CN118124234A - Heat reflection aerogel PET composite heat insulation board and preparation method thereof - Google Patents

Heat reflection aerogel PET composite heat insulation board and preparation method thereof Download PDF

Info

Publication number
CN118124234A
CN118124234A CN202410249316.8A CN202410249316A CN118124234A CN 118124234 A CN118124234 A CN 118124234A CN 202410249316 A CN202410249316 A CN 202410249316A CN 118124234 A CN118124234 A CN 118124234A
Authority
CN
China
Prior art keywords
aerogel
insulation board
pet
modified layer
inorganic adhesive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202410249316.8A
Other languages
Chinese (zh)
Inventor
朱秦江
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN202410249316.8A priority Critical patent/CN118124234A/en
Publication of CN118124234A publication Critical patent/CN118124234A/en
Pending legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A30/00Adapting or protecting infrastructure or their operation
    • Y02A30/24Structural elements or technologies for improving thermal insulation
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02BCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
    • Y02B80/00Architectural or constructional elements improving the thermal performance of buildings
    • Y02B80/10Insulation, e.g. vacuum or aerogel insulation

Landscapes

  • Building Environments (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention relates to the technical field of covering or lining made of organic plastics with or without reinforcing materials or filling materials, and discloses a heat reflection aerogel PET composite heat-insulation board and a preparation method thereof. Meanwhile, the thermal deformation difference between the inorganic adhesive and the foamed PET substrate is large, and the adhesive film is cracked and falls off due to temperature stress. Based on this finding, the inventors improved the ductility of the adhesive film by adding aerogel powder so that it was not easily broken when subjected to shearing force, and the thermal deformation amount was consistent with that of the foamed PET substrate, and the subsequent construction was allowed to be performed on the aerogel modified layer without difficulty. Meanwhile, the aerogel modified layer has fire resistance, water resistance, mildew resistance and infrared reflectivity of more than 0.85, so that the fire resistance and heat insulation performance of the composite heat insulation board are obviously improved.

