CN117720769B - 一种复合阻燃增效剂以及一种阻燃尼龙材料 - Google Patents
一种复合阻燃增效剂以及一种阻燃尼龙材料 Download PDFInfo
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- CN117720769B CN117720769B CN202410171561.1A CN202410171561A CN117720769B CN 117720769 B CN117720769 B CN 117720769B CN 202410171561 A CN202410171561 A CN 202410171561A CN 117720769 B CN117720769 B CN 117720769B
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- flame retardant
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- 239000003063 flame retardant Substances 0.000 title claims abstract description 105
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 101
- 239000002131 composite material Substances 0.000 title claims abstract description 55
- 239000004677 Nylon Substances 0.000 title claims abstract description 26
- 229920001778 nylon Polymers 0.000 title claims abstract description 26
- 239000000463 material Substances 0.000 title claims abstract description 15
- ZQKXQUJXLSSJCH-UHFFFAOYSA-N melamine cyanurate Chemical compound NC1=NC(N)=NC(N)=N1.O=C1NC(=O)NC(=O)N1 ZQKXQUJXLSSJCH-UHFFFAOYSA-N 0.000 claims description 29
- SDDHGPUTTUMFDO-UHFFFAOYSA-N benzenesulfonic acid;1,3,5-triazine-2,4,6-triamine Chemical compound NC1=NC(N)=NC(N)=N1.OS(=O)(=O)C1=CC=CC=C1 SDDHGPUTTUMFDO-UHFFFAOYSA-N 0.000 claims description 16
- 239000003963 antioxidant agent Substances 0.000 claims description 11
- 230000003078 antioxidant effect Effects 0.000 claims description 11
- 229920000877 Melamine resin Polymers 0.000 claims description 10
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 claims description 10
- 229940092714 benzenesulfonic acid Drugs 0.000 claims description 10
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 10
- 229940074404 sodium succinate Drugs 0.000 claims description 9
- ZDQYSKICYIVCPN-UHFFFAOYSA-L sodium succinate (anhydrous) Chemical compound [Na+].[Na+].[O-]C(=O)CCC([O-])=O ZDQYSKICYIVCPN-UHFFFAOYSA-L 0.000 claims description 9
- 238000006243 chemical reaction Methods 0.000 claims description 7
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 claims description 6
- XYXJKPCGSGVSBO-UHFFFAOYSA-N 1,3,5-tris[(4-tert-butyl-3-hydroxy-2,6-dimethylphenyl)methyl]-1,3,5-triazinane-2,4,6-trione Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C)=C1CN1C(=O)N(CC=2C(=C(O)C(=CC=2C)C(C)(C)C)C)C(=O)N(CC=2C(=C(O)C(=CC=2C)C(C)(C)C)C)C1=O XYXJKPCGSGVSBO-UHFFFAOYSA-N 0.000 claims description 3
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims description 3
- 238000000034 method Methods 0.000 abstract description 5
- 229920000742 Cotton Polymers 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 4
- 230000001737 promoting effect Effects 0.000 abstract 1
- 230000009044 synergistic interaction Effects 0.000 abstract 1
- 238000002156 mixing Methods 0.000 description 15
- 238000001035 drying Methods 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 9
- 239000008367 deionised water Substances 0.000 description 6
- 229910021641 deionized water Inorganic materials 0.000 description 6
- 238000009472 formulation Methods 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 238000001125 extrusion Methods 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- 229920002292 Nylon 6 Polymers 0.000 description 4
- 239000012065 filter cake Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 239000004114 Ammonium polyphosphate Substances 0.000 description 3
- 239000004594 Masterbatch (MB) Substances 0.000 description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- 239000004952 Polyamide Substances 0.000 description 3
- 235000019826 ammonium polyphosphate Nutrition 0.000 description 3
- 229920001276 ammonium polyphosphate Polymers 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000005469 granulation Methods 0.000 description 3
- 230000003179 granulation Effects 0.000 description 3
- 238000001746 injection moulding Methods 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920002647 polyamide Polymers 0.000 description 3
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical group [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 3
- 235000019982 sodium hexametaphosphate Nutrition 0.000 description 3
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 3
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 150000007974 melamines Chemical class 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 238000005303 weighing Methods 0.000 description 2
- DXZMANYCMVCPIM-UHFFFAOYSA-L zinc;diethylphosphinate Chemical compound [Zn+2].CCP([O-])(=O)CC.CCP([O-])(=O)CC DXZMANYCMVCPIM-UHFFFAOYSA-L 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229920001281 polyalkylene Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- -1 polyol fatty acid ester Chemical class 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
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- Compositions Of Macromolecular Compounds (AREA)
- Fireproofing Substances (AREA)
Abstract
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CN202410171561.1A CN117720769B (zh) | 2024-02-07 | 2024-02-07 | 一种复合阻燃增效剂以及一种阻燃尼龙材料 |
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CN117720769A CN117720769A (zh) | 2024-03-19 |
CN117720769B true CN117720769B (zh) | 2024-04-30 |
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Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1174563A (zh) * | 1994-12-01 | 1998-02-25 | Dsm有限公司 | 阻燃聚酰胺组合物 |
CN1334287A (zh) * | 2000-07-26 | 2002-02-06 | 西巴特殊化学品控股有限公司 | 低厚度的透明聚合物制品 |
CN1482192A (zh) * | 2001-09-26 | 2004-03-17 | 希普雷公司 | 与外涂光刻胶一起使用的涂料组合物 |
CN1711313A (zh) * | 2002-11-04 | 2005-12-21 | 西巴特殊化学品控股有限公司 | 阻燃剂组合物 |
CN1860165A (zh) * | 2003-10-01 | 2006-11-08 | 西巴特殊化学品控股有限公司 | 阻燃剂组合物 |
CN103408926A (zh) * | 2013-06-26 | 2013-11-27 | 安徽科聚新材料有限公司 | 一种聚酰胺复合材料及其制备方法 |
CN103642227A (zh) * | 2013-11-18 | 2014-03-19 | 安徽宜万丰电器有限公司 | 一种汽车塑料件用聚苯硫醚改性尼龙材料 |
JP2017128677A (ja) * | 2016-01-21 | 2017-07-27 | 株式会社Adeka | 帯電防止性熱可塑性樹脂組成物およびそれを成形してなる成形体 |
CN112143203A (zh) * | 2020-10-21 | 2020-12-29 | 横店集团得邦工程塑料有限公司 | 一种耐湿热pc/abs阻燃复合材料及其制备方法 |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2004111131A1 (ja) * | 2003-05-26 | 2004-12-23 | Polyplastics Co., Ltd. | 難燃性樹脂組成物 |
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- 2024-02-07 CN CN202410171561.1A patent/CN117720769B/zh active Active
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1174563A (zh) * | 1994-12-01 | 1998-02-25 | Dsm有限公司 | 阻燃聚酰胺组合物 |
CN1334287A (zh) * | 2000-07-26 | 2002-02-06 | 西巴特殊化学品控股有限公司 | 低厚度的透明聚合物制品 |
CN1482192A (zh) * | 2001-09-26 | 2004-03-17 | 希普雷公司 | 与外涂光刻胶一起使用的涂料组合物 |
CN1711313A (zh) * | 2002-11-04 | 2005-12-21 | 西巴特殊化学品控股有限公司 | 阻燃剂组合物 |
CN1860165A (zh) * | 2003-10-01 | 2006-11-08 | 西巴特殊化学品控股有限公司 | 阻燃剂组合物 |
CN103408926A (zh) * | 2013-06-26 | 2013-11-27 | 安徽科聚新材料有限公司 | 一种聚酰胺复合材料及其制备方法 |
CN103642227A (zh) * | 2013-11-18 | 2014-03-19 | 安徽宜万丰电器有限公司 | 一种汽车塑料件用聚苯硫醚改性尼龙材料 |
JP2017128677A (ja) * | 2016-01-21 | 2017-07-27 | 株式会社Adeka | 帯電防止性熱可塑性樹脂組成物およびそれを成形してなる成形体 |
CN112143203A (zh) * | 2020-10-21 | 2020-12-29 | 横店集团得邦工程塑料有限公司 | 一种耐湿热pc/abs阻燃复合材料及其制备方法 |
Non-Patent Citations (1)
Title |
---|
琥珀酸钠对十溴联苯醚的降解作用研究;江利梅等;山东化工;20211231;第50卷(第15期);257-262 * |
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Address after: No. 436 Anxian Road, Group 15, Wenquan Community, Chengdu Cross Strait Science and Technology Industrial Development Park, Wenjiang District, Chengdu City, Sichuan Province, 610000 Patentee after: Sichuan Xingjinghua Technology Co.,Ltd. Country or region after: China Address before: No. 79, Xingxin Road, Chengdu cross strait science and Technology Industrial Development Park, Wenjiang District, Chengdu, Sichuan 610000 Patentee before: Sichuan Xingjinghua Technology Co.,Ltd. Country or region before: China |