CN101168983A - Thermal insulation decorative brick and producing method thereof - Google Patents
Thermal insulation decorative brick and producing method thereof Download PDFInfo
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- CN101168983A CN101168983A CNA2007101694363A CN200710169436A CN101168983A CN 101168983 A CN101168983 A CN 101168983A CN A2007101694363 A CNA2007101694363 A CN A2007101694363A CN 200710169436 A CN200710169436 A CN 200710169436A CN 101168983 A CN101168983 A CN 101168983A
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- insulation
- brick
- hollow
- tile
- heat
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- 238000009413 insulation Methods 0.000 title claims abstract description 43
- 239000011449 brick Substances 0.000 title claims description 32
- 238000000034 method Methods 0.000 title abstract description 9
- 238000004519 manufacturing process Methods 0.000 claims abstract description 13
- 239000004570 mortar (masonry) Substances 0.000 claims abstract description 9
- 238000000465 moulding Methods 0.000 claims abstract description 5
- 239000011464 hollow brick Substances 0.000 claims description 35
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 11
- 239000000843 powder Substances 0.000 claims description 11
- 239000000463 material Substances 0.000 claims description 10
- 229910052802 copper Inorganic materials 0.000 claims description 9
- 239000010949 copper Substances 0.000 claims description 9
- 229920006389 polyphenyl polymer Polymers 0.000 claims description 8
- 229920001971 elastomer Polymers 0.000 claims description 7
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 6
- 239000004568 cement Substances 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 5
- 238000005516 engineering process Methods 0.000 claims description 5
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000011810 insulating material Substances 0.000 claims description 4
- 239000003973 paint Substances 0.000 claims description 4
- 239000004793 Polystyrene Substances 0.000 claims description 3
- 229920002522 Wood fibre Polymers 0.000 claims description 3
- 238000001125 extrusion Methods 0.000 claims description 3
- 239000011468 face brick Substances 0.000 claims description 3
- 239000010881 fly ash Substances 0.000 claims description 3
- 239000000395 magnesium oxide Substances 0.000 claims description 3
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 claims description 3
- 229920002223 polystyrene Polymers 0.000 claims description 3
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 3
- 229910001948 sodium oxide Inorganic materials 0.000 claims description 3
- CBOCVOKPQGJKKJ-UHFFFAOYSA-L Calcium formate Chemical compound [Ca+2].[O-]C=O.[O-]C=O CBOCVOKPQGJKKJ-UHFFFAOYSA-L 0.000 claims description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 2
- 239000006004 Quartz sand Substances 0.000 claims description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 2
- 229940044172 calcium formate Drugs 0.000 claims description 2
- 235000019255 calcium formate Nutrition 0.000 claims description 2
- 239000004281 calcium formate Substances 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- -1 extruded sheet Substances 0.000 claims description 2
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 claims description 2
- 238000012423 maintenance Methods 0.000 claims description 2
- 239000011490 mineral wool Substances 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 238000005498 polishing Methods 0.000 claims description 2
- 229920002635 polyurethane Polymers 0.000 claims description 2
- 239000004814 polyurethane Substances 0.000 claims description 2
- 230000002265 prevention Effects 0.000 claims description 2
- 239000007921 spray Substances 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims description 2
- 210000001138 tear Anatomy 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- 239000000654 additive Substances 0.000 claims 1
- 230000000996 additive effect Effects 0.000 claims 1
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 15
- 238000010276 construction Methods 0.000 abstract description 6
- 239000000853 adhesive Substances 0.000 abstract description 3
- 230000001070 adhesive effect Effects 0.000 abstract description 3
- 238000004134 energy conservation Methods 0.000 abstract description 3
- 239000003513 alkali Substances 0.000 abstract description 2
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 239000012774 insulation material Substances 0.000 abstract 2
- 239000012790 adhesive layer Substances 0.000 abstract 1
- 238000009434 installation Methods 0.000 abstract 1
- 239000010410 layer Substances 0.000 abstract 1
- 239000002344 surface layer Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 description 2
- 208000019901 Anxiety disease Diseases 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- 230000036506 anxiety Effects 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 230000037396 body weight Effects 0.000 description 1
- 238000009435 building construction Methods 0.000 description 1
- 239000011083 cement mortar Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000023753 dehiscence Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000007730 finishing process Methods 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000011527 polyurethane coating Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
Images
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- Building Environments (AREA)
- Finishing Walls (AREA)
Abstract
The invention relates to an insulation facing tile, and a production method thereof. The insulation facing tile is characterized in that the hollow tile is made of the low weight insulation material, either the left side or the right side of the hollow tile is produced to be raised head shaped, the other side is produced to be a groove shape which can be put into the raised head, the hollow part of the hollow tile is filled with an insulation body made of the insulation material and tightly combined with the inner surface of the hollow tile, and a colored ornament surface is adhered on an adhesive layer on the outer surface of the hollow tile. The ornament surface of the tile is directed outward, the raised head of another tile is inserted into the groove and leveled, and the joint is filled with insulation mortar, to form an outer wall. The tile integrates three construction processes of a wall enclosure structure, an insulating layer, and the ornament surface layer together, the on-site installation is simple, convenient, and quick, the quality is easy to be ensured, with safety and reliability, and crack, falling off, cold bridge, alkali resistance and molding of the outer wall surface are avoided; the requirements on energy conservation, environmental protection and aesthetic appearance are met, and the insulation effect is good; the invention can replace a hollow tile, an outer wall insulation adhesive ornament surface and an invention ornament plate.
Description
One, technical field
What the present invention relates to is a kind of building to be worked the materials for wall of the effect of going along with sb. to guard him, specifically a kind of heat-preserving facing brick and production method thereof.
Two, background technology
In recent years, the anxiety of the resource and the energy has caused people's great attention, many advantages such as the solid brick of firing than earth because of hollow brick economizes the land resource, need not fire, in light weight, the support energetically that has obtained national policy in building construction has obtained using widely.Though hollow on the hollow brick brick body has sound insulation, heat insulation effect, because the air transmitted heat of hollow part is very fast, effect of heat insulation is not good.The hollow brick cement composition of using is more now, causes body weight, sound insulation, effect of heat insulation all undesirable.In order to strengthen indoor temperature in winter, people are by adding decorative layer again at the exterior surface of wall adhesive insulating layer, just can reach the building energy conservation requirement.The insulation of skin at present has several different methods, and that mainly uses has EPS polyphenyl board exterior wall paste heat-preserving, XPS extruded sheet exterior wall paste heat-preserving, adhesive polystyrene granule heat-insulating, polyurethane coating insulation, the insulation of decorative plate of outer wall technology for applying and sandwich wall insulation etc. several.Though several heat preserving methods have played certain insulation effect to the house, but weak point is: the working procedure complexity, the job site workload is big, the labour intensity height, difficult quality guarantee, insulation is yielding when high and low temperature, phenomenon such as cause thermal insulation dehiscence, leak, come off, and heat insulation effect is poor.The EPS polyphenyl board exterior wall paste heat-preserving maximum as present application; its construction sequence is: use cement mortar screeding earlier on the body of wall that hollow brick is built into; polyphenyl plate is bonded on the metope fixes with expandable nail; reprocess fibre polymer mortar, glass cross are made topping, and outermost layer spraying inorganic coating is as decorative layer.That the multipass operation has been wasted is a large amount of artificial, material and duration; If the uneven polyphenyl plate of pasting of metope causes polyphenyl plate distortion or hollowing; Do not have the isolation layer polyphenyl plate overheated or to cross cold time distortion winter serious, cause phenomenons such as metope ftractures, leaks, comes off in summer.Decorative plate of outer wall technology for applying heat insulation effect is better, but difficulty of construction is big, the cost height, and the user is difficult to bear.
Three, summary of the invention
In order to solve the deficiencies in the prior art, the purpose of this invention is to provide that a kind of high insulating effect, construction are simple, long service life, low price, heat-preserving facing brick and production method thereof that facing is attractive in appearance.
Realize that the technical scheme that purpose of the present invention adopts is: this heat-preserving facing brick mainly is made up of hollow brick, insulation and decorative cover; The plush copper shape is made in a side of the left and right sides face of hollow brick, and the groove shape that can be put in the plush copper is made in another side; The hollow part of hollow brick is filled with the insulation of combining closely with the hollow brick inner face, is bonded with decorative cover by tack coat on the lateral surface of hollow brick; Decorative cover prevents the diaphragm that decorative cover weares and teares before being covered with application outward.
The production method of heat-preserving facing brick is: after the flyash with 14.8%, 49% magnesia, 15% sawdust, 20% sodium oxide molybdena, 1% rubber powder and 0.2% curing compound mix, stirred 10 minutes, and put into mould vibration, hollow brick is made in extrusion modling; Fill the insulation of making by heat insulating material in the hollow part of hollow brick, be bonded with decorative cover by tack coat on the lateral surface of hollow brick, decorative cover external application upper protective film, it is neat to be put on the tray sign indicating number, and with twining the film parcel, finished product is put in storage.
When building a wall, with the decorative cover of heat-preserving facing brick outwardly, the plush copper of another piece face brick is inserted levelling in the groove, and the contact site of brick and brick is filled and gone up insulating mortar, thereby forms the exterior wall of stifled surperficial magnificent a, high insulating effect.
Compared with prior art because the architectural feature of this heat-preserving facing brick is that the collection insulation is the novel architecture brick of one with facing, this brick body is light in the present invention, sound insulation, good heat-insulation effect; This brick is integrated masonry wall structure, insulation layer, finish coat, and with the synthetic procedure of three road working procedures, speed of application has improved more than three times, reduces construction cost; This brick of structures shape can specializedly be produced in enormous quantities, low cost of manufacture, and process is simple, long service life; On-the-spot install simply, convenient, fast, ensure the quality of products easily, safe and reliable, the metope of having avoided external wall outer insulation to occur ftractures, comes off, cold bridge, anti-alkali, phenomenon such as mouldy; Energy-saving and environmental protection and good looking appearance requirement have been satisfied, high insulating effect; So, build a wall hollow brick and all exterior-wall heat insulation stickup decorative cover and outer wall heat insulating and decorating plates in this alternative past of heat-preserving facing brick.
Four, description of drawings
Fig. 1 is the vertical view of heat-preserving facing brick of the present invention.
Fig. 2 is the A-A sectional structure chart of Fig. 1.
Five, the specific embodiment
In the accompanying drawings, heat-preserving facing brick of the present invention mainly is made up of hollow brick, insulation and decorative cover; Hollow brick 1 stirred 10 minutes after being mixed by the curing compound of 14.8% flyash, 49% magnesia, 15% sawdust, 20% sodium oxide molybdena, 1% rubber powder and 0.2%, put into that mould vibrates, extrusion modling is made; The hollow brick body that above-mentioned material is made is light, sound insulation, good heat-insulation effect; Described curing compound is the curing compound that ethylenediamine or other suitable constructional materialss are used.Plush copper 5 shapes are made in a side of the left and right sides face of hollow brick 1, and groove 6 shapes that can be put in the plush copper 5 are made in another side, and the hollow part of hollow brick 1 is filled with insulation 2, and insulation 2 is made by heat insulating material; Heat insulating material can be used the wherein a kind of of materials such as polyphenyl plate, polyurethane, granular polystyrene, extruded sheet, mineral wool; Difference according to fill insulant material combines closely insulation 2 and hollow brick 1 inner face by insufflation, pressurization, solidification method.Available 7% dicalcium powder on the lateral surface of hollow brick 1,58.5% Mi Shi, 30% 42.5
#Cement, 1% wood fibre, 2% rubber powder and 1.5% light agent, the iron oxide black, the iron oxide yellow chromatic timing powder that add trace again, adding stirs behind an amount of water makes the anticracking mortar, the pattern tool makes the mortar moulding after the hollow brick moulding, firmly contacts through technologies such as vibration, extruding, maintenance and hollow brick and forms decorative cover 4; Also reliable tack coat 3 is pasted fire prevention, heat insulation, waterproof alumina silicate panel on the lateral surface of hollow brick 1, and again with after the panel polishing, primer spray, colored paint, finish paint form decorative cover 4.Described tack coat 3 be by 35% 42.5
#After mixing, cement, 60% quartz sand, 3% rubber powder, 2% wood fibre, 2% calcium formate make; The decorative cover 4 outer diaphragms 7 that are covered with are not so that the protection facing has wearing and tearing before use.When building a wall, with the decorative cover of heat-preserving facing brick outwardly, the plush copper of another piece face brick is inserted levelling in the groove, and the contact site of brick and brick is filled and gone up insulating mortar, thereby forms the exterior wall of stifled surperficial magnificent a, high insulating effect.Described insulating mortar is exactly the material of system hollow brick.Plush copper is inserted in the groove can make the wall thermal insulating better effects if.The advantage of its heat-preserving facing brick: 1. heat-preserving facing brick is the hollow brick that is squeezed into by insulation, light material, and the middle vacancy of brick is fill insulant material again, and the low hollow brick of coefficient of thermal conductivity is incubated more; 2. finish coat is once finished " finishing process according to the requirement of building exterior decoration color on production line, and making brick surface finish error only is 0.001 ‰; 3. spillage of material is low, is zero loss substantially, the glossiness height; Product quality is finished and is controlled in the workshop, and packaging and warehousing detects before dispatching from the factory again after the assay was approved, makes product percent of pass reach 100%; 4. construct and work out the product modulus according to wide grade of modulus design floor height, product is marched into the arena and is not made of salt, Exposure to Sunlight etc., good management, and it is few to take the factory site, and mechanized handling is saved landing hire; 5. easy construction, quick, the duration short; 6. the wall surface finish is controlled well, is built into horizontal putting down vertically just, finishes building main body, and insulation, facing complete simultaneously; 7. can not occur ftractureing, come off, problem such as peeling, hollowing, cold bridge; 8. energy-conservation reaching more than 65%.
Claims (6)
1. heat-preserving facing brick and production method thereof, face brick mainly is made up of hollow brick, insulation and decorative cover; Plush copper (5) shape is made in a side that it is characterized in that the left and right sides face of hollow brick (1), groove (6) shape that can be put in the plush copper (5) is made in another side, the hollow part of hollow brick (1) is filled with the insulation (2) of combining closely with the hollow brick inner face, is bonded with decorative cover (4) by tack coat (3) on the lateral surface of hollow brick (1); Prevent the diaphragm (7) that decorative cover weares and teares before being covered with application outside the decorative cover (4).
2. production method of producing the described heat-preserving facing brick of claim 1, after the described hollow brick of its feature (1) is mixed by the curing compound of 14.8% flyash, 49% magnesia, 15% sawdust, 20% sodium oxide molybdena, 1% rubber powder and 0.2%, stirred 10 minutes, and put into mould vibration, extrusion modling is made.
3. the production method of heat-preserving facing brick as claimed in claim 1 is characterized in that the heat insulating material of described insulation (2) application can be used the wherein a kind of of materials such as polyphenyl plate, polyurethane, granular polystyrene, extruded sheet, mineral wool.
4. the production method of heat-preserving facing brick as claimed in claim 1, it is characterized in that described decorative panel (4) be with 7% dicalcium powder, 58.5% Mi Shi, 30% 42.5
#Cement, 1% wood fibre, 2% rubber powder and 1.5% light agent, the iron oxide black, the iron oxide yellow chromatic timing powder that add trace again, adding stirs behind an amount of water makes the anticracking mortar, the pattern tool makes the mortar moulding after the hollow brick moulding, firmly contacts formation through technologies such as vibration, extruding, maintenance and hollow brick.
5. as the production method of claim 1 or 4 described heat-preserving facing bricks, it is characterized in that described decorative panel (4) also can lean on tack coat (3) to paste fire prevention, heat insulation, waterproof alumina silicate panel on the lateral surface of hollow brick (1), with after the panel polishing, primer spray, colored paint, finish paint form again.
6. the production method of heat-preserving facing brick as claimed in claim 1, it is characterized in that described tack coat (3) be by 35% 42.5
#After mixing, cement, 60% quartz sand, 3% rubber powder, 2% polymeric additive, 2% calcium formate make.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2007101694363A CN101168983A (en) | 2007-11-11 | 2007-11-11 | Thermal insulation decorative brick and producing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2007101694363A CN101168983A (en) | 2007-11-11 | 2007-11-11 | Thermal insulation decorative brick and producing method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101168983A true CN101168983A (en) | 2008-04-30 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2007101694363A Pending CN101168983A (en) | 2007-11-11 | 2007-11-11 | Thermal insulation decorative brick and producing method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101168983A (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102417341A (en) * | 2011-07-22 | 2012-04-18 | 广州市建筑科学研究院有限公司 | Novel baking-free inorganic facing brick and preparation method thereof |
| CN102452126A (en) * | 2010-10-27 | 2012-05-16 | 陈景云 | How to make hollow bricks |
| CN104420609A (en) * | 2013-08-26 | 2015-03-18 | 唐代全 | Wall building brick free of secondary double-face decoration |
| CN106495613A (en) * | 2016-11-03 | 2017-03-15 | 威骏（湖北）高新实业股份有限公司 | A kind of heat preservation decoration integrative tapestry brick and preparation method thereof |
| CN107512881A (en) * | 2017-09-12 | 2017-12-26 | 成都新柯力化工科技有限公司 | A kind of external wall patch block of decorative heat preservation one and preparation method thereof |
| CN107663920A (en) * | 2017-09-23 | 2018-02-06 | 镇江市太浪新材料科技有限公司 | A kind of construction material brick with high fire protecting performance |
| CN110394880A (en) * | 2019-07-22 | 2019-11-01 | 中国建筑材料科学研究总院有限公司 | Imitation volcanic slag decorative sheet, imitation volcanic slag veneer decorative block and processing method thereof |
| CN112454654A (en) * | 2020-11-30 | 2021-03-09 | 东南大学扬州研究院 | Preparation method of novel heat-insulation building material |
| CN114278000A (en) * | 2021-11-17 | 2022-04-05 | 浙江绿城房屋服务系统有限公司 | Heat-insulating wall anti-cracking building block and manufacturing method thereof |
| CN117067357A (en) * | 2023-08-29 | 2023-11-17 | 马鞍山市苏林保温材料有限公司 | A kind of preparation method of thermal insulation material |
-
2007
- 2007-11-11 CN CNA2007101694363A patent/CN101168983A/en active Pending
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102452126A (en) * | 2010-10-27 | 2012-05-16 | 陈景云 | How to make hollow bricks |
| CN102417341A (en) * | 2011-07-22 | 2012-04-18 | 广州市建筑科学研究院有限公司 | Novel baking-free inorganic facing brick and preparation method thereof |
| CN104420609A (en) * | 2013-08-26 | 2015-03-18 | 唐代全 | Wall building brick free of secondary double-face decoration |
| CN106495613A (en) * | 2016-11-03 | 2017-03-15 | 威骏（湖北）高新实业股份有限公司 | A kind of heat preservation decoration integrative tapestry brick and preparation method thereof |
| CN106495613B (en) * | 2016-11-03 | 2019-02-05 | 威骏（湖北）高新实业股份有限公司 | A kind of thermal insulation and decoration integrated facing brick and preparation method thereof |
| CN107512881A (en) * | 2017-09-12 | 2017-12-26 | 成都新柯力化工科技有限公司 | A kind of external wall patch block of decorative heat preservation one and preparation method thereof |
| CN107663920A (en) * | 2017-09-23 | 2018-02-06 | 镇江市太浪新材料科技有限公司 | A kind of construction material brick with high fire protecting performance |
| CN110394880A (en) * | 2019-07-22 | 2019-11-01 | 中国建筑材料科学研究总院有限公司 | Imitation volcanic slag decorative sheet, imitation volcanic slag veneer decorative block and processing method thereof |
| CN112454654A (en) * | 2020-11-30 | 2021-03-09 | 东南大学扬州研究院 | Preparation method of novel heat-insulation building material |
| CN114278000A (en) * | 2021-11-17 | 2022-04-05 | 浙江绿城房屋服务系统有限公司 | Heat-insulating wall anti-cracking building block and manufacturing method thereof |
| CN117067357A (en) * | 2023-08-29 | 2023-11-17 | 马鞍山市苏林保温材料有限公司 | A kind of preparation method of thermal insulation material |
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Open date: 20080430 |