CN114989882A - 一种水性锻造润滑脱模剂及其制备方法 - Google Patents
一种水性锻造润滑脱模剂及其制备方法 Download PDFInfo
- Publication number
- CN114989882A CN114989882A CN202210583845.2A CN202210583845A CN114989882A CN 114989882 A CN114989882 A CN 114989882A CN 202210583845 A CN202210583845 A CN 202210583845A CN 114989882 A CN114989882 A CN 114989882A
- Authority
- CN
- China
- Prior art keywords
- release agent
- film forming
- water
- aqueous
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 45
- 238000005242 forging Methods 0.000 title claims abstract description 35
- 230000001050 lubricating effect Effects 0.000 title claims abstract description 33
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 26
- 238000002360 preparation method Methods 0.000 title abstract description 11
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000000203 mixture Substances 0.000 claims abstract description 11
- 239000000314 lubricant Substances 0.000 claims abstract description 10
- PKQYSCBUFZOAPE-UHFFFAOYSA-N 1,2-dibenzyl-3-methylbenzene Chemical compound C=1C=CC=CC=1CC=1C(C)=CC=CC=1CC1=CC=CC=C1 PKQYSCBUFZOAPE-UHFFFAOYSA-N 0.000 claims abstract description 7
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 6
- 239000003899 bactericide agent Substances 0.000 claims abstract description 6
- 239000008367 deionised water Substances 0.000 claims abstract description 6
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 6
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 5
- SRPWOOOHEPICQU-UHFFFAOYSA-N trimellitic anhydride Chemical compound OC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 SRPWOOOHEPICQU-UHFFFAOYSA-N 0.000 claims abstract description 5
- 230000002421 anti-septic effect Effects 0.000 claims abstract description 4
- 229920001577 copolymer Polymers 0.000 claims description 20
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 15
- 238000003756 stirring Methods 0.000 claims description 15
- 230000003578 releasing effect Effects 0.000 claims description 8
- 239000004744 fabric Substances 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 7
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 5
- 238000011049 filling Methods 0.000 claims description 5
- 238000001914 filtration Methods 0.000 claims description 5
- 229940102253 isopropanolamine Drugs 0.000 claims description 5
- 239000002994 raw material Substances 0.000 claims description 5