Description

Heat reflection aerogel PET composite heat insulation board and preparation method thereof
Technical Field
The invention relates to the technical field of covering or lining made of organic plastics with or without reinforcements or filling materials, in particular to a heat reflection aerogel PET composite heat insulation board and a preparation method thereof.
Background
Aerogel is a novel heat insulation material, and the heat insulation effect is far better than that of other types of heat insulation materials. The pore inside the aerogel is an open pore, and the pore diameter is 20-50 nanometers. Aerogel products on the market exist mainly in the form of aerogel powder and aerogel felt.
Foamed PET panels, i.e. building panels made of foamed polyester plastic. The raw materials are widely available and can be waste mineral water bottles, so that the effect of waste utilization is achieved. And different from other building heat insulation materials, the foaming PET plate has good mechanical strength and can be used as a stress member.
However, the foamed PET sheet itself has a very difficult disadvantage to overcome, in that it is difficult to connect with other building materials:
And (3) organic adhesive connection: due to the chemical nature of the foaming PET plate, the adhesive film formed by the aqueous organic adhesive and the foaming PET plate cannot be effectively combined, and the adhesive film and the foaming PET plate are separated from each other after being solidified; oily organic adhesives can cause corrosion to the foamed PET sheet.
And (3) cement mortar connection: the bonding between the foamed PET plate and the cement mortar is very weak, and the adhesive force is less than 0.1 megapascal.
And (3) inorganic adhesive connection: the inorganic adhesive has better adhesive force than cement mortar, but the connection is very easy to lose efficacy, and after other building components are adhered to the foaming PET plate by using the inorganic adhesive, the inorganic adhesive can be expanded with heat and contracted with cold or repeatedly pulled for a plurality of times, and then the inorganic adhesive falls off.
And (3) mechanical connection: the mechanical connectors such as bolts are difficult to seal in holes (gaps exist around the holes) after penetrating the foamed PET sheet, because conventional materials for sealing building boards are also adhesive or cement mortar in nature. If the foamed PET plate is used on the outer wall of a building, the mechanical connection may cause water leakage of the building.
For the above reasons, the existing foamed PET board is greatly limited in application, and the subsequent use scenes such as building wallboard, which need decoration or electromechanical construction on the board, are not suitable for using the foamed PET board.
Disclosure of Invention
The invention provides a heat reflection aerogel PET composite heat-insulating board and a preparation method thereof.
The technical problems to be solved are as follows: the foamed PET board is difficult to connect with other building materials and is not suitable for application in subsequent use scenarios requiring decoration or electromechanical construction on the board.
In order to solve the technical problems, the invention adopts the following technical scheme: the heat reflection aerogel PET composite heat insulation board comprises a foaming PET substrate and aerogel modified layers coated on two side board surfaces of the foaming PET substrate, wherein an anti-cracking net for preventing cracks of the aerogel modified layers from being prolonged is buried in the aerogel modified layers;
the aerogel modified layer is an inorganic adhesive doped with aerogel powder and is in a bendable foaming material state.
Further, the aerogel-modified layer has an infrared reflectance of not less than 0.85.
Further, the inorganic adhesive is a silicate adhesive.
Further, the aerogel powder is silica aerogel powder.
Further, the closed cell ratio of the foamed PET substrate is not less than 85%.
Further, the anti-cracking net is basalt gridding cloth or carbon fiber gridding cloth.
A preparation method of a heat reflection aerogel PET composite heat insulation board is characterized by comprising the following steps: the aerogel PET composite heat-insulating plate for preparing the aerogel PET composite heat-insulating plate convenient for subsequent construction comprises the following steps of:
step one: stirring and mixing the aerogel powder and the inorganic adhesive;
Step two: coating an inorganic adhesive containing aerogel powder on the upper plate surface of a horizontally-laid foamed PET substrate to form an aerogel modified layer, paving an anti-cracking net on the aerogel modified layer, and strickling to enable the anti-cracking net to be embedded into the aerogel modified layer;
step three: and (3) after the aerogel modified layer is solidified, turning over the foaming PET substrate and repeating the second step to finish coating on the two side plate surfaces of the foaming PET substrate.
In the first step, the aerogel powder and the inorganic adhesive are mixed under the working condition of constant temperature or temperature reduction, and ultrasonic treatment is not needed in the mixing process, so that the air in the aerogel powder is not replaced by the inorganic adhesive.
Compared with the prior art, the heat reflection aerogel PET composite heat insulation board and the preparation method thereof have the following beneficial effects:
