CN105694625A - Exterior wall waterproofing heat-insulating decorating integrated material and preparation method thereof - Google Patents
Exterior wall waterproofing heat-insulating decorating integrated material and preparation method thereof Download PDFInfo
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- CN105694625A CN105694625A CN201610083027.0A CN201610083027A CN105694625A CN 105694625 A CN105694625 A CN 105694625A CN 201610083027 A CN201610083027 A CN 201610083027A CN 105694625 A CN105694625 A CN 105694625A
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Abstract
The invention relates to an exterior wall waterproofing heat-insulating decorating integrated material and a preparation method thereof.The preparation method includes: using conventional resin like polyurea and polyurethane as raw materials, adding compound micropowder prepared from solid waste and sludge, and adding a mixed modifier and a thixotropic agent to prepare A-compound slurry; adding a promoter and a hardener, and performing spray coating, brush coating, roll coating and pouring methods to obtain the exterior wall waterproofing heat-insulating decorating integrated material.The material has the comprehensive advantages of good waterproof effect, high heat insulativity, high hardness, high hole closing rate, low density, good anti-seepage performance, high corrosion resistance, low linear expansion coefficient, high softening temperature, oxidization resistance, aging resistance, flame retardancy and firmness in binding with a substrate.When the material is used for building exterior walls, multiple times of leveling, waterproofing, heat insulating and decorating construction are not needed, on-site moisture-free operation and one-time forming can be realized, and the material is short in construction period, extremely low in cost and great in market prospect.
Description
Technical field
The present invention relates to a kind of external wall waterproof heat preservation decoration integrative material and preparation method thereof。
Background technology
In recent years, the waterproof thermal-insulated saving energy sense of construction wall is rooted in the hearts of the people, and exterior wall exterior water-proof heat preserving becomes the main flow of the energy-conservation form of body of wall with its many merits。Existing external wall is base course wall blank, cement mortar screeding layer, waterproof layer, adhesive mortar, heat-insulation layer, float coat and finish coat from the inside to surface successively。But, currently used various external wall waterproof, heat preservation technology are primarily present problems with:
(1), during the construction of exterior wall exterior water-proof heat preserving layer, material requested is of a great variety, need to repeatedly construct, complex process, and cost is high, and cost about 150 yuan-180 yuan/。
(2) heat-insulation layer and waterproof layer thermal expansion coefficient difference are relatively big, and under temperature alternate effect, the boundary layer between two-layer is easy to crack, peeling, cause making moist, even seep water so that external wall energy-saving effect significantly declines, and breakthrough not easy-to-search, maintenance cost is high。
(3) by the impact of construction technology, often there is crack in various degree in external wall windowsill, column, crossbeam etc., and in use, these cracks can continue to become big, thus causing the destruction of waterproof thermal-insulated system。This is also difficult point when existing building exterior wall design, construction。
(4) during existing building upgrading, load capacity, it has been determined that load owing to can not increase roofing, need to remove former waterproofing and thermal insulation of roofing finish coat, and difficulty is big, long in time limit, it is many to disturb residents, cost high。
(5), when existing waterproof, insulation material adopt inorganic material, water absorption rate is high, easy to crack, easily seeps water, and heat insulation effect is poor。When using organic material, then easy firing, easily decompose, not ageing-resistant。
In order to overcome the limitation of above traditional handicraft, research staff develops multiple waterproof and insulation integrated technology, such as waterproof thermal-insulated high-strength light plasterboard [prunetin grain husk, Zhejiang Polytechnical University, Master's thesis, 2013.3], waterproof and insulation integrated external thermal insulation system [China's detection science and technology, 2014,1,18-20] etc.。These integrated technique major parts still have employed the Multi-layer designs such as waterproof, insulation, facing, simply by waterproof thermal-insulated finish coat assembled in advance together, arrive anchored in situ construction subsequently again, or after anchoring finish coat at the scene, pour into a mould water-proof heat-insulation material again, although simplifying site construction technology, still suffer from following point:
(1) waterproof, insulation material therefor material be substantially free of change, still suffer from that interface is easy to crack, water absorption rate is high, inflammable, high in cost of production problem。
(2), after the inorganic material such as the Material Strength such as existing polyurethane, EPS is low, yielding, easily aging, glass bead doping, heat insulation effect difference, high in cost of production problem are still suffered from。
(3) multilayer material assembles still without the integration realizing real meaning。During in-situ spraying construction, it is still necessary to assembling finish coat。
(4) integrated material thickness is still relatively big, causes bonding or anchoring difficulty is big, and interface is easy to crack, and complicated shape is difficult to moulding, it is difficult to obtain variation style。
(5), during in-situ spraying construction, temperature impact is big, during high and cold or height thermally district construction, and construction difficulty, and weak effect。
Therefore, prepare easy construction, effective, cost is low, free of contamination water-proof heat preservation ornament integration material, remains the common problem in industry。
Summary of the invention
The present invention provides a kind of external wall waterproof heat preservation decoration integrative material and preparation method thereof, after adding accelerator and firming agent, can pass through the methods such as spraying, brushing, roller coating, cast, prepare water-proof heat preservation ornament integration material。This material has good water-proof effect, extremely efficient in preserving heat, hardness is high, rate of closed hole is high, density is low, anti-permeability performance is good, good corrosion resistance, linear expansion coefficient are low, softening temperature is high, antioxidation, ageing-resistant, fire-retardant be combined with substrate jail etc. overall merit。
The present invention adopts the following technical scheme that a kind of external wall waterproof heat preservation decoration integrative material, it is with matrix resin, diluent, composite micropowder, pigment, mixed modifier, thixotropic agent, accelerator and firming agent for raw material, with parts by weight: matrix resin is for 10-70 part, pigment is 1-10 part, mixed modifier is 0.5-10 part, thixotropic agent is 0-3.5 part, accelerator is 0-3 part, firming agent is 10-45 part, diluent is 0-10 part, composite micropowder is 2-50 part, and the weight ratio of matrix resin and firming agent is 5-10:1-5。
Described matrix resin is any one in epoxy, phenolic aldehyde, polyethylene terephthalate, polyurethane, acrylic acid, polrvinyl chloride, polystyrene, organosilicon, fluorocarbon resin or corresponding modified resin, or any two kinds of hybrid resins weight ratio mixing such as pressing, end group is any one in siloxy group, hydroxyl, carboxyl, amino or isocyanate group。
Described diluent includes any one in styrene, toluene, dimethylbenzene, ethylene glycol ether acetate, butyl acetate, rosin, n-butyl alcohol。
Described composite micropowder is that the mixing of micropowder of the same race composite or multiple micropowder is composite by weight mix homogeneously such as thick for 100-500 purpose micropowder and the 2000-5000 trickle powder of purpose；The material of described micropowder includes any one in quartz sand, silicon powder, mica powder, corundum, white fused alumina, flyash, meerschaum, hollow glass micropearl, or building, the powder particle made of Industrial Solid Waste, or any one in mud dry powder, Pulvis Talci, clay powder, Gypsum Fibrosum powder or the kaolin powder granule made。
Described pigment includes any one in rust red, titanium dioxide, white carbon black, permanent violet。
Described mixed modifier is with parts by weight: foaming agent 0-30 part, fire retardant 40-85 part, antioxidant 1-10, anti ultraviolet agent 5-15 part, levelling agent 0-10, surfactant 0-10 part, coupling agent 0-10 part and phase-change thermal storage granule 0-10 part；Described foaming agent is foaming agent corresponding with matrix resin；Described fire retardant is the mixture of any one or more in nitrogen system, silicon system, high purity alumina-magnesia, Borax, boric acid；Described antioxidant refers to the one in aromatic amine antioxidant, hindered phenol anti-oxidants；Described anti ultraviolet agent is any one in oxybenzoic acid phenyl ester, 2-(2-hydroxyl-5-aminomethyl phenyl) BTA, 2,4-DihydroxyBenzophenone, 2,4-DihydroxyBenzophenone, single benzoic acid resorcinol；Described levelling agent is any one in isophorone, DAA, Solvesso150；Described surfactant is the one in sodium polyacrylate, acetylenediol, sodium alkyl sulfonate, Span80, Tween20；Described coupling agent is the one in KH550, KH560 and KH570, and described phase-change thermal storage granule is paraffin particles。
Described thixotropic agent is nano-particle or nanometer sheet, including one or more the mixture in gaseous oxidation zinc, gaseous oxidation aluminum, aerosil, aeroge, Graphene, gaseous oxidation titanium, white carbon black, nano-bentonite, nano kaoline, nanoclay, nano-cellulose。
Described accelerator refers to the one in the extraordinary amine such as the organic tins such as dibutyltin dilaurate, pentamethyl-diethylenetriamine and dimethyl cyclohexyl amine and cobalt iso-octoate。
Described firming agent is one or more the mixture in two durene diisocyanate, polyamide, phenolic aldehyde amine, anhydrides, methyl ethyl ketone peroxide。
A kind of preparation method of described external wall waterproof heat preservation decoration integrative material, with matrix resin, diluent, composite micropowder, pigment, mixed modifier, thixotropic agent, accelerator and firming agent for raw material, it is mixed into slurry through high speed machine stirring, adopt again build, spray, roller coating or brush the material of preparation, concretely comprise the following steps:
(1) micropowder is composite: thick micropowder and trickle powder are individually weighed, by etc. weight mixing after put into batch mixer, pour container after being sufficiently mixed into；
(2) mixed modifier preparation: fire retardant, antioxidant, anti ultraviolet agent, levelling agent, surfactant, coupling agent and phase-change thermal storage granule are weighed successively, and put into ingredients pot by proportioning, stirring at low speed is until completely uniform；
(3) component A preparation: in the container filling composite micropowder, adds matrix resin and diluent, and on blender, low speed is sufficiently stirred for, until being thoroughly mixed uniformly, sequentially add pigment, mixed modifier, after being uniformly dispersed, add thixotropic agent, adjust viscosity and reach construction requirement；
(4) B component preparation: accelerator and firming agent are weighed by proportioning, puts into ingredients pot and stirs, can obtain B component；
(5) slurry preparation: by proportioning, pours B component in component A, and high-speed stirred makes the quick mix homogeneously of slurry；
(6) prepared by integrated material: under room temperature condition, base material or mold cavity surface are purged clean, adopt and topple over, brush, spray or any one method in roller coating, the slurry that volumetric usage is predetermined 0.25～1 is poured into mould or is coated on substrate surface, after 1-24h, namely obtaining described integrated material, described base material includes in cement-based material, stone material, pottery, glass, polymer, metal, timber, paper, cloth any one。
Beneficial effect:
(1) integrated material prepared, water resistance meets or exceeds country or the industry standard of the existing water-repellent paint such as GB/T19250-2013, GB/T23446-2009, GB/T23445-2009, JC/T2217-2014, and heat-insulating property also meets or exceeds country or the industrial trade standard of the existing insulation material such as GB/T21558-2008, JG/T158-2013, JG/T287-2013, JG/T420-2013。
(2) slurry of the integrated material prepared, can pass through the multiple technologies field operations such as cast, brushing, roller coating, spraying。During operation, it is clean that basal plane only needs air to purge, it is not necessary to whitewashes levelling。Also by technology such as cast, brushing, roller coating, sprayings, in plant produced, after being transported to scene, adopting mechanical anchor mode or integration slurry is bonding agent, is assembled to corresponding body of wall, short construction period, complete dry construction, no pollution。After also decoration panel can being anchored, the slurry of cast integrated material。The public building multiple style requirement of various medium and high-grade exterior finish can be met, it is also possible to be applied to existing building reducing energy consumption easily。
(3) integrated material that the present invention proposes is when preparing, and with usual resins for matrix, can add a large amount of solid waste or micropowder that mud is made, significantly reduce cost, and the feature of environmental protection is good。Meanwhile, the integrated material of preparation has high rate of closed hole and low-density, and compared with existing lamellar composite integrated material, thickness can reduce by more than 40 parts, can significantly reduce the load of exterior wall。Compared to virgin resin, due to the filling of the hard phases such as composite micropowder, hardness is high, and anti-permeability performance is good, good corrosion resistance, and linear expansion coefficient is low, and softening temperature is high, and during exterior wall coating, the maximum gauge of sagging is not 20cm。
