CN1153561C - 含聚硅氧烷的毛发定型组合物 - Google Patents
含聚硅氧烷的毛发定型组合物 Download PDFInfo
- Publication number
- CN1153561C CN1153561C CNB981082920A CN98108292A CN1153561C CN 1153561 C CN1153561 C CN 1153561C CN B981082920 A CNB981082920 A CN B981082920A CN 98108292 A CN98108292 A CN 98108292A CN 1153561 C CN1153561 C CN 1153561C
- Authority
- CN
- China
- Prior art keywords
- weight
- polymer
- methyl
- water
- polysiloxanes
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- -1 polysiloxane Polymers 0.000 title claims abstract description 23
- 229920001296 polysiloxane Polymers 0.000 title claims abstract description 16
- 239000000203 mixture Substances 0.000 title claims abstract description 13
- 229920000642 polymer Polymers 0.000 claims abstract description 24
- 239000000654 additive Substances 0.000 claims abstract description 5
- 230000009477 glass transition Effects 0.000 claims abstract description 4
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims abstract description 4
- 229920001577 copolymer Polymers 0.000 claims description 11
- CERQOIWHTDAKMF-UHFFFAOYSA-N alpha-methacrylic acid Natural products CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
- 238000006386 neutralization reaction Methods 0.000 claims description 4
- 230000000996 additive effect Effects 0.000 claims description 3
- 239000012752 auxiliary agent Substances 0.000 claims description 3
- 239000003153 chemical reaction reagent Substances 0.000 claims description 3
- LDHQCZJRKDOVOX-IHWYPQMZSA-N isocrotonic acid Chemical compound C\C=C/C(O)=O LDHQCZJRKDOVOX-IHWYPQMZSA-N 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- 229920001567 vinyl ester resin Polymers 0.000 claims description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 abstract description 11
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 abstract description 4
- 230000003472 neutralizing effect Effects 0.000 abstract 2
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 abstract 2
- 125000001302 tertiary amino group Chemical group 0.000 abstract 2
- 239000004615 ingredient Substances 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 10
- 229940058020 2-amino-2-methyl-1-propanol Drugs 0.000 description 9
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 9
- 239000000178 monomer Substances 0.000 description 6
- 239000013638 trimer Substances 0.000 description 6
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 5
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 5
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 230000002209 hydrophobic effect Effects 0.000 description 3
- UXFQFBNBSPQBJW-UHFFFAOYSA-N 2-amino-2-methylpropane-1,3-diol Chemical compound OCC(N)(C)CO UXFQFBNBSPQBJW-UHFFFAOYSA-N 0.000 description 2
