CN114231054A - 聚碳酸酯专用型钛白粉及其制备方法 - Google Patents

聚碳酸酯专用型钛白粉及其制备方法 Download PDF

Info

Publication number
CN114231054A
CN114231054A CN202111390699.3A CN202111390699A CN114231054A CN 114231054 A CN114231054 A CN 114231054A CN 202111390699 A CN202111390699 A CN 202111390699A CN 114231054 A CN114231054 A CN 114231054A
Authority
CN
China
Prior art keywords
titanium dioxide
polycarbonate
special
percent
tetrachloride
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202111390699.3A
Other languages
English (en)
Inventor
肖勇丽
淦文军
赵北东
冯燕
罗静
李开娟
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chongqing Panzhihua Iron And Steel Group Co ltd
Original Assignee
Chongqing Panzhihua Iron And Steel Group Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chongqing Panzhihua Iron And Steel Group Co ltd filed Critical Chongqing Panzhihua Iron And Steel Group Co ltd
Priority to CN202111390699.3A priority Critical patent/CN114231054A/zh
Publication of CN114231054A publication Critical patent/CN114231054A/zh
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/36—Compounds of titanium
    • C09C1/3607—Titanium dioxide
    • C09C1/3676—Treatment with macro-molecular organic compounds
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G23/00—Compounds of titanium
    • C01G23/04—Oxides; Hydroxides
    • C01G23/047—Titanium dioxide
    • C01G23/07—Producing by vapour phase processes, e.g. halide oxidation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00—Use of pretreated ingredients
    • C08K9/10—Encapsulated ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/36—Compounds of titanium
    • C09C1/3607—Titanium dioxide
    • C09C1/3653—Treatment with inorganic compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/36—Compounds of titanium
    • C09C1/3607—Titanium dioxide
    • C09C1/3684—Treatment with organo-silicon compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/36—Compounds of titanium
    • C09C1/3692—Combinations of treatments provided for in groups C09C1/3615 - C09C1/3684
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/006—Combinations of treatments provided for in groups C09C3/04 - C09C3/12
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/06—Treatment with inorganic compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/10—Treatment with macromolecular organic compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/12—Treatment with organosilicon compounds
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Geology (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)

Abstract

本发明涉及化工领域，具体涉及聚碳酸酯专用型钛白粉及其制备方法。本发明所解决的技术问题是提供聚碳酸酯专用型钛白粉及其制备方法。该聚碳酸酯专用型钛白粉是将四氯化钛、四氯化硅、三氯化铝氧化，得氯化初品，然后与有机物共混造粒获得。采用该方法制备的钛白粉工艺流程短、工序少、过程简单，钛白粉粒子堆密度大，干粉流动性佳。且制得的聚碳酸酯专用型钛白粉的主要化学成分含量，以质量百分比计包括：二氧化钛含量≥92％，氧化硅含量≥2.0％，氧化铝含量≥1.5％。