(4) slurry of the integrated material prepared, during foam-in-place, not only can effectively clog building slit, form the seamless continuous water-proof heat-insulation layer of large area, and can realize bonding without cavity with body of wall, no matter its facing is coating or face brick, all can effectively overcome facing defect to produce, and Engineering Reliability and life-span are greatly improved。
(5) addition of pigment, can obtain different color, it may be achieved waterproof, insulation, decoration integrated。After the technology such as cast, brushing, roller coating, spraying shapes, surface has smooth closely knit from skinning, not only enhances water proofing property, also enhances decorative effect。Also dependent on needs after slurry cast or coating, directly stick decoration panel, it is not necessary to bonding agent。
(6) use of mixed modifier so that integrated material prepared by the present invention has the ultraviolet aging resistance of excellence, non-oxidizability and anti-flammability。More than artificial ageing 1000h, or after natural environment placement for many years, integrated material outward appearance, color have no significant change, and after various acid-base solutions soak 3 days, still have the water proofing property of excellence。
(7) by the addition of thixotropic agent, high shear agitation is coordinated, can thickening, it is prevented that micropowder, pigment sink in the slurry, significantly improve composite micropowder dispersibility in matrix resin, thus promoting intensity and the hardness of integrated material。Meanwhile, during coating, it is not likely to produce sagging, even if at exterior wall alien invasion, it is possible to the integrated material that existing spray is standby thicker。Thixotropic agent have also obtained the closed pore of fine uniform, can further improve the mechanical performance of material and heat-insulating property after adding。
(8) integrated material prepared, all significantly high with the adhesive strength of the soft or hard substrates such as cement-based material, metal, ceramic tile, plastics, timber, cloth, even if during surface moisture, even more than the tearing strength of integrated material itself, strong bonded can be formed with external wall and finish coat。
(9) mixing of accelerator and firming agent uses so that the slurry of the integrated material of preparation, under-40～50 DEG C of ambient temperatures, all spontaneous curing can shape, be suitable for the construction operation in Different climate condition area after 1-24h。
(10) the inventive method device therefor and technique are simple, operate simple and easy and with low cost, and reaction condition is gentle, and energy consumption is little, and cost is low, reproducible, is suitable for large-scale production。Except external wall, apply also for heat-insulation and heat-preservation and the anticorrosions such as roof waterproof, and boiler, groove, tank, still, pipeline, naval vessel。
Accompanying drawing illustrates:
Fig. 1 is the preparation flow figure of composite mortar in example 1。
Fig. 2 is the digital photograph of the integrated material in example 1 after the demoulding。
Fig. 3 is the digital photograph of the porous form of integrated material in example 2。
Fig. 4 is the stereoscan photograph of the porous form of integrated material in example 3。
Detailed description of the invention:
A kind of external wall waterproof heat preservation decoration integrative material, it is with matrix resin, diluent, composite micropowder, pigment, mixed modifier, thixotropic agent, accelerator and firming agent for raw material, with parts by weight: matrix resin is for 10-70 part, and pigment is 1-10 part, and mixed modifier is 0.5-10 part, thixotropic agent is 0-3.5 part, accelerator is 0-3 part, and firming agent is 10-45 part, and diluent is 0-10 part, composite micropowder is 2-50 part, and the weight ratio of matrix resin and firming agent is 5-10:1-5。
Described matrix resin is any one in epoxy, phenolic aldehyde, polyethylene terephthalate, polyurethane, acrylic acid, polrvinyl chloride, polystyrene, organosilicon, fluorocarbon resin or corresponding modified resin, or any two kinds of hybrid resins weight ratio mixing such as pressing, end group is any one in siloxy group, hydroxyl, carboxyl, amino or isocyanate group。
Described diluent includes any one in styrene, toluene, dimethylbenzene, ethylene glycol ether acetate, butyl acetate, rosin, n-butyl alcohol。
