CN114709307A - A flip-chip light-emitting diode chip and preparation method thereof - Google Patents

A flip-chip light-emitting diode chip and preparation method thereof Download PDF

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CN114709307A
CN114709307A CN202210258743.3A CN202210258743A CN114709307A CN 114709307 A CN114709307 A CN 114709307A CN 202210258743 A CN202210258743 A CN 202210258743A CN 114709307 A CN114709307 A CN 114709307A
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李文涛
张亚
简弘安
张星星
胡加辉
金从龙
顾伟
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Jiangxi Zhao Chi Semiconductor Co Ltd
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    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10HINORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS
    • H10H20/00Individual inorganic light-emitting semiconductor devices having potential barriers, e.g. light-emitting diodes [LED]
    • H10H20/80Constructional details
    • H10H20/81Bodies
    • H10H20/811Bodies having quantum effect structures or superlattices, e.g. tunnel junctions
    • H10H20/812Bodies having quantum effect structures or superlattices, e.g. tunnel junctions within the light-emitting regions, e.g. having quantum confinement structures
    • HELECTRICITY
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    • H10HINORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS
    • H10H20/00Individual inorganic light-emitting semiconductor devices having potential barriers, e.g. light-emitting diodes [LED]
    • H10H20/01Manufacture or treatment
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10HINORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS
    • H10H20/00Individual inorganic light-emitting semiconductor devices having potential barriers, e.g. light-emitting diodes [LED]
    • H10H20/80Constructional details
    • H10H20/81Bodies
    • H10H20/814Bodies having reflecting means, e.g. semiconductor Bragg reflectors
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10HINORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS
    • H10H20/00Individual inorganic light-emitting semiconductor devices having potential barriers, e.g. light-emitting diodes [LED]
    • H10H20/80Constructional details
    • H10H20/81Bodies
    • H10H20/816Bodies having carrier transport control structures, e.g. highly-doped semiconductor layers or current-blocking structures
    • H10H20/8162Current-blocking structures

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Abstract

本发明提供一种倒装发光二极管芯片及其制备方法,该倒装发光二极管芯片包括依次层叠的N型半导体层、有源发光层、P型半导体层、电流阻挡层、电流扩展层、布拉格反射层以及电流传输层,所述布拉格反射层包括P型布拉格反射部和N型布拉格反射部,电流传输层包括P型电流传输部和N型电流传输部,其中,所述P型布拉格反射部上开设有第一通孔,所述N型布拉格反射部上开设有第二通孔,所述第一通孔用于将所述P型电流传输部与所述电流扩展层电性连接,所述第二通孔用于所述N型电流传输部与所述N型半导体层电性连接,在不改变电流传输能力的情况下,减少电流传输层的吸光,从而提升了倒装发光二极管芯片亮度。

Figure 202210258743

The invention provides a flip-chip light-emitting diode chip and a preparation method thereof. The flip-chip light-emitting diode chip comprises an N-type semiconductor layer, an active light-emitting layer, a P-type semiconductor layer, a current blocking layer, a current spreading layer, and a Bragg reflection layer stacked in sequence. layer and a current transmission layer, the Bragg reflection layer includes a P-type Bragg reflection part and an N-type Bragg reflection part, the current transmission layer includes a P-type current transmission part and an N-type current transmission part, wherein, on the P-type Bragg reflection part A first through hole is opened, a second through hole is opened on the N-type Bragg reflector, and the first through hole is used to electrically connect the P-type current transmission part and the current spreading layer. The second through hole is used for the electrical connection between the N-type current transmission part and the N-type semiconductor layer, and the light absorption of the current transmission layer is reduced without changing the current transmission capability, thereby improving the brightness of the flip-chip LED chip .

Figure 202210258743

Description

一种倒装发光二极管芯片及其制备方法A flip-chip light-emitting diode chip and preparation method thereof

技术领域technical field

本发明涉及半导体器件领域,特别涉及一种倒装发光二极管芯片及其制备方法。The invention relates to the field of semiconductor devices, in particular to a flip-chip light-emitting diode chip and a preparation method thereof.

背景技术Background technique

近年来,LED产业迅速发展升级,以其节能、高效、可靠性高等诸多优势应用于普通照明、特种照明、植因照明、景观照明、户内显示、户外显示、背光显示、紫外消杀、紫外固化等场景,而LED芯片在其中发挥着巨大的作用。In recent years, the LED industry has developed and upgraded rapidly. With its advantages of energy saving, high efficiency and high reliability, it is used in general lighting, special lighting, plant lighting, landscape lighting, indoor display, outdoor display, backlight display, ultraviolet disinfection, ultraviolet curing and other scenarios, and LED chips play a huge role in it.

目前,LED芯片结构主要分三种,最常见的是正装结构,其次是垂直结构和倒装结构。正装结构由于p,n电极在LED同一侧,容易出现电流拥挤以及热阻较高的现象,而垂直结构则可以很好的解决这两个问题,同时达到很高的电流密度和均匀度。未来灯具成本的降低除了材料成本,功率增大的同时,减少LED颗数显得尤为重要,垂直结构能够很好的满足这样的需求,这也导致垂直结构通常用于大功率LED应用领域,而正装技术一般应用于中小功率LED,另外,倒装技术也可以细分为两类,一类是在蓝宝石基础上倒装,蓝宝石衬底保留,利于散热,但是电流密度提升并不明显;另一类是采用倒装结构但剥离了衬底材料,可以实现电流密度的大幅度提升。At present, the LED chip structure is mainly divided into three types, the most common is the front-mounted structure, followed by the vertical structure and the flip-chip structure. The front-mounted structure is prone to current crowding and high thermal resistance because the p and n electrodes are on the same side of the LED, while the vertical structure can solve these two problems well and achieve high current density and uniformity at the same time. In addition to the cost of materials, the reduction of the cost of lamps in the future is particularly important to reduce the number of LEDs while the power increases. The vertical structure can well meet such needs, which also leads to the vertical structure is usually used in high-power LED applications, while the formal installation The technology is generally used in small and medium-power LEDs. In addition, flip-chip technology can also be subdivided into two categories. One is flip-chip on the basis of sapphire, and the sapphire substrate is retained, which is good for heat dissipation, but the current density increase is not obvious; the other type is The flip-chip structure is adopted but the substrate material is peeled off, which can achieve a substantial increase in current density.

