CN113774520A - 面料及其制备方法、服装 - Google Patents

面料及其制备方法、服装 Download PDF

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Publication number
CN113774520A
CN113774520A CN202111059627.0A CN202111059627A CN113774520A CN 113774520 A CN113774520 A CN 113774520A CN 202111059627 A CN202111059627 A CN 202111059627A CN 113774520 A CN113774520 A CN 113774520A
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fabric
bio
adipic acid
filament
nylon
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孟望舒
阿查拉·赫拉特
苏尼尔·普拉卡什
阿斯霍克·马哈尼
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Wuxi Paradise Textiles Ltd
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Wuxi Paradise Textiles Ltd
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Priority to CN202111059627.0A priority Critical patent/CN113774520A/zh
Priority to US17/502,294 priority patent/US11753746B2/en
Publication of CN113774520A publication Critical patent/CN113774520A/zh
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    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01GPRELIMINARY TREATMENT OF FIBRES, e.g. FOR SPINNING
    • D01G11/00Disintegrating fibre-containing articles to obtain fibres for re-use
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/14Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00Recovery of plastics or other constituents of waste material containing plastics
    • B29B17/02Separating plastics from other materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00Recovery of plastics or other constituents of waste material containing plastics
    • B29B17/04Disintegrating plastics, e.g. by milling
    • B29B17/0412Disintegrating plastics, e.g. by milling to large particles, e.g. beads, granules, flakes, slices
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    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/06Preparation of carboxylic acids or their salts, halides or anhydrides from carboxylic acid amides
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    • C07C51/42Separation; Purification; Stabilisation; Use of additives
    • C07C51/43Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation
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    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/03Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group
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    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/48Separation; Purification; Stabilisation; Use of additives
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    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16Dicarboxylic acids and dihydroxy compounds
    • C08G63/18Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
    • C08G63/181Acids containing aromatic rings
    • C08G63/183Terephthalic acids
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    • C08G69/00Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/26Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
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    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J11/00Recovery or working-up of waste materials
    • C08J11/04Recovery or working-up of waste materials of polymers
    • C08J11/10Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/04Dry spinning methods
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/08Melt spinning methods
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    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F13/00Recovery of starting material, waste material or solvents during the manufacture of artificial filaments or the like
    • D01F13/04Recovery of starting material, waste material or solvents during the manufacture of artificial filaments or the like of synthetic polymers
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
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    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/44Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
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    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/88Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/90Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyamides
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/88Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/92Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/12Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyamide as constituent
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/04Blended or other yarns or threads containing components made from different materials
    • D02G3/045Blended or other yarns or threads containing components made from different materials all components being made from artificial or synthetic material
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/283Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads synthetic polymer-based, e.g. polyamide or polyester fibres
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • D03D15/54Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads coloured
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • D03D15/56Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads elastic
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D35/00Smallware looms, i.e. looms for weaving ribbons or other narrow fabrics
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04BKNITTING
    • D04B1/00Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D04B1/14Other fabrics or articles characterised primarily by the use of particular thread materials
    • D04B1/16Other fabrics or articles characterised primarily by the use of particular thread materials synthetic threads
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04BKNITTING
    • D04B1/00Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D04B1/14Other fabrics or articles characterised primarily by the use of particular thread materials
    • D04B1/18Other fabrics or articles characterised primarily by the use of particular thread materials elastic threads
    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41DOUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D1/00Garments
    • A41D1/06Trousers
    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41DOUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D31/00Materials specially adapted for outerwear
    • A41D31/04Materials specially adapted for outerwear characterised by special function or use
    • A41D31/18Elastic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00Recovery of plastics or other constituents of waste material containing plastics
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    • B29B2017/0203Separating plastics from plastics
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2367/00Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08J2377/00Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
    • C08J2377/06Polyamides derived from polyamines and polycarboxylic acids
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
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    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/02Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
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    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
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    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
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    • D10B2331/12Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyureas
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Abstract

本发明提供一种面料及其制备方法、服饰,包括:基于纺织废料得到生物基合成纤维切片;采用预设配方的纺液从所述生物基合成纤维切片中得到挤出长丝;以生物基弹力纤维为基础长丝和所述挤出长丝进行编织互锁,以得到所述面料。本发明的所述面料基于纺织废料而得到,实现了废物再利用,且避免了纺织废料对环境的污染;同时,所述面料的制备过程中采用预设配方的纺液,可以增强所述布料的不透明性和亲水性。

Description

面料及其制备方法、服装
技术领域
本发明涉及纺织行业技术领域,特别是涉及一种面料及其制备方法、服饰。
背景技术
纺织行业在纺织品的生产过程中以及实际使用后都造成污染。由于时尚的快速变化以及人们状态、年龄或天气的变化,大多数纺织材料甚至在他们实用寿命之前就被浪费了。大部分纺织废料被倾倒或焚化;两者都进一步造成环境污染。
发明内容
为实现上述目的及其他相关目的,本发明提供一种面料的制备方法,包括:
基于纺织废料得到生物基合成纤维切片;
采用预设配方的纺液从所述生物基合成纤维切片中得到挤出长丝;
以生物基弹力纤维为基础长丝和所述挤出长丝进行编织互锁,以得到所述面料。
可选地,所述生物基合成纤维切片包括聚对苯二甲酸乙二醇酯切片和尼龙切片;所述基于纺织废料得到生物基合成纤维切片包括:
从所述纺织废料中回收聚对苯二甲酸乙二醇酯和尼龙;
对所述聚对苯二甲酸乙二醇酯在分子水平上解聚成对苯二甲酸二甲酯;
将所述对苯二甲酸二甲酯与生物基-MEG反应以得到所述聚对苯二甲酸乙二醇酯切片;
对所述尼龙在分子水平上解聚成对己二酸;
将所述对己二酸与生物基1,5-戊烷二胺反应以得到所述尼龙切片。
可选地,对所述聚对苯二甲酸乙二醇酯在分子水平上解聚成对苯二甲酸二甲酯之后,在所述对苯二甲酸二甲酯与所述生物基-MEG反应之前,还包括对所述对苯二甲酸二甲酯进行纯化处理的步骤;
对所述尼龙在分子水平上解聚成对己二酸之后,在所述对己二酸与所述生物基1,5-戊烷二胺反应之前,还包括对所述对己二酸进行纯化处理的步骤。
可选地,基于闭环重结晶工艺对所述对苯二甲酸二甲酯进行纯化处理,基于闭环重结晶工艺对所述对己二酸进行纯化处理。
可选地,所述预设配方的纺液包括:氨基甲酸乙酯、TiO2、二甘醇、丙烯腈-丁二烯-苯乙烯、炭黑和增粘剂。
可选地,以生物基弹力纤维为基础长丝和所述挤出长丝进行编织互锁之前,所述生物基弹力纤维和所述挤出长丝分别位于编织中线相对的两侧。
可选地,所述生物基弹力纤维包括透明氨纶长丝。
本发明还提供一种面料,所述面料采用如以上任一方案的所述的面料的制备方法制备而得到。
本发明还提供一种服饰,所述服饰采用如以上任一方案的所述的面料制备而得到。
如上所述,本发明的面料及其制备方法、服饰,具有以下有益效果:本发明的所述面料基于纺织废料而得到,实现了废物再利用,且避免了纺织废料对环境的污染;同时,所述面料的制备过程中采用预设配方的纺液,可以增强所述布料的不透明性和亲水性。
附图说明
图1为本发明的面料的制备方法的流程图。
图2及图3为本发明的制备方法中以生物基弹力纤维为基础长丝和所述挤出长丝进行编织互锁之前,所述生物基弹力纤维和所述挤出长丝分别位于编织中线相对的两侧的示意图。
图4为本发明的面料的制备方法中以生物基弹力纤维为基础长丝和所述挤出长丝进行编织互锁后得到的编织长丝的示意图。
图5为本发明的服饰的制备流程图。
元件标号说明:
1、生物基弹力纤维,2、挤出长丝,3、编制中线。
具体实施方式
下面将结合本发明实施例中的附图,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。
以下描述中的优选实施例只作为举例,本领域技术人员可以想到其他显而易见的变型。在以下描述中界定的本发明的基本原理可以应用于其他实施方案、变形方案、改进方案、等同方案以及没有背离本发明的精神和范围的其他技术方案。
纺织行业在纺织品的生产过程中以及实际使用后都造成污染。由于时尚的快速变化以及人们状态、年龄或天气的变化,大多数纺织材料甚至在他们实用寿命之前就被浪费了。大部分纺织废料被倾倒或焚化;两者都进一步造成环境污染。可持续性问题促使这些纺织品被更新、回收或再利用。这启发由回收的纺织废料制备合成纤维。
此外,由于具有大规模生产的可能性和比天然纤维更好的整体性能,常规的合成纺织被认为是最经济和高效的生活用品。此外,未来市场有望进一步上涨。通常,合成纤维具有一定程度的半透明性和高透光率,这限制了时尚设计计师使用更精致的面料和浅色。传统上,使用粗支数、多层面料或厚的化学涂层来避免高透光率;而每种途径都存在其缺点。
实施例一
请参阅图1所示,本发明提供一种面料的制备方法,包括:
S1:基于纺织废料得到生物基合成纤维切片;
S2:采用预设配方的纺液从所述生物基合成纤维切片中得到挤出长丝;
S3:以生物基弹力纤维为基础长丝和所述挤出长丝进行编织互锁,以得到所述面料。
本发明的所述面料的制备方法中的面料基于纺织废料而得到,实现了废物再利用,且避免了纺织废料对环境的污染;同时,所述面料的制备过程中采用预设配方的纺液,可以增强所述布料的不透明性和亲水性。
实施例二
请结合图1参阅图2至图4,本实施例中还提供一种面料的制备方法,本实施例中面料的制备方法与实施例一中的面料的制备方法大致相同,二者的区别在于,本实施例中的面料的制备方法相较于实施例一中的面料的制备方法还包括如下内容。
作为示例,所述生物基合成纤维切片可以包括聚对苯二甲酸乙二醇酯切片和尼龙切片;步骤S1中,所述基于纺织废料得到生物基合成纤维切片包括:
S11:从所述纺织废料中回收聚对苯二甲酸乙二醇酯和尼龙;
S12:对所述聚对苯二甲酸乙二醇酯在分子水平上解聚成对苯二甲酸二甲酯;
S13:将所述对苯二甲酸二甲酯与生物基-MEG反应以得到所述聚对苯二甲酸乙二醇酯切片;
S14:对所述尼龙在分子水平上解聚成对己二酸;
S15:将所述对己二酸与生物基1,5-戊烷二胺反应以得到所述尼龙切片。
需要说明的是,步骤S1的具体步骤顺序并不以上述步骤S11至S15的顺序限制,在其他实施例中,步骤S1的具体步骤顺序可以根据实际需要进行调整。
作为示例,对所述聚对苯二甲酸乙二醇酯在分子水平上解聚成对苯二甲酸二甲酯之后,在所述对苯二甲酸二甲酯与所述生物基-MEG反应之前,还包括对所述对苯二甲酸二甲酯进行纯化处理的步骤;即步骤S12与步骤S13之间还包括对所述对苯二甲酸二甲酯进行纯化处理的步骤;
对所述尼龙在分子水平上解聚成对己二酸之后,在所述对己二酸与所述生物基1,5-戊烷二胺反应之前,还包括对所述对己二酸进行纯化处理的步骤;即步骤S14与步骤S15之间还包括对所述对己二酸进行纯化处理的步骤。
作为示例,可以基于闭环重结晶工艺对所述对苯二甲酸二甲酯进行纯化处理,可以基于闭环重结晶工艺对所述对己二酸进行纯化处理。
作为示例,所述预设配方的纺液可以包括:氨基甲酸乙酯、TiO2、二甘醇、丙烯腈-丁二烯-苯乙烯、炭黑和增粘剂。
预设配方的纺液增强了对苯二甲酸乙二醇酯(PET)长丝的不透明度并且增加了亲水性和回收利用性。
具体的,由于在纺液染色期间添加了所述预设配方的纺液,缝合的浅色服装即使在几次洗涤之后仍保持独特的性质(即,柔软性、亲水性和不透明性)。此外,还可以避免用于不透明或亲水性的涂层材料的令人不快的化学层。
在一示例中,所述挤出长丝的密度可以为20旦尼尔至150旦尼尔之间,具体的,所述挤出长丝的密度可以为20旦尼尔、50旦尼尔、100旦尼尔或150旦尼尔等等。
作为示例,如图2及图3所示,以生物基弹力纤维1为基础长丝和所述挤出长丝2进行编织互锁之前,所述生物基弹力纤维1和所述挤出长丝2分别位于编织中线3相对的两侧。所述生物基弹力纤维1和所述挤出长丝2编织互锁后得到的编织长丝如图5所示。
具体的,所述生物基弹力纤维可以包括透明氨纶长丝。
具体的,通过使用透明氨纶长丝作为基础长丝,将挤出长丝与规则浅色长丝进行双面编织互锁,以制造这些浅色不透明的生物基服装。更为具体的,所述挤出长丝和普通长丝仅保留在每一侧上,而不出现在另一侧上,如图2至图4所示。拉伸和面料结构是基于如图4所示的编织长丝。最终面料的光泽非常暗淡,因此具备不透明性。
具体的,使用透明氨纶长丝作为基础长丝,将挤出长丝与所述透明氨纶长丝进行双面编织,使得所述透明氨纶长丝和所述挤出长丝在另一侧上可能不突出。所述透明氨纶长丝不仅结合两层编织物,而且为编织面料提供拉伸性。最后,由获得的面料缝合诸如上装和下装的服饰并检查其不透明性和亲水性。
本发明还提供一种面料,包括如以上任一方案所述的面料的制备方法制备而得到。
本发明还提供一种服饰,包括如以上任一方案所述的面料制备而得到。所述服饰的制备流程图如图5所示。
具体的,由于由细纱支数得到的双面编织结构,所以面料具有非常柔软的手感;另外,面料的正面含非常浅的颜色,使其精美诱人。最后,缝合具有部分生物基含量的浅色不透明亲水性回收合成面料以形成用于穿着者试验的服装。最终的面料具有持久的柔软度、亲水性和不透明性,甚至在重复洗涤之后,没有任何令人不快的松散化学涂层、内衬面料或多层面料。通过分析可以比较两种面料的不透明度。可见,不利用这些预设配方的纺液的面料使面料半透明;然而,具有所有相似的技术参数和颜色利用预设配方的纺液形成的面料提供不透明性。同样,在服装的情况下观察到这种效果。由给定方案制造的服装提供不透明性并且保证在其下层的内衣裤的不可见性,这对于具有相同技术参数的传统服装是不可能的。此外,由于在面料的内层中赋予亲水性,本发明导致更好的湿气管理和渗透性。
尽管本发明的应用不一定仅限于服装(上衣和下装),但他可能适用于需要类似特性的重要环境。此外,本发明的范围可以不限于所提及的两种合成纤维,即聚酯和尼龙,而是也可以应用于其他合成材料。令人感兴趣的是,通过在熔融纺丝过程中改变纺液配方,可以根据客户的需要微调该功能。
本发明旨在回收利用传统的合成纤维,从纺织废料合成部分生物基纤维,并促进对附加功能(包括不透明性和亲水性)的赋予。所提出的产品是可持续的,碳足迹较低,同时比传统的化石燃料基合成纤维更具功能性。
对于本领域技术人员而言,显然本发明不限于上述示范性实施例的细节,而且在不背离本发明的精神或基本特征的情况下,能够以其他的具体形式实现本发明。因此,无论从哪一点来看,均应将实施例看作是示范性的,而且是非限制性的,本发明的范围由所附权利要求而不是上述说明限定,因此旨在将落在权利要求的等同要件的含义和范围内的所有变化囊括在本发明内。不应将权利要求中的任何附图标记视为限制所涉及的权利要求。
此外,应当理解,虽然本说明书按照实施方式加以描述,但并非每个实施方式仅包含一个独立的技术方案,说明书的这种叙述方式仅仅是为清楚起见,本领域技术人员应当将说明书作为一个整体,各实施例中的技术方案也可以经适当组合,形成本领域技术人员可以理解的其他实施方式。

Claims (9)

1.一种面料的制备方法,其特征在于,包括:
基于纺织废料得到生物基合成纤维切片;
采用预设配方的纺液从所述生物基合成纤维切片中得到挤出长丝;
以生物基弹力纤维为基础长丝和所述挤出长丝进行编织互锁,以得到所述面料。
2.根据权利要求1所述的面料的制备方法,其特征在于:所述生物基合成纤维切片包括聚对苯二甲酸乙二醇酯切片和尼龙切片;所述基于纺织废料得到生物基合成纤维切片包括:
从所述纺织废料中回收聚对苯二甲酸乙二醇酯和尼龙;
对所述聚对苯二甲酸乙二醇酯在分子水平上解聚成对苯二甲酸二甲酯;
将所述对苯二甲酸二甲酯与生物基-MEG反应以得到所述聚对苯二甲酸乙二醇酯切片;
对所述尼龙在分子水平上解聚成对己二酸;
将所述对己二酸与生物基1,5-戊烷二胺反应以得到所述尼龙切片。
3.根据权利要求2所述的面料的制备方法,其特征在于:
对所述聚对苯二甲酸乙二醇酯在分子水平上解聚成对苯二甲酸二甲酯之后,在所述对苯二甲酸二甲酯与所述生物基-MEG反应之前,还包括对所述对苯二甲酸二甲酯进行纯化处理的步骤;
对所述尼龙在分子水平上解聚成对己二酸之后,在所述对己二酸与所述生物基1,5-戊烷二胺反应之前,还包括对所述对己二酸进行纯化处理的步骤。
4.根据权利要求3所述的面料的制备方法,其特征在于:基于闭环重结晶工艺对所述对苯二甲酸二甲酯进行纯化处理,基于闭环重结晶工艺对所述对己二酸进行纯化处理。
5.根据权利要求1所述的面料的制备方法,其特征在于:所述预设配方的纺液包括:氨基甲酸乙酯、TiO2、二甘醇、丙烯腈-丁二烯-苯乙烯、炭黑和增粘剂。
6.根据权利要求1所述的面料的制备方法,其特征在于:以生物基弹力纤维为基础长丝和所述挤出长丝进行编织互锁之前,所述生物基弹力纤维和所述挤出长丝分别位于编织中线相对的两侧。
7.根据权利要求1至6中任一项所述的面料的制备方法,其特征在于:所述生物基弹力纤维包括透明氨纶长丝。
8.一种面料,其特征在于,所述面料采用如权利要求1至7中任一项所述的面料的制备方法制备而得到。
9.一种服饰,其特征在于:所述服饰采用如权利要求8所述的面料制备而得到。
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Application publication date: 20211210