CN116446192B - 一种发热保暖面料及其制备方法 - Google Patents
一种发热保暖面料及其制备方法 Download PDFInfo
- Publication number
- CN116446192B CN116446192B CN202310500897.3A CN202310500897A CN116446192B CN 116446192 B CN116446192 B CN 116446192B CN 202310500897 A CN202310500897 A CN 202310500897A CN 116446192 B CN116446192 B CN 116446192B
- Authority
- CN
- China
- Prior art keywords
- heating
- parts
- warming
- fabric
- span
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000010438 heat treatment Methods 0.000 title claims abstract description 76
- 239000004744 fabric Substances 0.000 title claims abstract description 55
- 238000010792 warming Methods 0.000 title claims abstract description 33
- 238000002360 preparation method Methods 0.000 title claims abstract description 32
- 238000004519 manufacturing process Methods 0.000 title description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 32
- 239000002245 particle Substances 0.000 claims abstract description 22
- 238000009413 insulation Methods 0.000 claims abstract description 15
- 239000011248 coating agent Substances 0.000 claims abstract description 12
- 238000000576 coating method Methods 0.000 claims abstract description 12
- 229920000742 Cotton Polymers 0.000 claims abstract description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229920002401 polyacrylamide Polymers 0.000 claims abstract description 8
- 239000008367 deionised water Substances 0.000 claims abstract description 6
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 6
- 239000002994 raw material Substances 0.000 claims abstract description 6
- 239000004965 Silica aerogel Substances 0.000 claims abstract description 5
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 5
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 5
- 239000002562 thickening agent Substances 0.000 claims abstract description 5
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 30
- 239000004005 microsphere Substances 0.000 claims description 24
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 20
- -1 tween-40 Polymers 0.000 claims description 17
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims description 16
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 15
- 239000003973 paint Substances 0.000 claims description 15
- 239000011787 zinc oxide Substances 0.000 claims description 15
- 229910001928 zirconium oxide Inorganic materials 0.000 claims description 15
- 239000003054 catalyst Substances 0.000 claims description 12
- 239000003921 oil Substances 0.000 claims description 12
- 229920001690 polydopamine Polymers 0.000 claims description 12
- RNWHGQJWIACOKP-UHFFFAOYSA-N zinc;oxygen(2-) Chemical class [O-2].[Zn+2] RNWHGQJWIACOKP-UHFFFAOYSA-N 0.000 claims description 10
- 238000001354 calcination Methods 0.000 claims description 9
- BSDOQSMQCZQLDV-UHFFFAOYSA-N butan-1-olate;zirconium(4+) Chemical compound [Zr+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] BSDOQSMQCZQLDV-UHFFFAOYSA-N 0.000 claims description 8
- 238000006243 chemical reaction Methods 0.000 claims description 8
