CN115363981A - Polarizing brightening liquid eye shadow and preparation method thereof - Google Patents
Polarizing brightening liquid eye shadow and preparation method thereof Download PDFInfo
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- CN115363981A CN115363981A CN202111213516.0A CN202111213516A CN115363981A CN 115363981 A CN115363981 A CN 115363981A CN 202111213516 A CN202111213516 A CN 202111213516A CN 115363981 A CN115363981 A CN 115363981A
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- 238000002360 preparation method Methods 0.000 title claims abstract description 68
- 239000007788 liquid Substances 0.000 title claims abstract description 46
- 238000005282 brightening Methods 0.000 title claims abstract description 32
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 134
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 72
- 239000002994 raw material Substances 0.000 claims abstract description 68
- 239000002562 thickening agent Substances 0.000 claims abstract description 25
- 229920001577 copolymer Polymers 0.000 claims abstract description 24
- 239000003906 humectant Substances 0.000 claims abstract description 21
- 239000003086 colorant Substances 0.000 claims abstract description 20
- 229920002385 Sodium hyaluronate Polymers 0.000 claims abstract description 17
- 229940010747 sodium hyaluronate Drugs 0.000 claims abstract description 17
- YWIVKILSMZOHHF-QJZPQSOGSA-N sodium;(2s,3s,4s,5r,6r)-6-[(2s,3r,4r,5s,6r)-3-acetamido-2-[(2s,3s,4r,5r,6r)-6-[(2r,3r,4r,5s,6r)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2- Chemical compound [Na+].CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 YWIVKILSMZOHHF-QJZPQSOGSA-N 0.000 claims abstract description 17
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 claims abstract description 12
- ANZUDYZHSVGBRF-UHFFFAOYSA-N 3-ethylnonane-1,2,3-triol Chemical compound CCCCCCC(O)(CC)C(O)CO ANZUDYZHSVGBRF-UHFFFAOYSA-N 0.000 claims abstract description 12
- ZAKOWWREFLAJOT-CEFNRUSXSA-N D-alpha-tocopherylacetate Chemical compound CC(=O)OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C ZAKOWWREFLAJOT-CEFNRUSXSA-N 0.000 claims abstract description 12
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229960005323 phenoxyethanol Drugs 0.000 claims abstract description 12
- 229940042585 tocopherol acetate Drugs 0.000 claims abstract description 12
- 239000003607 modifier Substances 0.000 claims abstract description 9
- 239000000203 mixture Substances 0.000 claims description 42
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 30
- 238000003756 stirring Methods 0.000 claims description 28
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 24
- 239000011575 calcium Substances 0.000 claims description 24
- 229910052791 calcium Inorganic materials 0.000 claims description 24
- 239000008367 deionised water Substances 0.000 claims description 18
- 229910021641 deionized water Inorganic materials 0.000 claims description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 18
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims description 16
- OWBTYPJTUOEWEK-UHFFFAOYSA-N butane-2,3-diol Chemical compound CC(O)C(C)O OWBTYPJTUOEWEK-UHFFFAOYSA-N 0.000 claims description 14
- 235000011187 glycerol Nutrition 0.000 claims description 14
- 229910001887 tin oxide Inorganic materials 0.000 claims description 12
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 8
- 229920002125 Sokalan® Polymers 0.000 claims description 8
- 229960001631 carbomer Drugs 0.000 claims description 8
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 8
- 238000009924 canning Methods 0.000 claims description 7
- 229940085237 carbomer-980 Drugs 0.000 claims description 7
- 238000006243 chemical reaction Methods 0.000 claims description 7
- 239000002131 composite material Substances 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 7
- 125000001181 organosilyl group Chemical group [SiH3]* 0.000 claims description 7
- 239000002245 particle Substances 0.000 claims description 7
- SNAAJJQQZSMGQD-UHFFFAOYSA-N aluminum magnesium Chemical compound [Mg].[Al] SNAAJJQQZSMGQD-UHFFFAOYSA-N 0.000 claims description 3
- 229940049638 carbomer homopolymer type c Drugs 0.000 claims description 3
- 229940043234 carbomer-940 Drugs 0.000 claims description 3
- 239000000230 xanthan gum Substances 0.000 claims description 3
- 235000010493 xanthan gum Nutrition 0.000 claims description 3