Description

聚碳酸酯专用型钛白粉及其制备方法
技术领域
本发明涉及化工领域，具体涉及聚碳酸酯专用型钛白粉及其制备方法。
背景技术
聚碳酸酯(英文Polycarbonate，简称PC)是指分子链中以碳酸酯基(-OROCO-)为基础链段的热塑性高分子聚合物，因其具有高冲击强度、高耐热性、阻燃和透明性等，使其在各种应用中的表现优于其他透明聚合物，从而成为用途最广的高性能树脂之一，广泛应用于建材、汽车、电子电气、食品包装和医疗保健等行业。
但同大多数聚合物一样，PC通常对于紫外线辐射不是十分稳定，在紫外线的作用下会发生光老化而导致降解。出现黄变现象，同时透光率、光泽度以及强度和韧性都将大幅度降低。
而钛白粉是一种性能优异的白色颜料，广泛应用于涂料、塑料、造纸、油墨、电子等领域，被称为“工业味精”。经过特殊处理的钛白粉可吸收紫外光，屏蔽产生的活性电子，应用在PC树脂体系中，可起到降低紫外线对PC树脂的降解作用，改善PC制品的性能，延长其使用寿命。但随着全球经济技术水平的提升，各行各业对清洁、环保、智能、自动化生产等要求越来越高，常规工艺生产的钛白粉粒子粒径小，比表面积大，堆密度小，干粉流动性差，不利于钛白粉包装、输送和加料。
且中国专利CN107805321A虽然公开了一种聚碳酸酯专用型二氧化钛颜料的制备方法，以氯化法工艺制备的金红石型二氧化钛初品为原料，进行湿法打浆，然后湿法包覆1～2％的氧化硅和1～3％的氧化铝，洗涤、烘干、汽粉得半成品，再将半成品打浆，湿法添加0.5～2％的有机表面改性剂氨基改性聚硅氧烷进行有机处理，处理后的浆料再次烘干、粉碎制得聚氨酯专用型二氧化钛颜料。但该制备方法流程长、工序多，过程复杂。
发明内容
为了解决现有技术的不足，本发明目的在于提供了聚碳酸酯专用型钛白粉及其制备方法。采用该方法制备的钛白粉工艺流程短、工序少、过程简单，钛白粉粒子堆密度大，干粉流动性佳。
本发明首先提供了聚碳酸酯专用型钛白粉的制备方法，包括以下步骤：
(1)将四氯化钛、四氯化硅、三氯化铝氧化，得氯化初品；
(2)将氯化初品与有机物共混造粒，即可。
其中，上述聚碳酸酯专用型钛白粉的制备方法，步骤(1)中，所述四氯化硅以氧化硅计占四氯化钛、四氯化硅、三氯化铝的2.0～4.0wt％。
其中，上述聚碳酸酯专用型钛白粉的制备方法，步骤(1)中，三氯化铝以氧化铝计占反应物四氯化钛、四氯化硅、三氯化铝的1.5～4.0wt％。
其中，上述聚碳酸酯专用型钛白粉的制备方法，步骤(2)中，有机物的化学成分包括：相同质量比的聚硅氧烷和木质素磺酸钠。
其中，上述聚碳酸酯专用型钛白粉的制备方法，步骤(2)中，有机物的化学成分包括：相同质量比的聚硅氧烷和聚丙烯酸钠。
其中，上述聚碳酸酯专用型钛白粉的制备方法，步骤(2)中，所述有机物为氯化初品总质量的0.5～2.0％。
本发明还提供上述方法制备的聚碳酸酯专用型钛白粉。
其中，上述聚碳酸酯专用型钛白粉的主要化学成分含量，以质量百分比计包括：二氧化钛含量≥92％，氧化硅含量≥2.0％，氧化铝含量≥1.5％。
其中，上述聚碳酸酯专用型钛白粉，其化学成分还包括包覆在外层的有机物。
其中，上述聚碳酸酯专用型钛白粉，平均粒径200±20nm，堆积密度≥0.8g/cm3。
有益效果：本发明针对聚碳酸酯对钛白粉的特殊要求，在四氯化钛氧化阶段添加四氯化硅和三氯化铝，使二氧化钛中包含有氧化硅和氧化铝，屏蔽二氧化钛吸收紫外光产生的活性电子，应用在PC树脂体系中，可起到降低紫外线对PC树脂的降解作用，改善PC制品的性能，延长其使用寿命。在氯化初品表面均匀包覆一层有机物，改善钛白粉与聚氨酯树脂体系的相容性，提升钛白粉在聚氨酯树脂体系中的分散性，以改善制品的强度和韧性。进行造粒处理，能够提高钛白粉粒子的堆密度和干粉流动性，且制备的聚碳酸酯专用型钛白粉SEM检测平均粒径200±20nm，堆积密度(松散)≥0.8g/cm3。且本发明制备工艺流程短、工序少、过程简单。
具体实施方式
本发明首先提供了聚碳酸酯专用型钛白粉的制备方法，包括以下步骤：
(1)将四氯化钛、四氯化硅、三氯化铝一起加入氧化炉中进行氧化，得到氯化初品；所述四氯化硅的添加量以氧化硅计为反应物全部总质量的2.0～4.0wt％；三氯化铝的添加量以氧化铝计为反应物全部总质量的1.5～4.0wt％。
(2)将步骤(1)所得氯化初品与有机物一起加入造粒系统中进行造粒，即为聚碳酸酯专用型钛白粉。其中，有机物的成分是等质量比的聚硅氧烷与木质素磺酸钠或等质量比的聚硅氧烷与聚丙烯酸钠。有机物的添加量为氯化初品总质量的0.5～2.0％。
本发明针对聚碳酸酯对钛白粉的特殊要求，在四氯化钛氧化阶段添加四氯化硅和三氯化铝，通过氯化法生产工艺，使二氧化钛中包含有氧化硅和氧化铝，从而屏蔽二氧化钛吸收紫外光产生的活性电子，将该钛白粉应用在PC树脂体系中，可起到降低紫外线对PC树脂的降解作用，改善PC制品的性能，延长其使用寿命。
本发明在氯化初品表面均匀包覆一层有机物，能够改善钛白粉与聚氨酯树脂体系的相容性，提升钛白粉在聚氨酯树脂体系中的分散性，以改善制品的强度和韧性。
本发明制备方法步骤(2)中进行造粒处理，能提高钛白粉粒子的堆密度和干粉流动性。
本发明还提供上述方法制备的聚碳酸酯专用型钛白粉。该钛白粉主要化学成分含量，以质量百分比计包括：二氧化钛含量≥92％，氧化硅含量≥2.0％，氧化铝含量≥1.5％，外层进行有机包覆。
实施例1
将四氯化钛、四氯化硅、三氯化铝一起加入氧化炉中进行氧化，四氯化硅的添加量以氧化硅计为反应物全部总质量的2.0％，三氯化铝的添加量以氧化铝计为反应物全部总质量的1.5％，得到氯化初品。将氯化初品与有机物一起加入造粒系统中进行造粒，有机物为聚硅氧烷和木质素磺酸钠，有机物的添加量分别为氯化初品总质量的0.25％，造粒所得粒子即为聚碳酸酯专用型钛白粉。
实施例2
将四氯化钛、四氯化硅、三氯化铝一起加入氧化炉中进行氧化，四氯化硅的添加量以氧化硅计为反应物全部总质量的3.0％，三氯化铝的添加量以氧化铝计为反应物全部总质量的2.7％，得到氯化初品。将氯化初品与有机物一起加入造粒系统中进行造粒，有机物为聚硅氧烷和聚丙烯酸钠，有机物的添加量分别为氯化初品总质量的0.6％，造粒所得粒子即为聚碳酸酯专用型钛白粉。
实施例3
将四氯化钛、四氯化硅、三氯化铝一起加入氧化炉中进行氧化，四氯化硅的添加量以氧化硅计为反应物全部总质量的4.0％，三氯化铝的添加量以氧化铝计为反应物全部总质量的4.0％，得到氯化初品。将氯化初品与有机物一起加入造粒系统中进行造粒，有机物为聚硅氧烷和木质素磺酸钠，有机物的添加量为氯化初品总质量的1.0％，造粒所得粒子即为聚碳酸酯专用型钛白粉。

