CN107417167A - A kind of Novel fireproof material and preparation method thereof - Google Patents
A kind of Novel fireproof material and preparation method thereof Download PDFInfo
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- CN107417167A CN107417167A CN201710467223.2A CN201710467223A CN107417167A CN 107417167 A CN107417167 A CN 107417167A CN 201710467223 A CN201710467223 A CN 201710467223A CN 107417167 A CN107417167 A CN 107417167A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing halogen
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00017—Aspects relating to the protection of the environment
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/28—Fire resistance, i.e. materials resistant to accidental fires or high temperatures
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/40—Porous or lightweight materials
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Abstract
The invention discloses a kind of Novel fireproof material, include the raw material of following parts by weight：13~18 parts of flyash, 15~25 parts of black mud powder, 13~18 parts of natural mica piece powder, 15~20 parts of hollow glass microbead, 8~15 parts of polyvinyl chloride resin, 5~10 parts of rice bran, 3~9 parts of expanded perlite, 2~4 parts of alundum (Al2O3), 7~12 parts of clinker, 3~7 parts of diamond dust, 1~4 part of glass fibre, 2~4 parts of carbon fiber, 1~2 part of fire retardant, 2~3 parts of activating agent.The cost of material is low for Novel fireproof of the present invention, heat-proof quality is good, fire resistance period length, is adapted to various fire engineerings to use.
Description
Technical field
The invention belongs to fireproof material technology field, and in particular to a kind of Novel fireproof material and preparation method thereof.
Background technology
Fire proofing material just refers to construction or the art work with certain grade above fire protecting performance, according to Building technology rule
Following three can be divided into：(1) incombustible material：As concrete, brick or hollow brick, watt, building stones, steel, aluminium, glass, glass fibers
Dimension, mineral wool, pottery, mortar, lime and it is other not because it is burning hot cause burning, fusing, failure by rupture and generation pernicious gas it
Material；(2) refractory slab：Such as wood cement board, the plate of resistance to calcined plaster material；(3) flame resistant material：As resistance to combustion plywood, resistance to combustion are fine
Tie up the materials such as plate, resistance to combustion plastic plate, plasterboard.
The energy and material are the bases of Chinese national economy, while are also the bottleneck of Chinese national economy development, and energy-conservation is
Through the fundamental state policy as China.The 30% of the about total national total energy consumption of the building energy consumption in China, is developed rapidly in Building Trade in China
Today, if not paying attention to the use of energy-conserving product, building energy consumption ratio will increase with the increase of building.Using light
Matter, insulation, heat-insulated construction material are one of effective measures for reducing energy consumption.Firmly build portion and the Ministry of Public Security in 2009 No. 46 and
The text of the Fire-Fighting Bureau under the Ministry of Public Security 65 in 2011 provides that all skins must install and use the dress that insulation fire prevention reaches the requirement of A levels
Exterior material.Show ornament materials of the in the market only with national standard B levels, so the insulation that research and development national standard A levels are horizontal
Fire proofing material is extremely urgent.
At the same time, it is also the major issue that enterprise is considered to reduce refractory material cost.Although have makes on the market
Fire wall etc. is prepared with stalk material, cost is relatively low, but their heat-proof quality is poor, and fire resistance period is short, it is impossible to meet country
Standard and《Code for fire protection design of buildings》Requirement.
The content of the invention
The invention provides a kind of Novel fireproof material and preparation method thereof, solve the problems, such as in above-mentioned background technology,
The cost of material is low for Novel fireproof of the present invention, heat-proof quality is good, fire resistance period length, is adapted to various fire engineerings to use.
In order to solve the problems, such as that prior art is present, adopt the following technical scheme that：
A kind of Novel fireproof material, include the raw material of following parts by weight：It is 13~18 parts of flyash, 15~25 parts of black mud powder, natural
13~18 parts of mica sheet powder, 15~20 parts of hollow glass microbead, 8~15 parts of polyvinyl chloride resin, 5~10 parts of rice bran, expanded perlite 3
~9 parts, 2~4 parts of alundum (Al2O3), 7~12 parts of clinker, 3~7 parts of diamond dust, 1~4 part of glass fibre, 2~4 parts of carbon fiber,
1~2 part of fire retardant, 2~3 parts of activating agent.
Preferably, the Novel fireproof material, the raw material of following parts by weight is included：14~17 parts of flyash, black mud powder 18
~22 parts, 15~17 parts of natural mica piece powder, 16~18 parts of hollow glass microbead, 10~13 parts of polyvinyl chloride resin, 7~9 parts of rice bran,
5~8 parts of expanded perlite, 2.2~3.4 parts of alundum (Al2O3), 9~11 parts of clinker, 4~6 parts of diamond dust, glass fibre 2~3
Part, 2.6~3.3 parts of carbon fiber, 1~2 part of fire retardant, 2.1~2.6 parts of activating agent.
Preferably, the Novel fireproof material, the raw material of following parts by weight is included：16 parts of flyash, black mud powder 20 part, day
Right 16 parts of mica sheet powder, 17 parts of hollow glass microbead, 12 parts of polyvinyl chloride resin, 8 parts of rice bran, 7 parts of expanded perlite, alundum (Al2O3)
2.8 parts, 10 parts of clinker, 5 parts of diamond dust, 2.7 parts of glass fibre, 3 parts of carbon fiber, 1.5 parts of fire retardant, 2.4 parts of activating agent.
Preferably, the glass fibre is alkali-free glass fibre, a diameter of 8~12 microns of the alkali-free glass fibre.
Preferably, the activating agent uses AES activating agents.
Preferably, the black mud powder is made up of the sludge in fish pond or reservoir bottom.
A kind of method for preparing the Novel fireproof material, comprises the following steps：
（1）Flyash, black mud powder, natural mica piece powder, hollow glass microbead, polyvinyl chloride resin, rice bran, swollen is weighed by above-mentioned formula
Swollen perlite, alundum (Al2O3), clinker, diamond dust, glass fibre, carbon fiber, fire retardant, activating agent, it is standby；
（2）By flyash, black mud powder, natural mica piece powder, hollow glass microbead, rice bran, expanded perlite, alundum (Al2O3),
Clinker, diamond dust, glass fibre, carbon fiber stir well mixed, are placed in grinder and grind 1~2 hour, obtain mixed-powder；
（3）By step（2）Obtained mixed-powder adds water, and it is 20%~30% to make its water content, is placed in sealing reactor, heating
To 50~60 degrees Celsius, polyvinyl chloride resin is added, stirring reaction 20~60 minutes, fire retardant and activating agent is added, stirs, obtain
Mixed slurry；
（4）By step（3）Obtained mixed slurry is placed in mould, is press-formed, and is dried, and its water content is less than 5%, is produced
The Novel fireproof material.
Preferably, the step（4）The pressure of middle extrusion forming is 13~18MPa, and pressing time is 20~30 minutes.
Compared with prior art, it has the advantages that the present invention：
The cost of material is low for Novel fireproof of the present invention, heat-proof quality is good, fire resistance period length, is adapted to various fire engineerings to make
With specific as follows：
（1）The present invention uses them, one side production cost using flyash, black mud powder, rice bran, clinker as raw material
It is low, it on the other hand will become waste material, rubbish and be recycled again into secondary resource, this meets national environmental protection policy, while black mud powder
It is bonding agent natural well, is favorably improved the performance of the fire proofing material；
（2）The rapid foaming and intumescing that chemically reacts is produced after the expanded perlite of the present invention, the mixing such as hollow glass microbead, possesses guarantor
Warm heat-insulating, fire-preventing anti-flaming function, significantly improve the fire protection flame retarding function of the Novel fireproof material；
（3）Present invention blending carbon fiber improves the anti-folding and compression strength of product, prevents contraction fissure, improves intensity, Er Qiejia
Material weight, the intensity of reinforcing material can be reduced by entering carbon fiber；
（4）The glass fibre of the present invention does not produce chemical reaction with other materials, is entirely to improve product by physical action
Service behaviour and mechanical property, fine effect is played to the stability of product, when extending the fire resisting of the Novel fireproof material
Between.
Embodiment
With reference to specific embodiment, the present invention is expanded on further.These embodiments are merely to illustrate the present invention and not had to
In limitation the scope of the present invention.
Embodiment 1
The present embodiment is related to a kind of Novel fireproof material, includes the raw material of following parts by weight：13 parts of flyash, 15 parts of black mud powder,
13 parts of natural mica piece powder, 15 parts of hollow glass microbead, 8 parts of polyvinyl chloride resin, 5 parts of rice bran, 3 parts of expanded perlite, alundum (Al2O3)
2 parts, 7 parts of clinker, 3 parts of diamond dust, 1 part of glass fibre, 2 parts of carbon fiber, 1 part of fire retardant, 2 parts of activating agent.
Wherein, the glass fibre is alkali-free glass fibre, a diameter of 8~12 microns of the alkali-free glass fibre.
Wherein, the activating agent uses AES activating agents.
Wherein, the black mud powder is made up of fish pond sludge.
A kind of method for preparing the Novel fireproof material, comprises the following steps：
（1）Flyash, black mud powder, natural mica piece powder, hollow glass microbead, polyvinyl chloride resin, rice bran, swollen is weighed by above-mentioned formula
Swollen perlite, alundum (Al2O3), clinker, diamond dust, glass fibre, carbon fiber, fire retardant, activating agent, it is standby；
（2）By flyash, black mud powder, natural mica piece powder, hollow glass microbead, rice bran, expanded perlite, alundum (Al2O3),
Clinker, diamond dust, glass fibre, carbon fiber stir well mixed, are placed in grinder and grind 1~2 hour, obtain mixed-powder；
（3）By step（2）Obtained mixed-powder adds water, and it is 20% to make its water content, is placed in sealing reactor, is heated to 50
Degree Celsius, polyvinyl chloride resin is added, stirring reaction 20 minutes, fire retardant and activating agent is added, stirs, obtain mixed slurry；
（4）By step（3）Obtained mixed slurry is placed in mould, is press-formed, and is dried, and its water content is less than 5%, is produced
The Novel fireproof material.
Wherein, the step（4）The pressure of middle extrusion forming is 13MPa, and pressing time is 20 minutes.
Embodiment 2
The present embodiment is related to a kind of Novel fireproof material, includes the raw material of following parts by weight：18 parts of flyash, 25 parts of black mud powder,
18 parts of natural mica piece powder, 20 parts of hollow glass microbead, 15 parts of polyvinyl chloride resin, 10 parts of rice bran, 9 parts of expanded perlite, three oxidations two
4 parts of aluminium, 12 parts of clinker, 7 parts of diamond dust, 4 parts of glass fibre, 4 parts of carbon fiber, 2 parts of fire retardant, 3 parts of activating agent.
Wherein, the glass fibre is alkali-free glass fibre, a diameter of 8~12 microns of the alkali-free glass fibre.
Wherein, the activating agent uses AES activating agents.
Wherein, the black mud powder is made up of the sludge of reservoir bottom.
A kind of method for preparing the Novel fireproof material, comprises the following steps：
（1）Flyash, black mud powder, natural mica piece powder, hollow glass microbead, polyvinyl chloride resin, rice bran, swollen is weighed by above-mentioned formula
Swollen perlite, alundum (Al2O3), clinker, diamond dust, glass fibre, carbon fiber, fire retardant, activating agent, it is standby；
（2）By flyash, black mud powder, natural mica piece powder, hollow glass microbead, rice bran, expanded perlite, alundum (Al2O3),
Clinker, diamond dust, glass fibre, carbon fiber stir well mixed, are placed in grinder and grind 2 hours, obtain mixed-powder；
（3）By step（2）Obtained mixed-powder adds water, and it is 30% to make its water content, is placed in sealing reactor, is heated to 60
Degree Celsius, polyvinyl chloride resin is added, stirring reaction 60 minutes, fire retardant and activating agent is added, stirs, obtain mixed slurry；
（4）By step（3）Obtained mixed slurry is placed in mould, is press-formed, and is dried, and its water content is less than 5%, is produced
The Novel fireproof material.
Wherein, the step（4）The pressure of middle extrusion forming is 18MPa, and pressing time is 30 minutes.
Embodiment 3
The present embodiment is related to a kind of Novel fireproof material, includes the raw material of following parts by weight：14 parts of flyash, 18 parts of black mud powder,
15 parts of natural mica piece powder, 16 parts of hollow glass microbead, 10 parts of polyvinyl chloride resin, 7 parts of rice bran, 5 parts of expanded perlite, three oxidations two
2.2 parts of aluminium, 9 parts of clinker, 4 parts of diamond dust, 2 parts of glass fibre, 2.6 parts of carbon fiber, 1 part of fire retardant, 2.1 parts of activating agent.
Wherein, the glass fibre is alkali-free glass fibre, a diameter of 8~12 microns of the alkali-free glass fibre.
Wherein, the activating agent uses AES activating agents.
Wherein, the black mud powder is made up of the sludge of reservoir bottom.
A kind of method for preparing the Novel fireproof material, comprises the following steps：
（1）Flyash, black mud powder, natural mica piece powder, hollow glass microbead, polyvinyl chloride resin, rice bran, swollen is weighed by above-mentioned formula
Swollen perlite, alundum (Al2O3), clinker, diamond dust, glass fibre, carbon fiber, fire retardant, activating agent, it is standby；
（2）By flyash, black mud powder, natural mica piece powder, hollow glass microbead, rice bran, expanded perlite, alundum (Al2O3),
Clinker, diamond dust, glass fibre, carbon fiber stir well mixed, are placed in grinder and grind 1~2 hour, obtain mixed-powder；
（3）By step（2）Obtained mixed-powder adds water, and it is 22% to make its water content, is placed in sealing reactor, is heated to 52
Degree Celsius, polyvinyl chloride resin is added, stirring reaction 30 minutes, fire retardant and activating agent is added, stirs, obtain mixed slurry；
（4）By step（3）Obtained mixed slurry is placed in mould, is press-formed, and is dried, and its water content is less than 5%, is produced
The Novel fireproof material.
Wherein, the step（4）The pressure of middle extrusion forming is 14MPa, and pressing time is 22 minutes.
Embodiment 4
The present embodiment is related to a kind of Novel fireproof material, includes the raw material of following parts by weight：17 parts of flyash, 22 parts of black mud powder,
17 parts of natural mica piece powder, 18 parts of hollow glass microbead, 13 parts of polyvinyl chloride resin, 9 parts of rice bran, 8 parts of expanded perlite, three oxidations two
3.4 parts of aluminium, 11 parts of clinker, 6 parts of diamond dust, 3 parts of glass fibre, 3.3 parts of carbon fiber, 2 parts of fire retardant, 2.6 parts of activating agent.
Wherein, the glass fibre is alkali-free glass fibre, a diameter of 8~12 microns of the alkali-free glass fibre.
Wherein, the activating agent uses AES activating agents.
Wherein, the black mud powder is made up of the sludge of fish pond bottom.
A kind of method for preparing the Novel fireproof material, including lower step：
（1）Flyash, black mud powder, natural mica piece powder, hollow glass microbead, polyvinyl chloride resin, rice bran, swollen is weighed by above-mentioned formula
Swollen perlite, alundum (Al2O3), clinker, diamond dust, glass fibre, carbon fiber, fire retardant, activating agent, it is standby；
（2）By flyash, black mud powder, natural mica piece powder, hollow glass microbead, rice bran, expanded perlite, alundum (Al2O3),
Clinker, diamond dust, glass fibre, carbon fiber stir well mixed, are placed in grinder and grind 1~2 hour, obtain mixed-powder；
（3）By step（2）Obtained mixed-powder adds water, and it is 29% to make its water content, is placed in sealing reactor, is heated to 58
Degree Celsius, polyvinyl chloride resin is added, stirring reaction 50 minutes, fire retardant and activating agent is added, stirs, obtain mixed slurry；
（4）By step（3）Obtained mixed slurry is placed in mould, is press-formed, and is dried, and its water content is less than 5%, is produced
The Novel fireproof material.
Wherein, the step（4）The pressure of middle extrusion forming is 16MPa, and pressing time is 28 minutes.
Embodiment 5
The present embodiment is related to a kind of Novel fireproof material, includes the raw material of following parts by weight：16 parts of flyash, 20 parts of black mud powder,
16 parts of natural mica piece powder, 17 parts of hollow glass microbead, 12 parts of polyvinyl chloride resin, 8 parts of rice bran, 7 parts of expanded perlite, three oxidations two
2.8 parts of aluminium, 10 parts of clinker, 5 parts of diamond dust, 2.7 parts of glass fibre, 3 parts of carbon fiber, 1.5 parts of fire retardant, 2.4 parts of activating agent.
Wherein, the glass fibre is alkali-free glass fibre, a diameter of 8~12 microns of the alkali-free glass fibre.
Wherein, the activating agent uses AES activating agents.
Wherein, the black mud powder is made up of the sludge in fish pond or reservoir bottom.
A kind of method for preparing the Novel fireproof material, comprises the following steps：
（1）Flyash, black mud powder, natural mica piece powder, hollow glass microbead, polyvinyl chloride resin, rice bran, swollen is weighed by above-mentioned formula
Swollen perlite, alundum (Al2O3), clinker, diamond dust, glass fibre, carbon fiber, fire retardant, activating agent, it is standby；
（2）By flyash, black mud powder, natural mica piece powder, hollow glass microbead, rice bran, expanded perlite, alundum (Al2O3),
Clinker, diamond dust, glass fibre, carbon fiber stir well mixed, are placed in grinder and grind 1~2 hour, obtain mixed-powder；
（3）By step（2）Obtained mixed-powder adds water, and it is 27% to make its water content, is placed in sealing reactor, is heated to 53
Degree Celsius, polyvinyl chloride resin is added, stirring reaction 45 minutes, fire retardant and activating agent is added, stirs, obtain mixed slurry；
（4）By step（3）Obtained mixed slurry is placed in mould, is press-formed, and is dried, and its water content is less than 5%, is produced
The Novel fireproof material.
Wherein, the step（4）The pressure of middle extrusion forming is 16MPa, and pressing time is 26 minutes.
The specific embodiment of the present invention is described above.It is to be appreciated that the invention is not limited in above-mentioned
Particular implementation, those skilled in the art can make various deformations or amendments within the scope of the claims, this not shadow
Ring the substantive content of the present invention.
Claims (8)
1. a kind of Novel fireproof material, it is characterised in that include the raw material of following parts by weight：13~18 parts of flyash, black mud powder
15~25 parts, 13~18 parts of natural mica piece powder, 15~20 parts of hollow glass microbead, 8~15 parts of polyvinyl chloride resin, rice bran 5~10
Part, 3~9 parts of expanded perlite, 2~4 parts of alundum (Al2O3), 7~12 parts of clinker, 3~7 parts of diamond dust, 1~4 part of glass fibre,
2~4 parts of carbon fiber, 1~2 part of fire retardant, 2~3 parts of activating agent.
2. Novel fireproof material according to claim 1, it is characterised in that include the raw material of following parts by weight：Flyash
14~17 parts, 18~22 parts of black mud powder, 15~17 parts of natural mica piece powder, 16~18 parts of hollow glass microbead, polyvinyl chloride resin 10~
13 parts, 7~9 parts of rice bran, 5~8 parts of expanded perlite, 2.2~3.4 parts of alundum (Al2O3), 9~11 parts of clinker, diamond dust 4~6
Part, 2~3 parts of glass fibre, 2.6~3.3 parts of carbon fiber, 1~2 part of fire retardant, 2.1~2.6 parts of activating agent.
3. Novel fireproof material according to claim 1, it is characterised in that include the raw material of following parts by weight：Flyash
16 parts, 20 parts of black mud powder, 16 parts of natural mica piece powder, 17 parts of hollow glass microbead, 12 parts of polyvinyl chloride resin, 8 parts of rice bran, expansion it is precious
7 parts of pearl rock, 2.8 parts of alundum (Al2O3), 10 parts of clinker, 5 parts of diamond dust, 2.7 parts of glass fibre, 3 parts of carbon fiber, fire retardant 1.5
Part, 2.4 parts of activating agent.
4. Novel fireproof material according to claim 1, it is characterised in that the glass fibre is alkali-free glass fibre,
A diameter of 8~12 microns of the alkali-free glass fibre.
5. Novel fireproof material according to claim 1, it is characterised in that the activating agent uses AES activating agents.
6. Novel fireproof material according to claim 1, it is characterised in that the black mud powder is by fish pond or reservoir bottom
Sludge be made.
A kind of 7. method for preparing any one of the claim 1~6 Novel fireproof material, it is characterised in that the preparation side
Method comprises the following steps：
（1）Flyash, black mud powder, natural mica piece powder, hollow glass microbead, polyvinyl chloride resin, rice bran, swollen is weighed by above-mentioned formula
Swollen perlite, alundum (Al2O3), clinker, diamond dust, glass fibre, carbon fiber, fire retardant, activating agent, it is standby；
（2）By flyash, black mud powder, natural mica piece powder, hollow glass microbead, rice bran, expanded perlite, alundum (Al2O3),
Clinker, diamond dust, glass fibre, carbon fiber stir well mixed, are placed in grinder and grind 1~2 hour, obtain mixed-powder；
（3）By step（2）Obtained mixed-powder adds water, and it is 20%~30% to make its water content, is placed in sealing reactor, heating
To 50~60 degrees Celsius, polyvinyl chloride resin is added, stirring reaction 20~60 minutes, fire retardant and activating agent is added, stirs, obtain
Mixed slurry；
（4）By step（3）Obtained mixed slurry is placed in mould, is press-formed, and is dried, and its water content is less than 5%, is produced
The Novel fireproof material.
8. preparation method according to claim 7, it is characterised in that the step（4）The pressure of middle extrusion forming is 13
~18MPa, pressing time are 20~30 minutes.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111910865A (en) * | 2020-07-20 | 2020-11-10 | 甘肃巴斯得建筑节能材料科技有限公司 | Preparation method of capsule type high-flame-retardant fireproof heat-insulation decorative plate |
| CN115160838A (en) * | 2022-09-02 | 2022-10-11 | 昀迪新能源科技(苏州)有限公司 | Fireproof coating, preparation method and application thereof in power battery |
| DE102021114649B3 (en) | 2021-06-08 | 2022-10-20 | Long-Ann Chiu | Composition for fire prevention, explosion prevention and thermal insulation and method for the production thereof |
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Application publication date: 20171201 |