Described composite micropowder is that the mixing of micropowder of the same race composite or multiple micropowder is composite by weight mix homogeneously such as thick for 100-500 purpose micropowder and the 2000-5000 trickle powder of purpose；The material of described micropowder includes any one in quartz sand, silicon powder, mica powder, corundum, white fused alumina, flyash, meerschaum, hollow glass micropearl, or building, the powder particle made of Industrial Solid Waste, or any one in mud dry powder, Pulvis Talci, clay powder, Gypsum Fibrosum powder or the kaolin powder granule made。
Described pigment includes any one in rust red, titanium dioxide, white carbon black, permanent violet。
Described mixed modifier is with parts by weight: foaming agent 0-30 part, fire retardant 40-85 part, antioxidant 1-10, anti ultraviolet agent 5-15 part, levelling agent 0-10, surfactant 0-10 part, coupling agent 0-10 part and phase-change thermal storage granule 0-10 part；Described foaming agent is foaming agent corresponding with matrix resin；Described fire retardant is the mixture of any one or more in nitrogen system, silicon system, high purity alumina-magnesia, Borax, boric acid；Described antioxidant refers to the one in aromatic amine antioxidant, hindered phenol anti-oxidants；Described anti ultraviolet agent is any one in oxybenzoic acid phenyl ester, 2-(2-hydroxyl-5-aminomethyl phenyl) BTA, 2,4-DihydroxyBenzophenone, 2,4-DihydroxyBenzophenone, single benzoic acid resorcinol；Described levelling agent is any one in isophorone, DAA, Solvesso150；Described surfactant is the one in sodium polyacrylate, acetylenediol, sodium alkyl sulfonate, Span80, Tween20；Described coupling agent is the one in KH550, KH560 and KH570, and described phase-change thermal storage granule is paraffin particles。
Described thixotropic agent is nano-particle or nanometer sheet, including one or more the mixture in gaseous oxidation zinc, gaseous oxidation aluminum, aerosil, aeroge, Graphene, gaseous oxidation titanium, white carbon black, nano-bentonite, nano kaoline, nanoclay, nano-cellulose。
Described accelerator refers to the one in extraordinary amine, the cobalt iso-octoate such as the organic tins such as dibutyltin dilaurate, pentamethyl-diethylenetriamine, dimethyl cyclohexyl amine。
Described firming agent needs to cause the activation of matrix resin monomer produce free radical and carry out chain polymerization, is one or more the mixture in two durene diisocyanate, polyamide, phenolic aldehyde amine, anhydrides, methyl ethyl ketone peroxide etc.。
Described preparation method comprises the following steps:
(1) micropowder is composite: thick micropowder and trickle powder are individually weighed, by etc. weight mixing after put into batch mixer, pour container after being sufficiently mixed into；
(2) mixed modifier preparation: fire retardant, antioxidant, anti ultraviolet agent, levelling agent, surfactant, coupling agent and phase-change thermal storage granule are weighed successively, and put into ingredients pot by proportioning, stirring at low speed is until completely uniform；
(3) component A preparation: in the container filling composite micropowder, adds matrix resin and diluent, and on blender, low speed is sufficiently stirred for, until being thoroughly mixed uniformly, sequentially add pigment, mixed modifier, after being uniformly dispersed, add thixotropic agent, adjust viscosity and reach construction requirement；
(4) B component preparation: accelerator and firming agent are weighed by proportioning, puts into ingredients pot and stirs, can obtain B component；
(5) slurry preparation: by proportioning, pours B component in component A, and high-speed stirred makes the quick mix homogeneously of slurry；
(6) prepared by integrated material: under room temperature condition, base material or mold cavity surface are purged clean, adopt and topple over, brush, spray or any one method in roller coating, the slurry that volumetric usage is predetermined 0.25～1 is poured into mould or is coated on substrate surface, after 1-24h, namely obtaining described integrated material, described base material includes in cement-based material, stone material, pottery, glass, polymer, metal, timber, paper, cloth any one。
Embodiment 1
