CN113883405A - 覆盖有二维材料的氢罐和氢管道、以及用于输送氢的装置 - Google Patents

覆盖有二维材料的氢罐和氢管道、以及用于输送氢的装置 Download PDF

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CN113883405A
CN113883405A CN202110708891.6A CN202110708891A CN113883405A CN 113883405 A CN113883405 A CN 113883405A CN 202110708891 A CN202110708891 A CN 202110708891A CN 113883405 A CN113883405 A CN 113883405A
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hydrogen
dimensional material
tank
polydopamine
type polymer
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R·福斯特
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Airbus SAS
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Abstract

一种用于输送氢的装置(1),所述装置包括氢罐(10)和用于输送氢的至少一个管道(20a,20b)。氢罐的或氢输送管道的至少一个表面被混合有聚多巴胺型聚合物的二维材料(30a,30b)所覆盖。本发明还涉及一种氢罐(10),并且涉及一种氢输送管道(20a,20b),所述氢罐的和所述氢输送管道的一个表面被混合有聚多巴胺型聚合物的二维材料(30a,30b)所覆盖。

Description

覆盖有二维材料的氢罐和氢管道、以及用于输送氢的装置
本发明涉及在氢罐与氢消耗器(例如发动机或燃料电池)之间输送氢的领域。氢通常以其二氢(H2)的形式、以液态或气态储存在罐中。类似地,可以藉由一个或多个氢输送管道将处于液态或气态的氢从罐输送至消耗器。罐和输送管道通常是金属类型的。已知的是,由于氢分子(H2)的尺寸较小,这些分子有穿过罐或输送管道的壁、特别是在焊接点处泄漏的趋势。已知使用屏障层来涂覆罐或氢输送管道以减少泄漏。然而,所述屏障层的有效性不是最佳。因此,为了避免爆炸的风险,必须提供一种用于排放泄漏的氢的通风系统,或者一种用于通过与氮混合来中和氢的系统。然而,这种通风或中和系统具有增加氢输送装置重量的缺点,特别是当所述氢输送装置安装在飞行器上时,这是期望避免的。
另外,氢穿过罐或输送管道的壁的泄漏可能引起氢脆现象,这种现象可能导致罐或输送管道的劣化。
发明内容
本发明的一个目的尤其在于提供对这些问题的解决方案。本发明涉及一种用于将氢输送至至少一个氢消耗器的装置,所述装置包括氢罐和用于输送氢的至少一个管道,其特征在于,氢罐的或所述至少一个氢输送管道的至少一个表面被混合有聚多巴胺型聚合物的二维材料覆盖。
二维材料形成防止比如氢气的气体通过的屏障。由此,由二维材料覆盖的表面具有防止氢穿过泄漏的优点,这使得可以防止氢穿过氢罐的或氢输送管道的壁而泄漏。另外,聚多巴胺型聚合物具有的优点在于施加有该聚多巴胺型聚合物的表面具有高粘附性能。因此,将二维材料与这种聚合物混合的事实使得可以提高二维材料到由此二维材料覆盖的罐或管道的表面的粘附性能。
根据可以单独或组合地使用的多种不同实施例:
-所述至少一个表面对应于所述氢罐或所述至少一个氢输送管道的内表面;
-所述至少一个表面对应于所述氢罐或所述至少一个氢输送管道的外表面;
-所述二维材料选自以下二维材料:
.石墨烯;
.氧化石墨烯;
.HBN(六方氮化硼);
-所述二维材料与聚多巴胺型聚合物混合;
-所述二维材料以0.5%与2%之间的重量比例与呈小片形式的聚多巴胺型聚合物混合;
-所述二维材料和所述聚多巴胺型聚合物的混合物在所述氢罐的或所述至少一个氢输送管道的所述表面上形成厚度小于500微米的层。
本发明还涉及一种氢罐,该氢罐包括被二维材料覆盖的至少一个表面。
本发明还涉及一种氢输送管道,该氢输送管道包括被二维材料覆盖的至少一个表面。
具体实施方式
通过阅读以下描述并检查附图将更好地理解本发明。
图1A示意性地展示了根据本发明的一个实施例的氢输送装置。
图1B是图1A的区域Z的细节视图。
图1A所表示的氢输送装置1包括氢罐10和一组氢输送管道20a、20b。氢罐10包括壳体12,该壳体的多个部分藉由焊接点16a联结在一起。根据第一替代方案,壳体12是金属的。根据第二替代方案,壳体12由复合材料制成。氢输送管道20a包括藉由焊接点16b焊接至氢罐10的管部22。管部22例如由与用于氢罐的壳体12的材料相同的材料制成。氢输送管道20b还包括藉由焊接点16c焊接至氢输送管道20a的管部22的管部。氢罐10的外侧由隔热体14层覆盖。类似地,氢输送管道20a的外侧由隔热体24层覆盖。
氢罐的壳体12包括罐内侧的第一面F1和罐外侧的第二面F2。第一面F1和第二面F2中的至少一者的表面覆盖有二维材料。在图1B所展示的示例中,第一面F1的表面覆盖有二维材料30a,并且第二面F2的表面覆盖有二维材料30b。二维材料30a和/或30b还覆盖焊接点16a。
优选地,氢管道的管部、比如氢管道20a的管部22也包括覆盖有二维材料的至少一个表面。就像罐10一样,氢管道的管部的这个表面可以是管部的内表面或管部的外表面。二维材料还覆盖焊接点16b和16c。
二维材料30a、30b形成防止氢穿过的屏障。由此,由二维材料覆盖的表面具有防止氢穿过泄漏的优点,这使得可以防止氢穿过氢罐的壳体12或穿过氢输送管道的管部22而泄漏。
二维材料例如选自以下二维材料:
-石墨烯;
-氧化石墨烯;
-HBN(六方氮化硼)。
然而,二维材料的这些示例不会限制本发明。可以采用其他二维材料,只要这些二维材料不可渗透氢。
石墨烯和HBN具有不可渗透氢以及水和水蒸气的优点。氧化石墨烯不可渗透氢,但是可渗透水蒸气。因此,考虑到氢罐或管道中容纳的氢通常不是绝对纯净的,而是可能混合有水蒸气,因此无论该氢以何种形式(液态或气态)储存在罐10中或在输送管道20a、20b中循环,都可以使用石墨烯和HBN。当氢以液态形式储存在罐10中或在输送管道20a、20b中循环时,由于氢处于液态时的温度使水无法处于蒸气态或液态、仅可处于固态,因此氧化石墨烯也可以作为二维材料。
有利地,二维材料混合有聚多巴胺型聚合物(也被称为PDA)。这种聚合物具有的优点在于施加有该聚合物的表面具有高粘附性能。因此,将二维材料与这种聚合物混合的事实使得可以提高二维材料到由此二维材料覆盖的罐或管道的表面的粘附性能。
二维材料例如与呈小片形式的聚多巴胺型聚合物混合。在一个特定实施例中,在混合物中二维材料(例如HBN)的重量比例在0.5%与2%之间。
在另外的特定实施例中,二维材料和聚多巴胺型聚合物的混合物在其所施加至的氢罐或氢输送管道的表面形成厚度小于500微米的层。
二维材料(例如HBN)和聚多巴胺型聚合物的混合物可以以多种不同方式(例如:喷涂、刷涂、浸泡、喷墨印刷等)施加至罐或管道的表面。由此,此混合物易于施加至此表面,包括施加至焊接点16a、16b、16c。因此,本发明使得可以保护整个罐和/或氢输送管道,包括通常最易发生氢泄漏的焊接点区域。
当二维材料(例如HBN)和聚多巴胺型聚合物的混合物施加至氢罐(或氢输送管道)的外部面F2的表面时,聚多巴胺型聚合物的粘附性能使得可以有助于将隔热体14或24粘附到此表面上。

Claims (8)

1.一种用于将氢输送至至少一个氢消耗器的装置(1),所述装置包括氢罐(10)和用于输送氢的至少一个管道(20a,20b),所述氢罐的或所述至少一个氢输送管道的至少一个表面覆盖有二维材料(30a,30b),其特征在于,所述二维材料混合有聚多巴胺型聚合物。
2.根据权利要求1所述的装置,其特征在于,所述至少一个表面对应于所述氢罐的或所述至少一个氢输送管道的内表面(F1)。
3.根据权利要求1和2中任一项所述的装置,其特征在于,所述至少一个表面对应于所述氢罐的或所述至少一个氢输送管道的外表面(F2)。
4.根据前述权利要求中任一项所述的装置,其特征在于,所述二维材料选自以下二维材料:
-石墨烯;
-氧化石墨烯;
-HBN(六方氮化硼)。
5.根据前述权利要求中任一项所述的装置,其特征在于,所述二维材料以0.5%与2%之间的重量比例与呈小片形式的聚多巴胺型聚合物混合。
6.根据前述权利要求中任一项所述的装置,其特征在于,所述二维材料和所述聚多巴胺型聚合物的混合物在所述氢罐的或所述至少一个氢输送管道的所述表面上形成厚度小于500微米的层。
7.一种氢罐(10),其特征在于,所述氢罐包括被混合有聚多巴胺型聚合物的二维材料覆盖的至少一个表面(F1,F2)。
8.一种氢输送管道(20a,20b),其特征在于,所述氢输送管道包括被混合有聚多巴胺型聚合物的二维材料(30a,30b)覆盖的至少一个表面。
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