Claims (10)

1.聚碳酸酯专用型钛白粉的制备方法，其特征在于：包括以下步骤：
(1)将四氯化钛、四氯化硅、三氯化铝氧化，得氯化初品；
(2)将氯化初品与有机物共混造粒，即可。
2.根据权利要求1所述的聚碳酸酯专用型钛白粉的制备方法，其特征在于：步骤(1)中，所述四氯化硅以氧化硅计占四氯化钛、四氯化硅、三氯化铝的2.0～4.0wt％。
3.根据权利要求1或2所述的聚碳酸酯专用型钛白粉的制备方法，其特征在于：步骤(1)中，三氯化铝以氧化铝计占反应物四氯化钛、四氯化硅、三氯化铝的1.5～4.0wt％。
4.根据权利要求1～3任一项所述的聚碳酸酯专用型钛白粉的制备方法，其特征在于：步骤(2)中，有机物的化学成分包括：相同质量比的聚硅氧烷和木质素磺酸钠。
5.根据权利要求1～4任一项所述的聚碳酸酯专用型钛白粉的制备方法，其特征在于：步骤(2)中，有机物的化学成分包括：相同质量比的聚硅氧烷和聚丙烯酸钠。
6.根据权利要求1～5任一项所述的聚碳酸酯专用型钛白粉的制备方法，其特征在于：步骤(2)中，所述有机物为氯化初品总质量的0.5～2.0％。
7.权利要求1～6任一项所述的聚碳酸酯专用型钛白粉。
8.根据权利要求7所述的聚碳酸酯专用型钛白粉，其特征在于：其化学成分以质量百分比计包括：二氧化钛含量≥92％，氧化硅含量≥2.0％，氧化铝含量≥1.5％。
9.根据权利要求7或8所述的聚碳酸酯专用型钛白粉，其特征在于：其化学成分还包括包覆在外层的有机物。
10.根据权利要求7～9任一项所述的聚碳酸酯专用型钛白粉，其特征在于：平均粒径200±20nm，堆积密度≥0.8g/cm3。
CN202111390699.3A 2021-11-23 2021-11-23 聚碳酸酯专用型钛白粉及其制备方法 Pending CN114231054A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202111390699.3A CN114231054A (zh) 2021-11-23 2021-11-23 聚碳酸酯专用型钛白粉及其制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202111390699.3A CN114231054A (zh) 2021-11-23 2021-11-23 聚碳酸酯专用型钛白粉及其制备方法

Publications (1)

Publication Number Publication Date
CN114231054A true CN114231054A (zh) 2022-03-25

Family

ID=80750470

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202111390699.3A Pending CN114231054A (zh) 2021-11-23 2021-11-23 聚碳酸酯专用型钛白粉及其制备方法

Country Status (1)

Country Link
CN (1) CN114231054A (zh)

