CN1138451A - 新颖的头发定型剂 - Google Patents
新颖的头发定型剂 Download PDFInfo
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- CN1138451A CN1138451A CN96105533A CN96105533A CN1138451A CN 1138451 A CN1138451 A CN 1138451A CN 96105533 A CN96105533 A CN 96105533A CN 96105533 A CN96105533 A CN 96105533A CN 1138451 A CN1138451 A CN 1138451A
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- 229920000642 polymer Polymers 0.000 claims abstract description 40
- 229920001577 copolymer Polymers 0.000 claims abstract description 35
- 229920001519 homopolymer Polymers 0.000 claims abstract description 20
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- 229920002635 polyurethane Polymers 0.000 claims abstract description 6
- 239000004814 polyurethane Substances 0.000 claims abstract description 6
- 239000008266 hair spray Substances 0.000 claims description 22
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 13
- -1 alkyl hydro carbons Chemical class 0.000 claims description 9
- 229930195733 hydrocarbon Natural products 0.000 claims description 2
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 claims 2
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- 239000000178 monomer Substances 0.000 abstract description 14
- 239000003795 chemical substances by application Substances 0.000 abstract description 8
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- JWYVGKFDLWWQJX-UHFFFAOYSA-N 1-ethenylazepan-2-one Chemical compound C=CN1CCCCCC1=O JWYVGKFDLWWQJX-UHFFFAOYSA-N 0.000 abstract 3
- 125000000129 anionic group Chemical group 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 22
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- 239000000203 mixture Substances 0.000 description 8
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- 239000002270 dispersing agent Substances 0.000 description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 6
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- 239000012153 distilled water Substances 0.000 description 6
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- 239000000843 powder Substances 0.000 description 6
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- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 5
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 229960000935 dehydrated alcohol Drugs 0.000 description 4
- UPBDXRPQPOWRKR-UHFFFAOYSA-N furan-2,5-dione;methoxyethene Chemical compound COC=C.O=C1OC(=O)C=C1 UPBDXRPQPOWRKR-UHFFFAOYSA-N 0.000 description 4
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 4
