CN106085579A - 高脱模性低残留可循环使用轮毂锻造用润滑剂 - Google Patents
高脱模性低残留可循环使用轮毂锻造用润滑剂 Download PDFInfo
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Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
- C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/06—Metal compounds
- C10M2201/062—Oxides; Hydroxides; Carbonates or bicarbonates
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
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- C10M2207/14—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/141—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings monocarboxylic
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
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- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
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- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/04—Siloxanes with specific structure
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Abstract
本发明公开了一种高脱模性低残留可循环使用轮毂锻造用润滑剂，由耐高温润滑剂、高分子聚合物、无机物、有机金属盐类、纯水、其它助剂组成。本发明对人体无伤害，作业环境良好，而且可循环使用，减少废水处理。
Description
技术领域
本发明涉及一种轮毂锻造用润滑剂。
背景技术
锻造是人类发明的最古老的生产技术之一。人类发明和使用金属几千年的历史，都伴随锻造技术的发展。从最初锻造农具和制造盔甲，到现在生活中随处可见的千千万万的锻造产品，都证明这一技术对人类的宝贵价值。目前，人类生产的金属材料中的很大部分，都是经过锻造方法加工成成品零件的。随着人们对材料利用率和成形件使用性能要求的提高和成本的降低，锻造近年来得到了很大的发展。其中，热锻成形在锻造成形中应用非常广泛，历史也最为悠久。
热锻可成形很多复杂形状零件，同时几乎所有可变形的金属都可采用热锻来成形，其中钢是应用最为广泛的一种材料。但热锻件氧化现象严重，成形件的尺寸精度、表面质量相对冷锻和温锻都低，能耗高。这就对加工过程中所使用的润滑剂的润滑性和脱模性提出了较高的要求。本课题的锻造润滑剂通过铆钉试验来模拟锻造过程中的润滑性和脱模性，结果均优于石墨型。
热锻模在服役过程中工况恶劣，其寿命普遍很低，从而直接影响了锻件的成本和生产单位的经济效益。热模锻在模锻行业占有主导地位，我国热锻模平均寿命与国际先进水平有较大差距。因此，如何提高模具的使用寿命，降低锻件成本是热加工行业中亟待解决的问题。使用本课题的锻造润滑剂磨具寿命可以达到10000次以上，大大优于同类的石墨型产品。
在工业4.0时代，提出了适合我国国情的工业化2025计划。汽车工业作为最具代表一个国家的工业水平的行业之一，在新时期对生产加工过程和产品质量提出了更高的要求。例如：高档汽车轮毂等大尺寸的精密部件的锻造对于加工条件、自动化程度、部件的精密度、以及模具寿命等的要求越来越高。这就要求在锻造过程使用的润滑剂具有更好的润滑性、脱模性以及可循环使用性。与此同时，本着“以人为本，和谐发展”的理念，倡导绿色生产，对生产过程中使用的介质也有了更多环保上的要求。
发明内容
本发明的目的在于提供一种对人体无伤害，作业环境良好，而且可循环使用，减少废水处理的高脱模性低残留可循环使用轮毂锻造用润滑剂。
本发明的技术解决方案是：
一种高脱模性低残留可循环使用轮毂锻造用润滑剂，其特征是：由下列重量百分比的成分组成：
耐高温润滑剂…………………………5～20％
高分子聚合物…………………………5～30％
无机物…………………………………1～15％
有机金属盐类…………………………1～30％
纯水……………………………………20～75%
其它助剂………………………………1～15%。
耐高温润滑剂是二硫化钼、硅烷、苯甲酸盐、苯乙酸盐、邻苯二甲酸盐、肉桂酸、硬脂酸盐中的一种或几种；
高分子聚合物是聚丙烯酸盐、聚丙烯酸酯、聚醚、聚乙烯聚氧乙烯磷酸、丙烯酸和顺丁烯马来酸酐的共聚物、乙烯与醋酸乙烯的共聚物、聚乙烯蜡、聚酰亚胺中的一种或几种。
无机物是硫酸盐、碳酸盐、硅酸盐、硼酸盐、磷酸盐、金属氢氧化物中的一种或几种。
有机金属盐类是木质素磺酸钙、木质素磺酸锌、木质素磺酸镁、木质素磺酸钠中的一种或几种。
其他助剂是改性硅油、乳化硅油、硅氧烷、2-甲基-4-异噻唑啉-3-酮、1,2-苯并异噻唑啉-3-酮、脂肪醇聚氧乙烯（5~12）醚、烷基酚聚氧乙烯（5~12）醚、脂肪醇聚氧乙烯聚氧丙烯醚、烷基醇酰胺、磺酸盐、季铵盐中的一种或几种。
本发明选用多种高性能环保型高分子材料复合设计配方，产品适用于钢、铸铁、铝合金等金属材质的锻造，高温吸附性好（吸附量>8g/m2），具有优良脱模性和润滑性的双重功效（铆钉试验铆钉高度≥14.9mm，顶出负荷≤25kg）。
添加高品质耐温耐磨润滑剂设计，使产品能够适应较高温度（最高使用温度>1000℃）的作业环境，对于轮毂等大型部件的锻造也具有良好的效果，且模具寿命高（模具使用10000次以上）。
配方原料均选用生物可降度高、对人和环境无害的可替代原料，使用过程中残留量少（残留量<2%），对人体无伤害，作业环境良好，而且可循环使用，减少废水处理，综合经济效益好（相对于石墨型产品，循环使用综合成本节约25%以上）。
本发明对于我国高端制造领域有着非常重要的贡献。在保护环境安全和人体健康，发展低碳、绿色经济等方面具有重要意义。
下面结合实施例对本发明作进一步说明。
具体实施方式
实施例1：
将下列重量组分在一定条件下混合搅拌，得高脱模性低残留可循环使用轮毂锻造用润滑剂：
苯甲酸盐…………………………10％
聚丙烯酸盐………………………8%
聚乙烯蜡…………………………2%
氢氧化钠…………………………5%
木质素磺酸钙……………………8%
乳化硅油…………………………0.5%
1,2-苯并异噻唑啉-3-酮…………0.5%
水…………………………………余量。
实施例2：
一种高脱模性低残留可循环使用轮毂锻造用润滑剂，由下列重量百分比的成分组成：
耐高温润滑剂…………………………5～20％（例5%、12%、20%）
高分子聚合物…………………………5～30％（例5%、12%、30%）
无机物…………………………………1～15％（例1%、10%、15%）
有机金属盐类…………………………1～30％（例1%、12%、30%）
纯水…………………………………20～75%（例20%、50%、75%）
其它助剂……………………………1～15%（例1%、10%、15%）。
上述各组分用量之和为100%。
耐高温润滑剂是二硫化钼、硅烷、苯甲酸盐、苯乙酸盐、邻苯二甲酸盐、肉桂酸、硬脂酸盐中的一种或几种；
高分子聚合物是聚丙烯酸盐、聚丙烯酸酯、聚醚、聚乙烯聚氧乙烯磷酸、丙烯酸和顺丁烯马来酸酐的共聚物、乙烯与醋酸乙烯的共聚物、聚乙烯蜡、聚酰亚胺中的一种或几种。
无机物是硫酸盐、碳酸盐、硅酸盐、硼酸盐、磷酸盐、金属氢氧化物中的一种或几种。
有机金属盐类是木质素磺酸钙、木质素磺酸锌、木质素磺酸镁、木质素磺酸钠中的一种或几种。
其他助剂是改性硅油、乳化硅油、硅氧烷、2-甲基-4-异噻唑啉-3-酮、1,2-苯并异噻唑啉-3-酮、脂肪醇聚氧乙烯（5~12）醚、烷基酚聚氧乙烯（5~12）醚、脂肪醇聚氧乙烯聚氧丙烯醚、烷基醇酰胺、磺酸盐、季铵盐中的一种或几种。
Claims (6)
1.一种高脱模性低残留可循环使用轮毂锻造用润滑剂，其特征是：由下列重量百分比的成分组成：
耐高温润滑剂…………………………5～20％
高分子聚合物…………………………5～30％
无机物…………………………………1～15％
有机金属盐类…………………………1～30％
纯水……………………………………20～75%
其它助剂………………………………1～15%。
2.根据权利要求1所述的高脱模性低残留可循环使用轮毂锻造用润滑剂，其特征是：耐高温润滑剂是二硫化钼、硅烷、苯甲酸盐、苯乙酸盐、邻苯二甲酸盐、肉桂酸、硬脂酸盐中的一种或几种。
3.根据权利要求1所述的高脱模性低残留可循环使用轮毂锻造用润滑剂，其特征是：高分子聚合物是聚丙烯酸盐、聚丙烯酸酯、聚醚、聚乙烯聚氧乙烯磷酸、丙烯酸和顺丁烯马来酸酐的共聚物、乙烯与醋酸乙烯的共聚物、聚乙烯蜡、聚酰亚胺中的一种或几种。
4.根据权利要求1所述的高脱模性低残留可循环使用轮毂锻造用润滑剂，其特征是：无机物是硫酸盐、碳酸盐、硅酸盐、硼酸盐、磷酸盐、金属氢氧化物中的一种或几种。
5.根据权利要求1所述的高脱模性低残留可循环使用轮毂锻造用润滑剂，其特征是：有机金属盐类是木质素磺酸钙、木质素磺酸锌、木质素磺酸镁、木质素磺酸钠中的一种或几种。
6.根据权利要求1所述的高脱模性低残留可循环使用轮毂锻造用润滑剂，其特征是：其他助剂是改性硅油、乳化硅油、硅氧烷、2-甲基-4-异噻唑啉-3-酮、1,2-苯并异噻唑啉-3-酮、脂肪醇聚氧乙烯（5~12）醚、烷基酚聚氧乙烯（5~12）醚、脂肪醇聚氧乙烯聚氧丙烯醚、烷基醇酰胺、磺酸盐、季铵盐中的一种或几种。
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