the above-mentioned fermentor tank, but its technology is complicated, the requirement condition harshness, the investment cost height.
The objective of the invention is to overcome above-mentioned the deficiencies in the prior art, provide the resource abundance cheap again nutrition material source, it is simple to produce operation, production cost is low, the formation that helps profitable strain can suppress the harmful microbe activity again effectively, ferment effect is better, produces steady quality, the preparation method of a kind of agricultural biochemical humic acid compound that nutritive ingredient is more complete.
The objective of the invention is to realize by following technical proposals:
The component of this mixture contains organotrophy material, inorganic nutrients material, composite growth element, also contains live bacteria agent.
Component of this mixture and ratio thereof are:
Organotrophy material 100; Inorganic nutrients material 5～15; Composite growth element 0.5～2; Live bacteria agent 0.5～2.
It produces operation:
The organotrophy base-material that at first will allot according to the above ratio and inorganic nutrients base-material are pulverized to go forward side by side to be sieved to pulverizer and are required the order number, after finishing above-mentioned operation, being about to above-mentioned base-material packs in the stirrer, and add after an amount of water stirs, make it to reach satisfactory pH value by weak acid (alkali) adjusting, in regulating the culture base-material of pH value, add growth hormone according to the above ratio and inoculate active bacteria formulation, stir again, to put into fermentation vat (jar) fermentation through the culture material after the above-mentioned operation, keep corresponding constant temperature, go out pond and cooling after keeping fermentation coupling fate, as then being dried to the former powder that contains requirement moisture as solid-state, as to be used for the liquid state material that then will ferment be liquid through lixiviate (squeezing).
Be specifically described as follows:
A. base-material is pulverized: at first organotrophy base-material and inorganic nutrients base-material are pulverized after 20～40 mesh sieves sieve with pulverizer, so that the making full use of of each nutrition composition uniform mixing and microorganism;
B. batch mixing stirs: the organotrophy material that sieves and inorganic nutrients material are packed in the stirrer in ratio shown in above-mentioned, add an amount of water and stir;
C. regulate pH value: the mixed resin that stirs is regulated pH value by weak acid (alkali) make it to reach 5～7.5;
D. add growth hormone, the inoculation active bacteria formulation: in regulating the culture base-material of pH value, add growth hormone and inoculate active bacteria formulation, stir again in ratio shown in above-mentioned;
E. charging fermentation: the culture material that will finish above-mentioned operation is put into fermentation vat (jar) and is fermented, and keeps 60～70 ℃ of constant temperature, and keeping ferments promptly finished and ferment the pond in 7～15 days;
F. discharging: the material that will finish fermentation takes out the back cooling;
G. drying or lixiviate: as being used as the solid-state former powder that then is dried to moisture≤15%; As be used for liquid state then will ferment material through lixiviate or squeezing for liquid.
Advantage of the present invention mainly contains:
1, organotrophy material aboundresources is cheap, for a large amount of crop straws of farmland depleted and agricultural byproducts waste residue have been opened up new outlet and for wide material sources, nutritious, cheap resource are provided as second development and utilization;
2, already contg vegetablefats can satisfy the bio-transformation condition of microorganism fully in the organotrophy material of the present invention's employing, does not need to add animal and plant fat more in addition, has both reduced production cost, also is of value to the lixiviate of fermented liq;
3, this mixture is nutritious complete, it has overcome the shortcoming of former mixture hypotrophy, not only contain nitrogen, phosphorus, potassium, also closed constant and trace elements such as calcium, magnesium, sulphur, copper, iron, zinc, manganese, selenium, cobalt, they or as the integral part of enzymic activity base or keep the activity of enzyme; Or essential by the normal fermentation of microorganism and growth, or can not to synthesize all to be indispensable, irreplaceable important substance by the organic compound of external source supply;
4, the present invention is on the basis of natural wide spectrum bacterial classification, add a spot of active bacteria formulation, loaded down with trivial details operations such as sterilization of fermentation material or interpolation inhibitor have been saved, and overcome the negative effect of its generation, reduced cost again, also can just form the probiotics superiority in early days, can suppress the harmful microbe activity effectively in fermentation;
5, of many uses, the effect of this mixture significantly, can be used for herding, Poultry farming industry, the plant husbandry of farmland woods fruit etc. effectively, the dry powder mixture can directly apply to animal feedstuff additive, veterinary drug, farm crop fertilizer etc., liquid complex can be composite with animal nutrient, nutrient for plants, pharmaceutical chemicals etc., as animal feedstuff additive, leaf leaven, veterinary drug, agricultural chemicals etc.
The invention will be further described below in conjunction with embodiment:
Organotrophy material package of the present invention is drawn together crop straw, sawdust, poor slag, cereal seed, grouts, feces of livestock and poultry etc.; The inorganic nutrients material package is drawn together major elements such as nitrogen, phosphorus, potassium and calcium, magnesium, sulphur; The composite growth element comprises that B family is little and gives birth to plain and trace elements such as copper, iron, zinc, manganese, selenium, cobalt; Active bacteria formulation comprises actinomycetes etc.
In the organotrophy material, crop materials such as corn stalk, broomcorn straw, beanstalk bar, millet straw and bagasse, beet pulp etc. are as main organic nutrilite resource, adding an amount of wood chip is in order to reduce cost and to save operation, vinasse are byproducts of wine industry, it contains abundant vitamin B group and protein, but the needs of microorganism in the afterfermentation process.Contain outside nitrogen, phosphorus, potassium and the trace element in fresh, the exsiccant feces of livestock and poultry, also contain certain VITAMIN, be rich in the crude protein composition in it simultaneously, can reduce the interpolation of inorganic nitrogen, reduced cost.Major elements such as the nitrogen in the inorganic nutrients material, phosphorus, potassium and calcium, magnesium, sulphur, the formation thalline composition that they have, have as the integral part of enzymic activity base or keep the activity of enzyme, adjusting oxidation one reduction potential that has, the energy that has as autotrophic bacteria, by the normal fermentation of microorganism essential.In the composite growth element that adds, contain multiple vitamin B group and trace element, certain micro-organisms can not synthesize one or more micro-organic compound then must be supplied with by external source, and these VITAMIN are integral parts of the active group of plurality of enzymes, without them, enzyme is just stiff.As V
B1Biological function be oxidative decarboxylation, the ketone group transferance of α ketone acid, essential by many microorganism growth, the biological function of pantothenic acid is an acyl migration; more bacterium and yeast need external source to supply with; nicotinic acid is hydrogen carrier, catalytic oxidation-reduction reaction, for microorganism all over needs, and V
B6Be the coenzyme of amino acid racemase, glutamic-pyruvic transaminase and decarboxylase, many milk-acid bacterias and fungi are required, V
B12Be the transmission of a carbon back, vitamin H is that fatty acid biological is synthetic, and β decarboxylation, cobalt be the carrier of hydrogen atom fixedly, and the general something lost of many microorganisms needs, and trace elements such as copper, iron, zinc, manganese, selenium, cobalt all play an important role in the activity of microorganism, and cobalt is V
B12One of composition, lacked then V of cobalt
B12Can not synthesize, selenium is the active group of hydrogenlyase glycine reductase enzyme, and zinc is the active group of alcoholdehydrogenase, serum lactic dehydrogenase, and the activator of zymohexase, manganese are superoxide dismutase, the active group of phosphoric acid enol pyruvic acid carboxylase Hydratase, phosphoenolpyruvate etc.On the basis of natural wide spectrum bacterial classification.The active ingredient that adds has not only saved loaded down with trivial details operations such as sterilization of fermentation material or adding inhibitor, has overcome its negative effect, has reduced cost, also can just form the superiority of probiotics in fermentation in early days, suppresses the harmful microbe activity.
Embodiment 1:
The organotrophy material is allotted in following ratio: corn stalk 40%, sawdust 20%, vinasse 15%, wheat bran 10%, Semen Maydis powder 10%, soya-bean cake 5%;
Per 100 kilograms of organotrophy material mix 6 kilograms of following ratios of inorganic nutrients material and allot: 1.5 kilograms of carbon ammoniums, 1.5 kilograms in urea, 1 kilogram of calcium superphosphate, 1.5 kilograms of diammonium phosphate, 0.2 kilogram of vitriolate of tartar, 0.1 kilogram in sodium sulfate, 0.1 kilogram in sal epsom, 0.1 kilogram in sulphur;
Per 100 kilograms of organotrophy material add 1 kilogram of composite growth element in the culture base-material, and its ratio is: V
B1100 grams, calcium pantothenate 120 grams, nicotinic acid 200 grams, V
B6Gram, vitamin H 300 grams, V
B12150 grams, courage cash 20 grams, Sodium Selenite 20 grams, cobalt chloride 40 grams;
1 kilogram in actinomycetes that add live bacteria agent in per 100 kilograms of organotrophy material.
Producing operation after each material is assorted does not repeat as previously mentioned.
Embodiment 2:
Organotrophy material ratio is: sawdust 20%, beet pulp 40%, corn stalk 10%, vinasse 10%, Semen Maydis powder 8%, cow dung 12%;
Per 100 kilograms of organotrophy material mix 8 kilograms of inorganic nutrients material, its ratio is: 2 kilograms of carbon ammoniums, 3 kilograms in urea, 1.5 kilograms of calcium superphosphate, 1 kilogram of diammonium phosphate, 0.1 kilogram of vitriolate of tartar, 0.1 kilogram in sodium sulfate, 0.2 kilogram in sal epsom, 0.1 kilogram in sulphur.
Composite growth is plain to add 0.5 kilogram by per 100 kilograms of organotrophy material, and its ratio is: V
B150 grams, calcium pantothenate 150 grams, nicotinic acid 70 grams, V
B630 grams, vitamin H 140 grams, V
B1220 grams, courage cash 20 grams, Sodium Selenite 10 grams, cobalt chloride 10 grams.
Live bacteria agent adopts actinomycetes to mix 1.5 kilograms by per 100 kilograms of organotrophy material.
After material was assorted, it produced operation by preceding described the carrying out of literary composition.
Embodiment 3:
The organotrophy material is allotted in following each material ratio: sawdust 30%, bagasse 20%, corn stalk 10%, vinasse 20%, rice bran 10%, cottonseed cake 5%, cow dung 5%;
The inorganic nutrients material mixes 10 kilograms by per 100 kilograms of organotrophy material and allots, and its ratio is: 2.5 kilograms of carbon ammoniums, 3.5 kilograms in urea, 1.5 kilograms of calcium superphosphate.2 kilograms of diammonium phosphate, 0.1 kilogram of vitriolate of tartar, 0.2 kilogram in sodium sulfate, 0.1 kilogram in sal epsom, 0.1 kilogram in sulphur;
The composite growth element mixes 0.1 kilogram by per 100 kilograms of organotrophy material and allots, and its ratio is as follows: V
B110 grams, calcium pantothenate 20 grams, nicotinic acid 10 grams, V
B65 grams, vitamin H 10 grams, V
B1210 grams, courage cash 20 grams, Sodium Selenite 5 grams, cobalt chloride 10 grams;
Live bacteria agent adopts actinomycetes to mix 2 kilograms of ratios in per 100 kilograms of organotrophy material and allots.
After material is assorted, produce operation by preceding described carrying out.
Claims (5)
1, comprise the preparation method of a kind of agricultural biochemical humic acid compound of organic nutrilite, inorganic nutrients material and composite growth element, it is characterized by: also comprise active bacteria formulation, its component is by weight proportion: organotrophy material 100; Inorganic nutrients material 5～15; Composite growth element 0.5～2; Active ingredient 0.5～2;
It produces operation:
A. base-material is pulverized: at first organotrophy material and inorganic nutrients material are pulverized after 20～40 mesh sieves sieve with pulverizer;
B. batch mixing stirs: add suitable quantity of water and stir;
C. regulating pH value is 5～7.5;
D. add growth hormone and inoculate active bacteria formulation;
E. charging fermentation: put into the fermentation vat fermentation, keep 60 ℃～70 ℃ constant temperature, keep fermentation 7～15 days;
F. discharging: the material of finishing fermentation takes out cooling;
G. be dried to the former powder of moisture≤15%.
2, the preparation method of a kind of agricultural biochemical humic acid compound according to claim 1 is characterized by: also comprise poor slag in its organotrophy material.
3, the preparation method of a kind of agricultural biochemical humic acid compound according to claim 1 and 2 is characterized by: its inorganic nutrients material also comprises major element calcium, magnesium, sulphur.
4, the preparation method of a kind of agricultural biochemical humic acid compound according to claim 1 and 2 is characterized by: its composite growth element also comprises trace copper, iron, zinc, manganese, selenium, cobalt.
5, according to the preparation method of claim 1 or 3 described a kind of agricultural biochemical humic acid compounds, it is characterized by: its composite growth element also comprises trace copper, iron, zinc, manganese, selenium, cobalt.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 97118762 CN1182797A (en) | 1997-10-08 | 1997-10-08 | Method for preparing agricultural biochemical humic acid compound |
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| CN 97118762 CN1182797A (en) | 1997-10-08 | 1997-10-08 | Method for preparing agricultural biochemical humic acid compound |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102942396A (en) * | 2012-11-28 | 2013-02-27 | 宁夏共享集团有限责任公司 | Method for producing water-soluble fertilizers with biochemical humic acid |
| CN103819238A (en) * | 2014-01-28 | 2014-05-28 | 南宁普田润生物有机肥有限公司 | Whole organic culture medium and preparation method thereof |
| CN104692935A (en) * | 2015-02-13 | 2015-06-10 | 广西福星化肥有限责任公司 | Compound fertilizer and preparation method thereof |
| CN104909880A (en) * | 2015-05-27 | 2015-09-16 | 句容市茅山盛开园林有限公司 | Fertilizer for garden and park plants, and preparation method thereof |
-
1997
- 1997-10-08 CN CN 97118762 patent/CN1182797A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102942396A (en) * | 2012-11-28 | 2013-02-27 | 宁夏共享集团有限责任公司 | Method for producing water-soluble fertilizers with biochemical humic acid |
| CN102942396B (en) * | 2012-11-28 | 2014-08-20 | 宁夏共享集团有限责任公司 | Method for producing water-soluble fertilizers with biochemical humic acid |
| CN103819238A (en) * | 2014-01-28 | 2014-05-28 | 南宁普田润生物有机肥有限公司 | Whole organic culture medium and preparation method thereof |
| CN103819238B (en) * | 2014-01-28 | 2016-03-09 | 南宁普田润生物有机肥有限公司 | A kind of all organic cultivation medium and preparation method thereof |
| CN104692935A (en) * | 2015-02-13 | 2015-06-10 | 广西福星化肥有限责任公司 | Compound fertilizer and preparation method thereof |
| CN104909880A (en) * | 2015-05-27 | 2015-09-16 | 句容市茅山盛开园林有限公司 | Fertilizer for garden and park plants, and preparation method thereof |
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