CN113817453B - 一种纳米有机硼交联剂及其制备方法与应用 - Google Patents
一种纳米有机硼交联剂及其制备方法与应用 Download PDFInfo
- Publication number
- CN113817453B CN113817453B CN202111240942.3A CN202111240942A CN113817453B CN 113817453 B CN113817453 B CN 113817453B CN 202111240942 A CN202111240942 A CN 202111240942A CN 113817453 B CN113817453 B CN 113817453B
- Authority
- CN
- China
- Prior art keywords
- silicon dioxide
- nano silicon
- nano
- organic boron
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000003431 cross linking reagent Substances 0.000 title claims abstract description 61
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 title claims abstract description 39
- 229910052796 boron Inorganic materials 0.000 title claims abstract description 39
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 100
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 47
- 239000005543 nano-size silicon particle Substances 0.000 claims abstract description 46
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical compound [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000007822 coupling agent Substances 0.000 claims abstract description 21
- 229920002907 Guar gum Polymers 0.000 claims abstract description 15
- 239000012530 fluid Substances 0.000 claims abstract description 15
- 239000000665 guar gum Substances 0.000 claims abstract description 15
- 229960002154 guar gum Drugs 0.000 claims abstract description 15
- 235000010417 guar gum Nutrition 0.000 claims abstract description 15
- 239000002562 thickening agent Substances 0.000 claims abstract description 14
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims abstract description 10
- 125000005619 boric acid group Chemical group 0.000 claims abstract description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 24
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- 239000004327 boric acid Substances 0.000 claims description 7
- -1 boric acid ester Chemical class 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 239000000377 silicon dioxide Substances 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 4
- 238000010992 reflux Methods 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 239000000654 additive Substances 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- 239000003921 oil Substances 0.000 description 14
- 238000001035 drying Methods 0.000 description 12
- 239000000243 solution Substances 0.000 description 10
- 238000004132 cross linking Methods 0.000 description 9
- 239000007789 gas Substances 0.000 description 6
- 238000009210 therapy by ultrasound Methods 0.000 description 6
- 238000005303 weighing Methods 0.000 description 6
- 238000002390 rotary evaporation Methods 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 4
- WRECIMRULFAWHA-UHFFFAOYSA-N trimethyl borate Chemical compound COB(OC)OC WRECIMRULFAWHA-UHFFFAOYSA-N 0.000 description 4
- NHDIQVFFNDKAQU-UHFFFAOYSA-N tripropan-2-yl borate Chemical group CC(C)OB(OC(C)C)OC(C)C NHDIQVFFNDKAQU-UHFFFAOYSA-N 0.000 description 4
- 239000004971 Cross linker Substances 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 238000010008 shearing Methods 0.000 description 3
- 230000008719 thickening Effects 0.000 description 3
- LGQXXHMEBUOXRP-UHFFFAOYSA-N tributyl borate Chemical compound CCCCOB(OCCCC)OCCCC LGQXXHMEBUOXRP-UHFFFAOYSA-N 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 2
- 239000012267 brine Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 229920005615 natural polymer Polymers 0.000 description 2
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 229910052723 transition metal Inorganic materials 0.000 description 2
- 150000003624 transition metals Chemical class 0.000 description 2
- VJIFBECQKOBRHM-UHFFFAOYSA-N 2-silylethanamine Chemical compound NCC[SiH3] VJIFBECQKOBRHM-UHFFFAOYSA-N 0.000 description 1
- ZPZDIFSPRVHGIF-UHFFFAOYSA-N 3-aminopropylsilicon Chemical compound NCCC[Si] ZPZDIFSPRVHGIF-UHFFFAOYSA-N 0.000 description 1
- 239000006087 Silane Coupling Agent Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229940063013 borate ion Drugs 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 238000009933 burial Methods 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000009096 changqing Substances 0.000 description 1
- 125000003636 chemical group Chemical group 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/60—Compositions for stimulating production by acting on the underground formation
- C09K8/62—Compositions for forming crevices or fractures
- C09K8/66—Compositions based on water or polar solvents
- C09K8/68—Compositions based on water or polar solvents containing organic compounds
- C09K8/685—Compositions based on water or polar solvents containing organic compounds containing cross-linking agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/60—Compositions for stimulating production by acting on the underground formation
- C09K8/84—Compositions based on water or polar solvents
- C09K8/86—Compositions based on water or polar solvents containing organic compounds
- C09K8/88—Compositions based on water or polar solvents containing organic compounds macromolecular compounds
- C09K8/887—Compositions based on water or polar solvents containing organic compounds macromolecular compounds containing cross-linking agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/60—Compositions for stimulating production by acting on the underground formation
- C09K8/84—Compositions based on water or polar solvents
- C09K8/86—Compositions based on water or polar solvents containing organic compounds
- C09K8/88—Compositions based on water or polar solvents containing organic compounds macromolecular compounds
- C09K8/90—Compositions based on water or polar solvents containing organic compounds macromolecular compounds of natural origin, e.g. polysaccharides, cellulose
- C09K8/905—Biopolymers
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
Claims (5)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202111240942.3A CN113817453B (zh) | 2021-10-25 | 2021-10-25 | 一种纳米有机硼交联剂及其制备方法与应用 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202111240942.3A CN113817453B (zh) | 2021-10-25 | 2021-10-25 | 一种纳米有机硼交联剂及其制备方法与应用 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN113817453A CN113817453A (zh) | 2021-12-21 |
CN113817453B true CN113817453B (zh) | 2023-10-31 |
Family
ID=78919053
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202111240942.3A Active CN113817453B (zh) | 2021-10-25 | 2021-10-25 | 一种纳米有机硼交联剂及其制备方法与应用 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN113817453B (zh) |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105733548A (zh) * | 2016-01-29 | 2016-07-06 | 河南大学 | 一种胍胶压裂液纳米交联剂的制备方法 |
CN107641507A (zh) * | 2016-07-21 | 2018-01-30 | 中国石油化工股份有限公司 | 一种交联剂及其制备方法和应用 |
CN111139052A (zh) * | 2018-11-06 | 2020-05-12 | 中国石油化工股份有限公司 | 一种低浓度的羟丙基胍胶压裂液及制备方法 |
CN111139053A (zh) * | 2018-11-06 | 2020-05-12 | 中国石油化工股份有限公司 | 一种纳米二氧化硅有机硼交联剂及其制备方法 |
CN112920791A (zh) * | 2021-01-26 | 2021-06-08 | 中国石油大学(华东) | 一种压裂液用硼改性碳纳米管交联剂及其制备方法与应用 |
CN113025300A (zh) * | 2019-12-09 | 2021-06-25 | 中国石油天然气股份有限公司 | 一种交联剂及其制备方法与应用 |
-
2021
- 2021-10-25 CN CN202111240942.3A patent/CN113817453B/zh active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105733548A (zh) * | 2016-01-29 | 2016-07-06 | 河南大学 | 一种胍胶压裂液纳米交联剂的制备方法 |
CN107641507A (zh) * | 2016-07-21 | 2018-01-30 | 中国石油化工股份有限公司 | 一种交联剂及其制备方法和应用 |
CN111139052A (zh) * | 2018-11-06 | 2020-05-12 | 中国石油化工股份有限公司 | 一种低浓度的羟丙基胍胶压裂液及制备方法 |
CN111139053A (zh) * | 2018-11-06 | 2020-05-12 | 中国石油化工股份有限公司 | 一种纳米二氧化硅有机硼交联剂及其制备方法 |
CN113025300A (zh) * | 2019-12-09 | 2021-06-25 | 中国石油天然气股份有限公司 | 一种交联剂及其制备方法与应用 |
CN112920791A (zh) * | 2021-01-26 | 2021-06-08 | 中国石油大学(华东) | 一种压裂液用硼改性碳纳米管交联剂及其制备方法与应用 |
Non-Patent Citations (1)
Title |
---|
王彦玲等.表面硼改性的纳米交联剂在中性条件下的交联性能.《精细石油化工》.第第34卷卷(第第3期期),57-60. * |
Also Published As
Publication number | Publication date |
---|---|
CN113817453A (zh) | 2021-12-21 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN110183573B (zh) | 一种阳离子聚合物增稠剂、制备方法及用于耐高温压裂液 | |
CN105062458B (zh) | 一种适用于非常规储层的低碳烃无水压裂液交联剂的制备与应用 | |
CN111518239B (zh) | 一种乳液型压裂液降阻剂及其制备方法 | |
CN113881052A (zh) | 一种超支化改性纳米材料及其制备方法和在稠油降粘剂中的应用 | |
US20230391959A1 (en) | Preparation method for and application of modified siloxane-based supercritical carbon dioxide thickener | |
CN109321219A (zh) | 一种适用于油气井高温固井的油井水泥沉降稳定剂及其制备方法和固井水泥浆 | |
CN111440604B (zh) | 一种自破乳型抗盐稠油冷采驱油剂及其制备方法和应用 | |
CN107828402B (zh) | 一种提高深层稠油co2气驱过程采收率的化学添加剂 | |
CN112210039A (zh) | 一种驱油石墨烯用分散剂的制备方法 | |
CN113956862B (zh) | 一种可降低pH依赖的胍胶压裂液凝胶、胍胶压裂液体系及其制备方法与应用 | |
CN113817453B (zh) | 一种纳米有机硼交联剂及其制备方法与应用 | |
CN109554170B (zh) | 一种抗钙抗高温钻井液降滤失剂及其制备方法 | |
CN111394084B (zh) | 一种驱油剂及其制备和应用 | |
CN107986981B (zh) | 一种双子型气湿反转剂化合物及其制备方法与应用 | |
CN107794023A (zh) | 一种应用于超临界co2干法压裂的增稠剂及其制备方法 | |
CN106634916A (zh) | 一种新型水基降粘降凝剂的制备方法 | |
CN116655828A (zh) | 一种压裂用改性瓜尔胶及其制备方法 | |
CN110305245A (zh) | 一种超支化聚合物稠油降粘剂及其制备方法 | |
CN112552885B (zh) | 一种抗超高温180℃增粘型完井液与修井液 | |
CN110724514A (zh) | 一种纳米高温乳化胶凝酸及制备方法 | |
CN112480898B (zh) | 一种复合清洁压裂液体系及制备方法 | |
CN110643340B9 (zh) | 用于稠油热采的高效水溶性降粘洗油剂及其制备方法 | |
CN114591468A (zh) | 一种用于稠油冷采的油水界面活化减阻剂及制备方法 | |
CN112251204A (zh) | 一种耐高温压裂液用纳米纤维素交联剂及其制备方法与应用 | |
CN117343233B (zh) | 一种抗温酸化转向剂及制备方法和碳酸盐岩储层酸化酸液 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
CB03 | Change of inventor or designer information | ||
CB03 | Change of inventor or designer information |
Inventor after: Deng Qingchun Inventor after: Liu Yanhua Inventor after: Cheng Jinjin Inventor after: Wu Xiangyang Inventor after: Yu Bo Inventor after: Wang Yaoguo Inventor before: Deng Qingchun Inventor before: Liu Yanhua Inventor before: Cheng Jinjin Inventor before: Wu Xiangyang Inventor before: Yu Bo Inventor before: Tian Yuqin Inventor before: Wang Yaoguo |
|
GR01 | Patent grant | ||
GR01 | Patent grant |