CN1164541C - 甲苯选择性歧化和甲苯与碳九及其以上芳烃歧化与烷基转移方法 - Google Patents

甲苯选择性歧化和甲苯与碳九及其以上芳烃歧化与烷基转移方法 Download PDF

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Publication number
CN1164541C
CN1164541C CNB011319534A CN01131953A CN1164541C CN 1164541 C CN1164541 C CN 1164541C CN B011319534 A CNB011319534 A CN B011319534A CN 01131953 A CN01131953 A CN 01131953A CN 1164541 C CN1164541 C CN 1164541C
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China
Prior art keywords
toluene
disproportionation
unit
aromatics
transalkylation
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Expired - Lifetime
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CNB011319534A
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English (en)
Chinese (zh)
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CN1413968A (zh
Inventor
л�ڿ�
谢在库
杨卫胜
孔德金
朱冬茂
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China Petroleum and Chemical Corp
Sinopec Shanghai Research Institute of Petrochemical Technology
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China Petroleum and Chemical Corp
Sinopec Shanghai Research Institute of Petrochemical Technology
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Priority to CNB011319534A priority Critical patent/CN1164541C/zh
Application filed by China Petroleum and Chemical Corp, Sinopec Shanghai Research Institute of Petrochemical Technology filed Critical China Petroleum and Chemical Corp
Priority to JP2003538106A priority patent/JP4360909B2/ja
Priority to EP02776641A priority patent/EP1447395B1/en
Priority to KR1020047005878A priority patent/KR100909841B1/ko
Priority to PCT/CN2002/000732 priority patent/WO2003035589A1/zh
Priority to US10/277,694 priority patent/US6774273B2/en
Publication of CN1413968A publication Critical patent/CN1413968A/zh
Priority to ZA2004/02874A priority patent/ZA200402874B/en
Application granted granted Critical
Publication of CN1164541C publication Critical patent/CN1164541C/zh
Anticipated expiration legal-status Critical
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/08—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
    • C07C6/12—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/02—Monocyclic hydrocarbons
    • C07C15/067—C8H10 hydrocarbons
    • C07C15/08—Xylenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/02—Monocyclic hydrocarbons
    • C07C15/04—Benzene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/08—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
    • C07C6/12—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
    • C07C6/123—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring of only one hydrocarbon
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/08—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
    • C07C6/12—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
    • C07C6/126—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring of more than one hydrocarbon
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • C07C2529/26—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C07C2529/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11 containing iron group metals, noble metals or copper
    • C07C2529/44—Noble metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C07C2529/48—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11 containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • C07C2529/78—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65 containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
CNB011319534A 2001-10-22 2001-10-22 甲苯选择性歧化和甲苯与碳九及其以上芳烃歧化与烷基转移方法 Expired - Lifetime CN1164541C (zh)

Priority Applications (7)

Application Number Priority Date Filing Date Title
CNB011319534A CN1164541C (zh) 2001-10-22 2001-10-22 甲苯选择性歧化和甲苯与碳九及其以上芳烃歧化与烷基转移方法
EP02776641A EP1447395B1 (en) 2001-10-22 2002-10-18 THE SELECTIVE DISMUTATION PROCESS OF TOLUENE AND THE DISMUTATION AND TRANSALKYLATION PROCESS OF TOLUENE AND AROMATIC HYDROCARBONS OF C9 AND C9&plus
KR1020047005878A KR100909841B1 (ko) 2001-10-22 2002-10-18 톨루엔의 선택적 불균등화 방법 및 톨루엔 및 ｃ9 및ｃ9+의 방향족 탄화수소들의 불균등화 및 트랜스알킬화 방법
PCT/CN2002/000732 WO2003035589A1 (en) 2001-10-22 2002-10-18 The selective dismutation process of toluene and the dismut5ation and transalkylation process of toluene and aromatic hydrocarbons of c9 and c9+
JP2003538106A JP4360909B2 (ja) 2001-10-22 2002-10-18 トルエンの選択的不均化方法、トルエンとｃ９、ｃ９＋芳香族炭化水素との不均化およびアルキル交換反応方法
US10/277,694 US6774273B2 (en) 2001-10-22 2002-10-22 Process for selective disproportionation of toluene and disproportionation and transalkylation of toluene and C9+ aromatics
ZA2004/02874A ZA200402874B (en) 2001-10-22 2004-04-16 The selective dismutation process of toluene and the dismutation and transai kylation process of toluene and aromatic hydrocarbons of c9 and c9+

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CNB011319534A CN1164541C (zh) 2001-10-22 2001-10-22 甲苯选择性歧化和甲苯与碳九及其以上芳烃歧化与烷基转移方法

Publications (2)

Publication Number Publication Date
CN1413968A CN1413968A (zh) 2003-04-30
CN1164541C true CN1164541C (zh) 2004-09-01

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Country Status (7)

Country Link
US (1) US6774273B2 (enExample)
EP (1) EP1447395B1 (enExample)
JP (1) JP4360909B2 (enExample)
KR (1) KR100909841B1 (enExample)
CN (1) CN1164541C (enExample)
WO (1) WO2003035589A1 (enExample)
ZA (1) ZA200402874B (enExample)

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CN109790084A (zh) * 2016-10-04 2019-05-21 埃克森美孚化学专利公司 重质芳烃的烷基转移

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CN100335449C (zh) * 2005-06-22 2007-09-05 中国石油化工股份有限公司 用于芳烃生产的方法
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KR100843436B1 (ko) * 2007-04-27 2008-07-03 삼성토탈 주식회사 유사 이동층 크실렌 혼합물 전처리 공정 및 추가의 크실렌이성질화 공정을 포함하는 방향족 화합물의 분리 방법
KR100963746B1 (ko) * 2008-03-13 2010-06-14 삼성토탈 주식회사 유사 이동층 분리법에 의한 방향족 화합물의 분리방법
CN101811926B (zh) * 2009-02-19 2013-06-05 中国石油化工股份有限公司 芳烃联合生产的方法
CN101885661B (zh) * 2009-05-13 2013-09-18 中国石油化工股份有限公司 芳烃联合生产的组合方法
CN101993335B (zh) * 2009-08-31 2013-12-04 中国石油化工股份有限公司 芳烃生产中对二甲苯增产的组合方法
CN101993332B (zh) * 2009-08-31 2013-06-19 中国石油化工股份有限公司 联合生产芳烃的组合方法
KR101173345B1 (ko) 2009-11-10 2012-08-10 에스케이이노베이션 주식회사 방향족 화합물을 포함하는 유분으로부터 고부가 방향족 제품 및 올레핀 제품을 생산하는 방법
CN102199066B (zh) * 2010-03-25 2014-05-28 中国石油化工股份有限公司 一种烷基芳烃异构化方法
JP5759262B2 (ja) * 2011-05-24 2015-08-05 Ｊｘ日鉱日石エネルギー株式会社 キシレンの製造方法
CN104557434B (zh) * 2013-10-28 2019-05-14 中国石油化工股份有限公司 生产对二甲苯的方法
RU2687104C2 (ru) * 2014-02-13 2019-05-07 Бипи Корпорейшен Норт Америка Инк. Энергосберегающий способ фракционирования для разделения выходящего потока реактора процессов переалкилирования tol/с9+
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CN106925339B (zh) * 2015-12-31 2019-09-03 中国石油天然气股份有限公司 用于碳八芳烃中二甲苯异构化反应的多级孔分子筛催化剂的制备方法
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US6774273B2 (en) 2004-08-10
KR20040064694A (ko) 2004-07-19
CN1413968A (zh) 2003-04-30
KR100909841B1 (ko) 2009-07-28
EP1447395B1 (en) 2011-12-21
JP2005506376A (ja) 2005-03-03
ZA200402874B (en) 2005-05-25
JP4360909B2 (ja) 2009-11-11
EP1447395A4 (en) 2009-11-11
US20030130549A1 (en) 2003-07-10
WO2003035589A1 (en) 2003-05-01
EP1447395A1 (en) 2004-08-18

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