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3532462A (en) * 1963-04-27 1970-10-06 Bayer Ag Method of effecting gas-phase reactions
US20070207176A1 (en) * 2006-03-03 2007-09-06 Shin-Etsu Chemical Co., Ltd. Powder treated with a power treating agent comprising an organopolysiloxane and cosmetic comprising the powder
US20080187486A1 (en) * 2006-11-02 2008-08-07 Alan Roger Eaton Process for producing titanium dioxide particles having reduced chlorides
US20080202385A1 (en) * 2000-04-27 2008-08-28 Narayanan Sankara Subramanian Process for making durable titanium dioxide pigment in the chloride process without wet treatment
CN102612494A (zh) * 2010-02-22 2012-07-25 纳幕尔杜邦公司 在二氧化钛的制备中原位形成硅、铝和钛的氯化物的方法
CN103013184A (zh) * 2012-12-29 2013-04-03 锦州钛业有限公司 一种塑料色母粒专用型二氧化钛颜料的制备方法
CN111410854A (zh) * 2020-05-11 2020-07-14 华东理工大学 一种涤纶抗紫外纳米二氧化钛的分散方法

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3532462A (en) * 1963-04-27 1970-10-06 Bayer Ag Method of effecting gas-phase reactions
US20080202385A1 (en) * 2000-04-27 2008-08-28 Narayanan Sankara Subramanian Process for making durable titanium dioxide pigment in the chloride process without wet treatment
US20070207176A1 (en) * 2006-03-03 2007-09-06 Shin-Etsu Chemical Co., Ltd. Powder treated with a power treating agent comprising an organopolysiloxane and cosmetic comprising the powder
US20080187486A1 (en) * 2006-11-02 2008-08-07 Alan Roger Eaton Process for producing titanium dioxide particles having reduced chlorides
CN102612494A (zh) * 2010-02-22 2012-07-25 纳幕尔杜邦公司 在二氧化钛的制备中原位形成硅、铝和钛的氯化物的方法
US20120219494A1 (en) * 2010-02-22 2012-08-30 Charles David Musick Process for in-situ formation of chlorides of silicon, aluminum and titanium in the preparation of tiatanium dioxide
CN103013184A (zh) * 2012-12-29 2013-04-03 锦州钛业有限公司 一种塑料色母粒专用型二氧化钛颜料的制备方法
CN111410854A (zh) * 2020-05-11 2020-07-14 华东理工大学 一种涤纶抗紫外纳米二氧化钛的分散方法

Similar Documents

Publication Publication Date Title
CN101835824B (zh) 高耐热性母料、热线遮蔽透明树脂成形体、以及热线遮蔽透明层压体
JP4655105B2 (ja) 紫外線遮蔽透明樹脂成形体およびその製造方法
CN101362868B (zh) 提高粉末涂料耐候性能的纳米复合改性剂及其制备方法
JP6588588B2 (ja) 樹脂強化用充填材及び樹脂組成物
CA2095738A1 (en) Coated inorganic particles
JP2006077075A (ja) 樹脂組成物と紫外線遮蔽用透明樹脂成形体および紫外線遮蔽用透明樹脂積層体
WO2022246778A1 (zh) 一种纳米改性聚乙烯抗老化专用料的制备方法
EP0870731A1 (en) Titanium dioxide reduced in volatile water content, process for producing the same, and masterbatch containing the same
CN103112890A (zh) 钛白粉生产过程中的酸解工艺
JP2009161707A (ja) 複合樹脂組成物およびそれを用いてなる成形体
CN107043516A (zh) 具有改善耐候性的深色耐热abs树脂组合物
CN102504565A (zh) 高散热性并具有吸热性高分子材料及其制备方法
CN108690336A (zh) 一种可生物降解的聚乳酸农用地膜及其加工工艺
CN114231054A (zh) 聚碳酸酯专用型钛白粉及其制备方法
ES2379864T3 (es) Pigmentos tratados con compuestos organosulfónicos
CN1239611C (zh) 阻燃性聚酯树脂组合物、其成型品及其成型方法
CN108822396A (zh) 一种再生塑料电脑桌材料及其制备方法
CN100564434C (zh) 有机膦化合物处理的无机固体颗粒
CN105153574A (zh) 一种硅藻土改性的pvc塑料的制备方法
CN111363318A (zh) 一种阻燃抑烟ptt聚酯复合材料及其制备方法
CN106380583A (zh) 一种反应型抗老化共聚酯的合成方法
CN109679184A (zh) 一种耐腐蚀的改性塑料及其制备方法
CN115260728A (zh) 改性聚碳酸酯及其制备方法
JP2017007889A (ja) 複合タングステン酸化物微粒子、赤外線遮蔽樹脂組成物及び赤外線遮蔽成形体
JP2006126468A (ja) 近赤外線遮蔽剤及びそれを含む樹脂組成物

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20220325