- 229920001285 xanthan gum Polymers 0.000 claims description 3
- 229940082509 xanthan gum Drugs 0.000 claims description 3
- WLAMNBDJUVNPJU-UHFFFAOYSA-N 2-methylbutyric acid Chemical compound CCC(C)C(O)=O WLAMNBDJUVNPJU-UHFFFAOYSA-N 0.000 claims description 2
- 229920002907 Guar gum Polymers 0.000 claims description 2
- 229940082484 carbomer-934 Drugs 0.000 claims description 2
- 239000000665 guar gum Substances 0.000 claims description 2
- 229960002154 guar gum Drugs 0.000 claims description 2
- 235000010417 guar gum Nutrition 0.000 claims description 2
- 230000010287 polarization Effects 0.000 claims description 2
- 230000002708 enhancing effect Effects 0.000 claims 3
- 238000004519 manufacturing process Methods 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 8
- 238000000034 method Methods 0.000 abstract description 8
- 230000008569 process Effects 0.000 abstract description 3
- 230000009471 action Effects 0.000 abstract description 2
- RGKMZNDDOBAZGW-UHFFFAOYSA-N aluminum calcium Chemical compound [Al].[Ca] RGKMZNDDOBAZGW-UHFFFAOYSA-N 0.000 description 21
- 238000012360 testing method Methods 0.000 description 13
- 230000008859 change Effects 0.000 description 7
- 239000000843 powder Substances 0.000 description 6
- OSCJHTSDLYVCQC-UHFFFAOYSA-N 2-ethylhexyl 4-[[4-[4-(tert-butylcarbamoyl)anilino]-6-[4-(2-ethylhexoxycarbonyl)anilino]-1,3,5-triazin-2-yl]amino]benzoate Chemical compound C1=CC(C(=O)OCC(CC)CCCC)=CC=C1NC1=NC(NC=2C=CC(=CC=2)C(=O)NC(C)(C)C)=NC(NC=2C=CC(=CC=2)C(=O)OCC(CC)CCCC)=N1 OSCJHTSDLYVCQC-UHFFFAOYSA-N 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000010445 mica Substances 0.000 description 4
- 229910052618 mica group Inorganic materials 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 241000122205 Chamaeleonidae Species 0.000 description 1
- 206010040954 Skin wrinkling Diseases 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 238000010668 complexation reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000003974 emollient agent Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 235000003642 hunger Nutrition 0.000 description 1
- 230000001795 light effect Effects 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000006884 silylation reaction Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Images
Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
- A61K8/585—Organosilicon compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/25—Silicon; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/26—Aluminium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8147—Homopolymers or copolymers of acids; Metal or ammonium salts thereof, e.g. crotonic acid, (meth)acrylic acid; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/10—Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/26—Optical properties
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/42—Colour properties
- A61K2800/43—Pigments; Dyes
- A61K2800/438—Thermochromatic; Photochromic; Phototropic
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/48—Thickener, Thickening system
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/592—Mixtures of compounds complementing their respective functions
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/592—Mixtures of compounds complementing their respective functions
- A61K2800/5922—At least two compounds being classified in the same subclass of A61K8/18
Abstract
The invention belongs to the technical field of A61K, and particularly relates to a polarized light brightening liquid eye shadow and a preparation method thereof. A polarized light brightening liquid eye shadow is prepared from phase A, phase B, phase C, phase D, phase E and phase F; the preparation raw materials of the phase A comprise: thickeners, humectants; the preparation raw materials of the phase B comprise: aminomethyl propanol; the preparation raw materials of the phase C comprise: dimethylsilylated silica, VP/VA copolymer; the raw materials for preparing the phase D comprise phenoxyethanol and ethylhexyl glycerol; the phase E comprises hydrolyzed sodium hyaluronate and tocopherol acetate; the phase F comprises a skin feel modifier and a coloring agent. The polarized light brightening liquid eye shadow prepared by the invention can further improve the ductility of the liquid eye shadow on the surface of eye skin in the use process under the action of silica, and improves the makeup effect of the liquid eye shadow.
Description
Technical Field
The invention belongs to the technical field of A61K, and particularly relates to a polarized light brightening liquid eye shadow and a preparation method thereof.
Background
With the improvement of living standard, people are pursuing beauty in addition to satisfying the basic hunger problem. With the increase of the demand of people, products in the field of color cosmetics are more and more, including eye liners, eye shadows, lipsticks and other color cosmetics products.
However, in the current stage, the eye shadow of eye makeup is mainly made of powder, and the pearlescent eye shadow is mainly made of mica, so that the phenomena of powder flying and the like often occur, and the using effect of the makeup is influenced. In order to improve the makeup effect of the powder eye shadow, researchers have studied liquid eye shadows, which can improve the phenomenon of traditional powder eye shadow powder flying. For example, chinese patent publication No. CN112237553A discloses a waterproof liquid eye shadow and a preparation method thereof, in the disclosed patent, the waterproof liquid eye shadow is prepared by interaction of a solvent, a film-forming agent, a thickener, an adsorbent, an emollient, a filler, a pearlizing agent, a skin conditioner, a humectant and an antioxidant, however, in the disclosed patent, an organic solvent and mica are used, and the use of mica powder not only affects the gloss feeling, but also the use of the organic solvent causes the eye shadow to have greasy feeling and affects the experience feeling of a user.
In order to ensure excellent gloss and better stability and polarization of liquid eye shadow, researchers still need to optimize the formula and the product.
Disclosure of Invention
In order to solve the technical problems, the invention provides a polarized light brightening liquid eye shadow which is prepared from a raw material comprising an A phase, a B phase, a C phase, a D phase, an E phase and an F phase;
the preparation raw materials of the phase A comprise: thickeners, humectants;
the preparation raw materials of the phase B comprise: aminomethyl propanol;
the preparation raw materials of the phase C comprise: silica dimethyl silylate, VP/VA copolymer;
the raw materials for preparing the phase D comprise phenoxyethanol and ethylhexyl glycerol;
the phase E comprises hydrolyzed sodium hyaluronate and tocopherol acetate;
the phase F comprises a skin feel modifier and a coloring agent.
In some preferred embodiments, the thickener is selected from at least one of xanthan gum, magnesium aluminum silicate, carbomer, guar gum.
More preferably, the carbomer is at least one selected from the group consisting of carbomer 980, carbomer 940, carbomer 971, and carbomer 934.
It is further preferred that the carbomer comprises carbomer 980.
More preferably, the weight ratio of said thickener to silica dimethyl silylate is 1: (1-3).
More preferably, the weight ratio of said thickener to silica dimethyl silylate is 1:2.5.
during the experimental process, which was obtained through a great deal of research from the applicant's creative experiments, the weight ratio of thickener and silica dimethyl silylate added in the present application was controlled to be 1: (1-3), in particular in a weight ratio of 1:2.5, the stability of the system and the texture of the liquid eyeshadow produced can be greatly improved, especially when the thickener used is carbomer, which the applicant speculates may be due to: the active group that its exists of carbomer 980 that adds in this application can form further complexation with the active group in the system between to in the existence of dimethyl silylation silica, can form further absorption between active ingredient, form stable state between carbomer 980 in coordination, both can increase the stability of liquid eye shadow, avoid appearing the phenomenon of being harder.
In some preferred embodiments, the colorant is selected from at least one of calcium aluminoborosilicate/CI 77891/silica, calcium aluminoborosilicate/CI 77891/silica/tin oxide, and calcium aluminoborosilicate/CI 77891/silica.
Further preferably, the colorant comprises calcium aluminoborosilicate/CI 77891/silica, calcium aluminoborosilicate/CI 77891/silica/tin oxide, calcium aluminoborosilicate/CI 77891/silica.
In some preferred embodiments, the weight ratio of silica dimethyl silylate to VP/VA copolymer is 1: (5-15).
In some preferred embodiments, the humectant in phase a comprises glycerin and methyl propylene glycol; the weight ratio of the glycerol to the methyl propylene glycol is 1: (1-5).
In some preferred embodiments, the preparation feedstock further comprises deionized water.
In some preferred embodiments, the preparation raw materials comprise, in weight percent: 0.1-0.3% of thickening agent, 0.8-5.5% of humectant, 0.1-0.3% of aminomethyl propanol, 0.2-1% of dimethyl silyl silica, 1-5% of VP/VA copolymer, 0.5-1% of phenoxyethanol, 0.1-0.5% of ethylhexyl glycerol, 0.1-1% of hydrolyzed sodium hyaluronate, 0.05-0.5% of tocopherol acetate, 0.5-2% of skin feel regulator, 6-40% of colorant and the balance of deionized water to 100%.
Further preferably, the preparation raw materials comprise, by weight: 0.1-0.15% of thickening agent, 0.8-4.5% of humectant, 0.1-0.15% of aminomethyl propanol, 0.2-0.4% of dimethyl silyl silica, 2-4% of VP/VA copolymer, 0.5-1% of phenoxyethanol, 0.1-0.2% of ethylhexyl glycerol, 0.1-0.3% of hydrolyzed sodium hyaluronate, 0.05-0.2% of tocopherol acetate, 0.5-1.5% of skin feel regulator, 6-28% of colorant and the balance of deionized water to 100%.
The second aspect of the present invention provides a method for preparing a polarized light brightening liquid eye shadow, comprising the following steps:
1) Adding deionized water into a reaction device, heating to 80-100 ℃, adding a phase A preparation raw material, and mixing;
2) Adding the preparation raw material of the phase B into the step 1), mixing, and uniformly stirring to obtain a mixture B;
3) Stirring the preparation raw material of the phase C in the mixture B until no particles exist to obtain a mixture C;
4) Adding the D phase preparation raw material and the E phase preparation raw material into the mixture C, and stirring and mixing to obtain a mixture D;
5) And adding the compounded F-phase preparation raw material into the mixture D, uniformly stirring, and canning to obtain the composite material.
Has the advantages that: the polarized light brightening liquid eye shadow provided by the invention has the following advantages:
1. the polarized light brightening liquid eye shadow prepared by the method can improve the stability of the prepared liquid eye shadow under the interaction of dimethyl silyl silica and a thickening agent, and avoids the phenomenon of hard touch;
2. the polarized light brightening liquid eye shadow prepared by the invention can further improve the ductility of the liquid eye shadow on the surface of eye skin in the use process under the action of silica, and improves the makeup effect of the liquid eye shadow;
3. the polarized light brightening liquid eye shadow prepared by the method can realize the polarized light effect under the mutual synergistic effect of aluminum calcium borosilicate/CI 77891/silica, aluminum calcium borosilicate/CI 77891/silica/tin oxide and aluminum calcium borosilicate/CI 77891/silica, three color change effects are realized, the use experience is improved, and the polarized light brightening liquid eye shadow prepared by the method is easy to remove makeup;
4. the polarized light brightening liquid eye shadow prepared by the invention has excellent high and low temperature stability, is not changed after being placed at 45 ℃ for 12 days, and does not have any influence on the performance after being circulated for 8 times at 45 ℃/25 ℃/-10 ℃;
5. the polarizing brightening liquid eye shadow prepared by the method is compounded by the raw materials of the phase A, the phase B, the phase C, the phase D, the phase E and the phase F to achieve the polarizing (chameleon) effect, and the defects of low luster and unobvious brightening effect after makeup are overcome; meanwhile, a certain content of silica is added into the compound raw materials to improve the ductility of the product and also can show a soft focus effect. The dimethyl silyl silica is added, so that the product has better compatibility, and the problems of natural moisture regulation, improvement of human skin nutrition, prevention of skin wrinkling and the like can be solved by adding a proper amount of humectant.
Drawings
FIG. 1 is a graph showing the results of the high temperature and cold resistance tests of the eye shadow prepared in example 1 of the present application;
fig. 2 is a graph showing the results of cycle testing of the eye shadow prepared in example 1 of the present application.
Detailed Description
Examples
Example 1
A polarized light brightening liquid eye shadow is prepared from the following raw materials in percentage by weight: 0.12% of thickening agent, 4% of humectant, 0.12% of aminomethyl propanol, 0.3% of silica dimethyl silylate, 3% of VP/VA copolymer, 0.85% of phenoxyethanol, 0.15% of ethylhexyl glycerol, 0.2% of hydrolyzed sodium hyaluronate, 0.1% of tocopherol acetate, 1% of skin feel regulator, 25% of colorant and the balance of deionized water to 100%.
The thickening agent is carbomer 980, and is purchased from Jiamu Suo Nissian in Guangzhou city;
the humectant comprises glycerin and methyl propylene glycol, and the weight ratio of the glycerin to the methyl propylene glycol is 1:3;
the VP/VA copolymer, INCI: VP/VA COPOLYMER, CAS:25086-89-9, purchased from Kyoho-shigao-Ninghua, guangzhou;
the skin feel modifier is silica, purchased from korea advanced chemistry;
the colorant is aluminum calcium borosilicate/CI 77891/silica, aluminum calcium borosilicate/CI 77891/silica/stannic oxide, aluminum calcium borosilicate/CI 77891/silica, and the weight ratio is 8:8:9;
calcium alumino borosilicate/CI 77891/silica, calcium alumino borosilicate/CI 77891/silica/tin oxide, calcium alumino borosilicate/CI 77891/silica were all available from Fujian Kuncao materials science and technology, inc.;
hydrolyzed sodium hyaluronate was purchased from behabo ltd, guangzhou;
a preparation method of a polarized light brightening liquid eye shadow comprises the following steps:
1) Adding deionized water into a reaction device, heating to 85 ℃, adding a phase A preparation raw material, and mixing;
2) Adding the preparation raw material of the phase B into the step 1), mixing, and uniformly stirring to obtain a mixture B;
3) Stirring the preparation raw material of the phase C in the mixture B until no particles exist to obtain a mixture C;
4) Adding the D phase preparation raw material and the E phase preparation raw material into the mixture C, and stirring and mixing to obtain a mixture D;
5) And adding the compounded F-phase preparation raw material into the mixture D, uniformly stirring, and canning to obtain the composite material.
Example 2
A polarized light brightening liquid eye shadow is prepared from the following raw materials in percentage by weight: 0.12% of thickening agent, 4% of humectant, 0.12% of aminomethyl propanol, 0.3% of silica dimethyl silylate, 3% of VP/VA copolymer, 0.85% of phenoxyethanol, 0.15% of ethylhexyl glycerol, 0.2% of hydrolyzed sodium hyaluronate, 0.1% of tocopherol acetate, 1% of skin feel regulator, 25% of colorant and the balance of deionized water to 100%.
The thickening agent is carbomer 940 with the model of HZ007, which is purchased from Shandong Huangcata New materials Co., ltd;
the humectant comprises glycerin and methyl propylene glycol, and the weight ratio of glycerin to methyl propylene glycol is 1:3;
the VP/VA copolymer, INCI: VP/VA COPOLYMER, CAS:25086-89-9, purchased from Kyoho-shigao-Ninghua, guangzhou;
the skin feel modifier is silica, purchased from korea advanced chemistry;
the colorant is aluminum calcium borosilicate/CI 77891/silica, aluminum calcium borosilicate/CI 77891/silica/tin oxide, aluminum calcium borosilicate/CI 77891/silica, and the weight ratio of the aluminum calcium borosilicate/CI 77891/silica is 8:8:9;
calcium alumino borosilicate/CI 77891/silica, calcium alumino borosilicate/CI 77891/silica/tin oxide, calcium alumino borosilicate/CI 77891/silica were all available from Fujian Kuncao materials science and technology, inc.;
hydrolyzed sodium hyaluronate was purchased from behabo ltd, guangzhou;
a preparation method of a polarized light brightening liquid eye shadow comprises the following steps:
1) Adding deionized water into a reaction device, heating to 85 ℃, adding a phase A preparation raw material, and mixing;
2) Adding the preparation raw material of the phase B into the step 1), mixing, and uniformly stirring to obtain a mixture B;
3) Stirring the preparation raw material of the phase C in the mixture B until no particles exist to obtain a mixture C;
4) Adding the D phase preparation raw material and the E phase preparation raw material into the mixture C, and stirring and mixing to obtain a mixture D;
5) And adding the compounded F-phase preparation raw material into the mixture D, uniformly stirring, and canning to obtain the composite material.
Example 3
A polarized light brightening liquid eye shadow is prepared from the following raw materials in percentage by weight: 0.12% of thickening agent, 4% of humectant, 0.12% of aminomethyl propanol, 0.3% of silica dimethyl silylate, 3% of VP/VA copolymer, 0.85% of phenoxyethanol, 0.15% of ethylhexyl glycerol, 0.2% of hydrolyzed sodium hyaluronate, 0.1% of tocopherol acetate, 1% of skin feel regulator, 25% of colorant and the balance of deionized water to 100%.
The thickening agent is xanthan gum which is purchased from Jia bath adjacent daily chemical in Guangzhou city;
the humectant comprises glycerin and methyl propylene glycol, and the weight ratio of glycerin to methyl propylene glycol is 1:3;
the VP/VA copolymer, INCI: VP/VA COPOLYMER, CAS:25086-89-9, purchased from Kyoho-shigao-Ninghua, guangzhou;
the skin feel modifier is silica, and is purchased from Korean advanced chemistry;
the colorant is aluminum calcium borosilicate/CI 77891/silica, aluminum calcium borosilicate/CI 77891/silica/tin oxide, aluminum calcium borosilicate/CI 77891/silica, and the weight ratio of the aluminum calcium borosilicate/CI 77891/silica is 8:8:9;
calcium alumino borosilicate/CI 77891/silica, calcium alumino borosilicate/CI 77891/silica/tin oxide, calcium alumino borosilicate/CI 77891/silica were all available from Fujian Kuncao materials science and technology, inc.;
hydrolyzed sodium hyaluronate was purchased from baihabo ltd, guangzhou;
a preparation method of a polarized light brightening liquid eye shadow comprises the following steps:
1) Adding deionized water into a reaction device, heating to 85 ℃, adding a phase A preparation raw material, and mixing;
2) Adding the preparation raw material of the phase B into the step 1), mixing, and uniformly stirring to obtain a mixture B;
3) Stirring the preparation raw material of the phase C in the mixture B until no particles exist to obtain a mixture C;
4) Adding the D phase preparation raw material and the E phase preparation raw material into the mixture C, and stirring and mixing to obtain a mixture D;
5) And adding the compounded F-phase preparation raw material into the mixture D, uniformly stirring, and canning to obtain the composite material.
Example 4
A polarized light brightening liquid eye shadow is prepared from the following raw materials in percentage by weight: 0.12% of thickening agent, 4% of humectant, 0.12% of aminomethyl propanol, 0.3% of silica dimethyl silylate, 3% of VP/VA copolymer, 0.85% of phenoxyethanol, 0.15% of ethylhexyl glycerol, 0.2% of hydrolyzed sodium hyaluronate, 0.1% of tocopherol acetate, 1% of skin feel regulator, 25% of colorant and the balance of deionized water to 100%.
The thickening agent is magnesium aluminum silicate, and is purchased from Jiamu Suo Nian chemical in Guangzhou city;
the humectant comprises glycerin and methyl propylene glycol, and the weight ratio of glycerin to methyl propylene glycol is 1:3;
the VP/VA copolymer, INCI: VP/VA COPOLYMER, CAS:25086-89-9, purchased from Kyoho Suo Nissan Kazakh, guangzhou;
the skin feel modifier is silica, purchased from korea advanced chemistry;
the colorant is aluminum calcium borosilicate/CI 77891/silica, aluminum calcium borosilicate/CI 77891/silica/tin oxide, aluminum calcium borosilicate/CI 77891/silica, and the weight ratio of the aluminum calcium borosilicate/CI 77891/silica is 8:8:9;
calcium alumino borosilicate/CI 77891/silica, calcium alumino borosilicate/CI 77891/silica/tin oxide, calcium alumino borosilicate/CI 77891/silica are all available from Fujian Kuncui materials science and technology, inc.;
hydrolyzed sodium hyaluronate was purchased from baihabo ltd, guangzhou;
a preparation method of a polarized light brightening liquid eye shadow comprises the following steps:
1) Adding deionized water into a reaction device, heating to 85 ℃, adding a phase A preparation raw material, and mixing;
2) Adding the preparation raw material of the phase B into the step 1), mixing, and uniformly stirring to obtain a mixture B;
3) Stirring the preparation raw material of the phase C in the mixture B until no particles exist to obtain a mixture C;
4) Adding the D phase preparation raw materials and the E phase preparation raw materials into the mixture C, and stirring and mixing to obtain a mixture D;
5) And adding the compounded F-phase preparation raw material into the mixture D, uniformly stirring, and canning to obtain the composite material.
Example 5
A polarized light brightening liquid eye shadow is prepared from the following raw materials in percentage by weight: 0.12% of thickening agent, 4% of humectant, 0.12% of aminomethyl propanol, 0.3% of dimethyl silyl silica, 3% of VP/VA copolymer, 0.85% of phenoxyethanol, 0.15% of ethylhexyl glycerol, 0.2% of hydrolyzed sodium hyaluronate, 0.1% of tocopherol acetate, 1% of skin feel modifier, 25% of colorant and the balance of deionized water to 100%.
The thickening agent is carbomer 980, and is purchased from Jiamu Suo Nissian in Guangzhou city;
the humectant comprises glycerin and methyl propylene glycol, and the weight ratio of glycerin to methyl propylene glycol is 1:3;
the VP/VA copolymer, INCI: VP/VA COPOLYMER, CAS:25086-89-9, purchased from Kyoho-shigao-Ninghua, guangzhou;
the skin feel modifier is mica, and is purchased from Henhao science and technology Limited, anhui;
the colorant is aluminum calcium borosilicate/CI 77891/silica, aluminum calcium borosilicate/CI 77891/silica/stannic oxide, aluminum calcium borosilicate/CI 77891/silica, and the weight ratio is 8:8:9;
calcium alumino borosilicate/CI 77891/silica, calcium alumino borosilicate/CI 77891/silica/tin oxide, calcium alumino borosilicate/CI 77891/silica were all available from Fujian Kuncao materials science and technology, inc.;
hydrolyzed sodium hyaluronate was purchased from behabo ltd, guangzhou;
a preparation method of a polarized light brightening liquid eye shadow comprises the following steps:
1) Adding deionized water into a reaction device, heating to 85 ℃, adding a phase A preparation raw material, and mixing;
2) Adding the preparation raw material of the phase B into the step 1), mixing, and uniformly stirring to obtain a mixture B;
3) Stirring the preparation raw material of the phase C in the mixture B until no particles exist to obtain a mixture C;
4) Adding the D phase preparation raw materials and the E phase preparation raw materials into the mixture C, and stirring and mixing to obtain a mixture D;
5) And adding the compounded F-phase preparation raw material into the mixture D, uniformly stirring, and canning to obtain the composite material.
And (4) performance testing:
1. and (3) testing cold resistance: the product prepared in example 1 was subjected to a cold resistance test by placing at-5 ℃ for two months, then returning to room temperature, and observing the change in the appearance of the eye shadow;
2. and (3) testing high-temperature resistance: the product prepared in the example 1 is subjected to a high temperature resistance test, and the test method is that the product is placed at 50 ℃ for two months and then is returned to the room temperature, and the change of the appearance of the eye shadow is observed;
the specific test results are shown in fig. 1.
3. And (3) testing high and low temperature cycle performance: the product prepared in example 1 was subjected to high and low temperature cycle performance testing, heated to 40 ℃, then placed at 25 ℃, and then placed at-10 ℃ for 8 cycles, and the change in the appearance of the eye shadow was observed.
The specific test results are shown in fig. 2.
And the results are reported in the table below.
| Experiment of | Cold resistance | High temperature resistance | High and low temperature cyclePerformance of |
| Example 1 | Without any change | Without any change | Without any change |
4. The eye shadow prepared in examples 1 to 5 was collected and placed at 2X 2cm 3 The cube of (1) was measured for hardness by a shore durometer after it was molded, and the specific test values were recorded in the following table, and the test results were recorded in the following table (in this application, the larger the hardness value, the larger the hardness).
Claims (10)
1. A polarized light brightening liquid eye shadow is characterized in that the preparation raw materials comprise an A phase, a B phase, a C phase, a D phase, an E phase and an F phase;
the preparation raw materials of the phase A comprise: thickeners, humectants;
the preparation raw materials of the phase B comprise: aminomethyl propanol;
the preparation raw materials of the phase C comprise: silica dimethyl silylate, VP/VA copolymer;
the raw materials for preparing the phase D comprise phenoxyethanol and ethylhexyl glycerol;
the phase E comprises hydrolyzed sodium hyaluronate and tocopherol acetate;
the phase F comprises a skin feel modifier and a coloring agent.
2. A polarized light enhancing liquid eye shadow according to claim 1, wherein said thickener is at least one selected from the group consisting of xanthan gum, magnesium aluminum silicate, carbomer, guar gum.
3. A polarized light enhancing liquid eye shadow according to claim 2, wherein the carbomer is selected from at least one of carbomer 980, carbomer 940, carbomer 971, carbomer 934.
4. A polarized light enhancing liquid eye shadow as claimed in claim 1, wherein said colorant is at least one selected from the group consisting of calcium aluminoborosilicate/CI 77891/silica, calcium aluminoborosilicate/CI 77891/silica/tin oxide, and calcium aluminoborosilicate/CI 77891/silica.
5. A polarization brightening liquid eye shadow according to claim 1, wherein the weight ratio of dimethylsilylated silica and VP/VA copolymer is 1: (5-15).
6. A light-polarizing and brightening liquid eye shadow according to claim 1, wherein said humectant in phase a comprises glycerin and methyl propylene glycol; the weight ratio of the glycerol to the methyl propylene glycol is 1: (1-5).
7. A light-polarizing and brightening liquid eye shadow according to claim 1, wherein the preparation raw material further comprises deionized water.
8. The polarized light brightening liquid eye shadow of claim 7, wherein the raw materials for preparation comprise, in weight percent: 0.1-0.3% of thickening agent, 0.8-5.5% of humectant, 0.1-0.3% of aminomethyl propanol, 0.2-1% of dimethyl silyl silica, 1-5% of VP/VA copolymer, 0.5-1% of phenoxyethanol, 0.1-0.5% of ethylhexyl glycerol, 0.1-1% of hydrolyzed sodium hyaluronate, 0.05-0.5% of tocopherol acetate, 0.5-2% of skin feel regulator, 6-40% of colorant and the balance of deionized water to 100%.
9. The light-polarizing and brightening liquid eye shadow according to claim 8, wherein the preparation raw materials comprise, by weight: 0.1-0.15% of thickening agent, 0.8-4.5% of humectant, 0.1-0.15% of aminomethyl propanol, 0.2-0.4% of dimethyl silyl silica, 2-4% of VP/VA copolymer, 0.5-1% of phenoxyethanol, 0.1-0.2% of ethylhexyl glycerol, 0.1-0.3% of hydrolyzed sodium hyaluronate, 0.05-0.2% of tocopherol acetate, 0.5-1.5% of skin feel regulator, 6-28% of colorant and the balance of deionized water to 100%.
10. A method of making a polarized light brightened liquid eye shadow according to any one of claims 7 to 9, comprising the steps of:
1) Adding deionized water into a reaction device, heating to 80-100 ℃, adding a phase A preparation raw material, and mixing;
2) Adding the preparation raw material of the phase B into the step 1), mixing, and uniformly stirring to obtain a mixture B;
3) Stirring the preparation raw material of the phase C in the mixture B until no particles exist to obtain a mixture C;
4) Adding the D phase preparation raw materials and the E phase preparation raw materials into the mixture C, and stirring and mixing to obtain a mixture D;
5) And adding the compounded F-phase preparation raw material into the mixture D, uniformly stirring, and canning to obtain the composite material.
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