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 3
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 3
- 239000006082 mold release agent Substances 0.000 claims description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 2
- 238000004090 dissolution Methods 0.000 claims description 2
- 238000000034 method Methods 0.000 claims 3
- RDWXSJCICPOOKO-UHFFFAOYSA-N 2-methyl-1,2-benzothiazol-3-one Chemical compound C1=CC=C2C(=O)N(C)SC2=C1 RDWXSJCICPOOKO-UHFFFAOYSA-N 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 239000002085 irritant Substances 0.000 abstract description 3
- 231100000021 irritant Toxicity 0.000 abstract description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- -1 2-phenylpropyl Chemical group 0.000 description 4
- 239000010439 graphite Substances 0.000 description 4
- 229910002804 graphite Inorganic materials 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- YKBJQDXMLXQZTP-UHFFFAOYSA-N [Cl].[P].[S] Chemical compound [Cl].[P].[S] YKBJQDXMLXQZTP-UHFFFAOYSA-N 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 230000007123 defense Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000003306 harvesting Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 210000002345 respiratory system Anatomy 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
- C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/06—Metal compounds
- C10M2201/062—Oxides; Hydroxides; Carbonates or bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/06—Well-defined aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
- C10M2205/026—Butene
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/14—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/142—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings polycarboxylic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
- C10M2209/086—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type polycarboxylic, e.g. maleic acid
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/105—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing three carbon atoms only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/106—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing four carbon atoms only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
- C10M2219/104—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/04—Detergent property or dispersant property