- ZKYCLDTVJCJYIB-UHFFFAOYSA-N 2-methylidenedecanamide Chemical compound CCCCCCCCC(=C)C(N)=O ZKYCLDTVJCJYIB-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 241000195940 Bryophyta Species 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229920002396 Polyurea Polymers 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- SLINHMUFWFWBMU-UHFFFAOYSA-N Triisopropanolamine Chemical compound CC(O)CN(CC(C)O)CC(C)O SLINHMUFWFWBMU-UHFFFAOYSA-N 0.000 description 2
- 229920004482 WACKER® Polymers 0.000 description 2
- 125000002843 carboxylic acid group Chemical group 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 2
- 238000003475 lamination Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 235000011929 mousse Nutrition 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 125000000094 2-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 description 1
- 239000004472 Lysine Substances 0.000 description 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- 206010070834 Sensitisation Diseases 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000001414 amino alcohols Chemical class 0.000 description 1
- 125000004103 aminoalkyl group Chemical group 0.000 description 1
- 229920013822 aminosilicone Polymers 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- DCCMANRPEHXGDK-UHFFFAOYSA-L azane;hydroxy-[[[hydroxy(oxido)phosphoryl]methyl-(phosphonomethyl)amino]methyl]phosphinate;platinum(2+) Chemical compound N.N.[Pt+2].OP(O)(=O)CN(CP(O)(O)=O)CP([O-])([O-])=O DCCMANRPEHXGDK-UHFFFAOYSA-L 0.000 description 1
- 230000006399 behavior Effects 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000008266 hair spray Substances 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 150000007529 inorganic bases Chemical group 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- PNLUGRYDUHRLOF-UHFFFAOYSA-N n-ethenyl-n-methylacetamide Chemical compound C=CN(C)C(C)=O PNLUGRYDUHRLOF-UHFFFAOYSA-N 0.000 description 1
- ZQXSMRAEXCEDJD-UHFFFAOYSA-N n-ethenylformamide Chemical compound C=CNC=O ZQXSMRAEXCEDJD-UHFFFAOYSA-N 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- XFHJDMUEHUHAJW-UHFFFAOYSA-N n-tert-butylprop-2-enamide Chemical compound CC(C)(C)NC(=O)C=C XFHJDMUEHUHAJW-UHFFFAOYSA-N 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000007530 organic bases Chemical group 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920006112 polar polymer Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000008313 sensitization Effects 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 125000004469 siloxy group Chemical group [SiH3]O* 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 125000005023 xylyl group Chemical group 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8147—Homopolymers or copolymers of acids; Metal or ammonium salts thereof, e.g. crotonic acid, (meth)acrylic acid; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8158—Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/896—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
- A61K8/898—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/594—Mixtures of polymers
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Silicon Polymers (AREA)
Abstract
一种毛发定型组合物，除常规助剂和添加剂外，还含有(A)0.5-15%(重量)含羧基聚合物，该聚合物在中和形式时是水可分散的或水溶性的，其玻璃相变温度高于0℃，(B)基于所用聚合物(A)的0.5-30%(重量)含伯、仲或叔氨基的聚硅氧烷，(C)0-50%(重量)低分子量中和试剂。
Description
合成聚合物成功地用于固定发型已有近50年的历史。起初，优选使用乙烯基内酯的均聚物和共聚物；后来，含羧酸基的聚合物变得逐渐重要起来。理想的定型特性，例如在高湿度条件下的高强度、有弹性、易于从毛发上洗去以及与其它配制成分的相容性可通过将疏水性的、弹性化的并含羧基的单体混合共聚获得(参见：Robert Y.Lochhead，103卷，1988年12月，24 ff.，Rolf-Dieter Reinhardt Cosmetics and Toiletries Manufacture World Wide1995，189m ff.)。
现如今，虽然上述的要求可通过各种聚合物获得，但使用这些聚合物固定发型使人愈来愈感到不愉快的呆板和“不自然”。曾尝试向配方中添加其它成分以求改善，但到目前为止仍未获得完全令人满意的结果：添加常规增塑剂，虽然改善了操作，但同时在许多情况下降低了定型效果。常用的聚硅氧烷与极性聚合物不相容并且在许多情况下还需其它添加剂(如将它们全部配制进去)。在产品贮存和使用期间还可能导致分层现象(参见EP-A 0408311，第1页第25行等)。
已不乏有将聚硅氧烷基与毛发定型聚合物共价结合以防止分层现象的尝试。例如EP-A-0408311描述了含有含聚硅氧烷基单体、常规亲水性和疏水性单体的毛发护理聚合物。EP-A-0412704至EP-A-0412707建议将分子量为1000-50000的大单体形式的聚硅氧烷另外与疏水性和亲水性单体聚合。
含硅氧烷基的大单体的合成极其繁杂。由于其高分子量，将未反应的大单体和它们的非反应性杂质与共聚物分离几乎不可能。因此它们具有毒性和致敏危险性并影响溶解性。此外，为获得良好效果，经常仅将所得共聚物与其它聚合物、载体和其它助剂结合(正如上述专利文献所教导的那样)。
本发明的目的是提供不具有上述缺点的含有聚硅氧烷的毛发定型产品。
我们发现本发明的目的通过下述得以实现，因此，本发明提供的毛发定型组合物除常规助剂和添加剂外，还含有
(A)0.5-15％(重量)含羧基聚合物，该聚合物在中和形式时是水可分散的或水溶性的，其玻璃相变温度高于0℃，
(B)基于所用聚合物(A)的0.5-30％(重量)含伯、仲或叔氨基的聚硅氧烷，
(C)0-50％(重量)低分子量中和试剂。
适宜的含羧基的聚合物(A)的实例是巴豆酸与乙烯基酯、(甲基)丙烯酸/(甲基)丙烯酸酯与或不与其它含氮共聚单体的共聚物、和马来酸与乙烯基醚的单酯共聚物，它们常用于毛发定型喷雾剂、摩丝和凝胶中(参见：Robert Y.Lochhead，103卷，1988年12月，24 ff.，Rolf-Dieter Reinhardt Cosmeticsand Toiletries Manufacture World Wide 1995，189m ff.)。
适宜的含羧基聚脲如德国专利DE 4225045中所述。但也可使用本发明中特别限定的用作毛发定型剂的聚合物。这种情况下，例如可通过提高羧酸基的比率改善易洗去性或通过改变疏水性单体含量来影响定型。
重要的是中和形式的聚合物并且其玻璃相变温度高于0℃，优选高于10℃，尤其是高于20℃。
新的毛发定型组合物含0.5-15％，优选2-10％(重量)的聚合物(A)。
特别地，适宜的含氨基硅氧烷(B)是下式的那些物质
其中各个R1可以相同或不同，是式-(CH2)n-R3，其中n是0-10的整数。
x和y是使聚硅氧烷嵌段的分子量为300-30000的整数。
基团R1可选自，尤其是甲基、乙基、丙基、丁基、异丁基、戊基、异戊基、己基、辛基、癸基、十二烷基和十八烷基；环脂族基团，尤其是环己基；芳基，尤其是苯基和萘基；混合芳香-脂族基，如苄基和苯乙基以及甲苯基或二甲苯基。
各个R2可以相同或不同，是式-(CH2)n-R3，其中n是0-10的整数。R3可以是-H，含1-20个碳的脂族烃基或可以是芳基。优选扩大到其中至少一个R3是-N(R4)2，其中R4是-H或含1-20个碳脂族的烃基，可以是芳基或含1-12个碳的氨基烷基的化合物。
各个R4可以相同或不同。
优选的适宜硅氧烷是下式的化合物
适宜的中和试剂(C)首先是无机碱，如碳酸钠或碳酸钾和氨；其次是有机碱，如氨基醇，尤其是2-氨基-2-甲基-1-丙醇(AMP)、三乙醇胺、三异丙醇胺(TIPA)、一乙醇胺、二乙醇胺、三(2-羟基-1-丙基)胺、2-氨基-2-甲基-1，3-丙二醇(AMDP)或2-氨基-2-羟甲基-1，3-丙二醇以及二胺，如赖氨酸。
用于该新毛发定型组合物的共聚物中羧基的明确中和程度为5-100％，优选为30-95％。
该新的混合物可用作发凝胶、液体毛发定型组合物、发用摩丝和特别是毛发喷雾剂。
在许多情况下，应该清楚，基于配制产品的聚合物的使用比率为0.1-15％(重量)，优选是1-5％(重量)。
特别适宜的其它聚合物是N-乙烯基内酯和乙烯基酰胺，例如乙烯基吡咯烷酮、乙烯基己内酰胺、乙烯基甲酰胺和乙烯基(甲基)乙酰胺的聚合物和共聚物。适宜的其它聚合物还有含硫聚酰胺、聚脲和聚酯，如EP-A 0696607、DE 4225045或US 3779993中所述的那些。
实例：
| 序号.：1 | 硅氧烷1)- | 量2)- | 膜透明性+ | 再分散性+ | 光滑性3)- |
| 2 | Tegomer A-Si2120TM | 10 | + | + | + |
| 3 | Tegomer A-Si2320TM | 10 | + | + | + |
| 4 | Silikonl IM 11TM | 10 | - | + | ○ |
| 5 | Tegomer A-Si2120TM | 5 | + | + | + |
| 6 | Tegomer A-Si2320TM | 5 | + | + | + |
| 7 | Silikonl IM 11TM | 5 | - | + | ○ |