随着产业的发展,如何让倒装发光二极管芯片在不剥离衬底材料的情况下发光更亮,光效更高,成为我们无限追求的目标。With the development of the industry, how to make the flip-chip light-emitting diode chip emit brighter and higher light efficiency without stripping the substrate material has become our infinite pursuit.

发明内容SUMMARY OF THE INVENTION

基于此,本发明提供了一种倒装发光二极管芯片及其制备方法,目的在于在倒装发光二极管芯片不剥离衬底材料的情况下,提升发光亮度。Based on this, the present invention provides a flip-chip light-emitting diode chip and a preparation method thereof, which aim to improve light-emitting brightness without peeling off the substrate material of the flip-chip light-emitting diode chip.

根据本发明实施例当中的一种倒装发光二极管芯片,包括依次层叠的N型半导体层、有源发光层、P型半导体层、电流阻挡层、电流扩展层、布拉格反射层以及电流传输层,所述布拉格反射层包括P型布拉格反射部和N型布拉格反射部,电流传输层包括P型电流传输部和N型电流传输部,其中,所述P型布拉格反射部上开设有第一通孔,所述N型布拉格反射部上开设有第二通孔,所述第一通孔用于将所述P型电流传输部与所述电流扩展层电性连接,所述第二通孔用于所述N型电流传输部与所述N型半导体层电性连接。A flip-chip light-emitting diode chip according to an embodiment of the present invention includes an N-type semiconductor layer, an active light-emitting layer, a P-type semiconductor layer, a current blocking layer, a current spreading layer, a Bragg reflection layer, and a current transmission layer stacked in sequence, The Bragg reflection layer includes a P-type Bragg reflection part and an N-type Bragg reflection part, and the current transmission layer includes a P-type current transmission part and an N-type current transmission part, wherein the P-type Bragg reflection part is provided with a first through hole , the N-type Bragg reflector is provided with a second through hole, the first through hole is used to electrically connect the P-type current transmission part and the current spreading layer, and the second through hole is used for The N-type current transfer portion is electrically connected to the N-type semiconductor layer.

优选地,所述倒装发光二极管芯片还包括衬底、缓冲层、绝缘保护层和键合金属层;Preferably, the flip-chip LED chip further comprises a substrate, a buffer layer, an insulating protection layer and a bonding metal layer;

所述缓冲层、所述N型半导体层、所述有源发光层、所述P型半导体层、所述电流阻挡层、所述电流扩展层、所述布拉格反射层、所述电流传输层、所述绝缘保护层以及所述键合金属层依次层叠在所述衬底上。the buffer layer, the N-type semiconductor layer, the active light-emitting layer, the P-type semiconductor layer, the current blocking layer, the current spreading layer, the Bragg reflection layer, the current transport layer, The insulating protection layer and the bonding metal layer are sequentially stacked on the substrate.

优选地,所述电流扩展层为氧化铟锡层,所述电流扩展层的厚度为

Figure BDA0003549817070000021
Preferably, the current spreading layer is an indium tin oxide layer, and the thickness of the current spreading layer is
Figure BDA0003549817070000021

优选地,所述布拉格反射层为低折射率层与高折射率层交替层叠的周期性结构,其中,所述低折射率层为SiO2层,所述高折射率层为Ti3O5层。Preferably, the Bragg reflection layer is a periodic structure in which low refractive index layers and high refractive index layers are alternately stacked, wherein the low refractive index layer is a SiO 2 layer, and the high refractive index layer is a Ti 3 O 5 layer .

优选地,所述第一通孔和所述第二通孔的面积为20um2~1000um2Preferably, the area of the first through hole and the second through hole is 20um 2 to 1000um 2 .

优选地,所述第一通孔和所述第二通孔分别设置有多个,且相邻两个所述第一通孔之间的间隔为10μm~200μm,相邻两个所述第二通孔之间的间隔为10μm~200μm。Preferably, a plurality of the first through holes and the second through holes are respectively provided, and the interval between two adjacent first through holes is 10 μm˜200 μm, and two adjacent second through holes are spaced between 10 μm and 200 μm. The spacing between the through holes is 10 μm˜200 μm.

优选地,所述绝缘保护层包括P型绝缘保护部和N型绝缘保护部,所述键合金属层包括P型键合金属部和N型键合金属部,所述P型绝缘保护部上开设有第三通孔,所述N型绝缘保护部上开设有第四通孔,所述P型绝缘保护部与所述P型电流传输部通过所述第三通孔电性连接,所述N型绝缘保护部与所述N型电流传输部通过所述第四通孔电性连接。Preferably, the insulating protection layer includes a P-type insulating protection portion and an N-type insulating protection portion, the bonding metal layer includes a P-type bonding metal portion and an N-type bonding metal portion, and the P-type insulating protection portion is on the A third through hole is opened, a fourth through hole is opened on the N-type insulating protection part, the P-type insulating protection part and the P-type current transmission part are electrically connected through the third through hole, and the The N-type insulating protection part and the N-type current transmission part are electrically connected through the fourth through hole.

优选地,所述倒装发光二极管芯片还开设有隔离槽,所述隔离槽的角度为30°~80°。Preferably, the flip-chip light emitting diode chip is further provided with an isolation groove, and the angle of the isolation groove is 30°˜80°.

根据本发明实施例当中的一种倒装发光二极管芯片的制备方法,用于制备上述的倒装发光二极管芯片,所述制备方法包括:A method for preparing a flip-chip light-emitting diode chip according to an embodiment of the present invention is used to prepare the above-mentioned flip-chip light-emitting diode chip, and the preparation method includes:

提供一生长所需的衬底;providing a substrate required for growth;

在所述衬底上依次外延生长缓冲层、N型半导体层、有源发光层、P型半导体层、电流阻挡层、电流扩展层、布拉格反射层、电流传输层、绝缘保护层以及键合金属层;A buffer layer, an N-type semiconductor layer, an active light-emitting layer, a P-type semiconductor layer, a current blocking layer, a current spreading layer, a Bragg reflection layer, a current transport layer, an insulating protective layer and a bonding metal are sequentially epitaxially grown on the substrate Floor;

其中,在生长完所述布拉格反射层后,在所述布拉格反射层上刻蚀出第一通孔和第二通孔。Wherein, after the Bragg reflection layer is grown, a first through hole and a second through hole are etched on the Bragg reflection layer.

