CN102942396B - Method for producing water-soluble fertilizers with biochemical humic acid - Google Patents
Method for producing water-soluble fertilizers with biochemical humic acid Download PDFInfo
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- CN102942396B CN102942396B CN201210491270.8A CN201210491270A CN102942396B CN 102942396 B CN102942396 B CN 102942396B CN 201210491270 A CN201210491270 A CN 201210491270A CN 102942396 B CN102942396 B CN 102942396B
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- humic acid
- soluble fertilizer
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- acid water
- fertilizers
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- 239000003337 fertilizer Substances 0.000 title claims abstract description 59
- 239000004021 humic acid Substances 0.000 title claims abstract description 35
- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 title claims abstract description 33
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 22
- 239000000463 material Substances 0.000 claims abstract description 30
- 238000002360 preparation method Methods 0.000 claims abstract description 20
- 238000000855 fermentation Methods 0.000 claims abstract description 17
- 230000004151 fermentation Effects 0.000 claims abstract description 17
- 238000000034 method Methods 0.000 claims abstract description 13
- 238000006243 chemical reaction Methods 0.000 claims abstract description 12
- 241000894006 Bacteria Species 0.000 claims abstract description 10
- 230000008569 process Effects 0.000 claims abstract description 4
- 150000001875 compounds Chemical class 0.000 claims description 23
- 239000003795 chemical substances by application Substances 0.000 claims description 17
- 239000000047 product Substances 0.000 claims description 17
- 230000003750 conditioning effect Effects 0.000 claims description 13
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical group [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 12
- 239000000843 powder Substances 0.000 claims description 12
- 210000003608 fece Anatomy 0.000 claims description 9
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 8
- 238000001704 evaporation Methods 0.000 claims description 7
- 230000008020 evaporation Effects 0.000 claims description 7
- 230000003203 everyday effect Effects 0.000 claims description 7
- 239000002068 microbial inoculum Substances 0.000 claims description 7
- 238000012856 packing Methods 0.000 claims description 7
- 239000010902 straw Substances 0.000 claims description 7
- 239000006228 supernatant Substances 0.000 claims description 7
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims description 6
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 6
- 239000000284 extract Substances 0.000 claims description 6
- 239000010871 livestock manure Substances 0.000 claims description 6
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims description 6
- 241001465754 Metazoa Species 0.000 claims description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 4
- 229940037003 alum Drugs 0.000 claims description 4
- 239000002518 antifoaming agent Substances 0.000 claims description 4
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 claims description 4
- 235000013305 food Nutrition 0.000 claims description 4
- 229920001296 polysiloxane Polymers 0.000 claims description 4
- 239000011591 potassium Substances 0.000 claims description 4
- 229910052700 potassium Inorganic materials 0.000 claims description 4
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims description 3
- YASYEJJMZJALEJ-UHFFFAOYSA-N Citric acid monohydrate Chemical compound O.OC(=O)CC(O)(C(O)=O)CC(O)=O YASYEJJMZJALEJ-UHFFFAOYSA-N 0.000 claims description 3
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 3
- 241000287828 Gallus gallus Species 0.000 claims description 3
- 229910019142 PO4 Inorganic materials 0.000 claims description 3
- 241001494479 Pecora Species 0.000 claims description 3
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 3
- 241000209140 Triticum Species 0.000 claims description 3
- 235000021307 Triticum Nutrition 0.000 claims description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 3
- 240000008042 Zea mays Species 0.000 claims description 3
- 235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 claims description 3
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims description 3
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 claims description 3
- PYCBFXMWPVRTCC-UHFFFAOYSA-N ammonium metaphosphate Chemical compound N.OP(=O)=O PYCBFXMWPVRTCC-UHFFFAOYSA-N 0.000 claims description 3
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 3
- 239000004327 boric acid Substances 0.000 claims description 3
- 235000010338 boric acid Nutrition 0.000 claims description 3
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical group [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 3
- 239000004202 carbamide Substances 0.000 claims description 3
- 229960002303 citric acid monohydrate Drugs 0.000 claims description 3
- 239000013530 defoamer Substances 0.000 claims description 3
- -1 double superhosphate Chemical compound 0.000 claims description 3
- 239000004571 lime Substances 0.000 claims description 3
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims description 3
- 235000019341 magnesium sulphate Nutrition 0.000 claims description 3
- 235000009973 maize Nutrition 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 3
- 239000010452 phosphate Substances 0.000 claims description 3