| 8 | Tegomer A-Si2120TM | 2 | + | + | + |
| 9 | Tegomer A-Si2320TM | 2 | + | + | + |
| 10 | Silikonl IM 11TM | 2 | - | + | ○ |
| 11 | Tegomer A-Si2120TM | 5 | + | + | + |
| 12 | - | - | + | + | - |
| 13 | Tegomer A-Si2120TM | 5 | + | + | + |
| 14 | - | - | + | + | + |
| 15 | Tegomer A-Si2120TM | 5 | + | + | - |
| 16 | - | - | + | + | + |
1)硅氧烷Tegomer A-Si2320和Tegomer A-Si2120可从Goldenchmidt AG获得；Silikonol[硅油]IM 11可从Wacker获得。Tegomer A-Si 2320和Tegomer A-Si 2120的结构式如下，其中n为约10(A-Si 2120或约30(A Si-2320)。
硅氧烷IM 11可从Wacker获得，其结构式如下(n为约11)：
2)％(重量)是基于含酸聚合物的，
3)膜光滑性的测定通过对玻璃板上包膜刀片的膜的感官试验进行。该试验测试表面粗糙性和摩擦特性。
实施例1：
将10％(重量)浓度的丙烯酸叔丁酯/丙烯酸乙酯/甲基丙烯酸三聚物(购自BASF AG，Ludwigshafen的Luvimer 100PTM)的乙醇溶液用2-氨基-2-甲基-1-丙醇(AMP)调节pH到9.5。该配方得到透明的、水可再分散的膜。
实施例2-4：
类似于实施例1，用10％(重量)硅氧烷Tegomer A-Si 2120、Tegomer A-Si2320和Silikon IM 11制备下列产品：
100ml乙醇
10g丙烯酸叔丁酯/丙烯酸乙酯/甲基丙烯酸三聚物(购自BASF AG，Ludwigshafen的LuvimerTM)
1g硅氧烷
AMP调节pH到9.5
实施例5-7：
类似于实施例1，用5％(重量)硅氧烷Tegomer A-Si 2120、Tegomer A-Si2320和Silikon IM 11制备下列产品：
100ml乙醇
10g丙烯酸叔丁酯/丙烯酸乙酯/甲基丙烯酸三聚物(购自BASF AG，Ludwigshafen的Luvimer 100PTM)
0.5g硅氧烷
AMP调节pH到9.5
实施例8-10：
类似于实施例1，用2％(重量)硅氧烷Tegomer A-Si2120、Tegomer A-Si2320和Silikon IM 11制备下列产品：
100ml乙醇
10g丙烯酸叔丁酯/丙烯酸乙酯/甲基丙烯酸三聚物(购自BASF AG，Ludwigshafen的Luvimer 100PTM)
0.2g硅氧烷
AMP调节pH到9.5
实施例11：
产品含有：
100ml乙醇
10g辛基丙烯酰胺/丙烯酸酯/甲基丙烯酸丁基氨基乙酯共聚物(购自National Starch的AmphomerTM)
0.5g Temoger A-Si 2120
AMP调节pH到7.0
实施例12：
产品含有：
100ml乙醇
10g辛基丙烯酰胺/丙烯酸酯/甲基丙烯酸丁基氨基乙酯共聚物(购自National Starch的AmphomerTM)
AMP调节pH到7.0
实施例13、14：
如实施例11和12的产品，但使用乙酸乙烯酯/丙酸乙烯酯/巴豆酸三聚物(购自BASP AG的LuvisetTM CAP)。
实施例15、16：
如实施例11和12的产品，但使用丙烯酸/丙烯酸乙酯/N-叔丁基丙烯酰胺三聚物(购自BASP AG的UltraholdTM8)。
Claims (2)
1.一种毛发定型组合物，除常规助剂和添加剂外，还含有
(A)0.5-15％(重量)含羧基聚合物，该聚合物在中和形式时是水可分散的或水溶性的，其玻璃相变温度高于0℃，该聚合物选自巴豆酸与乙烯基酯、(甲基)丙烯酸/(甲基)丙烯酸酯与或不与其它含氮共聚单体的共聚物；
(B)基于所用聚合物(A)的0.5-30％(重量)的下式的含伯、仲或叔氨基的聚硅氧烷，
其中各个R1可以相同或不同，可选自甲基、乙基、丙基或丁基；
R2是式-(CH2)n-NR4，其中n是0-10的整数；
R4是-H或含1-20个碳脂族的烃基；
x和y是使聚硅氧烷嵌段的分子量为300-30000的整数；
(C)0-50％(重量)低分子量中和试剂。
2.权利要求1的毛发定型组合物，其中聚硅氧烷(B)含有不止一个氨基。
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19709277.2 | 1997-03-07 | ||
| DE19709277A DE19709277A1 (de) | 1997-03-07 | 1997-03-07 | Polysiloxanhaltige Haarfestigungsmittel |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1196926A CN1196926A (zh) | 1998-10-28 |
| CN1153561C true CN1153561C (zh) | 2004-06-16 |
Family
ID=7822500
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB981082920A Expired - Fee Related CN1153561C (zh) | 1997-03-07 | 1998-03-07 | 含聚硅氧烷的毛发定型组合物 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US5958390A (zh) |
| EP (1) | EP0862908B1 (zh) |
| JP (1) | JP3943229B2 (zh) |
| CN (1) | CN1153561C (zh) |
| DE (2) | DE19709277A1 (zh) |
| ES (1) | ES2221088T3 (zh) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1645580A3 (de) | 1999-03-12 | 2007-03-28 | Basf Aktiengesellschaft | Polyharnstoffe |
| DE19913875A1 (de) | 1999-03-26 | 2000-09-28 | Basf Ag | Wasserlösliche oder wasserdispergierbare polymere Salze |
| US6514918B1 (en) | 2000-08-18 | 2003-02-04 | Johnson & Johnson Consumer Companies, Inc. | Viscous, mild, and effective cleansing compositions |
| GB0111720D0 (en) * | 2001-05-14 | 2001-07-04 | Procter & Gamble | Terminal aminofunctional polysiloxane hair conditioning compositions and their use in hair colouring compositions |
| US7211243B2 (en) | 2001-05-14 | 2007-05-01 | The Procter & Gamble Company | Terminal aminofunctional polysiloxane hair conditioning compositions and their use in hair coloring compositions |
| FR2825628B1 (fr) * | 2001-06-07 | 2004-03-19 | Oreal | Composition cosmetique comportant un polymere comprenant des groupes de jonction capables d'etablir chacun au moins trois liaisons h |
| DE102004062201A1 (de) * | 2004-12-23 | 2006-07-13 | Basf Ag | Urethanverbindung, die ein Polyethergruppen-haltiges Siliconderivat und einen Stickstoffheterocyclus eingebaut enthält |
| RU2390327C2 (ru) * | 2005-05-28 | 2010-05-27 | Унилевер Нв | Состав аэрозольного лака для волос |
| US20070032610A1 (en) * | 2005-08-08 | 2007-02-08 | General Electric Company | Energy responsive composition and associated method |
| FR2894816B1 (fr) * | 2005-12-16 | 2008-02-01 | Oreal | Composition cosmetique ou pharmaceutique comprenant un copolymere comportant au moins un groupe ionisable, et procede de traitement cosmetique |
| US9243142B2 (en) * | 2011-11-16 | 2016-01-26 | Momentive Performance Materials Inc. | Association product of amino functional hydrophobic polymers with hydrophilic polymers containing acid groups, methods of preparation, and applications for employing the same |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4844888A (en) * | 1987-11-13 | 1989-07-04 | The Gillette Company | Polysiloxane cosmetic composition |
| JPH01190619A (ja) * | 1988-01-25 | 1989-07-31 | Shiseido Co Ltd | 毛髪化粧料 |
| US5166276A (en) * | 1989-07-12 | 1992-11-24 | Mitsubishi Petrochemical Company Ltd. | Polymer for hair-care products |
| EP0878184A3 (en) * | 1989-08-07 | 1998-12-16 | The Procter & Gamble Company | Hair conditioning and styling compositions |
| DK0412707T3 (da) * | 1989-08-07 | 1994-06-13 | Procter & Gamble | Hårkonditionerings- og frisuresætningsmidler |
| DK0576578T3 (da) * | 1991-03-19 | 1996-05-06 | Procter & Gamble | Kosmetiske sammensætninger indeholdende hydrofobt modificeret ikke-ionisk polymer og umættet kvaternært ammoniumoverfladeaktivt middel |
| JPH0525025A (ja) * | 1991-07-22 | 1993-02-02 | Kao Corp | 毛髪化粧料 |
| JP3200449B2 (ja) * | 1991-08-20 | 2001-08-20 | 日本ユニカー株式会社 | セット保持性毛髪化粧料 |
| US5578298A (en) * | 1994-05-27 | 1996-11-26 | General Electric Company | Microemulsions for high viscosity amino silicone fluids and gums and their preparation |
| US5662892A (en) * | 1996-03-15 | 1997-09-02 | The Procter & Gamble Company | Personal care compositions containing hydrophobic linear copolymer and hydrophobic, volatile, branched hydrocarbon solvent |
| US5851516A (en) * | 1996-04-30 | 1998-12-22 | Shiseido Co., Ltd. | Formulation and application method for a neutralizing agent in the permanent waving of hair |
-
1997
- 1997-03-07 DE DE19709277A patent/DE19709277A1/de not_active Withdrawn
-
1998
- 1998-03-02 DE DE59811525T patent/DE59811525D1/de not_active Expired - Fee Related
- 1998-03-02 EP EP98103628A patent/EP0862908B1/de not_active Expired - Lifetime
- 1998-03-02 ES ES98103628T patent/ES2221088T3/es not_active Expired - Lifetime
- 1998-03-04 JP JP05195798A patent/JP3943229B2/ja not_active Expired - Fee Related
- 1998-03-04 US US09/034,273 patent/US5958390A/en not_active Expired - Fee Related
- 1998-03-07 CN CNB981082920A patent/CN1153561C/zh not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| EP0862908B1 (de) | 2004-06-09 |
| US5958390A (en) | 1999-09-28 |
| DE59811525D1 (de) | 2004-07-15 |
| EP0862908A3 (de) | 2000-05-10 |
| JPH10273430A (ja) | 1998-10-13 |
| ES2221088T3 (es) | 2004-12-16 |
| DE19709277A1 (de) | 1998-09-10 |
| EP0862908A2 (de) | 1998-09-09 |
| CN1196926A (zh) | 1998-10-28 |
| JP3943229B2 (ja) | 2007-07-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1140248C (zh) | 挺感发型组合物 | |
| US6369117B1 (en) | Thickened aqueous composition and use | |
| CN1153561C (zh) | 含聚硅氧烷的毛发定型组合物 | |
| CN1089228C (zh) | 含有溶于水醇液体载体的磺基聚酯的抽吸式透明喷发配制剂 | |
| US6667029B2 (en) | Stable, aqueous cationic hydrogel | |
| CN1070357C (zh) | 用于保持发型的具有改善的定型力的化妆品组合物 | |
| CA2229706A1 (fr) | Composition cosmetique pressurisee et mousse resultante | |
| US6190647B1 (en) | Composition for increasing the stylability and luster of the hair | |
| EP0822802B1 (fr) | Composition cosmetique de fixation et de brillance | |
| CN1138799C (zh) | 基于聚乙烯基内酰胺的水溶性或水可分散的接枝共聚物，其制备方法及用途 | |
| CN1086936C (zh) | 头发化妆组合物 | |
| CN1295459A (zh) | 含具有特定特性的聚合物和离子型成膜聚合物的定型组合物 | |
| CN1229097C (zh) | 长效定型摩丝 | |
| CN1300587A (zh) | 包含一种具有特殊特性的聚合物和一种增稠聚合物的化妆品组合物 | |
| CA2226567A1 (en) | Nail enamel compositions | |
| CN1180765C (zh) | 气雾剂喷发胶组合物 | |
| EP0855897A1 (fr) | Laque a l'eau pour le traitement des matieres keratiniques, conditionnee dans un dispositif aerosol, comprenant au moins un polymere silicone greffe et applications | |
| ATE283681T1 (de) | Aerosol-haarsprayzusammensetzungen enthaltend eine mischung von siliconpropfcopolymeren | |
| KR19990028610A (ko) | Q하나 이상의 그라프트된 실리콘 중합체 및 (메트)아크릴아미드 또는 (메트)아크릴아미드 유도체의 하나 이상의 증점중합체 또는 공중합체를 포함하는 케라틴 물질 처리용 조성물및 그 용도 | |
| JPH09100221A (ja) | 毛髪処理剤組成物 | |
| CN1323189A (zh) | 头发定型组合物 | |
| JP4454856B2 (ja) | カチオン性ポリマーとその使用 | |
| CN1293028A (zh) | 包含至少一种硅氧烷/丙烯酸酯共聚物和至少一种接枝硅氧烷聚合物的化妆品组合物 | |
| CN1293029A (zh) | 含有包括至少一种硅氧烷/丙烯酸酯共聚物的美发组合物的气溶胶装置 | |
| JPH07173395A (ja) | ゲル組成物 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |