CN113969127A - 电缆密封环氧树脂及其制备方法 - Google Patents
电缆密封环氧树脂及其制备方法 Download PDFInfo
- Publication number
- CN113969127A CN113969127A CN202111368119.0A CN202111368119A CN113969127A CN 113969127 A CN113969127 A CN 113969127A CN 202111368119 A CN202111368119 A CN 202111368119A CN 113969127 A CN113969127 A CN 113969127A
- Authority
- CN
- China
- Prior art keywords
- epoxy resin
- parts
- bisphenol
- resin
- cable sealing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003822 epoxy resin Substances 0.000 title claims abstract description 85
- 229920000647 polyepoxide Polymers 0.000 title claims abstract description 85
- 238000007789 sealing Methods 0.000 title claims abstract description 29
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- 229920013822 aminosilicone Polymers 0.000 claims abstract description 24
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 24
- 229920005989 resin Polymers 0.000 claims abstract description 24
- 239000011347 resin Substances 0.000 claims abstract description 24
- 229920002050 silicone resin Polymers 0.000 claims abstract description 23
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims abstract description 19
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims abstract description 15
- 239000007822 coupling agent Substances 0.000 claims abstract description 13
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 claims description 38
- 238000000227 grinding Methods 0.000 claims description 25
- KIKYOFDZBWIHTF-UHFFFAOYSA-N bis(oxiran-2-ylmethyl) cyclohex-3-ene-1,2-dicarboxylate Chemical compound C1CC=CC(C(=O)OCC2OC2)C1C(=O)OCC1CO1 KIKYOFDZBWIHTF-UHFFFAOYSA-N 0.000 claims description 11
- 229910052739 hydrogen Inorganic materials 0.000 claims description 10
- 239000001257 hydrogen Substances 0.000 claims description 10
- -1 phenyl hydrogen Chemical class 0.000 claims description 10
- 125000003368 amide group Chemical group 0.000 claims description 8
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 8
- 238000001816 cooling Methods 0.000 claims description 8
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 7
- 239000004841 bisphenol A epoxy resin Substances 0.000 claims description 4
- 239000004842 bisphenol F epoxy resin Substances 0.000 claims description 4
- 239000002994 raw material Substances 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 3
- 239000004593 Epoxy Substances 0.000 claims 2
- 229920001296 polysiloxane Polymers 0.000 claims 2
- 239000000945 filler Substances 0.000 abstract description 4
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 22
- KTPIWUHKYIJBCR-UHFFFAOYSA-N bis(oxiran-2-ylmethyl) cyclohex-4-ene-1,2-dicarboxylate Chemical compound C1C=CCC(C(=O)OCC2OC2)C1C(=O)OCC1CO1 KTPIWUHKYIJBCR-UHFFFAOYSA-N 0.000 description 14
- 230000000052 comparative effect Effects 0.000 description 13
- 239000003921 oil Substances 0.000 description 8
- 239000000126 substance Substances 0.000 description 7
- 239000006087 Silane Coupling Agent Substances 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 230000001276 controlling effect Effects 0.000 description 5
- YNDRMAAWTXUJPV-UHFFFAOYSA-N n-cyclohexyl-2-methylidenecyclohexan-1-amine Chemical compound C=C1CCCCC1NC1CCCCC1 YNDRMAAWTXUJPV-UHFFFAOYSA-N 0.000 description 4
- 239000000565 sealant Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 230000004927 fusion Effects 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000004321 preservation Methods 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 230000003746 surface roughness Effects 0.000 description 2
- ZYUVGYBAPZYKSA-UHFFFAOYSA-N 5-(3-hydroxybutan-2-yl)-4-methylbenzene-1,3-diol Chemical compound CC(O)C(C)C1=CC(O)=CC(O)=C1C ZYUVGYBAPZYKSA-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000001412 amines Chemical group 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- NHADDZMCASKINP-HTRCEHHLSA-N decarboxydihydrocitrinin Natural products C1=C(O)C(C)=C2[C@H](C)[C@@H](C)OCC2=C1O NHADDZMCASKINP-HTRCEHHLSA-N 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000003566 sealing material Substances 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- UKRDPEFKFJNXQM-UHFFFAOYSA-N vinylsilane Chemical compound [SiH3]C=C UKRDPEFKFJNXQM-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J163/00—Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Epoxy Resins (AREA)
- Sealing Material Composition (AREA)
Abstract
Description
实施例1 | 实施例2 | 实施例3 | 实施例4 | 实施例5 | 对比例1 | 对比例2 | 对比例3 | 对比例4 | |
固化时间(h) | 4.2 | 5.1 | 5.0 | 5.2 | 5.1 | 10.3 | 8.2 | 9.1 | 12 |
-180℃剪切强度(MPa) | 28.4 | 26.2 | 26.5 | 26.6 | 25.3 | 22.1 | 24.3 | 21.3 | 21.7 |
140℃剪切强度(MPa) | 4.8 | 4.1 | 4.4 | 4.5 | 4.2 | 3.1 | 3.4 | 2.8 | 2.8 |
剥离强度(N/25mm) | 301 | 198 | 245 | 261 | 252 | 160 | 187 | 121 | 145 |
表面粗糙度Ra(μm) | 2.6 | 2.7 | 2.7 | 2.9 | 2.8 | 3.3 | 3.1 | 6.1 | 3.4 |
Claims (8)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202111368119.0A CN113969127A (zh) | 2021-11-18 | 2021-11-18 | 电缆密封环氧树脂及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202111368119.0A CN113969127A (zh) | 2021-11-18 | 2021-11-18 | 电缆密封环氧树脂及其制备方法 |
Publications (1)
Publication Number | Publication Date |
---|---|
CN113969127A true CN113969127A (zh) | 2022-01-25 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202111368119.0A Pending CN113969127A (zh) | 2021-11-18 | 2021-11-18 | 电缆密封环氧树脂及其制备方法 |
Country Status (1)
Country | Link |
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CN (1) | CN113969127A (zh) |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2012117017A (ja) * | 2010-12-03 | 2012-06-21 | Kyocera Chemical Corp | 射出成形用エポキシ樹脂組成物、およびコイル部品 |
CN104531027A (zh) * | 2015-01-21 | 2015-04-22 | 广州聚合电子材料有限公司 | 环氧树脂类灌封材料及其制备方法和应用 |
-
2021
- 2021-11-18 CN CN202111368119.0A patent/CN113969127A/zh active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2012117017A (ja) * | 2010-12-03 | 2012-06-21 | Kyocera Chemical Corp | 射出成形用エポキシ樹脂組成物、およびコイル部品 |
CN104531027A (zh) * | 2015-01-21 | 2015-04-22 | 广州聚合电子材料有限公司 | 环氧树脂类灌封材料及其制备方法和应用 |
Non-Patent Citations (1)
Title |
---|
上海辞书出版社 * |
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TA01 | Transfer of patent application right |
Effective date of registration: 20230823 Address after: No. 9, Yijing Road, Yaotang Town, Jintan District, Changzhou City, Jiangsu Province, 213200 Applicant after: AgNOR (Jiangsu) Intelligent Electric Co.,Ltd. Address before: 213000 Room 601, unit D, building 1, Lanling apartment, Tianning District, Changzhou City, Jiangsu Province Applicant before: Huang Chengye Applicant before: Changzhou Mingyuan enterprise management partnership (L.P.) Applicant before: Changzhou Jiamao enterprise management partnership (L.P.) |
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RJ01 | Rejection of invention patent application after publication |
Application publication date: 20220125 |
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