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- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 3
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- 239000000463 material Substances 0.000 description 3
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- 238000002360 preparation method Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000001294 propane Substances 0.000 description 3
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 3
- 229920001567 vinyl ester resin Polymers 0.000 description 3
- ZKYCLDTVJCJYIB-UHFFFAOYSA-N 2-methylidenedecanamide Chemical compound CCCCCCCCC(=C)C(N)=O ZKYCLDTVJCJYIB-UHFFFAOYSA-N 0.000 description 2
- 229920005789 ACRONAL® acrylic binder Polymers 0.000 description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 2
- GQPLMRYTRLFLPF-UHFFFAOYSA-N Nitrous Oxide Chemical compound [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 2
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- 239000000654 additive Substances 0.000 description 2
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- 229910021529 ammonia Inorganic materials 0.000 description 2
- 239000012736 aqueous medium Substances 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- 150000001991 dicarboxylic acids Chemical class 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 2
- FKRCODPIKNYEAC-UHFFFAOYSA-N ethyl propionate Chemical compound CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- LDHQCZJRKDOVOX-IHWYPQMZSA-N isocrotonic acid Chemical compound C\C=C/C(O)=O LDHQCZJRKDOVOX-IHWYPQMZSA-N 0.000 description 2
- 239000011976 maleic acid Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- XFHJDMUEHUHAJW-UHFFFAOYSA-N n-tert-butylprop-2-enamide Chemical compound CC(C)(C)NC(=O)C=C XFHJDMUEHUHAJW-UHFFFAOYSA-N 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 229920001897 terpolymer Polymers 0.000 description 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- CRQWZKDIVBSAJD-UHFFFAOYSA-N 1-dodecoxydodecane;sodium Chemical compound [Na].CCCCCCCCCCCCOCCCCCCCCCCCC CRQWZKDIVBSAJD-UHFFFAOYSA-N 0.000 description 1
- OSSNTDFYBPYIEC-UHFFFAOYSA-N 1-ethenylimidazole Chemical compound C=CN1C=CN=C1 OSSNTDFYBPYIEC-UHFFFAOYSA-N 0.000 description 1
- PBGPBHYPCGDFEZ-UHFFFAOYSA-N 1-ethenylpiperidin-2-one Chemical class C=CN1CCCCC1=O PBGPBHYPCGDFEZ-UHFFFAOYSA-N 0.000 description 1
- 229940058020 2-amino-2-methyl-1-propanol Drugs 0.000 description 1
- RUMACXVDVNRZJZ-UHFFFAOYSA-N 2-methylpropyl 2-methylprop-2-enoate Chemical compound CC(C)COC(=O)C(C)=C RUMACXVDVNRZJZ-UHFFFAOYSA-N 0.000 description 1
- KFNGWPXYNSJXOP-UHFFFAOYSA-N 3-(2-methylprop-2-enoyloxy)propane-1-sulfonic acid Chemical compound CC(=C)C(=O)OCCCS(O)(=O)=O KFNGWPXYNSJXOP-UHFFFAOYSA-N 0.000 description 1
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical compound NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 1
- 102000008186 Collagen Human genes 0.000 description 1
- 108010035532 Collagen Proteins 0.000 description 1
- SNPLKNRPJHDVJA-ZETCQYMHSA-N D-panthenol Chemical compound OCC(C)(C)[C@@H](O)C(=O)NCCCO SNPLKNRPJHDVJA-ZETCQYMHSA-N 0.000 description 1
- XLYMOEINVGRTEX-ARJAWSKDSA-N Ethyl hydrogen fumarate Chemical compound CCOC(=O)\C=C/C(O)=O XLYMOEINVGRTEX-ARJAWSKDSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
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- 108010009736 Protein Hydrolysates Proteins 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000004378 air conditioning Methods 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- UTOVMEACOLCUCK-PLNGDYQASA-N butyl maleate Chemical compound CCCCOC(=O)\C=C/C(O)=O UTOVMEACOLCUCK-PLNGDYQASA-N 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
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- 239000003086 colorant Substances 0.000 description 1
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- FYUWIEKAVLOHSE-UHFFFAOYSA-N ethenyl acetate;1-ethenylpyrrolidin-2-one Chemical compound CC(=O)OC=C.C=CN1CCCC1=O FYUWIEKAVLOHSE-UHFFFAOYSA-N 0.000 description 1
- XLYMOEINVGRTEX-UHFFFAOYSA-N fumaric acid monoethyl ester Natural products CCOC(=O)C=CC(O)=O XLYMOEINVGRTEX-UHFFFAOYSA-N 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 210000004276 hyalin Anatomy 0.000 description 1
- 239000006115 industrial coating Substances 0.000 description 1
- 230000005865 ionizing radiation Effects 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 150000003951 lactams Chemical class 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- AWGZKFQMWZYCHF-UHFFFAOYSA-N n-octylprop-2-enamide Chemical compound CCCCCCCCNC(=O)C=C AWGZKFQMWZYCHF-UHFFFAOYSA-N 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000001272 nitrous oxide Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- KCXFHTAICRTXLI-UHFFFAOYSA-N propane-1-sulfonic acid Chemical compound CCCS(O)(=O)=O KCXFHTAICRTXLI-UHFFFAOYSA-N 0.000 description 1
- 239000003531 protein hydrolysate Substances 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical group CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8147—Homopolymers or copolymers of acids; Metal or ammonium salts thereof, e.g. crotonic acid, (meth)acrylic acid; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8158—Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
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- A—HUMAN NECESSITIES
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- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8164—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least one other carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers, e.g. poly (methyl vinyl ether-co-maleic anhydride)
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- A—HUMAN NECESSITIES
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- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
- A61K8/8182—Copolymers of vinyl-pyrrolidones. Compositions of derivatives of such polymers
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- A—HUMAN NECESSITIES
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- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/87—Polyurethanes
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/88—Polyamides
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
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- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
一种头发定型剂，包括：
A)0.5-20％重量的N-乙烯基己内酰胺均聚物或至少70％重量的N-乙烯基己内酰胺的阴离子或非离子共聚物(聚合物A)，和
B)0.5-20％重量的后成膜聚合物(聚合物B)，是从下组中选出：聚酰胺类、聚氨酯类和单烯基类不饱和的单体的均聚合物和共聚合物。
Description
本发明涉及新颖的头发定型剂，它含有聚合物混合物作为成膜剂。
含有一种聚酯和一种水容性聚合物的喷发胶组合物，例如一种N-乙烯基己内酰胺和N-乙烯基吡咯烷酮的共聚物，在WO-93/17658中公开过。
不过，这类喷发胶对水解作用敏感因而只能以受限制的方式使用和处理。
本发明的目的是开发头发定型剂，它有良好的定型性和水可洗去性以及低的粘性，没有上述的水解敏感性。
我们发现本发明的这个目的使用有下述组分的头发定型剂达到了：A)0.5-20％重量的至少有70％重量的N-乙烯基己内酰胺的均-或共聚物(聚合物A)，和B)0.5-20％重量的后成膜聚合物(聚合物B)，从下组中选出：聚酰胺类、聚氨酯类，和单烯类不饱和的单体的均-和共聚物。
适用的聚合物A为N-乙烯基己内酰胺的均聚物，本领域的技术人员都知道它可以用例如US-3145147中描述的方法制备。
更适用的聚合物A为N-乙烯基己内酰胺的共聚物和可再聚合的单体，该共聚物含有至少70％重量，优选85％重量的N-乙烯基己内酰胺。
聚合物A的适用的可再聚合的单体有：
具有酸功能的单体，诸如丙烯酸、甲基丙烯酸、丙烯酰氨基甲丙基磺酸(AMPS)、(甲基)丙烯酸3-磺丙基酯，如果要求的话，也可以采用全或部分中和的形式；
(甲基)丙烯酸C1-C18烷基酯类，诸如丙烯酸叔丁酯、丙烯酸乙酯、甲基丙烯酸异丁酯、甲基丙烯酸正丁酯、甲基丙烯酸甲酯、甲基丙烯酸乙酯和(甲基)丙烯酸羟烷基酯类；
C2-C10脂肪酸的乙烯酯类，诸如乙酸乙烯酯，丙酸乙酯和较长链和/或支链脂肪酸的乙烯酯，例如有支链的烷烃羧酸。
C3-C8 N-烷基(甲基)丙烯酰胺类，诸如甲基丙烯酰胺、N，N-二甲基丙烯酰胺、N-叔-丁基丙烯酰胺和N-叔-辛基丙烯酰胺；
N-乙烯基吡咯烷酮和N-乙烯基哌啶酮。
其他单体可以以单独的化合物或以混合物的形式用于共聚物A。
这类聚合物是已知的，或能够用传统的聚合方法制备。
例如，EP-455081描述了N-乙烯基吡咯烷酮、N-乙烯基己内酰胺和N-乙烯基咪唑共聚物。EP-74191公开了N-乙酰基吡咯烷酮、N-乙烯基己内酰胺和甲丙烯酸二甲基氨基乙酯的共聚物。
N-乙烯基己内酰胺的均聚物优选用于依据本发明的头发定型剂。
依据本发明的头发定型剂含有聚合物A量为0.5-20，优选为1-10％重量，以制成的定型剂的重量为基计。
作为聚合物B)，可以使用在美发品中已经使用的多种多样的聚合物。
适用的聚合物B)，依据本发明，除了A)之外的其他成膜聚合物，从下组中选出：聚酰胺类、聚氨酯类和单烯类不饱和单体的均-和共聚物。依据本发明，成膜剂聚合物可以是传统的头发定型聚合物，但也可以是工业用涂覆剂和粘结剂的成膜剂。
特别适用的单烯类不饱和单体的均-和共聚物有丙烯酸和甲基丙烯酸的C1-C12-烷基酯类，单烯类不饱和的C3-C5-一元羰酸和它们的乙烯酯类，马来酸和它的半酯类，甲基乙烯基醚，丙烯酰胺类，甲基丙烯酰胺类，N-烷基取代的(甲基)丙烯酰胺类，N-乙烯基吡咯烷酮，N-乙烯基咪唑和苯乙烯。
特别优选的聚合物B)是丙烯酸酯聚合物，例如丙烯酸/丙烯酸乙酯/N-叔丁基-丙烯酰胺的共聚物，甲基丙烯酸/丙烯酸叔丁酯/N-乙烯基吡咯烷酮的共聚物，以丙烯酸和乙酸乙烯酯为基础的共聚物，辛基丙烯酰胺/丙烯酸酯/甲基丙烯酸丁氨乙酯的共聚物，辛基丙烯酰胺/丙烯酸酯的共聚物，甲基丙烯酸乙酯/甲基丙烯酸/N-乙烯基吡咯烷酮的共聚物或丙烯酸酯与丙烯酸羟烷基酯的共聚物。这些共聚物市场有售，例如，按以下的商品名标出售：Amerhold，Ultrahold8，Ultrahold Strong，LuviflexVBM，Luvimer100P，Luvimer36D，Luvimer MAE30D，Acronal500D，Acudyne255，Stepanhold，LovocrylVersatyl和Amphomer。
优选的聚合物B是含磺酸酯的聚酰胺类，包括：-从20至99％摩尔的含有2至12个碳原子的一氨基羧酸或其内酰胺，-从0.5至40％摩尔的含有2至18个碳原子的二胺，-从0.5至25％摩尔的含有4至12个碳原子的含磺酸酯的二羧酸，和-从0至35％摩尔的含有2至16个碳原子的另一种二羧酸。优选的聚合物B)还有含磺酸酯的丙烯酸酯，包括：-从50至90％重量的一种或多种单体，从下组中选出：丙烯酸的或甲基丙烯酸的C1-C18烷基酯类，以及饱和的C2-C10-一元羧酸的乙烯基酯，-从10至25％重量含有磺酸的乙烯基单体，和-从0至40％重量的另一种单体，从下组中选出：丙烯酸、甲基丙烯酸、
丙烯酰胺、甲基丙烯酰胺、C3-C8-N-烷基丙烯酰胺和N，N-二甲基丙烯酰胺。
同样优选的聚合物B)还有依据DE-A4327514的微分散方式得到的共聚物，它们是下组中的物质通过自由基引发的共聚合反应或通过使用电离辐射引发的共聚合反应获得：-从40至99％重量的一种或多种非水溶的单乙烯基不饱和的单体，-从1至60％重量的一种或多种水溶的单乙烯基不饱和的单体和-从0至30％重量的一种或多种多在水介质中的乙烯基不饱和的单体，在从2至20％重量(以单体的总重量计)作为乳化剂的表面活性剂化合物存在的条件下，在水介质中以光学扫描测定，平均粒径为5至37nm。
适用的聚合物B)还有N-乙烯基吡咯烷酮的均-和共聚物，例如在市场上可买到的，诸如BASF公司以Luviskol命名的。这类聚合物通过N-乙烯基吡咯烷酮与乙酸乙烯酯和/或丙酸乙烯酯以各种比例聚合而获得，这类聚合物的例子有：
LuviskolK17，LuviskolK30，LuviskolK60，LuviskolK80，LuviskolK 90(适当的K值的聚乙烯基吡咯烷酮表示为一种粉剂或溶液(水的或水/乙醇的))。
LuviskolVA＝乙烯基吡咯烷酮/乙酸乙烯酯共聚物，具体的为：LuviskolVA73，LuviskolVA 64，LuviskolVA55，LuviskolVA 37和LuviskolVA 28。
其他适用的聚合物B)为乙烯基吡咯烷酮、乙酸乙烯酯和丙酸乙烯酯的三元聚合物，例如LuviskolVAP 343。
同样适用的还有乙酸乙烯酯与巴豆酸的共聚物；例如产品LuvisetCA，LuvisetCAP和National28-2930。
季铵化的聚季铵-4、聚季铵-6、聚季铵-7、聚季铵-10、聚季铵-11或聚季铵-16也可以使用。
其他适用的聚合物B)有甲基乙烯基醚(MVE)和马来酸酯的共聚物，例如MVE/马来酸一乙基酯、MVE/马来酸一异丙基酯或MVE/马来酸一丁基酯的共聚物，例如产品Gantrez ES-225，GantrezES-335，Gantrez ES-425，GantrezES-435和GantrezSP-215。
聚氨酯类，例如在WO 94/03510中所描述的，也可以用作聚合物B。聚苯乙烯磺酸的钠盐，例如以商品名Flexan130出售的，亦同样适用。
如果它们是由含酸的单体合成的，依据本发明，聚合物A和B可以采取酸的形式或部分或全部中和的形式用于头发定型剂。碱金属的氢氧化物类，氨和有机胺类，特别是氨基醇类，适于该中和反应，特别推荐2-氨基-2-甲基-1-丙醇。
聚合物A和B是在一种溶剂中，所用的溶剂优选水或醇类或水与低级醇的混合物。溶剂在头发定型剂中的比例通常为25-98％重量。
聚合物A和B能够通过把A和B溶解在一种溶剂中混合在一起成为粉剂，或通过，把另一种聚合物，一般总是呈固体，或也可以呈为溶液，混合加入到一种聚合物溶液中。聚合物B也可以呈为一种分散剂存在，聚合物A能够以粉或剂水溶液或水-醇溶液的形式加入。
依据本发明的头发定型剂的聚合物B的含量为0.5-20.0％，优选为1-5％，以制成的定型剂的重量计。
除了聚合物A和B以及一种溶剂外，依据本发明的头发定型剂，根据预订的用途，还可以含有惯用的美发添加剂，例如香精油、乳化剂、防腐剂，保养物质诸如泛醇、胶原、维生素、蛋白水解产物，稳定剂、pH调节剂，着色剂和其他惯用添加剂。
如果依据本发明的头发定型剂要作为喷发胶使用，一般要加入推进剂。惯用的推进剂是低级链烷烃类，例如丙烷或丁烷，二乙醚，氮气，氧化亚氮或二氧化碳或这些物质的混合物。依据本发明的头发定型剂也可以用含卤烃作为推进剂。当使用机械装置时，例如喷射泵，可以不要推进剂。
依据本发明头发定型剂有突出的应用性能，它们形成透明膜并在水/醇溶液中有低的粘度，因而它们即使采用在较高浓度仍有良好的推进性。令人惊异的是，非水容性成膜聚合物也可以与聚乙烯基己内酰胺结合加工制成能容易洗掉的头发定型剂。
在下面各实施例中所用的聚乙烯基己内酰胺溶液按在乙烯醇溶液中的重量计浓度为50％。依据Fikentscher的聚合物的K值为40(在乙烯醇中为1％)。
实施例1
一种头发定型剂的制备与性质4.0％重量的Luvimer 36D(丙烯酸叔-丁基酯、丙烯酸乙酯和甲基丙烯酸的共聚物的水分散剂，36％重量浓度)7.0％重量的聚乙烯基己内酰胺溶液89.0％重量的蒸馏水+)K值40
在室温下溶解并灌入喷射泵内。喷射两个模特的头发后，得到如下的定型剂评价：被处理的头发定形既好又有光泽且头发不粘黏。手握感松软，梳理性和水洗性亦佳。
实施例2-9
测定经处理的发丝的外观和性质以及下文中提到的各种配方的组合物的粘着性，结果列于表中。
发丝在各种配方中蘸过后，在滤纸上轻轻挤压、干燥并测量其韧性。
通过在10％重量浓度的十二烷基醚磺酸钠水溶液洗涤上述被处理的发丝测定洗掉性，在37℃在30秒钟内，浸没五次并挤干。然后用清水漂洗发丝，重复洗掉的过程并在滤纸上挤压发丝，干燥一整夜。然后测定发丝的残留量。
粘着性的评价
各种配制好的试样用缝宽120μm的刮浆刀涂覆在玻璃板上。湿膜在室温下干燥然后贮藏在75％相对湿度和20℃的空调柜中一整夜。为了测试，用一圆橡皮戳子(φ40mmShoreA硬度60±5)以250N把一塑性碳带压在聚合物膜上10秒钟。碳带的印迹粘附到聚合物膜上保持的程度是聚合物表面的粘着性。黏性1表示印痕保持黏附到聚合物膜上的程度为最小。
实施例25％重量的聚乙烯基己内酰胺溶液10.0％重量的依据WO/03510中实施例3的聚氨酯，25％的重量浓度的微分散水溶液85.0％重量的分散剂水
实施例35％重量的聚乙烯基己内酰胺溶液2.5％重量的由20％摩尔-己内酰胺、34％摩尔六亚甲基二胺、17％摩尔5-磺异苯二甲酸的钠盐和17％摩尔的异苯二甲酸构成的聚酰胺92.5％重量的分散剂水
实施例45％重量的聚乙烯基己内酰胺10％重量的丙烯酸酯微分散剂，依据DE-A 4327514实施例10(20％重量的固体含量)85％重量的分散剂水
实施例55.0％重量的聚乙烯基己内酰胺溶液2.5％重量的Luviskol VA 64P，N-乙烯基吡咯烷酮/乙酸乙烯酯的粉状共聚物52.5％重量的无水乙醇40.0％重量的蒸馏水
实施例65％重量的聚乙烯基己内酰胺溶液2.5％重量的Luvimer 100P，丙烯酸N-叔丁基酯/丙烯酸乙酯/甲基丙烯酸酯的粉状共聚物0.58％重量的2-氨基-2-甲基丙醇(AMP)52.50％重量的无水乙醇39.42％重量的蒸馏水
例75％重量的聚乙烯基己内酰胺溶液2.5％重量的Luviset CAP，乙酸乙烯酯/丙酸乙烯酯/巴豆酸的粉状三元共聚物0.19％重量的AMP52.50％重量的吸收剂乙醇39.81％重量的分散剂水
实施例85％重量的聚乙烯基己内酰胺溶液2.5％重量的Ultrahold 8，N-叔丁基丙烯酰胺、丙烯酸乙酯和丙烯酸的粉状三元共聚物0.23％重量的AMP52.50％重量的无水乙醇39.77％重量的蒸馏水
实施例95％重量的聚乙烯基己内酰胺溶液2.5％重量的Amphomer，烷基丙烯酸酰胺/丙烯酸酯共聚物0.41％重量的AMP52.50％重量的无水乙醇39.59％重量的蒸馏水
实施例106.8％重量的聚乙烯基己内酰胺溶液3.4％重量的Acronal 500D，50％重量浓度的丙烯酸酯/乙酸乙烯酯共聚物的一种阴离子共聚物水分散剂89.8％重量的蒸馏水
表1
| 试验序号 | 外观溶液 在玻璃 | 被处理的发丝 | 20℃，80％相对湿度下，5％重量浓 |
| 板上的膜 | 变硬 洗去效果 能力 | 度时溶液 的粘 性 | |
| 2 | 透明 透明 | 很好 好 | 1 |
| 3 | 透明 透明 | 很好 好 | 1 |
| 4 | 不透明 透明 | 很好 好 | 1 |
| 5 | 透明 透明 | 很好 好 | 1 |
| 6 | 透明 透明 | 很好 好 | 1 |
| 7 | 透明 透明 | 很好 好 | 1 |
| 8 | 透明 透明 | 很好 好 | 1 |
| 9 | 透明 几呼透明 | 很好 好 | 1 |
| 10 | 乳色 几呼透明 | 很好 仍好 | 1 |
实施例115％重量的聚乙烯基己内酰胺溶液2.5％重量的Luvimer100p0.58％重量的AMP52.50％重量的乙醇39.42％重量的丙烷与丁烷50∶50的混合物
实施例125％重量的聚乙烯基己内酰胺2.5％重量的Ultrahold8溶液2.5％重量的AMP37.27％重量的乙醇60％重量的丙烷、丁烷、和n-戊烷30∶50∶20的混合物
Claims (4)
1、一种头发定型剂，包括
A)0.5-20％重量的N-乙烯基己内酰胺均聚物或至少70％重量的N-乙烯基己内酰胺的阴离子或非离子共聚物(聚合物A)，和
B)0.5-20％重量的后成膜聚合物(聚合物B)，是从下组中选出：聚酰胺类、聚氨酯类和单烯基类不饱和的单体的均聚合物和共聚合物。
2、如权利要求1所述的头发定型剂，其中，所用的聚合物A是N乙烯基己内酰胺的一种均聚物。
3、如权利要求1或2所述的头发定型剂，其中，聚合物A的用量为1-10％重量。
4、如权利要求1至3中任一项中所述的头发定型剂，含有乙醇和低级烷烃类。
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| US6113881A (en) * | 1996-09-20 | 2000-09-05 | Helene Curtis, Inc. | Hair styling mousse compositions comprising carboxylated polyurethane resins |
| US5702692A (en) * | 1997-03-03 | 1997-12-30 | Colgate-Palmolive Company | Hair composition |
| JP3679569B2 (ja) * | 1997-09-24 | 2005-08-03 | 花王株式会社 | 毛髪及び頭皮処理用水性ヘアトニック組成物 |
| DE69830010T2 (de) * | 1998-01-08 | 2006-03-09 | H.B. Fuller Licensing & Financing, Inc., St. Paul | Thermoplastische zusammensetzung mit kristallinen und amorphen polymeren |
| US5968494A (en) | 1998-02-24 | 1999-10-19 | National Starch And Chemical Investment Holding Corporation | Polyurethanes with carboxylate functionality for hair fixative applications |
| FR2786392B1 (fr) * | 1998-11-26 | 2006-08-25 | Oreal | Composition de coiffage comprenant un polymere aux caracteristiques particulieres et un polymere non ionique |
| DE19957947C1 (de) * | 1999-12-02 | 2001-08-09 | Wella Ag | Polymerkombination für Haarbehandlungsmittel |
| FR2815854A1 (fr) * | 2000-10-30 | 2002-05-03 | Oreal | Composition cosmetique procurant de bonnes proprietes de tenue et comprenant un copolymere a motif acide |
| DE10150282A1 (de) * | 2001-10-12 | 2003-04-30 | Basf Ag | Haarkosmetische Zubereitungen |
| DE10202253A1 (de) * | 2002-01-21 | 2003-08-07 | Basf Ag | Neue Haarfestigungsmittel |
| US20040191195A1 (en) * | 2003-03-28 | 2004-09-30 | Carol Collins | Method of promoting a nail composition |
| DE102004053222B3 (de) * | 2004-11-04 | 2006-01-26 | Zschimmer & Schwarz Gmbh & Co. Kg Chemische Fabriken | Flüssigkeit, deren Verwendung zur Aufbereitung von Pulvermischungen auf Eisen- oder Edelstahlbasis sowie ein Verfahren zur Aufbereitung von Pulvermischungen auf Eisen- oder Edelstahlbasis |
| DE102004053221B3 (de) * | 2004-11-04 | 2006-02-02 | Zschimmer & Schwarz Gmbh & Co. Kg Chemische Fabriken | Flüssigkeit und deren Verwendung zur Aufbereitung von Hartmetallen |
| CA3016464A1 (en) | 2016-03-08 | 2017-09-14 | Soo-Young Kang | Long lasting cosmetic compositions |
| AU2018333932B2 (en) | 2017-09-13 | 2024-05-02 | Living Proof, Inc. | Long lasting cosmetic compositions |
| EP3681921A2 (en) | 2017-09-13 | 2020-07-22 | Living Proof, Inc. | Color protectant compositions |
| AU2018370210B2 (en) | 2017-11-20 | 2024-09-26 | Living Proof, Inc. | Properties for achieving long-lasting cosmetic performance |
| BR112020021902B1 (pt) | 2018-04-27 | 2024-02-20 | Living Proof, Inc | Composições cosméticas de poliuretano-ureia para tratamento capilar, método de preservação da ondulação no cabelo humano e os usos de poliuretano-ureia |
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|---|---|---|---|---|
| US3145147A (en) * | 1961-02-20 | 1964-08-18 | Gen Aniline & Film Corp | Film forming composition of copolymers of nu-vinyl-epsilon-caprolactam |
| JPS5849715A (ja) * | 1981-08-13 | 1983-03-24 | ジ−・エ−・エフ・コ−ポレ−シヨン | ビニルカプロラクタム／ビニルピロリドン／アクリル酸アルキルを含有する毛髪調合剤 |
| US4744978A (en) * | 1985-10-24 | 1988-05-17 | Dow Corning Corporation | Hair treating composition containing cationic organic polymer and carboxyfunctional silicone |
| US4923694A (en) * | 1988-08-25 | 1990-05-08 | Gaf Chemicals Corporation | Hydrolysis resistant vinyl lactam amino acrylamide polymers |
| DE4013872A1 (de) * | 1990-04-30 | 1991-10-31 | Basf Ag | Haarfestigungs- und haarpflegemittel |
| DE4013873A1 (de) * | 1990-04-30 | 1991-10-31 | Basf Ag | Verfahren zur herstellung von linearen polyamiden |
| US5182098A (en) * | 1991-10-09 | 1993-01-26 | Isp Investments Inc. | Terpolymer hair fixatives, aqueous solution process for making same and water-based hair spray formulations which meet VOC standards |
| US5221531A (en) * | 1991-11-25 | 1993-06-22 | Isp Investments Inc. | Polymer hair fixatives, aqueous-based solution process for making same and water-based hair spray formulations therewith which meet VOC standards |
| US5158762A (en) * | 1992-03-09 | 1992-10-27 | Isp Investments Inc. | Water-based hair spray compositions containing multiple polymers |
| WO1995000105A1 (en) * | 1993-06-25 | 1995-01-05 | Eastman Chemical Company | Hair spray formulations having increased clarity |
| US5599524A (en) * | 1993-07-21 | 1997-02-04 | National Starch And Chemical Investment Holding Corporation | Low VOC hair sprays with improved spray characteristics |
| US5637296A (en) * | 1994-08-31 | 1997-06-10 | Isp Investments Inc. | Low VOC hair spray resin composition of improved spray properties |
| US5603919A (en) * | 1995-01-05 | 1997-02-18 | Isp Investments Inc. | Low VOC hair spray fixative compositions containing a tetramer |
| US5716634A (en) * | 1995-09-13 | 1998-02-10 | Isp Investments Inc. | Clear, homogenized, flowable hydrogel of crosslinked N-vinyl lactam polymer |
-
1995
- 1995-03-27 DE DE19510474A patent/DE19510474A1/de not_active Withdrawn
-
1996
- 1996-03-20 DE DE59610466T patent/DE59610466D1/de not_active Expired - Lifetime
- 1996-03-20 EP EP96104390A patent/EP0734717B1/de not_active Expired - Lifetime
- 1996-03-20 ES ES96104390T patent/ES2200017T3/es not_active Expired - Lifetime
- 1996-03-26 CA CA002172671A patent/CA2172671A1/en not_active Abandoned
- 1996-03-27 JP JP8072522A patent/JPH08283129A/ja active Pending
- 1996-03-27 CN CN96105533A patent/CN1100525C/zh not_active Expired - Fee Related
-
1997
- 1997-06-20 US US08/879,775 patent/US6153179A/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101330901B (zh) * | 2005-12-01 | 2013-01-23 | 宝洁公司 | 二糖聚酯或寡糖聚酯在毛发定型产品中的用途 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH08283129A (ja) | 1996-10-29 |
| EP0734717A3 (de) | 1998-04-22 |
| EP0734717A2 (de) | 1996-10-02 |
| EP0734717B1 (de) | 2003-05-28 |
| US6153179A (en) | 2000-11-28 |
| CN1100525C (zh) | 2003-02-05 |
| ES2200017T3 (es) | 2004-03-01 |
| CA2172671A1 (en) | 1996-09-28 |
| DE19510474A1 (de) | 1996-10-02 |
| DE59610466D1 (de) | 2003-07-03 |
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