优选地,所述刻蚀出第一通孔和第二通孔的工艺为电感耦合等离子体刻蚀工艺。Preferably, the process of etching the first through hole and the second through hole is an inductively coupled plasma etching process.

与现有技术相比:本发明通过依次层叠的N型半导体层、有源发光层、P型半导体层、电流阻挡层、电流扩展层、布拉格反射层以及电流传输层,由于布拉格反射层包括P型布拉格反射部和N型布拉格反射部,且在P型布拉格反射部和N型布拉格反射部上分别开设有通孔,同时,将电流传输层置于布拉格反射层之上,使得电流传输层的P型电流传输部和N型电流传输部分别通过通孔与电流扩展层和N型半导体层电性连接,在不改变电流传输能力的情况下,减少电流传输层的吸光,从而提升了倒装发光二极管芯片亮度。Compared with the prior art: the present invention adopts the N-type semiconductor layer, the active light-emitting layer, the P-type semiconductor layer, the current blocking layer, the current spreading layer, the Bragg reflection layer and the current transmission layer stacked in sequence, because the Bragg reflection layer includes P Type Bragg reflection part and N type Bragg reflection part, and through holes are respectively opened on the P type Bragg reflection part and N type Bragg reflection part, at the same time, the current transmission layer is placed on the Bragg reflection layer, so that the current transmission layer The P-type current transmission part and the N-type current transmission part are electrically connected to the current spreading layer and the N-type semiconductor layer respectively through vias, which reduce the light absorption of the current transmission layer without changing the current transmission capability, thereby improving the flip chip LED chip brightness.

附图说明Description of drawings

图1为本发明实施例一当中的倒装发光二极管芯片的结构示意图;FIG. 1 is a schematic structural diagram of a flip-chip light-emitting diode chip in Embodiment 1 of the present invention;

图2为本发明实施例一当中的倒装发光二极管芯片的俯视示意图;FIG. 2 is a schematic top view of the flip-chip LED chip in the first embodiment of the present invention;

图3为本发明实施例二当中的倒装发光二极管芯片的制备方法的流程图;3 is a flow chart of a method for fabricating a flip-chip light-emitting diode chip in Embodiment 2 of the present invention;

图4为本发明实施例四当中的倒装发光二极管芯片的俯视示意图;4 is a schematic top view of a flip-chip light-emitting diode chip in Embodiment 4 of the present invention;

图5为本发明实施例五当中的倒装发光二极管芯片的俯视示意图;FIG. 5 is a schematic top view of a flip-chip light-emitting diode chip in Embodiment 5 of the present invention;

图6为本发明实施例五当中的倒装发光二极管芯片的结构示意图。FIG. 6 is a schematic structural diagram of a flip-chip light emitting diode chip in Embodiment 5 of the present invention.

具体实施方式Detailed ways

为了便于理解本发明,下面将参照相关附图对本发明进行更全面的描述。附图中给出了本发明的若干实施例。但是,本发明可以以许多不同的形式来实现,并不限于本文所描述的实施例。相反地,提供这些实施例的目的是使对本发明的公开内容更加透彻全面。In order to facilitate understanding of the present invention, the present invention will be described more fully hereinafter with reference to the related drawings. Several embodiments of the invention are presented in the accompanying drawings. However, the present invention may be embodied in many different forms and is not limited to the embodiments described herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete.

需要说明的是,当元件被称为“固设于”另一个元件,它可以直接在另一个元件上或者也可以存在居中的元件。当一个元件被认为是“连接”另一个元件,它可以是直接连接到另一个元件或者可能同时存在居中元件。本文所使用的术语“垂直的”、“水平的”、“左”、“右”以及类似的表述只是为了说明的目的。It should be noted that when an element is referred to as being "fixed to" another element, it can be directly on the other element or intervening elements may also be present. When an element is referred to as being "connected" to another element, it can be directly connected to the other element or intervening elements may also be present. The terms "vertical," "horizontal," "left," "right," and similar expressions are used herein for illustrative purposes only.

除非另有定义,本文所使用的所有的技术和科学术语与属于本发明的技术领域的技术人员通常理解的含义相同。本文中在本发明的说明书中所使用的术语只是为了描述具体的实施例的目的,不是旨在于限制本发明。本文所使用的术语“及/或”包括一个或多个相关的所列项目的任意的和所有的组合。Unless otherwise defined, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. The terms used herein in the description of the present invention are for the purpose of describing specific embodiments only, and are not intended to limit the present invention. As used herein, the term "and/or" includes any and all combinations of one or more of the associated listed items.

实施例一Example 1

请参阅图1和图2,图1为本发明实施例一中的倒装发光二极管芯片的结构示意图,图2为本发明实施例一当中的倒装发光二极管芯片的俯视示意图,其中,倒装发光二极管芯片包括衬底21、以及在衬底21上依次外延生长的缓冲层221、N型半导体层222、有源发光层223、P型半导体层224、电流阻挡层23、电流扩展层24、布拉格反射层25、电流传输层、绝缘保护层27以及键合金属层。Please refer to FIGS. 1 and 2. FIG. 1 is a schematic structural diagram of a flip-chip LED chip in Embodiment 1 of the present invention, and FIG. 2 is a schematic top view of the flip-chip LED chip in Embodiment 1 of the present invention. The light-emitting diode chip includes a substrate 21, a buffer layer 221, an N-type semiconductor layer 222, an active light-emitting layer 223, a P-type semiconductor layer 224, a current blocking layer 23, a current spreading layer 24, Bragg reflection layer 25, current transport layer, insulating protective layer 27 and bonding metal layer.