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/64—Environmental friendly compositions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
- Forging (AREA)
Abstract
本发明提供了一种水性锻造润滑脱模剂及其制备方法，一种水性锻造润滑脱模剂，包括如下重量百分比的各组分：高温润滑剂10～35％；成膜剂10～20％；PH调节剂10～20％；防腐杀菌剂0.3～3％；消泡剂0.01～0.5％；去离子水50～70％；所述的高温润滑剂为偏苯三酸酐、间苯二甲酸、二苄基甲苯中的一种或多种的混合物。本发明制得的水性锻造润滑脱模剂，可承受高温模具，保持稳定性、不产生刺激性气体，不对人体产生危害，绿色环保高效降低企业成本提高生产效率。
Description
技术领域
本发明涉及润滑脱模剂的制备领域，更具体的是涉及一种水性锻造润滑脱模剂及其制备方法。
背景技术
锻造是一种利用锻压机械对金属坯料施加压力，使其产生塑性形变以获得具有一定机械性能、一定形状和尺寸锻件的加工方法，是锻压的两大组成部分之一。如汽轮发电机轴、转子、叶轮、叶片、护环、大型水压机立柱、高压缸、轧钢机轧辊、内燃机曲轴、连杆、齿轮、轴承、以及国防工业方面的火炮等重要零件，均采用锻造生产。因此，锻造生产广泛的应用于冶金、矿山、汽车、拖拉机、收获机械、石油、化工、航空、航天、兵器等工业部门。
早期锻造生产工艺主要是利用矿物油与植物油对模具进行涂抹或涂刷充当润滑脱模剂，其优点使产品脱模变得方便，但缺点是燃点较低，遇高温燃烧，产生大量油烟与刺激性气体，对工作人员的皮肤与眼睛与呼吸道产生危害，其含有硫磷氯润滑剂和其它不环保的物质，燃烧后产生积碳，粘附在模具和产品上面，污染产品外形，同时污染工作间；后期又出现石墨乳型的热锻造润滑脱模剂，石墨的优点是具有层状结构，锻造时易随着复杂的毛坯变形而滑动起到润滑作用，具有热稳定性绝热性，因而具有良好的润滑性与脱模性。其缺点为会造成环境恶劣，石墨粉尘具有导电性，对安全有隐患，其对配管有腐蚀作用，且不易回收利用浪费资源。
发明内容
为解决现有技术中润滑脱模剂燃点低、燃烧时产生刺激性气体、积碳等问题，现提供一种水性锻造润滑脱模剂及其制备方法。
具体技术方案为：
一种水性锻造润滑脱模剂，包括如下重量百分比的各组分：
为使润滑脱模剂获得较高的燃点因此使用高温润滑剂，所述的高温润滑剂为偏苯三酸酐、间苯二甲酸、二苄基甲苯中的一种或多种的混合物。
所述成膜剂为异丁烯-马来酸酐共聚物以及EO、PO、BO共聚物中的一种或多种的混合物。
所述PH调节剂为一乙醇胺、二乙醇胺、三乙醇胺、异丙醇胺、氢氧化钠中的一种或多种混合。
为使润滑脱模剂长久耐用耐腐蚀，在配方中添加防腐杀菌剂，所述的防腐杀菌剂为1,2-苯丙异噻唑啉-3-酮、2-甲基-1,2-苯并异噻唑-3-酮中的一种或两种的混合物。
所述的消泡剂为乳化硅油类，优选为道康宁1247、道康宁1267、盟庆信MS550、MS575中的一种或几种的混合物。
一种水性锻造润滑脱模剂的制备方法，包括如下步骤：
S1:在反应釜中加入去离子水，边搅拌边缓缓加入成膜剂1，使其均匀分散在水中；
S2:将部分pH调节剂缓缓加入后，开始加热至成膜剂1完全溶解；
S3:待成膜剂1完全溶解后，将剩余PH调节剂缓慢加入并使其完全溶解，若加入PH调节剂过快时会引起温度的急剧上升、起泡；
S4:缓缓加入高温润滑剂，加热至完全溶解；
S5:在60℃以下加入成膜剂2，使其完全溶解；
S6:待已添加原料完全溶解后，冷却至40℃以下加入防腐杀菌剂、消泡剂，搅拌均匀后用滤布过滤灌装。
由于会产生大量的热，因此所述S2与S4中完全溶解的参数为在80±5℃温度条件下持续搅拌，搅拌时间为1小时以上。
所述S6中滤布的规格为80-120目。
有益效果：
(1)本发明提供的一种水性锻造润滑脱模剂，可承受模具350-700℃的高温，保持稳定性，不产生刺激性气体，不伤害操作人员的皮肤、眼睛、不积碳、无残渣堆积、从而避免喷枪堵塞、润滑性、脱模性能优异，适用于自动喷涂与手工喷涂等操作方式。
(2)本发明提供的一种水性锻造润滑脱模剂，不含石墨、不含硫氯磷、无油渍、无腐蚀、无刺激气味、绿色环保。
(3)本发明提供的一种水性锻造润滑脱模剂，兑水不分层，兑水比例高达1:20，适用于绝大部分钢铁及合金等黑色金属环保温热锻造客户要求的产品，有效提高生产效率，降低企业生产成本。
(4)本发明提供的一种水性锻造润滑脱模剂，通过优化脱模剂的组分，通过各组分之间的协同作用以使润滑脱模剂获得最优的性能。
具体实施方式
为了加深对本发明的理解，下面将结合实施例对本发明作进一步详述，该实施例仅用于解释本发明，并不构成对本发明保护范围的限定。
实施例1：
一种水性不含石墨锻造润滑脱模剂的配方以重量计算包括如下组分：
具体的制备方法如下所示：
S1、在反应釜中加入去离子水，边搅拌边缓缓加入异丁烯-马来酸酐共聚物，使其均匀分散在水中；
S2、将部分氢氧化钠缓缓加入后，在85℃下持续搅拌2小时至异丁烯-马来酸酐共聚物完全溶解；
S3、对异丁烯-马来酸酐共聚物是否完全溶解进行确认后，将余下的氢氧化钠缓缓加入使其完全溶解；
S4、缓缓加入偏苯三酸酐，间苯二甲酸在85℃下加热至完全溶解；
S5、60℃以下加入EOPO共聚物，使其完全溶解。
S6、确认已添加原料完全溶解后，冷却至40℃以下加入1,2-苯并噻唑-3-啉酮；道康宁1247；搅拌均一后用100目滤布过滤灌装，得到成品1。
实施例2：
一种水性不含石墨锻造润滑脱模剂的配方以重量计算包括如下组分：
具体的制备方法如下所示：
S1、在反应釜中加入去离子水，边搅拌边缓缓加入异丁烯-马来酸酐共聚物，使其均匀分散在水中；
S2、将一乙醇胺缓缓加入后，在85℃下持续搅拌2小时至异丁烯-马来酸酐共聚物完全溶解；
S3、对异丁烯-马来酸酐共聚物是否完全溶解进行确认后，将二乙醇胺缓缓加入使其完全溶解；
S4、缓缓加入间苯二甲酸、二苄基甲苯在85℃下加热至完全溶解；
S5、60℃以下加入EOBO共聚物，使其完全溶解。
S6、确认已添加原料完全溶解后，冷却至40℃以下加入1,2-苯并噻唑-3-啉酮；盟庆信MS550；搅拌均一后用100目滤布过滤灌装，得到成品2。
实施例3：
一种水性不含石墨锻造润滑脱模剂的配方以重量计算包括如下组分：
具体的制备方法如下所示：
S1、在反应釜中加入去离子水，边搅拌边缓缓加入异丁烯-马来酸酐共聚物，使其均匀分散在水中；
S2、将部分异丙醇胺缓缓加入后，在85℃下持续搅拌2小时至异丁烯-马来酸酐共聚物完全溶解；
S3、对异丁烯-马来酸酐共聚物是否完全溶解进行确认后，将余下的异丙醇胺缓缓加入使其完全溶解；
S4、缓缓加入偏苯三酸酐，二苄基甲苯在85℃下加热至完全溶解；
S5、60℃以下加入EOBO共聚物，使其完全溶解。
S6、确认已添加原料完全溶解后，冷却至40℃以下加入1,2-苯并噻唑-3-啉酮；道康宁1247；搅拌均一后用100目滤布过滤灌装，得到成品3。
将上述实施例1-3制得的成品1-3进行性能检测，经检验可得本制备方法制备得到的水性锻造润滑脱模剂可承受模具350-700℃的高温。
作为进一步改进，以上所述仅为本发明的较佳实施例而已，并不用以限制本发明，凡在本发明的精神和原则之内，所作的任何修改、等同替换、改进等，均应包含在本发明的保护范围之内。
Claims (8)
1.一种水性锻造润滑脱模剂，其特征在于，包括如下重量百分比的各组分：
所述的高温润滑剂为偏苯三酸酐、间苯二甲酸、二苄基甲苯中的一种或多种的混合物。
2.根据权利要求1所述的一种水性锻造润滑脱模剂，其特征在于，所述成膜剂为异丁烯-马来酸酐共聚物以及EO、PO、BO共聚物中的一种或多种的混合物。
3.根据权利要求1所述的一种水性锻造润滑脱模剂，其特征在于，所述PH调节剂为一乙醇胺、二乙醇胺、三乙醇胺、异丙醇胺、氢氧化钠中的一种或多种混合。
4.根据权利要求1所述的一种水性锻造润滑脱模剂，其特征在于，所述的防腐杀菌剂为1,2-苯丙异噻唑啉-3-酮、2-甲基-1,2-苯并异噻唑-3-酮中的一种或两种的混合物。
5.根据权利要求1所述的一种水性锻造润滑脱模剂，其特征在于，所述的消泡剂为道康宁1247、道康宁1267、盟庆信MS550、盟庆信MS575中的一种或几种的混合物。
6.如权利要求1-5任一一项权利要求所述的一种水性锻造润滑脱模剂的制备方法，其特征在于，包括如下步骤：
S1:在反应釜中加入去离子水，边搅拌边缓缓加入成膜剂1，使其均匀分散在水中；
S2:将部分pH调节剂缓缓加入后，开始加热至成膜剂1完全溶解；
S3:待成膜剂1完全溶解后，将剩余PH调节剂缓慢加入并使其完全溶解；
S4:缓缓加入高温润滑剂，加热至完全溶解；
S5:在60℃以下加入成膜剂2，使其完全溶解；
S6:待已添加原料完全溶解后，冷却至40℃以下加入防腐杀菌剂、消泡剂，搅拌均匀后用滤布过滤灌装。
7.根据权利要求6所述的一种水性锻造润滑脱模剂的制备方法，其特征在于，所述S2与S4中完全溶解的参数为在80±5℃温度条件下持续搅拌，搅拌时间为1小时以上。
8.根据权利要求6所述的一种水性锻造润滑脱模剂的制备方法，其特征在于，所述S6中滤布的规格为80-120目。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210583845.2A CN114989882A (zh) | 2022-05-27 | 2022-05-27 | 一种水性锻造润滑脱模剂及其制备方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210583845.2A CN114989882A (zh) | 2022-05-27 | 2022-05-27 | 一种水性锻造润滑脱模剂及其制备方法 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN114989882A true CN114989882A (zh) | 2022-09-02 |
Family
ID=83029823
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202210583845.2A Pending CN114989882A (zh) | 2022-05-27 | 2022-05-27 | 一种水性锻造润滑脱模剂及其制备方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN114989882A (zh) |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104513126A (zh) * | 2013-09-26 | 2015-04-15 | 赵朝华 | 一种烷基多苄基甲苯或烷基二苄基甲苯的制备方法和应用 |
| CN105176657A (zh) * | 2015-09-30 | 2015-12-23 | 江苏汉德福工业品科技有限公司 | 一种脱模剂 |
| CN106085579A (zh) * | 2016-06-22 | 2016-11-09 | 上海尤希路化学工业有限公司 | 高脱模性低残留可循环使用轮毂锻造用润滑剂 |
| CN109971532A (zh) * | 2019-04-24 | 2019-07-05 | 上海尤希路化学工业有限公司 | 高润滑、高脱模性钛合金锻造专用水性热锻加工油 |
| CN112159699A (zh) * | 2020-08-28 | 2021-01-01 | 希玛石油制品（镇江）有限公司 | 一种高效水溶性磁瓦脱模剂及其制备方法 |
| CN112334247A (zh) * | 2018-06-26 | 2021-02-05 | 株式会社Moresco | 水性组合物 |
| CN113372987A (zh) * | 2021-06-10 | 2021-09-10 | 西安思凯石化科技有限公司 | 铝合金锻造脱模剂 |
-
2022
- 2022-05-27 CN CN202210583845.2A patent/CN114989882A/zh active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104513126A (zh) * | 2013-09-26 | 2015-04-15 | 赵朝华 | 一种烷基多苄基甲苯或烷基二苄基甲苯的制备方法和应用 |
| CN105176657A (zh) * | 2015-09-30 | 2015-12-23 | 江苏汉德福工业品科技有限公司 | 一种脱模剂 |
| CN106085579A (zh) * | 2016-06-22 | 2016-11-09 | 上海尤希路化学工业有限公司 | 高脱模性低残留可循环使用轮毂锻造用润滑剂 |
| CN112334247A (zh) * | 2018-06-26 | 2021-02-05 | 株式会社Moresco | 水性组合物 |
| CN109971532A (zh) * | 2019-04-24 | 2019-07-05 | 上海尤希路化学工业有限公司 | 高润滑、高脱模性钛合金锻造专用水性热锻加工油 |
| CN112159699A (zh) * | 2020-08-28 | 2021-01-01 | 希玛石油制品（镇江）有限公司 | 一种高效水溶性磁瓦脱模剂及其制备方法 |
| CN113372987A (zh) * | 2021-06-10 | 2021-09-10 | 西安思凯石化科技有限公司 | 铝合金锻造脱模剂 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102311864B (zh) | 一种数控机床专用切削液 | |
| CN103831393A (zh) | 一种水性铝合金压铸脱模剂及其制备方法 | |
| CN101809131B (zh) | 用于热锻造应用的润滑剂 | |
| CN111117757A (zh) | 一种水溶性挥发冲压液及制备方法 | |
| CN111423928A (zh) | 一种铸铁和铝合金混合件加工用切削液及其制备方法 | |
| CN101245282B (zh) | 一种金属拉丝润滑剂 | |
| CN105112132B (zh) | 一种乳化防锈油及其制作方法 | |
| CN104818103B (zh) | 汽车用低碳钢件冷挤压成形润滑剂及其制备方法 | |
| CN114989882A (zh) | 一种水性锻造润滑脱模剂及其制备方法 | |
| CN104120017B (zh) | 一种渗透力强防锈性能好的水基切削液及其制备方法 | |
| CN105754690A (zh) | 一种镁合金切削液及其制备方法 | |
| CN105524691B (zh) | 一种环保锻造脱模油及其制备方法 | |
| CN103351937B (zh) | 一种水溶性切削液及其制备方法 | |
| CN109504513A (zh) | 一种水溶性不锈钢无缝钢管冷轧液及其制备方法 | |
| CN102433211A (zh) | 铜拉丝水基冷轧液及其制备方法 | |
| CN102311856B (zh) | 环保型纳米水溶性非油金属冷轧润滑剂及制备方法 | |
| CN105255541B (zh) | 一种锂基润滑脂组合物及制备方法 | |
| CN104450006A (zh) | 一种废内燃机油再生高性能润滑脂及制备方法 | |
| CN111909767A (zh) | 一种高性能的水基镁合金加工液 | |
| CN102604718A (zh) | 环保型水溶性非油金属防锈润滑剂 | |
| CN103451000A (zh) | 一种汽车刹车盘全合成切削液及其制备方法 | |
| CN112662459A (zh) | 一种应用于冷轧退火窄带钢板的轧制油及其制备方法 | |
| CN111518604A (zh) | 一种防腐蚀型航空发动机润滑油组合物及其制备方法 | |
| CN110951533A (zh) | 一种金属加工用长效微乳化切削液及其制备方法 | |
| CN109135879A (zh) | 一种用于黑色金属热锻压环保脱模剂 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20220902 |
|
| RJ01 | Rejection of invention patent application after publication |