- 239000011592 zinc chloride Substances 0.000 claims description 8
- 235000005074 zinc chloride Nutrition 0.000 claims description 8
- CTENFNNZBMHDDG-UHFFFAOYSA-N Dopamine hydrochloride Chemical compound Cl.NCCC1=CC=C(O)C(O)=C1 CTENFNNZBMHDDG-UHFFFAOYSA-N 0.000 claims description 7
- 229960001149 dopamine hydrochloride Drugs 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 7
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 6
- 239000003960 organic solvent Substances 0.000 claims description 6
- QKNYBSVHEMOAJP-UHFFFAOYSA-N 2-amino-2-(hydroxymethyl)propane-1,3-diol;hydron;chloride Chemical group Cl.OCC(N)(CO)CO QKNYBSVHEMOAJP-UHFFFAOYSA-N 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 5
- 230000001804 emulsifying effect Effects 0.000 claims description 5
- 238000001879 gelation Methods 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 238000002791 soaking Methods 0.000 claims description 5
- 238000005406 washing Methods 0.000 claims description 5
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims description 4
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 claims description 4
- 229920002125 Sokalan® Polymers 0.000 claims description 4
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 claims description 4
- 229920000136 polysorbate Polymers 0.000 claims description 4
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims description 3
- IKEHOXWJQXIQAG-UHFFFAOYSA-N 2-tert-butyl-4-methylphenol Chemical compound CC1=CC=C(O)C(C(C)(C)C)=C1 IKEHOXWJQXIQAG-UHFFFAOYSA-N 0.000 claims description 3
- 229920002907 Guar gum Polymers 0.000 claims description 3
- 229920001213 Polysorbate 20 Polymers 0.000 claims description 3
- NWGKJDSIEKMTRX-AAZCQSIUSA-N Sorbitan monooleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NWGKJDSIEKMTRX-AAZCQSIUSA-N 0.000 claims description 3
- IYFATESGLOUGBX-YVNJGZBMSA-N Sorbitan monopalmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O IYFATESGLOUGBX-YVNJGZBMSA-N 0.000 claims description 3
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 3
- LWZFANDGMFTDAV-BURFUSLBSA-N [(2r)-2-[(2r,3r,4s)-3,4-dihydroxyoxolan-2-yl]-2-hydroxyethyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O LWZFANDGMFTDAV-BURFUSLBSA-N 0.000 claims description 3
- 239000000665 guar gum Substances 0.000 claims description 3
- 235000010417 guar gum Nutrition 0.000 claims description 3
- 229960002154 guar gum Drugs 0.000 claims description 3
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 claims description 3
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 claims description 3
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 claims description 3
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 claims description 3
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 claims description 3
- 239000003208 petroleum Substances 0.000 claims description 3
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 claims description 3
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 claims description 3
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 3
- 229920000053 polysorbate 80 Polymers 0.000 claims description 3
- 235000010413 sodium alginate Nutrition 0.000 claims description 3
- 239000000661 sodium alginate Substances 0.000 claims description 3
- 229940005550 sodium alginate Drugs 0.000 claims description 3
- 235000011067 sorbitan monolaureate Nutrition 0.000 claims description 3
- LNAZSHAWQACDHT-XIYTZBAFSA-N (2r,3r,4s,5r,6s)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2s,3r,4s,5r,6r)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6r)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 claims description 2
- IRFSXVIRXMYULF-UHFFFAOYSA-N 1,2-dihydroquinoline Chemical compound C1=CC=C2C=CCNC2=C1 IRFSXVIRXMYULF-UHFFFAOYSA-N 0.000 claims description 2
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 claims description 2
- 244000215068 Acacia senegal Species 0.000 claims description 2
- 229920001817 Agar Polymers 0.000 claims description 2
- 229920001661 Chitosan Polymers 0.000 claims description 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims description 2
- 108010010803 Gelatin Proteins 0.000 claims description 2
- 229920000084 Gum arabic Polymers 0.000 claims description 2
- 244000043261 Hevea brasiliensis Species 0.000 claims description 2
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims description 2
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims description 2
- 239000004166 Lanolin Substances 0.000 claims description 2
- UAEPNZWRGJTJPN-UHFFFAOYSA-N Methylcyclohexane Natural products CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 claims description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 2
- 239000005062 Polybutadiene Substances 0.000 claims description 2
- 239000004698 Polyethylene Substances 0.000 claims description 2
- 229920001214 Polysorbate 60 Polymers 0.000 claims description 2
- 229920002396 Polyurea Polymers 0.000 claims description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 2
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 claims description 2
- 108010073771 Soybean Proteins Proteins 0.000 claims description 2
- 229920002472 Starch Polymers 0.000 claims description 2
- 235000010489 acacia gum Nutrition 0.000 claims description 2
- 239000000205 acacia gum Substances 0.000 claims description 2
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 claims description 2
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 2
- 239000008272 agar Substances 0.000 claims description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 2
- 239000005018 casein Substances 0.000 claims description 2
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 claims description 2
- 235000021240 caseins Nutrition 0.000 claims description 2
- 239000000839 emulsion Substances 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 239000008273 gelatin Substances 0.000 claims description 2
- 229920000159 gelatin Polymers 0.000 claims description 2
- 235000019322 gelatine Nutrition 0.000 claims description 2
- 235000011852 gelatine desserts Nutrition 0.000 claims description 2
- NUKZAGXMHTUAFE-UHFFFAOYSA-N hexanoic acid methyl ester Natural products CCCCCC(=O)OC NUKZAGXMHTUAFE-UHFFFAOYSA-N 0.000 claims description 2
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims description 2
- 229940039717 lanolin Drugs 0.000 claims description 2
- 235000019388 lanolin Nutrition 0.000 claims description 2
- 229920000609 methyl cellulose Polymers 0.000 claims description 2
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 claims description 2
- 239000001923 methylcellulose Substances 0.000 claims description 2
- 235000010981 methylcellulose Nutrition 0.000 claims description 2
- 229920003052 natural elastomer Polymers 0.000 claims description 2
- 229920001194 natural rubber Polymers 0.000 claims description 2
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 claims description 2
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 2
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 2
- 229920000058 polyacrylate Polymers 0.000 claims description 2
- 239000004584 polyacrylic acid Substances 0.000 claims description 2
- 229920002857 polybutadiene Polymers 0.000 claims description 2
- 229920000573 polyethylene Polymers 0.000 claims description 2
- 229920002635 polyurethane Polymers 0.000 claims description 2
- 239000004814 polyurethane Substances 0.000 claims description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 2
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 2
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 2
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 2
- 230000035484 reaction time Effects 0.000 claims description 2
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims description 2
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims description 2
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 2
- 229940001941 soy protein Drugs 0.000 claims description 2
- 239000008107 starch Substances 0.000 claims description 2
- 235000019698 starch Nutrition 0.000 claims description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 2
- 239000001993 wax Substances 0.000 claims description 2
- 239000000230 xanthan gum Substances 0.000 claims description 2
- 235000010493 xanthan gum Nutrition 0.000 claims description 2
- 229920001285 xanthan gum Polymers 0.000 claims description 2
- 229940082509 xanthan gum Drugs 0.000 claims description 2
- 239000008096 xylene Substances 0.000 claims description 2
- 229920005989 resin Polymers 0.000 claims 1
- 239000011347 resin Substances 0.000 claims 1
- 230000006872 improvement Effects 0.000 abstract description 11
- 238000007598 dipping method Methods 0.000 abstract description 5
- 230000000052 comparative effect Effects 0.000 description 13
- 230000000694 effects Effects 0.000 description 8
- 239000004753 textile Substances 0.000 description 4
- 239000004594 Masterbatch (MB) Substances 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000004964 aerogel Substances 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 230000020169 heat generation Effects 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 238000004321 preservation Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 229960001631 carbomer Drugs 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000002036 drum drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000003837 high-temperature calcination Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 210000001161 mammalian embryo Anatomy 0.000 description 1
- 238000002074 melt spinning Methods 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 230000004089 microcirculation Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000009740 moulding (composite fabrication) Methods 0.000 description 1
- 239000007783 nanoporous material Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0009—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using knitted fabrics
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0059—Organic ingredients with special effects, e.g. oil- or water-repellent, antimicrobial, flame-resistant, magnetic, bactericidal, odour-influencing agents; perfumes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0086—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
- D06N3/0088—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by directly applying the resin
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/06—Properties of the materials having thermal properties
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
本发明提出了一种发热保暖面料及其制备方法，属于面料技术领域。在纯棉面料上均匀浸渍一层发热保暖涂料，所述发热保暖涂料由以下原料按重量份制备而成：聚丙烯酰胺40‑50份、远红外发热颗粒5‑10份、二氧化硅气凝胶3‑5份、增稠剂1‑2份、抗氧剂0.1‑0.4份、去离子水70‑90份。本发明制得的面料具有远红外发热和提高保暖的功能，具有广阔的应用前景。
Description
技术领域
本发明涉及面料技术领域，具体涉及一种发热保暖面料及其制备方法。
背景技术
针织面料即是利用织针将纱线弯曲成圈并相互串套而形成的织物。针织面料的组织结构使得其具有良好的弹性和延伸性，织物柔软且透气度好。目前，市面上出现了一些功能性针织面料，其具有防辐射、杀菌、防火隔热等特殊功效，尤其是具有发热、保暖、保温效果的面料，其应用范围广，市场需求大，因此受到广泛研究。
中国专利申请CN105146780A公开了一种智能发热针织面料的生产工艺，属于纺织工艺技术领域。该申请首先将聚酯纤维母粒和远红外矿石粉母粒混合均匀，依次通过转鼓干燥，熔融喷丝，成型、卷绕及落桶，集束工序，牵伸，切割和打包，纺纱，织布和胚布成品工艺，并通过服装加工工艺制成保暖内衣，聚酯纤维由分散于其中的远红外发射颗粒发射远红外射线，以提供隔热和健康促进效果，本发明透气性强，不易破损，且具有优异的储热和隔热性能。
发明内容
本发明的目的在于提出一种发热保暖面料及其制备方法，制得的面料具有远红外发热和提高保暖性能的功能。
本发明的技术方案是这样实现的：
本发明提供一种发热保暖面料，在纯棉面料上均匀浸渍一层发热保暖涂料，所述发热保暖涂料由以下原料按重量份制备而成：聚丙烯酰胺40-50份、远红外发热颗粒5-10份、二氧化硅气凝胶3-5份、增稠剂1-2份、抗氧剂0.1-0.4份、去离子水70-90份。
作为本发明的进一步改进，所述远红外发热颗粒的制备方法如下：
S1.将锆酸四丁酯、司盘溶于有机溶剂中，制得油相；
S2.将氯化锌、吐温溶于水中，制得水相；
S3.将水相滴加于油相中，乳化，凝胶化反应，离心，洗涤，煅烧，制得氧化锌/氧化锆微球；
S4.将步骤S3制得的氧化锌/氧化锆微球分散于水中，加入多巴胺盐酸盐和催化剂，加热搅拌反应，制得聚多巴胺改性氧化锌/氧化锆微球；
S5.将步骤S4制得的聚多巴胺改性氧化锌/氧化锆微球焙烧，制得远红外发热颗粒。
作为本发明的进一步改进，步骤S1中所述锆酸四丁酯、司盘和有机溶剂的质量比为10-15:0.5-1:50-70，所述司盘选自司盘-20、司盘-40、司盘-60、司盘-80中的至少一种，所述有机溶剂选自二氯甲烷、氯仿、甲苯、二甲苯、石油醚、乙酸乙酯、乙酸甲酯、乙酸丁酯、环己烷、正己烷中的至少一种。
作为本发明的进一步改进，步骤S2中所述氯化锌、吐温和水的质量比为7-12:1-2:100；所述吐温选自吐温-20、吐温-40、吐温-60、吐温-80中的至少一种。
作为本发明的进一步改进，步骤S3中所述水相和油相的质量比为30-50:70-100，所述凝胶化反应的时间为15-20min，所述煅烧的温度为300-500℃，时间为1-2h。
作为本发明的进一步改进，步骤S4中所述氧化锌/氧化锆微球、多巴胺盐酸盐和催化剂的质量比为10-15:12-17:0.1-0.2，所述催化剂为pH＝5.5-6的Tris-HCl溶液，所述加热搅拌反应的温度为35-45℃，时间为1-2h。
作为本发明的进一步改进，步骤S5中所述焙烧的温度为1200-1500℃，时间为2-3h。
作为本发明的进一步改进，所述增稠剂选自甲基纤维素、羟丙基甲基纤维素、羧甲基纤维素钠、羟乙基纤维素、淀粉、明胶、海藻酸钠、干酪素、瓜尔胶、甲壳胺、阿拉伯树胶、黄原胶、大豆蛋白胶、天然橡胶、羊毛脂、琼脂、聚丙烯酰胺、聚乙烯醇、聚乙烯吡咯烷酮、聚氧化乙烯、卡波树脂、聚丙烯酸、聚丙烯酸钠、聚丙烯酸酯共聚乳液、顺丁橡胶、丁苯橡胶、聚氨酯、改性聚脲、低分子聚乙烯蜡中的至少一种。
作为本发明的进一步改进，所述抗氧剂选自二苯胺、对苯二胺、二氢喹啉、2，6-三级丁基-4-甲基苯酚、双(3，5-三级丁基-4-羟基苯基)硫醚、四〔β-(3，5-三级丁基-4-羟基苯基)丙酸〕季戊四醇酯、三辛酯、三癸酯、三(十二碳醇)酯和三(十六碳醇)酯中的至少一种。
本发明进一步保护一种上述发热保暖面料的制备方法，包括以下步骤：
(1)将发热保暖涂料中各组分按比例混合均匀，制得发热保暖涂料；
(2)将纯棉面料浸渍在发热保暖涂料中，浴比为1:30-50，浸渍15-30min，取出，85-95℃干燥35-45min，制得发热保暖面料。
本发明具有如下有益效果：远红外线是指波长范围为6-15μm的电磁波，其可以穿入人体组织2-3mm，与人体内分子形成共振效应，加剧分子运动，从而达到蓄热保暖、增强血液微循环和提高新陈代谢的作用。远红外纺织品可以吸收太阳光中的短波能量或人体散发的热量，并将其以远红外辐射方式作用于人体，在医疗保健、服用纺织品等领域具有广阔的应用前景。本发明通过溶胶凝胶反应和离子沉积煅烧氧化制得了氧化锌/氧化锆微球，具有较好的发射远红外线的效果，并在其表面包覆一层聚多巴胺层，在高温焙烧的作用下，聚多巴胺碳化形成碳层并于氧化锌和氧化锆部分反应，制得ZrC和ZnC，进一步提高了发射远红外线的发射效果，使得制得的面料具有发热保暖的功能。另外，二氧化硅气凝胶颗粒是一种低密度、低导热性、高孔隙率、高比表面积的纳米多孔材料，进一步提高了面料发热后的保暖性能。
具体实施方式
下面将对本发明实施例中的技术方案进行清楚、完整地描述，显然，所描述的实施例仅仅是本发明一部分实施例，而不是全部的实施例。基于本发明中的实施例，本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例，都属于本发明保护的范围。
制备例1远红外发热颗粒的制备
方法如下：
S1.将10重量份锆酸四丁酯、0.5重量份司盘-20溶于50重量份乙酸丁酯中，制得油相；
S2.将7重量份氯化锌、1重量份吐温-20溶于100重量份水中，制得水相；
S3.将30重量份水相滴加于70重量份油相中，乳化，凝胶化反应15min，离心，洗涤，300℃煅烧1h，制得氧化锌/氧化锆微球；
S4.将10重量份步骤S3制得的氧化锌/氧化锆微球分散于100重量份水中，加入12重量份多巴胺盐酸盐和0.1重量份催化剂，加热至35℃，搅拌反应1h，制得聚多巴胺改性氧化锌/氧化锆微球；
所述催化剂为pH＝5.5的Tris-HCl溶液；
S5.将步骤S4制得的聚多巴胺改性氧化锌/氧化锆微球在1200℃焙烧2h，制得远红外发热颗粒。
制备例2远红外发热颗粒的制备
方法如下：
S1.将15重量份锆酸四丁酯、1重量份司盘-40溶于70重量份石油醚中，制得油相；
S2.将12重量份氯化锌、2重量份吐温-40溶于100重量份水中，制得水相；
S3.将50重量份水相滴加于100重量份油相中，乳化，凝胶化反应20min，离心，洗涤，500℃煅烧2h，制得氧化锌/氧化锆微球；
S4.将15重量份步骤S3制得的氧化锌/氧化锆微球分散于100重量份水中，加入17重量份多巴胺盐酸盐和0.2重量份催化剂，加热至45℃，搅拌反应2h，制得聚多巴胺改性氧化锌/氧化锆微球；
所述催化剂为pH＝6的Tris-HCl溶液；
S5.将步骤S4制得的聚多巴胺改性氧化锌/氧化锆微球在1500℃焙烧3h，制得远红外发热颗粒。
制备例3远红外发热颗粒的制备
方法如下：
S1.将12重量份锆酸四丁酯、0.7重量份司盘-80溶于60重量份正己烷中，制得油相；
S2.将10重量份氯化锌、1.5重量份吐温-80溶于100重量份水中，制得水相；
S3.将40重量份水相滴加于85重量份油相中，乳化，凝胶化反应17min，离心，洗涤，400℃煅烧1.5h，制得氧化锌/氧化锆微球；
S4.将12重量份步骤S3制得的氧化锌/氧化锆微球分散于100重量份水中，加入15重量份多巴胺盐酸盐和0.15重量份催化剂，加热至40℃，搅拌反应1.5h，制得聚多巴胺改性氧化锌/氧化锆微球；
所述催化剂为pH＝5.7的Tris-HCl溶液；
S5.将步骤S4制得的聚多巴胺改性氧化锌/氧化锆微球在1350℃焙烧2.5h，制得远红外发热颗粒。
对比制备例1
与制备例3相比，不同之处在于，步骤S2中未添加氯化锌。
对比制备例2
与制备例3相比，不同之处在于，步骤S1中未添加锆酸四丁酯。
对比制备例3
与制备例3相比，不同之处在于，未进行步骤S4。
对比制备例4
与制备例3相比，不同之处在于，未进行步骤S5。
实施例1
一种发热保暖面料，在纯棉面料上均匀浸渍一层发热保暖涂料，所述发热保暖涂料由以下原料按重量份制备而成：聚丙烯酰胺40份、制备例1制得的远红外发热颗粒5份、二氧化硅气凝胶3份、瓜尔胶1份、双(3，5-三级丁基-4-羟基苯基)硫醚0.1份、去离子水70份。
制备方法包括以下步骤：
(1)将发热保暖涂料中各组分按比例混合均匀，制得发热保暖涂料；
(2)将纯棉面料浸渍在发热保暖涂料中，浴比为1:30，浸渍15min，取出，85℃干燥35min，制得发热保暖面料。
实施例2
一种发热保暖面料，在纯棉面料上均匀浸渍一层发热保暖涂料，所述发热保暖涂料由以下原料按重量份制备而成：聚丙烯酰胺50份、制备例2制得的远红外发热颗粒10份、二氧化硅气凝胶5份、海藻酸钠2份、2，6-三级丁基-4-甲基苯酚0.4份、去离子水90份。
制备方法包括以下步骤：
(1)将发热保暖涂料中各组分按比例混合均匀，制得发热保暖涂料；
(2)将纯棉面料浸渍在发热保暖涂料中，浴比为1:50，浸渍30min，取出，95℃干燥45min，制得发热保暖面料。
实施例3
一种发热保暖面料，在纯棉面料上均匀浸渍一层发热保暖涂料，所述发热保暖涂料由以下原料按重量份制备而成：聚丙烯酰胺45份、制备例3制得的远红外发热颗粒7份、二氧化硅气凝胶4份、羟丙基甲基纤维素1.5份、三(十六碳醇)酯0.25份、去离子水80份。
制备方法包括以下步骤：
(1)将发热保暖涂料中各组分按比例混合均匀，制得发热保暖涂料；
(2)将纯棉面料浸渍在发热保暖涂料中，浴比为1:40，浸渍22min，取出，90℃干燥40min，制得发热保暖面料。
对比例1
与实施例3相比，不同之处在于，远红外发热颗粒由对比制备例1制得。
对比例2
与实施例3相比，不同之处在于，远红外发热颗粒由对比制备例2制得。
对比例3
与实施例3相比，不同之处在于，远红外发热颗粒由对比制备例3制得。
对比例4
与实施例3相比，不同之处在于，远红外发热颗粒由对比制备例4制得。
测试例1
将本发明实施例1-3和对比例1-4制得的发热保暖面料进行性能测试。
采用全自动强度测试仪对面料的力学性能进行表征。
采用接触角测试仪在25℃下进行测试。在面料表面滴水，并使用数码相机置于平视位置拍照，计算接触角。
参照FZ/T 73036-2010《吸湿发热针织内衣》测试吸湿发热保暖性能。
结果见表1。
由上表可知，本发明实施例1-3制得的发热保暖面料具有更好的综合性能。
以上所述仅为本发明的较佳实施例而已，并不用以限制本发明，凡在本发明的精神和原则之内，所作的任何修改、等同替换、改进等，均应包含在本发明的保护范围之内。
Claims (9)
1.一种发热保暖面料，其特征在于，在纯棉面料上均匀浸渍一层发热保暖涂料，所述发热保暖涂料由以下原料按重量份制备而成：聚丙烯酰胺40-50份、远红外发热颗粒5-10份、二氧化硅气凝胶3-5份、增稠剂1-2份、抗氧剂0.1-0.4份、去离子水70-90份；
所述远红外发热颗粒的制备方法如下：
S1.将锆酸四丁酯、司盘溶于有机溶剂中，制得油相；
S2.将氯化锌、吐温溶于水中，制得水相；
S3.将水相滴加于油相中，乳化，凝胶化反应，离心，洗涤，煅烧，制得氧化锌/氧化锆微球；
S4.将步骤S3制得的氧化锌/氧化锆微球分散于水中，加入多巴胺盐酸盐和催化剂，加热搅拌反应，制得聚多巴胺改性氧化锌/氧化锆微球；
S5.将步骤S4制得的聚多巴胺改性氧化锌/氧化锆微球焙烧，制得远红外发热颗粒。
2.根据权利要求1所述发热保暖面料，其特征在于，步骤S1中所述锆酸四丁酯、司盘和有机溶剂的质量比为10-15:0.5-1:50-70，所述司盘选自司盘-20、司盘-40、司盘-60、司盘-80中的至少一种，所述有机溶剂选自二氯甲烷、氯仿、甲苯、二甲苯、石油醚、乙酸乙酯、乙酸甲酯、乙酸丁酯、环己烷、正己烷中的至少一种。
3.根据权利要求1所述发热保暖面料，其特征在于，步骤S2中所述氯化锌、吐温和水的质量比为7-12:1-2:100；所述吐温选自吐温-20、吐温-40、吐温-60、吐温-80中的至少一种。
4.根据权利要求1所述发热保暖面料，其特征在于，步骤S3中所述水相和油相的质量比为30-50:70-100，所述凝胶化反应的时间为15-20min，所述煅烧的温度为300-500℃，时间为1-2h。
5.根据权利要求1所述发热保暖面料，其特征在于，步骤S4中所述氧化锌/氧化锆微球、多巴胺盐酸盐和催化剂的质量比为10-15:12-17:0.1-0.2，所述催化剂为pH=5.5-6的Tris-HCl溶液，所述加热搅拌反应的温度为35-45℃，时间为1-2h。
6.根据权利要求1所述发热保暖面料，其特征在于，步骤S5中所述焙烧的温度为1200-1500℃，时间为2-3h。
7.根据权利要求1所述发热保暖面料，其特征在于，所述增稠剂选自甲基纤维素、羟丙基甲基纤维素、羧甲基纤维素钠、羟乙基纤维素、淀粉、明胶、海藻酸钠、干酪素、瓜尔胶、甲壳胺、阿拉伯树胶、黄原胶、大豆蛋白胶、天然橡胶、羊毛脂、琼脂、聚丙烯酰胺、聚乙烯醇、聚乙烯吡咯烷酮、聚氧化乙烯、卡波树脂、聚丙烯酸、聚丙烯酸钠、聚丙烯酸酯共聚乳液、顺丁橡胶、丁苯橡胶、聚氨酯、改性聚脲、低分子聚乙烯蜡中的至少一种。
8.根据权利要求1所述发热保暖面料，其特征在于，所述抗氧剂选自二苯胺、对苯二胺、二氢喹啉、2，6-三级丁基-4-甲基苯酚、双(3，5-三级丁基-4-羟基苯基)硫醚、四〔β-(3，5-三级丁基-4-羟基苯基)丙酸〕季戊四醇酯、三辛酯、三癸酯、三(十二碳醇)酯和三(十六碳醇)酯中的至少一种。
9.一种如权利要求1-8任一项所述发热保暖面料的制备方法，其特征在于，包括以下步骤：
（1）将发热保暖涂料中各组分按比例混合均匀，制得发热保暖涂料；
（2）将纯棉面料浸渍在发热保暖涂料中，浴比为1:30-50，浸渍15-30min，取出，85-95℃干燥35-45min，制得发热保暖面料。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202310500897.3A CN116446192B (zh) | 2023-05-06 | 2023-05-06 | 一种发热保暖面料及其制备方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202310500897.3A CN116446192B (zh) | 2023-05-06 | 2023-05-06 | 一种发热保暖面料及其制备方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN116446192A CN116446192A (zh) | 2023-07-18 |
| CN116446192B true CN116446192B (zh) | 2024-04-02 |
Family
ID=87120295
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202310500897.3A Active CN116446192B (zh) | 2023-05-06 | 2023-05-06 | 一种发热保暖面料及其制备方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN116446192B (zh) |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105440583A (zh) * | 2015-12-04 | 2016-03-30 | 武汉理工大学 | 一种多巴胺类化合物修饰或包裹纳米粒子改性聚合物复合材料及其制备方法 |
| CN106049029A (zh) * | 2016-07-07 | 2016-10-26 | 上海大学 | 一种聚多巴胺包覆二氧化钒复合粉体基智能调温纺织品及其制作工艺 |
| CN106620702A (zh) * | 2017-02-14 | 2017-05-10 | 扬州大学 | 一种金/氮掺杂的空心碳纳米球核壳材料的制备方法 |
| CN109824936A (zh) * | 2019-01-28 | 2019-05-31 | 徐扣华 | 一种利用聚多巴胺改性氮化铝微球制备散热膜的方法 |
| CN111875387A (zh) * | 2020-06-24 | 2020-11-03 | 广东工业大学 | 一种用碳包覆制备低氧含量、高热导的氮化硅陶瓷的方法及其应用 |
| WO2021234162A2 (fr) * | 2020-05-22 | 2021-11-25 | Lithcote-Europe | Revêtement nano-céramique, hybride, transparent et biocide pour support solide et support solide comportant un tel revêtement et son procédé d'obtention |
| CN114146709A (zh) * | 2021-12-17 | 2022-03-08 | 南京大学 | 一种具有还原和氧化双性能的铁/聚多巴胺/炭复合催化剂及其制备方法和应用 |
| CN114702765A (zh) * | 2022-06-07 | 2022-07-05 | 上海科进生物技术有限公司 | 一种改性纳米微球、pc/pet复合材料及其制备方法 |
| CN115874458A (zh) * | 2022-11-30 | 2023-03-31 | 清远市乐友家居用品有限公司 | 一种隔热窗帘布料及其制备方法 |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11387053B2 (en) * | 2018-07-04 | 2022-07-12 | Soochow University | Aramid fiber electrode and preparation method therefor |
-
2023
- 2023-05-06 CN CN202310500897.3A patent/CN116446192B/zh active Active
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105440583A (zh) * | 2015-12-04 | 2016-03-30 | 武汉理工大学 | 一种多巴胺类化合物修饰或包裹纳米粒子改性聚合物复合材料及其制备方法 |
| CN106049029A (zh) * | 2016-07-07 | 2016-10-26 | 上海大学 | 一种聚多巴胺包覆二氧化钒复合粉体基智能调温纺织品及其制作工艺 |
| CN106620702A (zh) * | 2017-02-14 | 2017-05-10 | 扬州大学 | 一种金/氮掺杂的空心碳纳米球核壳材料的制备方法 |
| CN109824936A (zh) * | 2019-01-28 | 2019-05-31 | 徐扣华 | 一种利用聚多巴胺改性氮化铝微球制备散热膜的方法 |
| WO2021234162A2 (fr) * | 2020-05-22 | 2021-11-25 | Lithcote-Europe | Revêtement nano-céramique, hybride, transparent et biocide pour support solide et support solide comportant un tel revêtement et son procédé d'obtention |
| CN111875387A (zh) * | 2020-06-24 | 2020-11-03 | 广东工业大学 | 一种用碳包覆制备低氧含量、高热导的氮化硅陶瓷的方法及其应用 |
| CN114146709A (zh) * | 2021-12-17 | 2022-03-08 | 南京大学 | 一种具有还原和氧化双性能的铁/聚多巴胺/炭复合催化剂及其制备方法和应用 |
| CN114702765A (zh) * | 2022-06-07 | 2022-07-05 | 上海科进生物技术有限公司 | 一种改性纳米微球、pc/pet复合材料及其制备方法 |
| CN115874458A (zh) * | 2022-11-30 | 2023-03-31 | 清远市乐友家居用品有限公司 | 一种隔热窗帘布料及其制备方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN116446192A (zh) | 2023-07-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105220481B (zh) | 一种婴儿服装专用的抗静电面料 | |
| CN109112657B (zh) | 一种自发热纤维素纤维及其制备方法和应用 | |
| CN109736078B (zh) | 一种吸湿凉爽运动面料的后整理工艺 | |
| CN102311505B (zh) | 一种基于废弃溶解性纤维制备纤维素纳米球的方法 | |
| CN107354527A (zh) | 一种速热保暖纤维素纤维的制备方法 | |
| CN110079924A (zh) | 一种含石墨烯面料及其制备方法 | |
| CN116446192B (zh) | 一种发热保暖面料及其制备方法 | |
| CN115029849A (zh) | 一种多功能保暖针织面料及其制备方法 | |
| CN112376142A (zh) | 一种吸湿发热纱线及其制备方法和应用 | |
| CN114318876A (zh) | 一种医疗用抗菌的纺丝面料及其制备方法 | |
| CN114539773A (zh) | 一种长效抗菌耐高温原液着色母粒及其制备方法和应用 | |
| CN103653318A (zh) | 一种羊毛衫及其生产方法 | |
| CN109680394A (zh) | 一种保暖面料 | |
| CN206501534U (zh) | 一种抗菌阻燃针织布 | |
| CN113235318B (zh) | 一种保暖阻燃面料的制备工艺 | |
| CN114574987B (zh) | 一种潮湿环境中具有保暖效果的聚酯纤维材料及其制备方法 | |
| CN206244979U (zh) | 一种抗菌保暖针织布 | |
| CN113249858B (zh) | 一种长效吸湿排汗抗菌针织面料及其制备方法 | |
| CN108842270A (zh) | 能对温度微调节的三维立体结构面料 | |
| CN111206409B (zh) | 一种多功能牛角瓜纤维混纺面料制备工艺 | |
| CN115142257A (zh) | 一种MXene柔性布料的制备方法及其应用 | |
| CN112900078A (zh) | 一种抗菌面料及其制备方法 | |
| CN105533874A (zh) | 一种用于服装的锁紧收口织带的制造方法 | |
| CN206359819U (zh) | 一种抗菌防辐射针织布 | |
| CN220785144U (zh) | 一种防雨防污衬衣面料 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20240311 Address after: No. 88, South Street, Industrial Concentration District, Yuetang Town, Yizheng, Yangzhou City, Jiangsu Province, 225000 Applicant after: Yangzhou nuodeli Textile Technology Co.,Ltd. Country or region after: China Address before: Room 301, No. 33, Lujiang West Street, Haizhu District, Guangzhou, Guangdong 510220 Applicant before: Guangzhou Deyi Clothing Co.,Ltd. Country or region before: China |
|
| GR01 | Patent grant | ||
| GR01 | Patent grant |