在本实施例当中,衬底21可以为蓝宝石衬底21,电流阻挡层23的材料可以为SiO2、SiN、Ti3O5中的一种或者多种,电流扩展层24为氧化铟锡层,该电流扩展层24的厚度为

Figure BDA0003549817070000041
示例而非限定,在一些实施例当中,电流扩展层24的厚度可以为,例如
Figure BDA0003549817070000042
等,其中,氧化铟锡是一种混合物,由90%浓度的In2O3和10%浓度的SnO2混合而成。另外,布拉格反射层25为低折射率层与高折射率层交替层叠的周期性结构,其中,所述低折射率层为SiO2层,所述高折射率层为Ti3O5层,需要说明的是,布拉格反射层25中低折射率层与高折射率层交替层叠的周期性为10个~30个,例如为15个,即布拉格反射层25中的低折射率层和高折射率层分别有15层,可以理解的,布拉格反射层25中低折射率层首先沉积于电流扩展层24上,其次再在低折射率层上沉积高折射率层。In this embodiment, the substrate 21 may be a sapphire substrate 21 , the material of the current blocking layer 23 may be one or more of SiO 2 , SiN and Ti 3 O 5 , and the current spreading layer 24 is an indium tin oxide layer , the thickness of the current spreading layer 24 is
Figure BDA0003549817070000041
By way of example and not limitation, in some embodiments, the thickness of the current spreading layer 24 may be, for example,
Figure BDA0003549817070000042
etc., where indium tin oxide is a mixture consisting of 90% concentration of In2O3 and 10 % concentration of SnO2 . In addition, the Bragg reflection layer 25 is a periodic structure in which low-refractive index layers and high-refractive index layers are alternately stacked, wherein the low-refractive index layer is a SiO 2 layer, and the high-refractive index layer is a Ti 3 O 5 layer. It should be noted that the periodicity of alternately stacking low-refractive index layers and high-refractive-index layers in the Bragg reflection layer 25 is 10 to 30, for example, 15, that is, the low-refractive-index layers and the high-refractive-index layers in the Bragg reflection layer 25 There are 15 layers respectively. It can be understood that the low refractive index layer in the Bragg reflection layer 25 is first deposited on the current spreading layer 24, and then the high refractive index layer is deposited on the low refractive index layer.

进一步的,电流传输层的材料为Cr、Al、Ti、Ni、Pt、Au中的一种或多种,绝缘保护层27的材料为SiO2、SiN、Ti3O5中的一种或者多种,键合金属层的材料为Cr、Al、Ti、Ni、Pt、Au中的一种或多种。Further, the material of the current transport layer is one or more of Cr, Al, Ti, Ni, Pt, and Au, and the material of the insulating protective layer 27 is one or more of SiO 2 , SiN, and Ti 3 O 5 . The material of the bonding metal layer is one or more of Cr, Al, Ti, Ni, Pt, and Au.

需要说的是,布拉格反射层25包括P型布拉格反射部和N型布拉格反射部,P型布拉格反射部上开设有第一通孔131,N型布拉格反射部上开设有第二通孔132,其中,P型布拉格反射部沉积于电流扩展层24上,由于在生长完P型半导体层224后,通过刻蚀做出MESA台阶12,将部分N型半导体层222裸露,所以使得N型布拉格反射部沉积于N型半导体层222上,在刻蚀出MESA台阶12后,需要再在此MESA台阶12的基础上刻蚀部分N型半导体层222和缓冲层221,直至暴露出衬底21,刻蚀结束后,衬底21与刻蚀倾斜的缓冲层221之间将形成隔离槽11,隔离槽11用于将各个芯片之间隔开,隔离槽11的角度为30°~80°,示例而非限定,在一些实施例当中,隔离槽11的角度可以为,例如40°、50°、60°等。It should be noted that the Bragg reflection layer 25 includes a P-type Bragg reflection part and an N-type Bragg reflection part, the P-type Bragg reflection part is provided with a first through hole 131, and the N-type Bragg reflection part is provided with a second through hole 132, Among them, the P-type Bragg reflector is deposited on the current spreading layer 24. After the P-type semiconductor layer 224 is grown, the MESA step 12 is formed by etching, and part of the N-type semiconductor layer 222 is exposed, so the N-type Bragg reflector is made. Part of the N-type semiconductor layer 222 is deposited on the N-type semiconductor layer 222. After the MESA step 12 is etched, part of the N-type semiconductor layer 222 and the buffer layer 221 need to be etched on the basis of the MESA step 12 until the substrate 21 is exposed. After the etching, an isolation trench 11 will be formed between the substrate 21 and the etched inclined buffer layer 221. The isolation trench 11 is used to separate the chips. The angle of the isolation trench 11 is 30° to 80°. To define, in some embodiments, the angle of the isolation groove 11 may be, for example, 40°, 50°, 60°, and the like.

另外,沉积于布拉格反射层25电流传输层包括P型电流传输部261和N型电流传输部262,可以理解的,P型电流传输部261通过第一通孔131与电流扩展层24电性连接,N型电流传输部262通过第二通孔132与N型半导体层222电性连接。In addition, the current transfer layer deposited on the Bragg reflection layer 25 includes a P-type current transfer portion 261 and an N-type current transfer portion 262. It can be understood that the P-type current transfer portion 261 is electrically connected to the current spreading layer 24 through the first through hole 131 , the N-type current transmission part 262 is electrically connected to the N-type semiconductor layer 222 through the second through hole 132 .

具体的,第一通孔131和第二通孔132分别设置有多个,且相邻两个第一通孔131之间的间隔为10μm~200μm,相邻两个第二通孔132之间的间隔为10μm~200μm,其中,多个第一通孔131并排设置所连成的直线与多个第二通孔132并排设置所连成的直线平行,示例而非限定,在本实施例一些较佳实施例当中,相邻两个第一通孔131之间的间隔为,例如20μm、30μm、40μm等,相邻两个第二通孔132之间的间隔为,例如20μm、30μm、40μm等,在本实施例当中,第一通孔131开设有7个,第一通孔131间隔20μm,若设一端的第一通孔131的位置为零点,则从一端的第一通孔131到另一端的第一通孔131的位置分别为0μm、20μm、40μm、60μm、80μm、100μm、120μm。Specifically, a plurality of first through holes 131 and second through holes 132 are respectively provided, and the interval between two adjacent first through holes 131 is 10 μm˜200 μm, and the distance between two adjacent second through holes 132 is 10 μm˜200 μm. The interval is 10 μm˜200 μm, wherein the straight line formed by the side-by-side arrangement of the plurality of first through holes 131 is parallel to the line formed by the side-by-side arrangement of the plurality of second through holes 132 , which is an example but not a limitation. In a preferred embodiment, the interval between two adjacent first through holes 131 is, for example, 20 μm, 30 μm, 40 μm, etc., and the interval between two adjacent second through holes 132 is, for example, 20 μm, 30 μm, 40 μm, etc. etc., in this embodiment, there are seven first through holes 131, and the first through holes 131 are spaced 20 μm apart. The positions of the first through holes 131 at the other end are 0 μm, 20 μm, 40 μm, 60 μm, 80 μm, 100 μm, and 120 μm, respectively.

另外,示例而非限定,在本实施例一些较佳实施例当中,第一通孔131的面积为20μm2~1000μm2,例如为100μm2、200μm2、300μm2等,第二通孔132的面积为20μm2~1000μm2,例如为100μm2、200μm2、300μm2等。In addition, by way of example but not limitation, in some preferred embodiments of this embodiment, the area of the first through hole 131 is 20 μm 2 to 1000 μm 2 , such as 100 μm 2 , 200 μm 2 , 300 μm 2 , etc. The area is 20 μm 2 to 1000 μm 2 , for example, 100 μm 2 , 200 μm 2 , 300 μm 2 or the like.

需要说明的是,在电流传输层上还依次沉积有绝缘保护层27以及键合金属层,其中,绝缘保护层27包括P型绝缘保护部和N型绝缘保护部,键合金属层包括P型键合金属部281和N型键合金属部282,P型绝缘保护部上开设有第三通孔141,N型绝缘保护部上开设有第四通孔142,P型键合金属部281与P型电流传输部261通过第三通孔141电性连接,N型键合金属部282与N型电流传输部262通过第四通孔142电性连接,可以理解的,P型键合金属部281通过第三通孔141与P型电流传输部261电性连接,P型电流传输部261再通过第一通孔131与电流扩展层24电性连接,而N型键合金属部282通过第四通孔142与N型电流传输部262电性连接,N型电流传输部262再通过第二通孔132与N型半导体层222电性连接。另外,在本实施例当中,第三通孔141和第四通孔142的数量分别为1个。It should be noted that an insulating protective layer 27 and a bonding metal layer are sequentially deposited on the current transport layer, wherein the insulating protective layer 27 includes a P-type insulating protective portion and an N-type insulating protective portion, and the bonding metal layer includes a P-type insulating protective portion. The bonding metal portion 281 and the N-type bonding metal portion 282, the P-type insulating protection portion is provided with a third through hole 141, the N-type insulating protection portion is provided with a fourth through hole 142, the P-type bonding metal portion 281 and the The P-type current transmission portion 261 is electrically connected through the third through hole 141 , and the N-type bonding metal portion 282 and the N-type current transmission portion 262 are electrically connected through the fourth through hole 142 . It can be understood that the P-type bonding metal portion 281 is electrically connected to the P-type current transmission part 261 through the third through hole 141, the P-type current transmission part 261 is electrically connected to the current spreading layer 24 through the first through hole 131, and the N-type bonding metal part 282 is electrically connected through the first through hole 131. The four through holes 142 are electrically connected to the N-type current transmission portion 262 , and the N-type current transmission portion 262 is further electrically connected to the N-type semiconductor layer 222 through the second through hole 132 . In addition, in this embodiment, the number of the third through hole 141 and the fourth through hole 142 is one, respectively.

综上,本发明通过依次层叠的N型半导体层222、有源发光层223、P型半导体层224、电流阻挡层23、电流扩展层24、布拉格反射层25以及电流传输层,由于布拉格反射层25包括P型布拉格反射部和N型布拉格反射部,且在P型布拉格反射部和N型布拉格反射部上分别开设有通孔,同时,将电流传输层置于布拉格反射层25之上,使得电流传输层的P型电流传输部261和N型电流传输部262分别通过通孔与电流扩展层24和N型半导体层222电性连接,在不改变电流传输能力的情况下,减少电流传输层的吸光,从而提升了倒装发光二极管芯片亮度。To sum up, in the present invention, the N-type semiconductor layer 222, the active light-emitting layer 223, the P-type semiconductor layer 224, the current blocking layer 23, the current spreading layer 24, the Bragg reflection layer 25 and the current transmission layer are sequentially stacked. 25 includes a P-type Bragg reflection part and an N-type Bragg reflection part, and through holes are respectively opened on the P-type Bragg reflection part and the N-type Bragg reflection part, and at the same time, the current transmission layer is placed on the Bragg reflection layer 25, so that The P-type current transfer portion 261 and the N-type current transfer portion 262 of the current transfer layer are electrically connected to the current spreading layer 24 and the N-type semiconductor layer 222 through vias, respectively, and the current transfer layer is reduced without changing the current transfer capability. light absorption, thereby improving the brightness of the flip-chip light-emitting diode chip.

实施例二Embodiment 2

请参阅图3,所示为本发明实施例二提出的倒装发光二极管芯片的制备方法,用于制备上述实施例一当中的倒装发光二极管芯片,所述方法具体包括步骤S201至步骤S207,其中:Please refer to FIG. 3 , which shows a method for preparing a flip-chip light-emitting diode chip according to the second embodiment of the present invention, which is used to prepare the flip-chip light-emitting diode chip in the above-mentioned first embodiment. The method specifically includes steps S201 to S207 . in:

步骤S201,提供一生长所需的衬底。Step S201, providing a substrate required for growth.

其中,衬底可以为蓝宝石衬底。Wherein, the substrate may be a sapphire substrate.

步骤S202,在衬底上依次外延生长缓冲层、N型半导体层、有源发光层以及P型半导体层。Step S202, a buffer layer, an N-type semiconductor layer, an active light-emitting layer and a P-type semiconductor layer are sequentially epitaxially grown on the substrate.

步骤S203,形成MESA台阶。Step S203, forming MESA steps.

在本实施例当中,首先在P型半导体层表面利用光刻技术形成图形,然后采用电感耦合等离子体刻蚀工艺从P型半导体层向衬底方向进行刻蚀,去除掉部分N型半导体层、有源发光层以及P型半导体层,然后去除光刻胶残胶,将N型半导体层部分裸露,形成MESA台阶。In this embodiment, first, a pattern is formed on the surface of the P-type semiconductor layer using photolithography technology, and then an inductively coupled plasma etching process is used to etch from the P-type semiconductor layer to the substrate direction to remove part of the N-type semiconductor layer, The active light-emitting layer and the P-type semiconductor layer are then removed, and the photoresist residue is removed, and the N-type semiconductor layer is partially exposed to form MESA steps.

