CN113696570B - 一种高色牢度耐水洗的聚乙烯面料及其制备工艺 - Google Patents

一种高色牢度耐水洗的聚乙烯面料及其制备工艺 Download PDF

Info

Publication number
CN113696570B
CN113696570B CN202111002261.3A CN202111002261A CN113696570B CN 113696570 B CN113696570 B CN 113696570B CN 202111002261 A CN202111002261 A CN 202111002261A CN 113696570 B CN113696570 B CN 113696570B
Authority
CN
China
Prior art keywords
parts
polyethylene
fabric
water
color
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN202111002261.3A
Other languages
English (en)
Other versions
CN113696570A (zh
Inventor
翁星星
刘涛涛
陈朝晖
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Housheng New Energy Technology Co Ltd
Original Assignee
Jiangsu Housheng New Energy Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangsu Housheng New Energy Technology Co Ltd filed Critical Jiangsu Housheng New Energy Technology Co Ltd
Priority to CN202111002261.3A priority Critical patent/CN113696570B/zh
Publication of CN113696570A publication Critical patent/CN113696570A/zh
Application granted granted Critical
Publication of CN113696570B publication Critical patent/CN113696570B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/006—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers provided for in C08G18/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
    • C09J151/08—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/07—Addition of substances to the spinning solution or to the melt for making fire- or flame-proof filaments
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/09—Addition of substances to the spinning solution or to the melt for making electroconductive or anti-static filaments
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/10—Other agents for modifying properties
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/44—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/46—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polyolefins
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
    • D06M11/55—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur trioxide; with sulfuric acid or thiosulfuric acid or their salts
    • D06M11/56—Sulfates or thiosulfates other than of elements of Groups 3 or 13 of the Periodic System
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/325—Amines
    • D06M13/328—Amines the amino group being bound to an acyclic or cycloaliphatic carbon atom
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/61—Polyamines polyimines
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/60—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
    • D06P1/613—Polyethers without nitrogen
    • D06P1/6138—Polymerisation products of glycols, e.g. Carbowax, Pluronics
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/642—Compounds containing nitrogen
    • D06P1/645—Aliphatic, araliphatic or cycloaliphatic compounds containing amino groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/642—Compounds containing nitrogen
    • D06P1/649—Compounds containing carbonamide, thiocarbonamide or guanyl groups
    • D06P1/6494—Compounds containing a guanyl group R-C-N=, e.g. (bi)guanadine, dicyandiamid amidines
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/651—Compounds without nitrogen
    • D06P1/65106—Oxygen-containing compounds
    • D06P1/65131—Compounds containing ether or acetal groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/653—Nitrogen-free carboxylic acids or their salts
    • D06P1/6533—Aliphatic, araliphatic or cycloaliphatic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673—Inorganic compounds
    • D06P1/67333—Salts or hydroxides
    • D06P1/67341—Salts or hydroxides of elements different from the alkaline or alkaline-earth metals or with anions containing those elements
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/79—Polyolefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02—Synthetic macromolecular fibres
    • B32B2262/0253—Polyolefin fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/20—Properties of the layers or laminate having particular electrical or magnetic properties, e.g. piezoelectric
    • B32B2307/21—Anti-static
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/30—Properties of the layers or laminate having particular thermal properties
    • B32B2307/306—Resistant to heat
    • B32B2307/3065—Flame resistant or retardant, fire resistant or retardant
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/714—Inert, i.e. inert to chemical degradation, corrosion
    • B32B2307/7145—Rot proof, resistant to bacteria, mildew, mould, fungi
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/06—Polyethene
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/20—Polyalkenes, polymers or copolymers of compounds with alkenyl groups bonded to aromatic groups

Abstract

本发明公开了一种高色牢度耐水洗的聚乙烯面料及其制备工艺。所述一种高色牢度耐水洗的聚乙烯面料包括聚乙烯基础面料、聚乙烯膜、粘结剂胶膜，所述聚乙烯基础面料和聚乙烯膜之间通过粘结剂胶膜复合。所述聚乙烯基础面料所需材料包括，以重量计：聚乙烯织物15‑30份、染料1‑10份、盐酸0.5‑1份、三羟甲基氨基甲烷0.5‑1份、盐酸多巴胺0.1‑0.4份、聚乙烯亚胺0.2‑0.5份、无水硫酸铜1‑3份。本发明通过对超高分子量聚乙烯进行表面接枝，提高面料的抗菌性能和舒适性，染料中加入固色剂、光稳定剂增强了面料的耐水洗色牢度、耐光色牢度。

Description

一种高色牢度耐水洗的聚乙烯面料及其制备工艺
技术领域
本发明涉及聚乙烯面料技术领域，具体为一种高色牢度耐水洗的聚乙烯面料及其制备工艺。
背景技术
聚乙烯面料具有强度高、密度低、绝缘性佳等优点，主要用于生产各种工业用纺织品，用途广泛。
聚乙烯因价格较低，是最常用的塑料聚合物，具有稳定的化学性质、耐光性差。市面上常见的聚乙烯面料耐水洗色牢度差，经过多次水洗，会发生褪色的现象，使用时间过长，易老化，发生电荷堆积，不耐静电，且舒适性也欠佳，因此发明一种高色牢度耐水洗的聚乙烯面料尤为重要。
发明内容
本发明的目的在于提供一种高色牢度耐水洗的聚乙烯面料及其制备工艺，以解决上述背景技术中提出的问题。
为了解决上述技术问题，本发明提供如下技术方案：
所述制备工艺包括以下步骤：
S1：染料的制备：将染色剂、[2-羟基-4-(辛氧基)苯基]苯基酮、固色剂和一半的水混合均匀，砂磨20-30min，加入至剩余水中，搅拌均匀，升温至40-60℃，加入聚乙二醇，搅拌0.5-1h；
S2：聚乙烯织物的制备：在超高分子量聚乙烯中加入烷基磺酸钠、2，6-三级丁基-4-甲基苯酚、氢氧化镁，混合均匀，形成纤维，进行织造；
S3：聚乙烯基础面料的制备：将聚乙烯织物浸泡于盐酸多巴胺混合溶液中，再用染料进行染色；
S4：聚乙烯膜的制备：取超高分子量聚乙烯树脂，加热成熔融状，双向拉伸；
S5：聚乙烯面料的制备：将聚乙烯基础面料置于辊轧机上，表面覆上粘结剂胶膜，然后覆盖聚乙烯膜，设置工作温度为100-135℃，辊轧。
作为优化，所述S1步骤中的染料所需材料包括，以重量计：水30-50份、染色剂5-15份、[2-羟基-4-(辛氧基)苯基]苯基酮10-15份、固色剂10-15份、聚乙二醇2-8份。
作为优化，所述固色剂制备工艺为：
A：在水中加入氯化铵，混合均匀，使用氮气保护，升温至70-90℃；
B：加入二乙烯三胺，调节pH至9-10；
C：加入双氰胺，混合均匀，升温至130-150℃，反应40-50min，降温至80-100℃，加水，用冰醋酸调节pH至6.5-7，即得固色剂。
面料经过多次洗涤，会出现染料迁移和褪色的问题，加入固色剂提高染料的固色能力，而且提高了面料的耐水洗色牢度和耐碱汗色牢度，此外，又加入了[2-羟基-4-(辛氧基)苯基]苯基酮作为光稳定剂，提高了上染率，也增强了耐光色牢度，使面料具有高色牢度。
作为优化，所述固色剂所需材料包括，以重量计：水60-80份、氯化铵10-35份、二乙烯三胺10-20份、双氰胺20-30份、冰醋酸20-30份。
作为优化，所述S3步骤中聚乙烯基础面料制备工艺为：
A：盐酸调节三羟甲基氨基甲烷水溶液pH至8-9，加入盐酸多巴胺和聚乙烯亚胺混合均匀；
B：将聚乙烯织物浸泡10-12h，反复洗涤，干燥后于无水硫酸铜水溶液中搅拌1-2h，洗涤，干燥；
C：干燥后浸泡于染料中，100-110℃浸泡1-2h，染色结束后，即得聚乙烯基础面料。
使用盐酸多巴胺在织物表面形成牢固涂覆层，对超高分子量聚乙烯织物进行接枝改性，提高面料的抗菌性，再将铜固定在织物表面，是聚乙烯面料舒适性提升。
超高分子量聚乙烯具有优异的耐化学性，染色难度大，在100-110℃下浸泡1-2h染色，颜色深度有所提升，提高其上染率，染料中因具有固色剂和光稳定剂，使得颜料与面料的附着力强，且耐摩擦色牢度、耐洗色牢度均有所提升。
作为优化，所述聚乙烯织物所需材料包括，以重量计：超高分子量聚乙烯30-50份、烷基磺酸钠0.5-2份、2，6-三级丁基-4-甲基苯酚0.2-0.5份、氢氧化镁0.2-0.5份。
作为优化，所述聚乙烯基础面料所需材料包括，以重量计：聚乙烯织物15-30份、染料1-10份、盐酸0.5-1份、三羟甲基氨基甲烷0.5-1份、盐酸多巴胺0.1-0.4份、聚乙烯亚胺0.2-0.5份、无水硫酸铜1-3份。
作为优化，所述粘结剂胶膜制备工艺为：
A：将聚碳酸酯二醇100-120℃真空脱水1-2h，加入异佛尔酮二异氰酸酯、1-4丁二醇、有机铋催化剂，混合均匀，通氮气保护，70-90℃下反应1-2h；
B：加入2，2-二羟甲基丙酸继续反应1-2h，降温至40-50℃，加入甲基丙烯酸甲酯、丙烯酸丁酯、三乙胺后反应15-30min，加入水混合均匀，升温至70-90℃；
C：加入偶氮二异丁腈，反应3-5h，减压蒸馏，冷却后铺在聚四氟乙烯模板上，成膜2-3h，烘箱内脱模即得粘结剂胶膜。
丙烯酸树脂在粘结过程中耐候性差，易出现褪色、变色的现象，采用丙烯酸树脂对聚氨酯进行改性，制成了聚氨酯-丙烯酸树脂复合胶粘剂，提高了聚乙烯基础面料和聚乙烯膜的粘结性、耐候性、耐水洗色牢度，制成的聚乙烯面料柔软亲肤。
作为优化，所述粘结剂胶膜所需材料包括，以重量计：聚碳酸酯二醇20-30份、异佛尔酮二异氰酸酯25-30份、1-4丁二醇2-6份、有机铋1-5份、2，2-二羟甲基丙酸1-5份、甲基丙烯酸甲酯5-20份、丙烯酸丁酯5-15份、三乙胺2-5份、水20-40份、偶氮二异丁腈5-10份。
作为优化，根据以上所述的一种高色牢度耐水洗的聚乙烯面料的制备工艺制备的聚乙烯面料。
与现有技术相比，本发明所达到的有益效果是：本发明制成的聚乙烯面料具有高色牢度，采用超高分子量聚乙烯，加入烷基磺酸钠、2，6-三级丁基-4-甲基苯酚、氢氧化镁，使聚乙烯面料具有防静电、耐老化、阻燃的优点，使用高温常压进行染色，使燃料可以渗透至面料内部，增强上染率，染料中加入固色剂以及光稳定剂使聚乙烯面料具有耐水洗色牢度、耐光色牢度，对超高分子量聚乙烯织物进行表面接枝，提高了面料的抑菌性，穿着舒适，采用聚氨酯-丙烯酸树脂作为胶粘剂，减少了胶膜易发黏的缺陷，提高了面料的耐水洗色牢度。
具体实施方式
下面将对本发明实施例中的技术方案进行清楚、完整地描述，显然，所描述的实施例仅仅是本发明一部分实施例，而不是全部的实施例。基于本发明中的实施例，本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例，都属于本发明保护的范围。
实施例1：所述制备工艺包括以下步骤：
S1：染料的制备：将染色剂、[2-羟基-4-(辛氧基)苯基]苯基酮、固色剂和一半的水混合均匀，砂磨20min，加入至剩余水中，搅拌均匀，升温至40℃，加入聚乙二醇，搅拌0.5h；
S2：聚乙烯织物的制备：在超高分子量聚乙烯中加入烷基磺酸钠、2，6-三级丁基-4-甲基苯酚、氢氧化镁，混合均匀，形成纤维，进行织造；
S3：聚乙烯基础面料的制备：将聚乙烯织物浸泡于盐酸多巴胺混合溶液中，再用染料进行染色；
S4：聚乙烯膜的制备：取超高分子量聚乙烯树脂，加热成熔融状，双向拉伸；
S5：聚乙烯面料的制备：将聚乙烯基础面料置于辊轧机上，表面覆上粘结剂胶膜，然后覆盖聚乙烯膜，设置工作温度为100℃，辊轧。
所述S1步骤中的染料所需材料包括，以重量计：水30份、染色剂5份、[2-羟基-4-(辛氧基)苯基]苯基酮10份、固色剂10份、聚乙二醇2份。
所述固色剂制备工艺为：
A：在水中加入氯化铵，混合均匀，使用氮气保护，升温至70℃；
B：加入二乙烯三胺，调节pH至9；
C：加入双氰胺，混合均匀，升温至130℃，反应40min，降温至80℃，加水，用冰醋酸调节pH至6.5，即得固色剂。
所述固色剂所需材料包括，以重量计：水60份、氯化铵10份、二乙烯三胺10份、双氰胺20份、冰醋酸20份。
所述S3步骤中聚乙烯基础面料制备工艺为：
A：盐酸调节三羟甲基氨基甲烷水溶液pH至8，加入盐酸多巴胺和聚乙烯亚胺混合均匀；
B：将聚乙烯织物浸泡10h，反复洗涤，干燥后于无水硫酸铜水溶液中搅拌1h，洗涤，干燥；
C：干燥后浸泡于染料中，100℃浸泡1h，染色结束后，即得聚乙烯基础面料。
所述聚乙烯织物所需材料包括，以重量计：超高分子量聚乙烯30份、烷基磺酸钠0.5份、2，6-三级丁基-4-甲基苯酚0.2份、氢氧化镁0.2份。
所述聚乙烯基础面料所需材料包括，以重量计：聚乙烯织物15份、染料1份、盐酸0.5份、三羟甲基氨基甲烷0.5份、盐酸多巴胺0.1份、聚乙烯亚胺0.2份、无水硫酸铜1份。
所述粘结剂胶膜制备工艺为：
A：将聚碳酸酯二醇100℃真空脱水1h，加入异佛尔酮二异氰酸酯、1-4丁二醇、有机铋催化剂，混合均匀，通氮气保护，70℃下反应1h；
B：加入2，2-二羟甲基丙酸继续反应1h，降温至40℃，加入甲基丙烯酸甲酯、丙烯酸丁酯、三乙胺后反应15min，加入水混合均匀，升温至70℃；
C：加入偶氮二异丁腈，反应3-5h，减压蒸馏，冷却后铺在聚四氟乙烯模板上，成膜2h，烘箱内脱模即得粘结剂胶膜。
所述粘结剂胶膜所需材料包括，以重量计：聚碳酸酯二醇20份、异佛尔酮二异氰酸酯25份、1-4丁二醇2份、有机铋1份、2，2-二羟甲基丙酸1份、甲基丙烯酸甲酯5份、丙烯酸丁酯5份、三乙胺2份、水20份、偶氮二异丁腈5份。
实施例2：所述制备工艺包括以下步骤：
S1：染料的制备：将染色剂、[2-羟基-4-(辛氧基)苯基]苯基酮、固色剂和一半的水混合均匀，砂磨23min，加入至剩余水中，搅拌均匀，升温至45℃，加入聚乙二醇，搅拌0.6h；
S2：聚乙烯织物的制备：在超高分子量聚乙烯中加入烷基磺酸钠、2，6-三级丁基-4-甲基苯酚、氢氧化镁，混合均匀，形成纤维，进行织造；
S3：聚乙烯基础面料的制备：将聚乙烯织物浸泡于盐酸多巴胺混合溶液中，再用染料进行染色；
S4：聚乙烯膜的制备：取超高分子量聚乙烯树脂，加热成熔融状，双向拉伸；
S5：聚乙烯面料的制备：将聚乙烯基础面料置于辊轧机上，表面覆上粘结剂胶膜，然后覆盖聚乙烯膜，设置工作温度为110℃，辊轧。
所述S1步骤中的染料所需材料包括，以重量计：水35份、染色剂8份、[2-羟基-4-(辛氧基)苯基]苯基酮12份、固色剂11份、聚乙二醇4份。
所述固色剂制备工艺为：
A：在水中加入氯化铵，混合均匀，使用氮气保护，升温至75℃；
B：加入二乙烯三胺，调节pH至9.3；
C：加入双氰胺，混合均匀，升温至135℃，反应43min，降温至90℃，加水，用冰醋酸调节pH至6.7，即得固色剂。
所述固色剂所需材料包括，以重量计：水65份、氯化铵15份、二乙烯三胺13份、双氰胺23份、冰醋酸22份。
所述S3步骤中聚乙烯基础面料制备工艺为：
A：盐酸调节三羟甲基氨基甲烷水溶液pH至8.3，加入盐酸多巴胺和聚乙烯亚胺混合均匀；
B：将聚乙烯织物浸泡10.5h，反复洗涤，干燥后于无水硫酸铜水溶液中搅拌1.5h，洗涤，干燥；
C：干燥后浸泡于染料中，105℃浸泡1.5h，染色结束后，即得聚乙烯基础面料。
所述聚乙烯织物所需材料包括，以重量计：超高分子量聚乙烯35份、烷基磺酸钠1份、2，6-三级丁基-4-甲基苯酚0.3份、氢氧化镁0.3份。
所述聚乙烯基础面料所需材料包括，以重量计：聚乙烯织物20份、染料5份、盐酸0.7份、三羟甲基氨基甲烷0.8份、盐酸多巴胺0.2份、聚乙烯亚胺0.3份、无水硫酸铜2份。
所述粘结剂胶膜制备工艺为：
A：将聚碳酸酯二醇105℃真空脱水1.5h，加入异佛尔酮二异氰酸酯、1-4丁二醇、有机铋催化剂，混合均匀，通氮气保护，75℃下反应1.5h；
B：加入2，2-二羟甲基丙酸继续反应1.5h，降温至45℃，加入甲基丙烯酸甲酯、丙烯酸丁酯、三乙胺后反应20min，加入水混合均匀，升温至75℃；
C：加入偶氮二异丁腈，反应3.5h，减压蒸馏，冷却后铺在聚四氟乙烯模板上，成膜2.5h，烘箱内脱模即得粘结剂胶膜。
所述粘结剂胶膜所需材料包括，以重量计：聚碳酸酯二醇22份、异佛尔酮二异氰酸酯26份、1-4丁二醇3份、有机铋3份、2，2-二羟甲基丙酸3份、甲基丙烯酸甲酯10份、丙烯酸丁酯8份、三乙胺3份、水25份、偶氮二异丁腈6份。
实施例3：所述制备工艺包括以下步骤：
S1：染料的制备：将染色剂、[2-羟基-4-(辛氧基)苯基]苯基酮、固色剂和一半的水混合均匀，砂磨25min，加入至剩余水中，搅拌均匀，升温至50℃，加入聚乙二醇，搅拌0.8h；
S2：聚乙烯织物的制备：在超高分子量聚乙烯中加入烷基磺酸钠、2，6-三级丁基-4-甲基苯酚、氢氧化镁，混合均匀，形成纤维，进行织造；
S3：聚乙烯基础面料的制备：将聚乙烯织物浸泡于盐酸多巴胺混合溶液中，再用染料进行染色；
S4：聚乙烯膜的制备：取超高分子量聚乙烯树脂，加热成熔融状，双向拉伸；
S5：聚乙烯面料的制备：将聚乙烯基础面料置于辊轧机上，表面覆上粘结剂胶膜，然后覆盖聚乙烯膜，设置工作温度为120℃，辊轧。
所述S1步骤中的染料所需材料包括，以重量计：水40份、染色剂10份、[2-羟基-4-(辛氧基)苯基]苯基酮13份、固色剂13份、聚乙二醇6份。
所述固色剂制备工艺为：
A：在水中加入氯化铵，混合均匀，使用氮气保护，升温至80℃；
B：加入二乙烯三胺，调节pH至9.8；
C：加入双氰胺，混合均匀，升温至140℃，反应45min，降温至95℃，加水，用冰醋酸调节pH至6.8，即得固色剂。
所述固色剂所需材料包括，以重量计：水70份、氯化铵20份、二乙烯三胺18份、双氰胺25份、冰醋酸25份。
所述S3步骤中聚乙烯基础面料制备工艺为：
A：盐酸调节三羟甲基氨基甲烷水溶液pH至8.5，加入盐酸多巴胺和聚乙烯亚胺混合均匀；
B：将聚乙烯织物浸泡11h，反复洗涤，干燥后于无水硫酸铜水溶液中搅拌1.8h，洗涤，干燥；
C：干燥后浸泡于染料中，108℃浸泡1.8h，染色结束后，即得聚乙烯基础面料。
所述聚乙烯织物所需材料包括，以重量计：超高分子量聚乙烯40份、烷基磺酸钠1.5份、2，6-三级丁基-4-甲基苯酚0.4份、氢氧化镁0.4份。
所述聚乙烯基础面料所需材料包括，以重量计：聚乙烯织物25份、染料8份、盐酸0.9份、三羟甲基氨基甲烷0.9份、盐酸多巴胺0.3份、聚乙烯亚胺0.4份、无水硫酸铜2.5份。
所述粘结剂胶膜制备工艺为：