- 229920000570 polyether Polymers 0.000 claims description 3
- 239000004323 potassium nitrate Substances 0.000 claims description 3
- 235000010333 potassium nitrate Nutrition 0.000 claims description 3
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 claims description 3
- 229910052939 potassium sulfate Inorganic materials 0.000 claims description 3
- 235000011151 potassium sulphates Nutrition 0.000 claims description 3
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims description 3
- 229910000368 zinc sulfate Inorganic materials 0.000 claims description 3
- 229960001763 zinc sulfate Drugs 0.000 claims description 3
- URDCARMUOSMFFI-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]ethyl-(2-hydroxyethyl)amino]acetic acid Chemical compound OCCN(CC(O)=O)CCN(CC(O)=O)CC(O)=O URDCARMUOSMFFI-UHFFFAOYSA-N 0.000 claims description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 2
- FCKYPQBAHLOOJQ-UHFFFAOYSA-N Cyclohexane-1,2-diaminetetraacetic acid Chemical compound OC(=O)CN(CC(O)=O)C1CCCCC1N(CC(O)=O)CC(O)=O FCKYPQBAHLOOJQ-UHFFFAOYSA-N 0.000 claims description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 2
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 claims description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 2
- 229910021538 borax Inorganic materials 0.000 claims description 2
- 239000001110 calcium chloride Substances 0.000 claims description 2
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 2
- 235000011148 calcium chloride Nutrition 0.000 claims description 2
- 239000008139 complexing agent Substances 0.000 claims description 2
- 229910000365 copper sulfate Inorganic materials 0.000 claims description 2
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims description 2
- 229960003280 cupric chloride Drugs 0.000 claims description 2
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims description 2
- PZZHMLOHNYWKIK-UHFFFAOYSA-N eddha Chemical compound C=1C=CC=C(O)C=1C(C(=O)O)NCCNC(C(O)=O)C1=CC=CC=C1O PZZHMLOHNYWKIK-UHFFFAOYSA-N 0.000 claims description 2
- 239000011790 ferrous sulphate Substances 0.000 claims description 2
- 235000003891 ferrous sulphate Nutrition 0.000 claims description 2
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims description 2
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims description 2
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 claims description 2
- 235000006408 oxalic acid Nutrition 0.000 claims description 2
- 239000004328 sodium tetraborate Substances 0.000 claims description 2
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 2
- 239000002689 soil Substances 0.000 abstract description 17
- 201000010099 disease Diseases 0.000 abstract description 9
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 abstract description 9
- 230000000694 effects Effects 0.000 abstract description 8
- 235000016709 nutrition Nutrition 0.000 abstract description 6
- 230000035764 nutrition Effects 0.000 abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 4
- 241000607479 Yersinia pestis Species 0.000 abstract description 3
- 230000035558 fertility Effects 0.000 abstract description 3
- 239000003607 modifier Substances 0.000 abstract 2
- 208000035240 Disease Resistance Diseases 0.000 abstract 1
- 241000238631 Hexapoda Species 0.000 abstract 1
- 230000037208 balanced nutrition Effects 0.000 abstract 1
- 235000019046 balanced nutrition Nutrition 0.000 abstract 1
- 238000001816 cooling Methods 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 239000011159 matrix material Substances 0.000 abstract 1
- 238000004806 packaging method and process Methods 0.000 abstract 1
- 230000002085 persistent effect Effects 0.000 abstract 1
- 238000003756 stirring Methods 0.000 abstract 1
- 230000009469 supplementation Effects 0.000 abstract 1
- 238000005303 weighing Methods 0.000 abstract 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 238000003973 irrigation Methods 0.000 description 4
- 230000002262 irrigation Effects 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 3
- 230000000844 anti-bacterial effect Effects 0.000 description 3
- 230000002045 lasting effect Effects 0.000 description 3
- 239000003895 organic fertilizer Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 238000013270 controlled release Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 241000244206 Nematoda Species 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 230000012010 growth Effects 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 238000009335 monocropping Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 231100000957 no side effect Toxicity 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 208000015380 nutritional deficiency disease Diseases 0.000 description 1
- 230000000050 nutritive effect Effects 0.000 description 1
- 238000009329 organic farming Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000002686 phosphate fertilizer Substances 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 230000008635 plant growth Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000000452 restraining effect Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000011573 trace mineral Substances 0.000 description 1
- 235000013619 trace mineral Nutrition 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/40—Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse
Landscapes
- Fertilizers (AREA)
Abstract