步骤S204,沉积电流阻挡层,并形成隔离槽。In step S204, a current blocking layer is deposited, and an isolation trench is formed.

具体的,采用PECVD(Plasma Enhanced Chemical Vapor Deposition,等离子体增强化学气相沉积)工艺在P型半导体层表面和MESA台阶表面沉积SiO2,后采用光刻工艺形成图形,并通过BOE溶液腐蚀掉部分SiO2,形成电流阻挡层。Specifically, a PECVD (Plasma Enhanced Chemical Vapor Deposition, plasma enhanced chemical vapor deposition) process is used to deposit SiO 2 on the surface of the P-type semiconductor layer and the MESA step surface, and then a photolithography process is used to form a pattern, and a part of the SiO is etched away by the BOE solution. 2 , forming a current blocking layer.

接着采用光刻技术在MESA台阶表面形成图形,再采用电感耦合等离子体刻蚀工艺刻从MESA台阶向衬底方向进行刻蚀,去除部分N型半导体层和缓冲层,直至暴露出衬底,随后去除光刻胶,形成隔离槽,在本实施例当中,隔离槽的开设角度为50°。Then, a pattern is formed on the surface of the MESA step by photolithography, and then the inductively coupled plasma etching process is used to etch from the MESA step to the substrate, and part of the N-type semiconductor layer and buffer layer are removed until the substrate is exposed. The photoresist is removed to form an isolation trench. In this embodiment, the opening angle of the isolation trench is 50°.

步骤S205,沉积电流扩展层和布拉格反射层,并在布拉格反射层上开孔。Step S205, depositing a current spreading layer and a Bragg reflection layer, and opening holes on the Bragg reflection layer.

需要说明的是,采用磁控溅射技术沉积电流扩展层,其中,电流扩展层为氧化铟锡层,再利用光刻技术在电流扩展层上形成图形,进一步的,利用氧化铟锡腐蚀液腐蚀掉部分电流扩展层,可以理解的,电流扩展层只沉积在P型半导体层和电流阻挡层上,而在MESA台阶上未沉积电流扩展层,最后将多余光刻胶去除,形成电流扩展层。It should be noted that the magnetron sputtering technology is used to deposit the current spreading layer, wherein the current spreading layer is an indium tin oxide layer, and then a pattern is formed on the current spreading layer by using a photolithography technique, and further, an indium tin oxide etching solution is used to corrode Part of the current spreading layer is removed. It is understandable that the current spreading layer is only deposited on the P-type semiconductor layer and the current blocking layer, while the current spreading layer is not deposited on the MESA steps. Finally, the excess photoresist is removed to form the current spreading layer.

沉积完电流扩展层后,采用电子束蒸镀工艺沉积布拉格反射层,具体的,在衬底、MESA台阶以及电流扩展层上沉积有布拉格反射层,再在布拉格反射层表面形成图形,随后采用电感耦合等离子体刻蚀工艺去除掉部分布拉格反射层,并去除光刻胶,形成布拉格反射层通孔,其中,布拉格反射层包括P型布拉格反射部和N型布拉格反射部,P型布拉格反射部沉积于电流扩展层上,N型布拉格反射部沉积于MESA台阶上,进一步的,P型布拉格反射部上开设有第一通孔,N型布拉格反射部上开设有第二通孔。After the current spreading layer is deposited, the Bragg reflection layer is deposited by electron beam evaporation. Specifically, a Bragg reflection layer is deposited on the substrate, MESA steps and the current spreading layer, and then a pattern is formed on the surface of the Bragg reflection layer, and then an inductor is used. The coupled plasma etching process removes part of the Bragg reflection layer and removes the photoresist to form through holes in the Bragg reflection layer, wherein the Bragg reflection layer includes a P-type Bragg reflection part and an N-type Bragg reflection part, and the P-type Bragg reflection part is deposited On the current spreading layer, the N-type Bragg reflector is deposited on the MESA step. Further, the P-type Bragg reflector is provided with a first through hole, and the N-type Bragg reflector is provided with a second through hole.

在本实施例当中,第一通孔和第二通孔均为圆形,在一些其他实施例当中,第一通孔和第二通孔的形状还可以为其他图形,例如为方形等,其中,第一通孔和第二通孔的面积均为314.15μm2,第一通孔之间的间隔为50μm,第二通孔之间的间隔为50μm。In this embodiment, the first through hole and the second through hole are both circular, and in some other embodiments, the shape of the first through hole and the second through hole may also be other shapes, such as a square, etc., wherein , the areas of the first through holes and the second through holes are both 314.15 μm 2 , the interval between the first through holes is 50 μm, and the interval between the second through holes is 50 μm.

步骤S206,沉积电流传输层。Step S206, depositing a current transport layer.

具体的,在布拉格反射层涂布负性光刻胶,通过曝光、显影形成图形,然后采用电子束蒸镀工艺蒸镀金属Cr、Al、Ti、Pt、Au、Pt、Ti后,采用Lift-Off工艺(金属剥离工艺)剥离部分金属,形成电流传输层,需要说明的是,电流传输层包括P型电流传输部和N型电流传输部,其中,P型电流传输部沉积在P型布拉格反射部上,N型电流传输部沉积在N型布拉格反射部上,可以理解的,P型电流传输部将第一通孔填充,N型电流传输部将第二通孔填充,那么,第一通孔实现了将P型电流传输部与电流扩展层电性连接,第二通孔实现了将N型电流传输部与N型半导体层电性连接,即与MESA台阶接触。Specifically, a negative photoresist is coated on the Bragg reflection layer, a pattern is formed by exposure and development, and then metal Cr, Al, Ti, Pt, Au, Pt, and Ti are evaporated by an electron beam evaporation process, and then Lift- The Off process (metal stripping process) peels off part of the metal to form a current transmission layer. It should be noted that the current transmission layer includes a P-type current transmission part and an N-type current transmission part, wherein the P-type current transmission part is deposited on the P-type Bragg reflection On the part, the N-type current transmission part is deposited on the N-type Bragg reflector. It can be understood that the P-type current transmission part fills the first through hole, and the N-type current transmission part fills the second through hole. Then, the first through hole is filled. The hole realizes the electrical connection between the P-type current transmission part and the current spreading layer, and the second through hole realizes the electrical connection between the N-type current transmission part and the N-type semiconductor layer, that is, contacts with the MESA step.

步骤S207,沉积绝缘保护层和键合金属层。Step S207, depositing an insulating protective layer and a bonding metal layer.

需要说明的是,沉积完电流传输层后,采用PECVD工艺沉积SiO2,形成绝缘保护层,其中,绝缘保护层包括P型绝缘保护部和N型绝缘保护部,再采用光刻工艺,在绝缘保护层上形成图形,随后使用BOE溶液腐蚀掉部分绝缘保护层,即分别在P型绝缘保护部和N型绝缘保护部上开孔,形成第三通孔和第四通孔,可以理解的,第三通孔设于P型电流传输部的上方,第四通孔设于N型电流传输部的上方。It should be noted that, after the current transport layer is deposited, SiO 2 is deposited by PECVD process to form an insulating protective layer, wherein the insulating protective layer includes a P-type insulating protective portion and an N-type insulating protective portion, and then a photolithography process is used to form the insulating protective layer. A pattern is formed on the protective layer, and then part of the insulating protective layer is etched away by using the BOE solution, that is, the P-type insulating protective part and the N-type insulating protective part are respectively opened to form the third through hole and the fourth through hole. It can be understood that, The third through hole is arranged above the P-type current transmission part, and the fourth through hole is arranged above the N-type current transmission part.

具体的,沉积完绝缘保护层并开孔后,涂布负性光刻胶,并曝光、显影形成图形,然后采用电子束蒸镀工艺,蒸镀金属Cr、Al、Ti、Pt、Au、Pt、Ti,再采用Lift-Off工艺剥离掉部分金属,将多余的光刻胶去除后,得到键合金属层,该键合金属层包括P型键合金属部和N型键合金属部,可以理解的,P型键合金属部将第三通孔进行填充,N型键合金属部将第四通孔进行填充,那么,P型键合金属部与P型电流传输部通过第三通孔电性连接,N型键合金属部与N型电流传输部通过第四通孔电性连接。Specifically, after the insulating protective layer is deposited and the holes are opened, a negative photoresist is coated, exposed and developed to form a pattern, and then metal Cr, Al, Ti, Pt, Au, Pt are evaporated by an electron beam evaporation process. , Ti, and then use the Lift-Off process to peel off part of the metal, and remove the excess photoresist to obtain a bonding metal layer. The bonding metal layer includes a P-type bonding metal part and an N-type bonding metal part, which can be It is understood that the P-type bonding metal part fills the third through hole, and the N-type bonding metal part fills the fourth through hole, then the P-type bonding metal part and the P-type current transmission part pass through the third through hole For electrical connection, the N-type bonding metal part and the N-type current transmission part are electrically connected through the fourth through hole.

实施例三Embodiment 3

请参阅图1和图2,本发明实施例三提供一种倒装发光二极管芯片,在本实施例当中,在提供的蓝宝石衬底21上依次外延生长缓冲层221、N型半导体层222、有源发光层223、P型半导体层224,并形成MESA台阶12,随后沉积电流阻挡层23,并形成隔离槽11,再沉积电流扩展层24和布拉格反射层25,并在布拉格反射层25上开孔,然后沉积电流传输层,最后沉积绝缘保护层27和键合金属层,其中,沉积于布拉格反射层通孔之上的电流传输层的面积不大于布拉格反射层通孔的面积。Referring to FIG. 1 and FIG. 2 , the third embodiment of the present invention provides a flip-chip light-emitting diode chip. In this embodiment, a buffer layer 221 , an N-type semiconductor layer 222 , a buffer layer 221 , an N-type semiconductor layer 222 , and a sapphire substrate 21 are epitaxially grown on the provided sapphire substrate 21 in sequence. The source light-emitting layer 223, the P-type semiconductor layer 224, and the MESA step 12 is formed, then the current blocking layer 23 is deposited, and the isolation trench 11 is formed, the current spreading layer 24 and the Bragg reflection layer 25 are deposited again, and the Bragg reflection layer 25 is opened. hole, then deposit a current transport layer, and finally deposit an insulating protective layer 27 and a bonding metal layer, wherein the area of the current transport layer deposited on the Bragg reflection layer through hole is not larger than that of the Bragg reflection layer through hole.

实施例四Embodiment 4

请参阅图4,所示为本发明实施例四当中的倒装发光二极管芯片的俯视示意图,本发明实施例四提供一种倒装发光二极管芯片,在本实施例当中,在提供的蓝宝石衬底21上依次外延生长缓冲层221、N型半导体层222、有源发光层223、P型半导体层224,并形成MESA台阶12,随后沉积电流阻挡层23,并形成隔离槽11,再沉积电流扩展层24和布拉格反射层25,并在布拉格反射层25上开孔,然后沉积电流传输层,最后沉积绝缘保护层27和键合金属层,其中,沉积于布拉格反射层通孔之上的电流传输层的面积大于布拉格反射层通孔的面积,减小了电流传输层与电流扩展的接触电阻,降低了芯片工作电压。Please refer to FIG. 4 , which is a schematic top view of the flip-chip light-emitting diode chip in the fourth embodiment of the present invention. The fourth embodiment of the present invention provides a flip-chip light-emitting diode chip. In this embodiment, the provided sapphire substrate A buffer layer 221, an N-type semiconductor layer 222, an active light-emitting layer 223, and a P-type semiconductor layer 224 are sequentially epitaxially grown on 21, and the MESA step 12 is formed, then the current blocking layer 23 is deposited, and the isolation trench 11 is formed, and then the current spread is deposited layer 24 and Bragg reflection layer 25, and opening holes on the Bragg reflection layer 25, then depositing a current transport layer, and finally depositing an insulating protective layer 27 and a bonding metal layer, wherein the current transport layer deposited on the Bragg reflection layer through holes The area of the layer is larger than the area of the through hole of the Bragg reflection layer, which reduces the contact resistance between the current transmission layer and the current spreading, and reduces the working voltage of the chip.

实施例五Embodiment 5

请参阅图5和图6,图5为本发明实施例五当中的倒装发光二极管芯片的俯视示意图,图6为本发明实施例五当中的倒装发光二极管芯片的结构示意图,本发明实施例五提供一种倒装发光二极管芯片,在本实施例当中,在提供的蓝宝石衬底21上依次外延生长缓冲层221、N型半导体层222、有源发光层223、P型半导体层224,并形成MESA台阶12,随后沉积电流阻挡层23,并形成隔离槽11,再沉积电流扩展层24和布拉格反射层25,并在布拉格反射层25上开孔,然后沉积电流传输层,最后沉积绝缘保护层27和键合金属层,其中,电流阻挡层23为非连续性的,且只在布拉格反射层25通孔下方设置,即起到了电流阻挡的作用,又减少了布拉格反射层25通孔之间SiO2的吸光,有效提升发光亮度。Please refer to FIGS. 5 and 6 , FIG. 5 is a schematic top view of a flip-chip LED chip in Embodiment 5 of the present invention, and FIG. 6 is a schematic structural diagram of a flip-chip LED chip in Embodiment 5 of the present invention. Fifth, a flip-chip light-emitting diode chip is provided. In this embodiment, a buffer layer 221 , an N-type semiconductor layer 222 , an active light-emitting layer 223 , and a P-type semiconductor layer 224 are epitaxially grown on the provided sapphire substrate 21 in sequence. Form MESA step 12, then deposit current blocking layer 23, and form isolation trench 11, then deposit current spreading layer 24 and Bragg reflection layer 25, and open holes on Bragg reflection layer 25, then deposit current transport layer, and finally deposit insulation protection layer 27 and bonding metal layer, wherein the current blocking layer 23 is discontinuous and is only provided under the through holes of the Bragg reflection layer 25, which not only plays the role of current blocking, but also reduces the distance between the through holes of the Bragg reflection layer 25. The light absorption of SiO 2 can effectively improve the luminous brightness.

各实施例制备出的倒装发光二极管芯片的性能测试结果如表1所示:The performance test results of the flip-chip light-emitting diode chips prepared in each embodiment are shown in Table 1:

表1Table 1

Figure BDA0003549817070000101
Figure BDA0003549817070000101

从表中可以看出,本发明制备的倒装发光二极管芯片较现有产品而言,在同样的测试电流下,发光亮度皆得到了不同程度的提升。It can be seen from the table that, compared with the existing products, the flip-chip light-emitting diode chips prepared by the present invention have improved luminous brightness to different degrees under the same test current.

以上所述实施例仅表达了本发明的几种实施方式,其描述较为具体和详细,但并不能因此而理解为对本发明专利范围的限制。应当指出的是,对于本领域的普通技术人员来说,在不脱离本发明构思的前提下,还可以做出若干变形和改进,这些都属于本发明的保护范围。因此,本发明专利的保护范围应以所附权利要求为准。The above-mentioned embodiments only represent several embodiments of the present invention, and the descriptions thereof are specific and detailed, but should not be construed as a limitation on the scope of the patent of the present invention. It should be pointed out that for those of ordinary skill in the art, without departing from the concept of the present invention, several modifications and improvements can also be made, which all belong to the protection scope of the present invention. Therefore, the protection scope of the patent of the present invention should be subject to the appended claims.

Claims (10)

1. A flip-chip light emitting diode chip is characterized by comprising an N-type semiconductor layer, an active light emitting layer, a P-type semiconductor layer, a current blocking layer, a current expansion layer, a Bragg reflection layer and a current transmission layer which are sequentially stacked, wherein the Bragg reflection layer comprises a P-type Bragg reflection part and an N-type Bragg reflection part, the current transmission layer comprises a P-type current transmission part and an N-type current transmission part, a first through hole is formed in the P-type Bragg reflection part, a second through hole is formed in the N-type Bragg reflection part, the first through hole is used for electrically connecting the P-type current transmission part with the current expansion layer, and the second through hole is used for electrically connecting the N-type current transmission part with the N-type semiconductor layer.
2. The flip light emitting diode chip of claim 1, wherein the flip light emitting diode chip further comprises a substrate, a buffer layer, an insulating protection layer, and a bonding metal layer;
the buffer layer, the N-type semiconductor layer, the active light emitting layer, the P-type semiconductor layer, the current blocking layer, the current spreading layer, the Bragg reflection layer, the current transmission layer, the insulating protection layer and the bonding metal layer are sequentially stacked on the substrate.
3. The flip-chip light emitting diode chip of claim 1, wherein the current spreading layer is an indium tin oxide layer, and the thickness of the current spreading layer is
Figure FDA0003549817060000011
4. The flip chip light emitting diode chip of claim 1, wherein the bragg reflective layer is a periodic structure in which low refractive index layers and high refractive index layers are alternately stacked, wherein the low refractive index layers are SiO2A layer of Ti as the high refractive index layer3O5And (3) a layer.
5. The flip chip led chip of claim 1, wherein the first and second vias have an area of 20um2~1000um2
6. The flip chip light emitting diode chip of claim 1, wherein the first through holes and the second through holes are respectively provided in plural, and an interval between two adjacent first through holes is 10 μm to 200 μm, and an interval between two adjacent second through holes is 10 μm to 200 μm.
7. The flip-chip light emitting diode chip of claim 2, wherein the insulating protection layer includes a P-type insulating protection portion and an N-type insulating protection portion, the bonding metal layer includes a P-type bonding metal portion and an N-type bonding metal portion, a third through hole is formed in the P-type insulating protection portion, a fourth through hole is formed in the N-type insulating protection portion, the P-type bonding metal portion is electrically connected to the P-type current transmission portion through the third through hole, and the N-type bonding metal portion is electrically connected to the N-type current transmission portion through the fourth through hole.
8. The flip chip led chip of claim 6, wherein the flip chip led chip further defines an isolation trench, and an angle of the isolation trench is 30 ° to 80 °.
9. A method for manufacturing a flip-chip light-emitting diode chip, for manufacturing the flip-chip light-emitting diode chip of any one of claims 1 to 8, the method comprising:
providing a substrate required by growth;
sequentially epitaxially growing a buffer layer, an N-type semiconductor layer, an active light-emitting layer, a P-type semiconductor layer, a current blocking layer, a current expansion layer, a Bragg reflection layer, a current transmission layer, an insulating protection layer and a bonding metal layer on the substrate;
and after the Bragg reflection layer grows, etching a first through hole and a second through hole on the Bragg reflection layer.
10. The method for manufacturing the flip chip light emitting diode chip as claimed in claim 9, wherein the process for etching the first through hole and the second through hole is an inductively coupled plasma etching process.
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