100 order silicon powders and 2000 order silicon powders are individually weighed, by etc. weight mixing after put into batch mixer, pour ingredients pot after being sufficiently mixed into。Successively by 10 parts of foaming agent, 55 parts of aluminium hydroxide fire retardants, 10 parts of aromatic amine anti-oxidant, 15 parts of oxybenzoic acid phenyl ester anti ultraviolet agents, 1 part of isophorone levelling agent, 2 parts of polyacrylic acid natrium surfactants, 2 parts of KH550 coupling agents and 10 parts of paraffin particles, weigh by proportioning, pouring another ingredients pot into, stirring at low speed is until completely uniform。In the container filling composite micropowder, adding acrylic resin and dilution with toluene agent, on blender, low speed is sufficiently stirred for, until being thoroughly mixed uniformly, sequentially adding pigment titanium white, mixed modifier, being uniformly dispersed。Each dispensing addition presses matrix resin 10 parts, diluent 10 parts, composite micropowder 50 parts, pigment 5 parts, 10 parts of proportionings of mixed modifier, adds 1 part of thixotropic agent nano-cellulose, is sufficiently stirred for acquisition component A slurry。Finally, add accelerator pentamethyl-diethylenetriamine and 12 parts of addition firming agent methyl ethyl ketone peroxides, high-speed stirred 10min by 2 parts, make the quick mix homogeneously of slurry。Under room temperature condition, mold cavity surface is purged clean, be coated with releasing agent, adopt tipping, pour the slurry that volumetric usage is predetermined 1/2 into mould, the demoulding after 10h, integrated material can be obtained。According to relevant criterion, the decorative cover the performance test results of integrated material prepared by this example is as shown in the table。
Embodiment 2
500 order mica powders and 5000 order flyash are individually weighed, by etc. weight mixing after put into batch mixer, pour ingredients pot after being sufficiently mixed into。Successively by 30 parts of foaming agent, the fire retardant of the 40 parts of weight such as Borax and boric acid mixing, 8 parts of p-phenylenediamine antioxidants, 12 parts of dihydroxy benaophenonel anti ultraviolet agents, 2 parts of DAA levelling agents, 1 part of alkyl sulfonic acid natrium surfactant, 5 parts of KH560 coupling agents and 2 parts of paraffin particles, weigh by proportioning, pouring another ingredients pot into, stirring at low speed is until completely uniform。In the container filling composite micropowder, adding epoxy resin, on blender, low speed is sufficiently stirred for, until being thoroughly mixed uniformly, sequentially adding pigment titanium white, mixed modifier, being uniformly dispersed。Each dispensing addition presses matrix resin 50 parts, composite micropowder 2 parts, pigment 10 parts, 0.5 part of proportioning of mixed modifier, adds the thixotropic agent of the weight mixing such as 3.5 parts of gaseous oxidation zinc and titanium oxide, is sufficiently stirred for acquisition component A slurry。Finally, add 34 parts of firming agent polyamide, high-speed stirred 1min, make the quick mix homogeneously of slurry。Under room temperature condition, base material or mold cavity surface are purged clean, releasing agent can be coated with as required, adopt and topple over, brush, spray or any one method in roller coating, the slurry that volumetric usage is predetermined 1/4 is poured into mould or is coated on substrate surface, after 24h, can obtaining integrated material, described substrate includes in the solid materials such as cement-based material, stone material, pottery, glass, polymer, metal, timber, paper, cloth any one。According to relevant criterion, the heat-insulating property test result of integrated material prepared by this example is as shown in the table。
Embodiment 3
200 order sludge dry powders and 3000 order Gypsum Fibrosum powders are individually weighed, by etc. weight mixing after put into batch mixer, pour ingredients pot after being sufficiently mixed into。Successively by 85 parts of antimony oxide fire retardants, 6 parts of secondary diarylamine antioxidants, 9 parts of single benzoic acid resorcinol anti ultraviolet agents, weighing by proportioning, pour another ingredients pot into, stirring at low speed is until completely uniform。In the container filling composite micropowder, adding polyurethane resin, on blender, low speed is sufficiently stirred for, until being thoroughly mixed uniformly, sequentially adding pigment titanium white, mixed modifier, being uniformly dispersed。Each dispensing addition presses matrix resin 70 parts, composite micropowder 18 parts, pigment 1 part, 2 parts of proportionings of mixed modifier, adds 2 parts of thixotropic agent aerosils, is sufficiently stirred for acquisition component A slurry。Finally, add accelerator pentamethyl-diethylenetriamine and 5 parts of addition firming agent two durene diisocyanate, high-speed stirred 5min by 2 parts, make the quick mix homogeneously of slurry。Under room temperature condition, base material or mold cavity surface are purged clean, releasing agent can be coated with as required, adopt and topple over, brush, spray or any one method in roller coating, the slurry that volumetric usage is predetermined 1/3 is poured into mould or is coated on substrate surface, after 1h, can obtaining integrated material, described substrate includes in the solid materials such as cement-based material, stone material, pottery, glass, polymer, metal, timber, paper, cloth any one。According to standards such as GB/T16777-2008, the water resistance test result of integrated material prepared by this example is as shown in the table。
Embodiment 4
200 order sludge dry powders and 4000 order sludge dry powders are individually weighed, by etc. weight mixing after put into batch mixer, pour ingredients pot after being sufficiently mixed into。Successively by 68 parts of compound phosphorus/magnesium fire retardants, 16 parts of secondary diarylamine antioxidants, 16 parts of single benzoic acid resorcinol anti ultraviolet agents, weighing by proportioning, pour another ingredients pot into, stirring at low speed is until completely uniform。In the container filling composite micropowder, adding polyurethane resin and diluent, on blender, low speed is sufficiently stirred for, until being thoroughly mixed uniformly, sequentially adding pigment titanium white, mixed modifier, being uniformly dispersed。Each dispensing addition presses matrix resin 30 parts, diluent 5 parts, composite micropowder 35 parts, pigment 2 parts, 3 parts of proportionings of mixed modifier, is sufficiently stirred for acquisition component A slurry。Finally, add 25 parts of firming agent methyl ethyl ketone peroxides, high-speed stirred 5min, make the quick mix homogeneously of slurry。Under room temperature condition, base material or mold cavity surface are purged clean, releasing agent can be coated with as required, adopt and topple over, brush, spray or any one method in roller coating, the slurry that volumetric usage is predetermined 1/3 is poured into mould or is coated on substrate surface, after 1h, can obtaining integrated material, described substrate includes in the solid materials such as cement-based material, stone material, pottery, glass, polymer, metal, timber, paper, cloth any one。
Claims (10)
1. an external wall waterproof heat preservation decoration integrative material, it is characterized in that, it is with matrix resin, diluent, composite micropowder, pigment, mixed modifier, thixotropic agent, accelerator and firming agent for raw material, with parts by weight: matrix resin is for 10-70 part, pigment is 1-10 part, mixed modifier is 0.5-10 part, thixotropic agent is 0-3.5 part, accelerator is 0-3 part, firming agent is 10-45 part, diluent is 0-10 part, and composite micropowder is 2-50 part, and the weight ratio of matrix resin and firming agent is 5-10:1-5。
2. external wall waterproof heat preservation decoration integrative material according to claim 1, it is characterized in that, described matrix resin is any one in epoxy, phenolic aldehyde, polyethylene terephthalate, polyurethane, acrylic acid, polrvinyl chloride, polystyrene, organosilicon, fluorocarbon resin or corresponding modified resin, or any two kinds of hybrid resins weight ratio mixing such as pressing, end group is any one in siloxy group, hydroxyl, carboxyl, amino or isocyanate group。
3. external wall waterproof heat preservation decoration integrative material according to claim 1, it is characterised in that described diluent includes any one in styrene, toluene, dimethylbenzene, ethylene glycol ether acetate, butyl acetate, rosin, n-butyl alcohol。
4. external wall waterproof heat preservation decoration integrative material according to claim 1, it is characterized in that, described composite micropowder is that the mixing of micropowder of the same race composite or multiple micropowder is composite by weight mix homogeneously such as thick for 100-500 purpose micropowder and the 2000-5000 trickle powder of purpose；The material of described micropowder includes any one in quartz sand, silicon powder, mica powder, corundum, white fused alumina, flyash, meerschaum, hollow glass micropearl, or building, the powder particle made of Industrial Solid Waste, or any one in mud dry powder, Pulvis Talci, clay powder, Gypsum Fibrosum powder or the kaolin powder granule made。
5. external wall waterproof heat preservation decoration integrative material according to claim 1, it is characterised in that described pigment includes any one in rust red, titanium dioxide, white carbon black, permanent violet。
6. external wall waterproof heat preservation decoration integrative material according to claim 1, it is characterized in that, described mixed modifier is with parts by weight: foaming agent 0-30 part, fire retardant 40-85 part, antioxidant 1-10, anti ultraviolet agent 5-15 part, levelling agent 0-10, surfactant 0-10 part, coupling agent 0-10 part and phase-change thermal storage granule 0-10 part；Described foaming agent is foaming agent corresponding with matrix resin；Described fire retardant is the mixture of any one or more in nitrogen system, silicon system, high purity alumina-magnesia, Borax, boric acid；Described antioxidant refers to the one in aromatic amine antioxidant, hindered phenol anti-oxidants；Described anti ultraviolet agent is any one in oxybenzoic acid phenyl ester, 2-(2-hydroxyl-5-aminomethyl phenyl) BTA, 2,4-DihydroxyBenzophenone, 2,4-DihydroxyBenzophenone, single benzoic acid resorcinol；Described levelling agent is any one in isophorone, DAA, Solvesso150；Described surfactant is the one in sodium polyacrylate, acetylenediol, sodium alkyl sulfonate, Span80, Tween20；Described coupling agent is the one in KH550, KH560 and KH570, and described phase-change thermal storage granule is paraffin particles。
7. external wall waterproof heat preservation decoration integrative material according to claim 1; it is characterized in that; described thixotropic agent is nano-particle or nanometer sheet, including one or more the mixture in gaseous oxidation zinc, gaseous oxidation aluminum, aerosil, aeroge, Graphene, gaseous oxidation titanium, white carbon black, nano-bentonite, nano kaoline, nanoclay, nano-cellulose。
8. external wall waterproof heat preservation decoration integrative material according to claim 1, it is characterized in that, described accelerator refers to the one in the extraordinary amine such as the organic tins such as dibutyltin dilaurate, pentamethyl-diethylenetriamine and dimethyl cyclohexyl amine and cobalt iso-octoate。
9. external wall waterproof heat preservation decoration integrative material according to claim 1, it is characterised in that described firming agent is one or more the mixture in two durene diisocyanate, polyamide, phenolic aldehyde amine, anhydrides, methyl ethyl ketone peroxide。
10. the preparation method of the external wall waterproof heat preservation decoration integrative material described in a claim 1, it is characterized in that, with matrix resin, diluent, composite micropowder, pigment, mixed modifier, thixotropic agent, accelerator and firming agent for raw material, it is mixed into slurry through high speed machine stirring, adopt again build, spray, roller coating or brush the material of preparation, concretely comprise the following steps:
(1) micropowder is composite: thick micropowder and trickle powder are individually weighed, by etc. weight mixing after put into batch mixer, pour container after being sufficiently mixed into；
(2) mixed modifier preparation: fire retardant, antioxidant, anti ultraviolet agent, levelling agent, surfactant, coupling agent and phase-change thermal storage granule are weighed successively, and put into ingredients pot by proportioning, stirring at low speed is until completely uniform；
(3) component A preparation: in the container filling composite micropowder, adds matrix resin and diluent, and on blender, low speed is sufficiently stirred for, until being thoroughly mixed uniformly, sequentially add pigment, mixed modifier, after being uniformly dispersed, add thixotropic agent, adjust viscosity and reach construction requirement；
(4) B component preparation: accelerator and firming agent are weighed by proportioning, puts into ingredients pot and stirs, can obtain B component；
(5) slurry preparation: by proportioning, pours B component in component A, and high-speed stirred makes the quick mix homogeneously of slurry；
(6) prepared by integrated material: under room temperature condition, base material or mold cavity surface are purged clean, adopt and topple over, brush, spray or any one method in roller coating, the slurry that volumetric usage is predetermined 0.25～1 is poured into mould or is coated on substrate surface, after 1-24h, namely obtaining described integrated material, described base material includes in cement-based material, stone material, pottery, glass, polymer, metal, timber, paper, cloth any one。
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101935386A (en) * | 2010-09-30 | 2011-01-05 | 北京立高科技股份有限公司 | Fireproof, waterproof, insulating and decorative integrated composite polyurethane material and preparation method thereof |
| CN102181144A (en) * | 2011-01-31 | 2011-09-14 | 北京东方雨虹防水技术股份有限公司 | Spray rigid polyurethane foam heat insulation waterproof integrated material |
-
2016
- 2016-02-05 CN CN201610083027.0A patent/CN105694625A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101935386A (en) * | 2010-09-30 | 2011-01-05 | 北京立高科技股份有限公司 | Fireproof, waterproof, insulating and decorative integrated composite polyurethane material and preparation method thereof |
| CN102181144A (en) * | 2011-01-31 | 2011-09-14 | 北京东方雨虹防水技术股份有限公司 | Spray rigid polyurethane foam heat insulation waterproof integrated material |
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