in the present invention, the inventors found that when other building members are connected to a foamed PET substrate by an inorganic adhesive, the connection is liable to fail because the inorganic adhesive (both of silicate adhesive and phosphate adhesive) is poor in ductility after curing and is liable to break after receiving a shearing force in a direction perpendicular to a glue film, whereas the foamed PET substrate is inferior in rigidity to steel or concrete, and is not effective in resisting deformation when the building members adhered to the foamed PET substrate by the inorganic adhesive are pulled, thereby causing the glue film of the inorganic adhesive to break by the shearing force. Meanwhile, the thermal deformation difference between the inorganic adhesive and the foamed PET substrate serving as a foaming material is large, and when the inorganic adhesive expands with heat and contracts with cold, the adhesive film of the inorganic adhesive can bear huge temperature stress to crack and fall off.
Based on the finding, the inventor adds aerogel powder into the inorganic adhesive to form a foaming material, so that the ductility of the adhesive film is greatly improved, the adhesive film is not easy to break when bearing shearing force, the thermal deformation is consistent with that of the foaming PET substrate, and the cracking and falling off caused by large difference of the thermal deformation are avoided. And by adding the anti-cracking net, even if the adhesive film cracks, the crack is difficult to continue to develop. The two are effectively connected with the foaming PET substrate, the foaming PET substrate is wrapped in the foaming PET substrate, the subsequent building construction can be performed on the aerogel modified layer, and the problem that the subsequent construction is difficult due to difficult connection or corrosion of the foaming PET substrate is solved. Meanwhile, the aerogel also improves the heat preservation effect of the foaming PET substrate.
The composite heat-insulating plate adopts the combined action of the binder and the fiber net, so that the rigidity of the plate is enhanced, and the plate has the structural stress capability. Meanwhile, the aerogel modified layer has the advantages of fire resistance, water resistance, mildew resistance and infrared reflectivity of more than 0.85 (the inventor discovers that the inorganic adhesive has an infrared reflection effect after being mixed with aerogel powder) and also has a reinforcing effect on the foaming PET substrate. The fire resistance and strength of the composite heat-insulating board are improved, the composite heat-insulating board has double effects of heat insulation and heat reflection, and the thermal resistance R value of the composite board is superior to that of the foamed PET substrate. The combination of the above points ensures that the composite heat-insulating plate can meet various requirements of building walls/floors such as stress, heat insulation, sound insulation and the like with extremely light weight and extremely thin thickness, and can achieve some unprecedented brand new effects when applied to the building, such as the building walls which are fixed on the light steel keels by gluing completely, such as an ultra-thin and ultra-light floor heating system.
Drawings
FIG. 1 is a perspective view of a heat reflective aerogel PET composite insulation panel in accordance with the present invention;
FIG. 2 is a cross-sectional view of a heat reflective aerogel PET composite insulation panel in accordance with the present invention;
in the figure, a 1-foaming PET substrate, a 2-aerogel modified layer and a 3-anti-cracking net are shown.
Detailed Description
As shown in fig. 1-2, a heat reflection aerogel PET composite heat insulation board comprises a foaming PET substrate 1 and aerogel modified layers 2 coated on two side plate surfaces of the foaming PET substrate 1, wherein an anti-cracking net 3 for preventing cracks of the aerogel modified layers 2 from extending is buried in the aerogel modified layers 2;
the aerogel modified layer 2 is an inorganic adhesive doped with aerogel powder and is in a bendable foaming material state.
If the aerogel-modified layer 2 is a foamed material, the thermal deformation amount is consistent with that of the foamed PET substrate 1, and the ductility thereof is significantly improved. In practical application, the aerogel modified layer 2 does not fall off even if the composite heat-insulating board is repeatedly trampled by constructors, and the composite heat-insulating board can be firmly hung no matter the composite heat-insulating board is used for attaching ceramic tiles, attaching line boxes, brushing cement mortar, brushing various coatings, attaching wallpaper and attaching decorative boards. The surface texture of the aerogel modified layer 2 is similar to that of ground glass, is a flat and quite rough surface, and can be firmly combined with cement mortar without roughening or scraping.
It is very difficult to make the inorganic adhesive into a foamed material directly connected to the foamed PET substrate 1. The existing inorganic adhesive, whether silicate adhesive or phosphate adhesive, cannot exist stably after being paved into a thin layer, and can escape before solidification.
However, if the powder itself with bubbles (because the adhesive film can only hold the lower powder) is doped into the inorganic adhesive to form the foaming material as in the present invention, it is also difficult and heavy. In practice, it was found that closed cell powders were doped into the inorganic binder and floated to the surface. The open-celled powder is doped into the inorganic adhesive, and although the floating to the surface is improved, the bubbles inside the mixture are replaced by the inorganic adhesive during the mixing process, and the effect is poor. The inventor has found after many attempts that, because the pores in the aerogel powder are very small, after the stirring condition is controlled, the bubbles in the aerogel powder can be ensured not to be replaced by the inorganic adhesive in the mixing process.
The infrared reflectance of the aerogel-modified layer 2 is not lower than 0.85. The infrared reflectivity of the aerogel powder is changed differently by different inorganic adhesives, so that the addition amount of the aerogel powder needs to be adjusted according to the actual situation, thereby changing the infrared reflectivity. Generally, the more aerogel powder is added, the higher the infrared reflectance.
In this embodiment, the inorganic binder is a silicate binder and the aerogel powder is silica aerogel powder. In this combination, the forces between the two are great and the floating can be effectively resisted during the mixing process. At the same time, the combination can be firmly combined with cement mortar (of course, the combination can also be firmly combined with other adhesives, but the cement mortar is most commonly used in building).
In this example, the closed cell ratio of the foamed PET substrate 1 was not less than 85%. The foamed PET substrate 1 is required to have a sufficient waterproof effect if it is to be used as a building exterior wall panel, and thus a closed cell ratio is required here to ensure a sufficient waterproof effect.
The anti-cracking net 3 is basalt gridding cloth or carbon fiber gridding cloth, and the materials can be firmly combined with the inorganic adhesive.
The preparation method of the heat reflection aerogel PET composite heat insulation board is used for preparing the heat reflection aerogel PET composite heat insulation board and comprises the following steps of:
step one: stirring and mixing the aerogel powder and the inorganic adhesive;
Step two: coating an inorganic adhesive containing aerogel powder on the upper plate surface of a horizontally-arranged foaming PET substrate 1 to form an aerogel modified layer 2, wherein the thickness of the aerogel modified layer 2 can be controlled by a toothed scraper;
Then paving an anti-cracking net 3 on the aerogel modified layer 2 and strickling to enable the anti-cracking net 3 to be embedded into the aerogel modified layer 2;
step three: and (3) after the aerogel modified layer 2 is solidified, turning over the foamed PET substrate 1 and repeating the second step, so that the two side plate surfaces of the foamed PET substrate 1 are coated.
In the first step, the aerogel powder and the inorganic adhesive are mixed under the working condition of constant temperature or temperature reduction, and ultrasonic treatment is not needed in the mixing process, so that the air in the aerogel powder is ensured not to be replaced by the inorganic adhesive. The formula of the inorganic adhesive and the aerogel powder ensures that the aerogel powder cannot float upwards. And the condition in the stirring process is controlled to avoid the bubbles in the aerogel powder from being replaced. Here, unlike the pores in the catalyst particles, the substance in the pores in the aerogel powder is air, which is not compatible with the inorganic binder. Meanwhile, as the pores are small enough, the air in the inorganic adhesive can be prevented from entering as long as the air cannot come out. Therefore, by controlling the temperature during the stirring process, the air is prevented from expanding and escaping from the aerogel powder due to the rising temperature. Meanwhile, ultrasonic vibration needs to be avoided, ultrasonic stirring is an efficient stirring mode, but air in aerogel powder can be driven out when the ultrasonic stirring mode is applied.
The composite insulation board in the embodiment has prepared a sample and is sent to be inspected, and the detection unit is as follows: the national detection pilot-operated group Beijing Limited company, the national building material industry building material and the structural safety quality supervision and inspection center.
The test results show that the adhesion between the foamed PET substrate 1 and the aerogel modified layer 2 exceeds 0.6 mpa, and the requirement of ceramic tile can be met by reaching 0.35 mpa.
Meanwhile, the composite heat-insulating board (thickness is 12 mm) in the embodiment has the surface density of 2.5 kg per square meter, the gypsum board surface density of paper with the same thickness is 8.7 kg per square meter, the glass fiber high-strength gypsum board surface density with the same thickness is 10 kg per square meter, and the PET composite board surface density is 1/3-1/4 of that of the two gypsum boards, but the performances of structural strength, heat-insulating effect and the like are higher.
In addition, the thermal conductivity of the aerogel heat reflection PET composite board is lower than that of the foaming PET substrate 1 with the same thickness, and the heat preservation effect is better.
The above examples are only illustrative of the preferred embodiments of the present invention and are not intended to limit the scope of the present invention, and various modifications and improvements made by those skilled in the art to the technical solution of the present invention should fall within the scope of protection defined by the claims of the present invention without departing from the spirit of the present invention.

Claims (8)

1. The utility model provides a heat reflection aerogel PET composite insulation board which characterized in that: the anti-cracking PET substrate comprises a foaming PET substrate (1) and aerogel modified layers (2) coated on two side plate surfaces of the foaming PET substrate (1), wherein an anti-cracking net (3) for preventing cracks of the aerogel modified layers (2) from being prolonged is buried in the aerogel modified layers (2);
The aerogel modified layer (2) is an inorganic adhesive doped with aerogel powder and is in a bendable foaming material state.
2. The heat reflection aerogel PET composite insulation board of claim 1, wherein: the infrared reflectivity of the aerogel modified layer (2) is not lower than 0.85.
3. The heat reflection aerogel PET composite insulation board of claim 1, wherein: the inorganic adhesive is silicate adhesive.
4. A heat reflective aerogel PET composite insulation board according to claim 3, wherein: the aerogel powder is silicon dioxide aerogel powder.
5. The heat reflection aerogel PET composite insulation board of claim 1, wherein: the closed cell rate of the foamed PET substrate (1) is not lower than 85%.
6. The heat reflection aerogel PET composite insulation board of claim 1, wherein: the anti-cracking net (3) is basalt gridding cloth or carbon fiber gridding cloth.
7. A preparation method of a heat reflection aerogel PET composite heat insulation board is characterized by comprising the following steps: a process for preparing a heat reflective aerogel PET composite insulation panel as defined in claim 4, comprising the steps of:
step one: stirring and mixing the aerogel powder and the inorganic adhesive;
Step two: coating an inorganic adhesive containing aerogel powder on the upper plate surface of a horizontally-arranged foamed PET substrate (1) to form an aerogel modified layer (2), paving an anti-cracking net (3) on the aerogel modified layer (2) and scraping the anti-cracking net to enable the anti-cracking net (3) to be embedded into the aerogel modified layer (2);
Step three: and (3) turning over the foamed PET substrate (1) after the aerogel modified layer (2) is solidified and repeating the second step, so that the two side plate surfaces of the foamed PET substrate (1) are coated.
8. The method for preparing the heat reflection aerogel PET composite insulation board according to claim 7, wherein the method comprises the following steps: in the first step, the aerogel powder and the inorganic adhesive are mixed under the working condition of constant temperature or temperature reduction, and ultrasonic treatment is not needed in the mixing process, so that the air in the aerogel powder is ensured not to be replaced by the inorganic adhesive.
CN202410249316.8A 2024-03-05 2024-03-05 Heat reflection aerogel PET composite heat insulation board and preparation method thereof Pending CN118124234A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202410249316.8A CN118124234A (en) 2024-03-05 2024-03-05 Heat reflection aerogel PET composite heat insulation board and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202410249316.8A CN118124234A (en) 2024-03-05 2024-03-05 Heat reflection aerogel PET composite heat insulation board and preparation method thereof

Publications (1)

Publication Number Publication Date
CN118124234A true CN118124234A (en) 2024-06-04

Family

ID=91229540

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202410249316.8A Pending CN118124234A (en) 2024-03-05 2024-03-05 Heat reflection aerogel PET composite heat insulation board and preparation method thereof

Country Status (1)

Country Link
CN (1) CN118124234A (en)

Similar Documents

Publication Publication Date Title
CN100585105C (en) Insulating decoration integral board for building exterior wall
CN100447359C (en) Method for making self-temperature-regulating phase-change heat-insulation wall and product thereof
CN201826405U (en) Environment-friendly wall insulating structure for prefabricated buildings
CN105694625A (en) Exterior wall waterproofing heat-insulating decorating integrated material and preparation method thereof
CN101725185B (en) Compound heat preservation die plate and concrete one-off construction outer wall heat preservation system and construction technology thereof
CN201883554U (en) Waterproof heat-insulting mortar layer
CN105328934A (en) Aerogel composite insulation board
CN102477775A (en) Composite thermal insulation structure of wall
CN101168983A (en) Thermal insulation decorative brick and producing method thereof
CN201128990Y (en) Composite environment-friendly thermal insulation material for wall
CN103266672B (en) External wall heat preservation system and construction technology of recombination of polystyrene foam and heat preservation inorganic fireproof plate
RU2473761C2 (en) Method to manufacture heat insulation panel and heat insulation panel
CN201896371U (en) Composite heat-insulating structure for wall body
CN201190339Y (en) Insulation structure for outer wall of building
CN200964652Y (en) Energy-saving waste-utilizing temperature-keeping building block
CN108894367A (en) A kind of cast-in-place fair-faced concrete external wall system and its construction technology
CN101424117B (en) Gypsum insulation plate and connection method thereof with major structure of construction
TW201144071A (en) Insulation material providing structural integrity and building elements and composites made thereof
CN101514580A (en) A general cladding construction method of wall thermal insulation decoration
CN118124234A (en) Heat reflection aerogel PET composite heat insulation board and preparation method thereof
CN201148676Y (en) Self-heat preserving energy-saving wall
CN201485980U (en) Outer wall heat-insulating system combining outer wall heat-insulating blocks and finished product heat-insulating plates
CN114161781A (en) Modified floating bead calcium silicate, preparation method thereof and heat-insulation and decoration integrated board
CN201184002Y (en) Spray painting rigid foam polyurethane water-proof and fire-proof heat preservation wall body
CN1785910A (en) Glass micro bead heat insulating fire proof grout

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination