CN116096777A - 一种金属粉末涂料用聚酯树脂及其制备方法和应用 - Google Patents
一种金属粉末涂料用聚酯树脂及其制备方法和应用 Download PDFInfo
- Publication number
- CN116096777A CN116096777A CN202280004573.4A CN202280004573A CN116096777A CN 116096777 A CN116096777 A CN 116096777A CN 202280004573 A CN202280004573 A CN 202280004573A CN 116096777 A CN116096777 A CN 116096777A
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- metal powder
- powder coating
- polyester resin
- mgkoh
- cooling
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Links
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 98
- 239000002184 metal Substances 0.000 title claims abstract description 98
- 238000000576 coating method Methods 0.000 title claims abstract description 96
- 239000000843 powder Substances 0.000 title claims abstract description 92
- 239000011248 coating agent Substances 0.000 title claims abstract description 89
- 229920001225 polyester resin Polymers 0.000 title claims abstract description 59
- 239000004645 polyester resin Substances 0.000 title claims abstract description 59
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims abstract description 34
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 21
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical class C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims abstract description 20
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 claims abstract description 17
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 claims abstract description 17
- 238000000034 method Methods 0.000 claims abstract description 14
- 239000002994 raw material Substances 0.000 claims abstract description 10
- 150000005846 sugar alcohols Polymers 0.000 claims abstract description 10
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 7
- 150000002367 halogens Chemical class 0.000 claims abstract description 6
- OZCWUNHGNVXCCO-UHFFFAOYSA-N oxiran-2-ylmethyl hydrogen carbonate Chemical group OC(=O)OCC1CO1 OZCWUNHGNVXCCO-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000000463 material Substances 0.000 claims description 41
- 238000001816 cooling Methods 0.000 claims description 34
- 239000002253 acid Substances 0.000 claims description 23
- 230000032050 esterification Effects 0.000 claims description 19
- 238000005886 esterification reaction Methods 0.000 claims description 19
- 238000006068 polycondensation reaction Methods 0.000 claims description 17
- 239000003963 antioxidant agent Substances 0.000 claims description 16
- 238000006243 chemical reaction Methods 0.000 claims description 15
- 230000003078 antioxidant effect Effects 0.000 claims description 14
- -1 glycidyl ester Chemical group 0.000 claims description 14
- 239000003054 catalyst Substances 0.000 claims description 10
- 238000010438 heat treatment Methods 0.000 claims description 10
- 229920005862 polyol Polymers 0.000 claims description 9
- 150000003077 polyols Chemical class 0.000 claims description 9
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 6
- 230000009257 reactivity Effects 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 230000009477 glass transition Effects 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 5
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 claims description 5
- 239000000155 melt Substances 0.000 claims description 4
- 238000002844 melting Methods 0.000 claims description 4
- 230000008018 melting Effects 0.000 claims description 4
- DSKYSDCYIODJPC-UHFFFAOYSA-N 2-butyl-2-ethylpropane-1,3-diol Chemical compound CCCCC(CC)(CO)CO DSKYSDCYIODJPC-UHFFFAOYSA-N 0.000 claims description 2
- QWGRWMMWNDWRQN-UHFFFAOYSA-N 2-methylpropane-1,3-diol Chemical compound OCC(C)CO QWGRWMMWNDWRQN-UHFFFAOYSA-N 0.000 claims description 2
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims description 2
- PMMYEEVYMWASQN-IMJSIDKUSA-N cis-4-Hydroxy-L-proline Chemical compound O[C@@H]1CN[C@H](C(O)=O)C1 PMMYEEVYMWASQN-IMJSIDKUSA-N 0.000 claims description 2
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 claims description 2
- 125000005843 halogen group Chemical group 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 14
- 239000000049 pigment Substances 0.000 abstract description 13
- 229920005989 resin Polymers 0.000 abstract description 9
- 239000011347 resin Substances 0.000 abstract description 9
- 230000008569 process Effects 0.000 abstract description 7
- 230000009286 beneficial effect Effects 0.000 abstract description 3
- 230000005484 gravity Effects 0.000 abstract description 2
- 230000006872 improvement Effects 0.000 abstract description 2
- 238000004062 sedimentation Methods 0.000 abstract description 2
- 230000000052 comparative effect Effects 0.000 description 14
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 9
- 239000000203 mixture Substances 0.000 description 7
- 229920000728 polyester Polymers 0.000 description 6
- 238000009826 distribution Methods 0.000 description 5
- 238000011160 research Methods 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 4
- 238000011161 development Methods 0.000 description 3
- 238000007599 discharging Methods 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 239000011261 inert gas Substances 0.000 description 3
- 206010040844 Skin exfoliation Diseases 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- HTZCNXWZYVXIMZ-UHFFFAOYSA-M benzyl(triethyl)azanium;chloride Chemical compound [Cl-].CC[N+](CC)(CC)CC1=CC=CC=C1 HTZCNXWZYVXIMZ-UHFFFAOYSA-M 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 238000004321 preservation Methods 0.000 description 2
- 238000004886 process control Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000012827 research and development Methods 0.000 description 2
- 238000007873 sieving Methods 0.000 description 2
- RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 description 2
- OQBLGYCUQGDOOR-UHFFFAOYSA-L 1,3,2$l^{2}-dioxastannolane-4,5-dione Chemical compound O=C1O[Sn]OC1=O OQBLGYCUQGDOOR-UHFFFAOYSA-L 0.000 description 1
- YJTKZCDBKVTVBY-UHFFFAOYSA-N 1,3-Diphenylbenzene Chemical group C1=CC=CC=C1C1=CC=CC(C=2C=CC=CC=2)=C1 YJTKZCDBKVTVBY-UHFFFAOYSA-N 0.000 description 1
- PXGZQGDTEZPERC-UHFFFAOYSA-N 1,4-cyclohexanedicarboxylic acid Chemical compound OC(=O)C1CCC(C(O)=O)CC1 PXGZQGDTEZPERC-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000002981 blocking agent Substances 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- BVFSYZFXJYAPQJ-UHFFFAOYSA-N butyl(oxo)tin Chemical compound CCCC[Sn]=O BVFSYZFXJYAPQJ-UHFFFAOYSA-N 0.000 description 1
- 239000010960 cold rolled steel Substances 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- JGFBRKRYDCGYKD-UHFFFAOYSA-N dibutyl(oxo)tin Chemical compound CCCC[Sn](=O)CCCC JGFBRKRYDCGYKD-UHFFFAOYSA-N 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- IPNPIHIZVLFAFP-UHFFFAOYSA-N phosphorus tribromide Chemical compound BrP(Br)Br IPNPIHIZVLFAFP-UHFFFAOYSA-N 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- YBRBMKDOPFTVDT-UHFFFAOYSA-N tert-butylamine Chemical compound CC(C)(C)N YBRBMKDOPFTVDT-UHFFFAOYSA-N 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/64—Polyesters containing both carboxylic ester groups and carbonate groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/81—Preparation processes using solvents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Paints Or Removers (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/CN2022/126222 WO2024082179A1 (fr) | 2022-10-19 | 2022-10-19 | Résine de polyester pour revêtement en poudre métallique, son procédé de préparation et son application |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN116096777A true CN116096777A (zh) | 2023-05-09 |
Family
ID=86214316
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202280004573.4A Pending CN116096777A (zh) | 2022-10-19 | 2022-10-19 | 一种金属粉末涂料用聚酯树脂及其制备方法和应用 |
Country Status (2)
| Country | Link |
|---|---|
| CN (1) | CN116096777A (fr) |
| WO (1) | WO2024082179A1 (fr) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050119443A1 (en) * | 2003-12-02 | 2005-06-02 | Barsotti Robert J. | Coating compositions with high solids content for vehicle coating |
| US20060135678A1 (en) * | 2004-12-16 | 2006-06-22 | Atsuya Kato | Aqueous amino resin dispersions and thermosetting water-based paint compositions |
| JP2009102548A (ja) * | 2007-10-24 | 2009-05-14 | Chuo Motor Wheel Co Ltd | アルミホイール用紫外線硬化型粉体塗料組成物及びアルミホイールの塗装方法 |
| CN104311806A (zh) * | 2014-10-20 | 2015-01-28 | 浙江天松新材料股份有限公司 | 一种高流平透明粉末涂料用聚酯树脂及其制备方法 |
| CN106046336A (zh) * | 2016-07-15 | 2016-10-26 | 广州擎天材料科技有限公司 | 一种具有羟基酸封端的水溶性聚酯树脂及其制备方法 |
| CN110408013A (zh) * | 2019-08-30 | 2019-11-05 | 广东工业大学 | 一种粉末涂料用聚酯树脂及其制备方法 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1229062B1 (fr) * | 2001-02-06 | 2005-10-19 | Dainippon Ink And Chemicals, Inc. | Composition de résine pour revêtement en poudre, revêtement en poudre et objet revêtu |
| CN104558559B (zh) * | 2014-12-04 | 2016-01-27 | 佛山市高明同德化工有限公司 | 一种相溶性广颜料分散性佳的饱和聚酯树脂及其制备方法 |
| CN107254240B (zh) * | 2017-04-20 | 2019-05-28 | 浙江传化天松新材料有限公司 | 一种环氧固化高表面装饰性、高耐水性粉末涂料用聚酯树脂及其制备方法 |
| CN107540826A (zh) * | 2017-07-31 | 2018-01-05 | 安徽优科新材料科技有限公司 | 新型高档自行车用饱和聚酯及其制备方法 |
| CN112566990B (zh) * | 2019-08-02 | 2022-02-18 | 擎天材料科技有限公司 | 一种聚酯树脂组合物、粉末涂料及工件 |
| CN112625224A (zh) * | 2020-12-28 | 2021-04-09 | 常州市碳索新材料科技有限公司 | 散热粉末涂料用聚酯树脂及其制备方法 |
| CN113999376B (zh) * | 2021-11-24 | 2023-06-13 | 新中法高分子材料股份有限公司 | 一种可双固化粉末涂料用高Tg高抗冲击性聚酯树脂及其制备方法和应用 |
| CN115124701B (zh) * | 2022-08-10 | 2023-12-22 | 浙江超浪新材料有限公司 | 一种双官能团聚酯树脂、粉末涂料及应用 |
-
2022
- 2022-10-19 CN CN202280004573.4A patent/CN116096777A/zh active Pending
- 2022-10-19 WO PCT/CN2022/126222 patent/WO2024082179A1/fr unknown
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050119443A1 (en) * | 2003-12-02 | 2005-06-02 | Barsotti Robert J. | Coating compositions with high solids content for vehicle coating |
| US20060135678A1 (en) * | 2004-12-16 | 2006-06-22 | Atsuya Kato | Aqueous amino resin dispersions and thermosetting water-based paint compositions |
| JP2009102548A (ja) * | 2007-10-24 | 2009-05-14 | Chuo Motor Wheel Co Ltd | アルミホイール用紫外線硬化型粉体塗料組成物及びアルミホイールの塗装方法 |
| CN104311806A (zh) * | 2014-10-20 | 2015-01-28 | 浙江天松新材料股份有限公司 | 一种高流平透明粉末涂料用聚酯树脂及其制备方法 |
| CN106046336A (zh) * | 2016-07-15 | 2016-10-26 | 广州擎天材料科技有限公司 | 一种具有羟基酸封端的水溶性聚酯树脂及其制备方法 |
| CN110408013A (zh) * | 2019-08-30 | 2019-11-05 | 广东工业大学 | 一种粉末涂料用聚酯树脂及其制备方法 |
Non-Patent Citations (3)
| Title |
|---|
| ZHOU, YM，等: "Synthesis of UV-curable polyesters with lateral double bonds by ring-opening polymerization and their properties", JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, vol. 18, no. 6, 29 July 2021 (2021-07-29), pages 1591 - 1601, XP037626171, DOI: 10.1007/s11998-021-00513-w * |
| 明姝婕: "高固低黏可UV固化聚酯的制备及其在涂料中的应用", 中国优秀硕士学位论文全文数据库 (工程科技Ⅰ辑), no. 02, 15 February 2021 (2021-02-15), pages 018 - 32 * |
| 许国徽，等: "新癸酸缩水甘油酯在粉末涂料用聚酯树脂中的应用", 涂料工业, vol. 51, no. 8, 31 August 2021 (2021-08-31), pages 17 - 24 * |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2024082179A1 (fr) | 2024-04-25 |
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