The invention relates to a method for producing water-soluble fertilizers, in particular to a method for producing the water-soluble fertilizers with biochemical humic acid. The method is characterized by including matrix fermentation, concentrated liquor preparation and finished product preparation: firstly, weighing prepared concentrated liquor; secondly, adding modifiers, heating and stirring the liquor in the whole process, controlling the temperature to range from 40 DEG C to 60 DEG C, and cooling the liquor to be below 30 DEG C after reaction to obtain the fertilizers; and thirdly, packaging the fertilizers. The mass ratio of the concentrated liquor, the modifiers and inorganic auxiliary materials is (55-80): (0.1-2): (20-45). The method is simple in manufacture, easy in operation and high in actionability, solves the problem of water solubility of organic fertilizers, provides nutrition, improves soil, prevents diseases and insect pests, and integrates the effects of fertilizer supplementation, bacterium resistance and disease resistance. The fertilizers have balanced nutrition, stable state and persistent fertilizer effects, crop yield can be remarkably improved, the quality of agricultural products is improved, and soil fertility is enhanced.
Description
Technical field
The present invention relates to a kind of production method of water-soluble fertilizer, especially relate to a kind of production method of biochemical humic acid water-soluble fertilizer.
Background technology
At home, due to life-time service chemical fertilizer, cause Soil degradation, soil fertility weakens, and quality of agricultural product declines, and brings hidden danger to food safety and HUMAN HEALTH.Promote the use of organic fertilizer, it is imperative that soil is improved.Especially the proposition of universal and " water-fertilizer integral " irrigation technique of industrialized agriculture, the novel fertilizer application mode that drip irrigation and spray irrigation etc. have remarkable water-saving function starts to be paid attention to and promote, the demand to water-soluble fertilizer of high-efficiency agriculture increases considerably, thereby contain humic acid water-soluble fertilizer as a kind of organic-inorganic mixed type water soluble fertilizer, be the trend of modern agricultural development.Yet existing machine class fertilizer exists water-soluble problem, can not realize supplementary fertilizer, antibacterial, disease-resistant three large effects in one, and state labile, fertilizer efficiency are not lasting.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art, provide a kind of make simple, easy to operate, exploitativeness is high, solve organic fertilizer water-soluble problem, nutrition, improvement soil, preventing disease and pest be provided, realize supplementary fertilizer, antibacterial, disease-resistant three large effects in one, balanced in nutrition, in stable condition, fertilizer efficiency lasting, can significantly improve crop yield, improve quality of agricultural product, strengthen the production method of a kind of biochemical humic acid water-soluble fertilizer of soil fertility.
In order to realize goal of the invention, the present invention realizes in the following way:
A production method for biochemical humic acid water-soluble fertilizer, is characterized in that: the method comprises the steps:
A, base-material fermentation: take 70%～80% stalk as basic material, add again 20%～30% excrement of animals, 1%～2% conditioning agent, then BM microbial inoculum is evenly admixed in compound, the mass ratio of compound and bacterium powder is 1000～2000:1, regulate moisture content to 50～55% of compound, pile in fermentation vat and ferment.Temperature is elevated to after 50 ℃, and machinery turning every day once;
B, concentrated solution preparation: by above-mentioned base-material completely and 2.0%～5.0% dilute alkaline soln 1:(5～8 in mass ratio of becoming thoroughly decomposed) mix, heated and stirred, temperature is controlled at 60～70 ℃, reaction 2～4h, extract supernatant liquor, and carry out evaporation concentration, remove 20%～40% moisture;
C, finished product preparation: the concentrated solution that first takes above-mentioned preparation, add again conditioning agent, the mass ratio of concentrated solution, conditioning agent and inorganic auxiliary material is (55～80): (0.1～2): (20～45), whole process heated and stirred, temperature is controlled at 40～60 ℃, after having reacted, is cooled to below 30 ℃, obtain this product, packing;
Described excrement of animals is sheep excrement, cow dung, chicken manure or pig manure;
Described stalk is maize straw, wheat stalk or straw;
Described inorganic conditioning agent is terra alba, lime powder or black alum;
Described diluted alkaline is sodium hydroxide, potassium hydroxide or ammoniacal liquor;
Described conditioning agent be in Citric acid monohydrate Food grade, sulfuric acid, oxalic acid, hydrochloric acid, T-1000A polyethers suds suppressor, T-30F silicone antifoam agent or GPE type defoamer one or both;
Described inorganic auxiliary material is two kinds, three kinds or multiple in ammonium nitrate, saltpetre, urea, primary ammonium phosphate, ammonium hydrogen phosphate, potassium primary phosphate, ammonium metaphosphate, potassium sulfate, double superhosphate, Repone K, magnesium sulfate, calcium chloride, borax, boric acid, ferrous sulfate, complexing agent (EDTA, DTPA, CDTA, EDDHA, HEEDTA), chelated iron (EDTA-2NaFe), zinc sulfate, manganous sulfate, copper sulfate or cupric chloride.
The present invention has following effect:
1) simple, easy to operate, exploitativeness is high, solve the water-soluble problem of organic fertilizer: production method provided by the invention comprises three parts, it is respectively base-material fermentation, concentrated solution preparation, finished product preparation: base-material fermentation: take 70%～80% stalk as basic material, add again 20%～30% excrement of animals, 1%～2% conditioning agent, then BM microbial inoculum is evenly admixed in compound, the mass ratio of compound and bacterium powder is 1000～2000:1, regulate moisture content to 50～55% of compound, pile in fermentation vat and ferment.Temperature is elevated to after 50 ℃, and machinery turning every day once; Concentrated solution preparation: by base-material completely and 2.0%～5.0% dilute alkaline soln 1:(5～8 in mass ratio of becoming thoroughly decomposed) mix, heated and stirred, temperature is controlled at 60～70 ℃, reaction 2～4h, extraction supernatant liquor, and carry out evaporation concentration, remove 20%～40% moisture; Finished product preparation first takes concentrated solution, then adds conditioning agent, and the mass ratio of concentrated solution, conditioning agent and inorganic auxiliary material is (55～80): (0.1～2): (20～45).Whole process heated and stirred, temperature is controlled at 40～60 ℃.After having reacted, be cooled to below 30 ℃ packing.
2) realize supplementary fertilizer, antibacterial, disease-resistant three large effects in one, balanced in nutrition, in stable condition, fertilizer efficiency is lasting: product application modern biotechnology provided by the invention, take plant slag body as raw material, through biological fermentation, produce the material of class coalification humic acids, except the xanthohumic acid of tool activity, also contain amino acid and multiple other physiologically active components of some amount.There is the functions such as saving water, resisting drought, nutrient controlled release and ecological regulation and control, in modern fertiliser production, be mainly used in aspect five of Controlled Release Fertilizers, activated phosphate fertilizer, an organic inorganic composite fertilizer, highly effective trace fertilizer, diseases prevention bio-feritlizer.Containing humic acid water-soluble fertilizer, be that mineral humic acids or biochemical humic acid are carried out after activation treatment, then add a kind of full nutrition, multi-functional readily avaiable fertilizer that solubility macroelement and other plant growth desired substances form, have aqua and the large class of pulvis two.
3) provide nutrition: biochemical humic acid water-soluble fertilizer provided by the invention provides the azophoska of quick-acting equilibriums and appropriate middle trace element for crop; Supply several physiological active substances simultaneously, stimulate crop growth and body physiological metabolism.
4) improvement soil: biochemical humic acid water-soluble fertilizer provided by the invention waters in soil, stationary state nutritive element in energy activating soil, the loose soil that hardens, and the performance that can effectively strengthen its ventilation, lead to oxygen.To saline-alkali soil, Baijiang soil, all can play the effect that regulates Soil structure, balance soil acidity or alkalinity.
5) preventing disease and pest: biochemical humic acid water-soluble fertilizer provided by the invention promotes that crop root is flourishing, robust plant, removes that rice shoot ossifys, yellow and contracting seedling; The nutritional deficiency diseases such as prevention leaflet, Huang Ye, leaf roll.Soil-borne disease of crop is had to obvious restraining effect, suppress nematode, high resistance continuous cropping, increases crop disease-resistant resistance.
6) synergy chemical fertilizer: the use of biochemical humic acid water-soluble fertilizer provided by the invention can reduce nitrogen volatilization loss, suppresses soil to quick-acting phosphorus fixations, discharges the potassium element in soil, and increases the K uptake of plant, improves the utilization ratio of azophoska.
7) biochemical humic acid water-soluble fertilizer provided by the invention can be supporting drip irrigation facility realize " water-fertilizer integral " and irrigate, use flexibly, simple to operate, saving of labor, save time, economize on water, pollution-free, have no side effect, be that development is green, the superior prod of Organic farming.
Embodiment
Embodiment mono-: a kind of production method of biochemical humic acid water-soluble fertilizer, the method comprises the steps:
A, base-material fermentation: 70% the maize straw of take is basic material, add 29% cow dung, 1% terra alba again, then BM microbial inoculum is evenly admixed in compound, the mass ratio of compound and bacterium powder is 1000:1, regulate the moisture content to 50% of compound, pile in fermentation vat and ferment.Temperature is elevated to after 50 ℃, and machinery turning every day once;
B, concentrated solution preparation: the sodium hydroxide solution that base-material is 2.0% with concentration completely by becoming thoroughly decomposed in mass ratio 1:8 mixes, heated and stirred, temperature is controlled at 60 ℃, and reaction 2h, extracts supernatant liquor, and evaporation concentration is removed 40% moisture;
C, finished product preparation: in reactor, add the above-mentioned concentrated solution that need make containing humic acid water-soluble fertilizer quality 55%, add respectively again the Citric acid monohydrate Food grade that need make containing humic acid water-soluble fertilizer quality 1. 9%, 0.1% T-1000A polyethers suds suppressor, 26.0% urea, 7.5% primary ammonium phosphate, 9.5% potassium sulfate, heated and stirred, control temperature at 50 ℃, reaction 45min.After having reacted, be cooled to, below 30 ℃, obtain this product packing.
Embodiment bis-: a kind of production method of biochemical humic acid water-soluble fertilizer, the method comprises the steps:
A, base-material fermentation: 78% the straw of take is basic material, add again 20.5% chicken manure, 1.5% lime powder, BM bacterium powder is evenly admixed to compound, then BM microbial inoculum is evenly admixed in compound, the mass ratio of compound and bacterium powder is 2000:1, regulate the moisture content to 55% of compound, pile in fermentation vat and ferment.Temperature is elevated to after 50 ℃, and machinery turning every day once;
B, concentrated solution preparation: the potassium hydroxide solution that base-material is 4.8% with concentration completely by becoming thoroughly decomposed in mass ratio 1:5 mixes, heated and stirred, temperature is controlled at 70 ℃, and reaction 3h, extracts supernatant liquor, and evaporation concentration is removed 20% moisture;
C, finished product preparation: in reactor, add the above-mentioned concentrated solution that need make containing humic acid water-soluble fertilizer quality 70%, add respectively again T-30F silicone antifoam agent, 16.4% ammonium nitrate, 13.5% potassium primary phosphate that need make containing humic acid water-soluble fertilizer quality 0.1%, heated and stirred, control temperature at 40 ℃, reaction 45min; After having reacted, be cooled to, below 30 ℃, obtain this product packing.
Embodiment tri-: a kind of production method of biochemical humic acid water-soluble fertilizer, the method comprises the steps:
A, base-material fermentation: 73% the wheat stalk of take is basic material, add 25% sheep excrement, 2% black alum again, then BM microbial inoculum is evenly admixed in compound, the mass ratio of compound and bacterium powder is 1600:1, regulate the moisture content to 55% of compound, pile in fermentation vat and ferment.Temperature is elevated to after 50 ℃, and machinery turning every day once;
B, concentrated solution preparation: the potassium hydroxide solution that base-material is 3.0% with concentration completely by becoming thoroughly decomposed in mass ratio 1:7 mixes, heated and stirred, temperature is controlled at 65 ℃, and reaction 4h, extracts supernatant liquor, and evaporation concentration is removed 30% moisture;
C, finished product preparation: in reactor, add the concentrated solution that need make containing humic acid water-soluble fertilizer quality 63.8 %, add respectively again the sulfuric acid that need make containing humic acid water-soluble fertilizer quality 1%, 0.2% GPE type defoamer, 23% saltpetre, 7% ammonium metaphosphate, 5% magnesium sulfate, heated and stirred, control temperature at 60 ℃, reaction 45min, after having reacted, is cooled to below 30 ℃, obtain this product, packing.
Embodiment tetra-: a kind of production method of biochemical humic acid water-soluble fertilizer, the method comprises the steps:
A, base-material fermentation: 75% the straw of take is basic material, add again 24% pig manure, 1% black alum, BM bacterium powder is evenly admixed to compound, then BM microbial inoculum is evenly admixed in compound, the mass ratio of compound and bacterium powder is 1500:1, regulate the moisture content to 55% of compound, pile in fermentation vat and ferment.Temperature is elevated to after 50 ℃, and machinery turning every day once;
B, concentrated solution preparation: the sodium hydroxide solution that base-material is 2.5% with concentration completely by becoming thoroughly decomposed in mass ratio 1:7 mixes, heated and stirred, temperature is controlled at 70 ℃, and reaction 3h, extracts supernatant liquor, and evaporation concentration is removed 30% moisture;
C, finished product preparation: in reactor, add the above-mentioned concentrated solution that need make containing humic acid water-soluble fertilizer quality 80%, add respectively again T-30F silicone antifoam agent, 5% boric acid, 9.9% zinc sulfate, 5% chelated iron that need make containing humic acid water-soluble fertilizer quality 0.1%, heated and stirred, control temperature at 40 ℃, reaction 45min; After having reacted, be cooled to, below 30 ℃, obtain this product packing.
Claims (7)
1. a production method for biochemical humic acid water-soluble fertilizer, is characterized in that: the method comprises the steps:
A, base-material fermentation: take 70%～80% stalk as basic material, add again 20%～30% excrement of animals, 1%～2% inorganic conditioning agent, then BM microbial inoculum is evenly admixed in compound, the mass ratio of compound and bacterium powder is 1000～2000:1, regulate moisture content to 50～55% of compound, pile in fermentation vat and ferment, temperature is elevated to after 50 ℃, and machinery turning every day once;
B, concentrated solution preparation: by above-mentioned base-material completely and 2.0%～5.0% dilute alkaline soln 1:(5～8 in mass ratio of becoming thoroughly decomposed) mix, heated and stirred, temperature is controlled at 60～70 ℃, reaction 2～4h, extract supernatant liquor, and carry out evaporation concentration, remove 20%～40% moisture;
C, finished product preparation: the concentrated solution that first takes above-mentioned preparation, add again conditioning agent and auxiliary material, the mass ratio of concentrated solution, conditioning agent and auxiliary material is (55～80): (0.1～2): (20～45), whole process heated and stirred, temperature is controlled at 40～60 ℃, after having reacted, is cooled to below 30 ℃, obtain this product, packing.
2. the production method of a kind of biochemical humic acid water-soluble fertilizer as claimed in claim 1, is characterized in that: described excrement of animals is sheep excrement, cow dung, chicken manure or pig manure.
3. the production method of a kind of biochemical humic acid water-soluble fertilizer as claimed in claim 1, is characterized in that: described stalk is maize straw, wheat stalk or straw.
4. the production method of a kind of biochemical humic acid water-soluble fertilizer as claimed in claim 1, is characterized in that: described inorganic conditioning agent is terra alba, lime powder or black alum.
5. the production method of a kind of biochemical humic acid water-soluble fertilizer as claimed in claim 1, is characterized in that: described diluted alkaline is sodium hydroxide, potassium hydroxide or ammoniacal liquor.
6. the production method of a kind of biochemical humic acid water-soluble fertilizer as claimed in claim 1, is characterized in that: described conditioning agent be in Citric acid monohydrate Food grade, sulfuric acid, oxalic acid, hydrochloric acid, T-1000A polyethers suds suppressor, T-30F silicone antifoam agent or GPE type defoamer one or both.
7. the production method of a kind of biochemical humic acid water-soluble fertilizer as claimed in claim 1, is characterized in that: described auxiliary material is that ammonium nitrate, saltpetre, urea, primary ammonium phosphate, ammonium hydrogen phosphate, potassium primary phosphate, ammonium metaphosphate, potassium sulfate, double superhosphate, Repone K, magnesium sulfate, calcium chloride, borax, boric acid, ferrous sulfate, complexing agent are selected from two kinds, three kinds or multiple in EDTA, DTPA, CDTA, EDDHA, HEEDTA, EDTA-2NaFe, zinc sulfate, manganous sulfate, copper sulfate or cupric chloride.
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