A：将聚碳酸酯二醇110℃真空脱水1.8h，加入异佛尔酮二异氰酸酯、1-4丁二醇、有机铋催化剂，混合均匀，通氮气保护，80℃下反应1.8h；
B：加入2，2-二羟甲基丙酸继续反应1.8h，降温至48℃，加入甲基丙烯酸甲酯、丙烯酸丁酯、三乙胺后反应25min，加入水混合均匀，升温至80℃；
C：加入偶氮二异丁腈，反应4h，减压蒸馏，冷却后铺在聚四氟乙烯模板上，成膜2.8h，烘箱内脱模即得粘结剂胶膜。
所述S3步骤中的粘结剂胶膜所需材料包括，以重量计：聚碳酸酯二醇25份、异佛尔酮二异氰酸酯28份、1-4丁二醇5份、有机铋4份、2，2-二羟甲基丙酸4份、甲基丙烯酸甲酯15份、丙烯酸丁酯10份、三乙胺4份、水30份、偶氮二异丁腈8份。
实施例4：所述制备工艺包括以下步骤：
S1：染料的制备：将染色剂、[2-羟基-4-(辛氧基)苯基]苯基酮、固色剂和一半的水混合均匀，砂磨30min，加入至剩余水中，搅拌均匀，升温至60℃，加入聚乙二醇，搅拌1h；
S2：聚乙烯织物的制备：在超高分子量聚乙烯中加入烷基磺酸钠、2，6-三级丁基-4-甲基苯酚、氢氧化镁，混合均匀，形成纤维，进行织造；
S3：聚乙烯基础面料的制备：将聚乙烯织物浸泡于盐酸多巴胺混合溶液中，再用染料进行染色；
S4：聚乙烯膜的制备：取超高分子量聚乙烯树脂，加热成熔融状，双向拉伸；
S5：聚乙烯面料的制备：将聚乙烯基础面料置于辊轧机上，表面覆上粘结剂胶膜，然后覆盖聚乙烯膜，设置工作温度为135℃，辊轧。
所述S1步骤中的染料所需材料包括，以重量计：水50份、染色剂15份、[2-羟基-4-(辛氧基)苯基]苯基酮15份、固色剂15份、聚乙二醇8份。
所述固色剂制备工艺为：
A：在水中加入氯化铵，混合均匀，使用氮气保护，升温至90℃；
B：加入二乙烯三胺，调节pH至10；
C：加入双氰胺，混合均匀，升温至150℃，反应50min，降温至100℃，加水，用冰醋酸调节pH至7，即得固色剂。
所述固色剂所需材料包括，以重量计：水80份、氯化铵35份、二乙烯三胺20份、双氰胺30份、冰醋酸30份。
所述S3步骤中聚乙烯基础面料制备工艺为：
A：盐酸调节三羟甲基氨基甲烷水溶液pH至9，加入盐酸多巴胺和聚乙烯亚胺混合均匀；
B：将聚乙烯织物浸泡12h，反复洗涤，干燥后于无水硫酸铜水溶液中搅拌2h，洗涤，干燥；
C：干燥后浸泡于染料中，110℃浸泡2h，染色结束后，即得聚乙烯基础面料。
所述聚乙烯织物所需材料包括，以重量计：超高分子量聚乙烯50份、烷基磺酸钠2份、2，6-三级丁基-4-甲基苯酚0.5份、氢氧化镁0.5份.
所述聚乙烯基础面料所需材料包括，以重量计：聚乙烯织物30份、染料10份、盐酸1份、三羟甲基氨基甲烷1份、盐酸多巴胺0.4份、聚乙烯亚胺0.5份、无水硫酸铜3份。
所述粘结剂胶膜制备工艺为：
A：将聚碳酸酯二醇120℃真空脱水2h，加入异佛尔酮二异氰酸酯、1-4丁二醇、有机铋催化剂，混合均匀，通氮气保护，90℃下反应2h；
B：加入2，2-二羟甲基丙酸继续反应2h，降温至50℃，加入甲基丙烯酸甲酯、丙烯酸丁酯、三乙胺后反应30min，加入水混合均匀，升温至90℃；
C：加入偶氮二异丁腈，反应5h，减压蒸馏，冷却后铺在聚四氟乙烯模板上，成膜3h，烘箱内脱模即得粘结剂胶膜。
所述粘结剂胶膜所需材料包括，以重量计：聚碳酸酯二醇30份、异佛尔酮二异氰酸酯30份、1-4丁二醇6份、有机铋5份、2，2-二羟甲基丙酸5份、甲基丙烯酸甲酯20份、丙烯酸丁酯15份、三乙胺5份、水40份、偶氮二异丁腈10份。
对比例
对比例1：与实施例2做对比，原料中不对超高分子量聚乙烯树脂进行接枝改性，制备工艺于本文相同。
对比例2：与实施例2做对比，染料中不加入固色剂和光稳定剂，制备工艺于本文相同。
实验数据
对实施例1至实施例4、对比例1、对比例2按GB/T20944.3-2008、GB/T3921-2008、GB/T8427-1998进行以下实验，实验数据见下表。
结论：对实施例1至实施例4制备的聚乙烯面料具有耐水洗色牢度、耐光色牢度、抗菌性以及舒适性。
最后应说明的是：以上所述仅为本发明的优选实施例而已，并不用于限制本发明，尽管参照前述实施例对本发明进行了详细的说明，对于本领域的技术人员来说，其依然可以对前述各实施例所记载的技术方案进行修改，或者对其中部分技术特征进行等同替换。凡在本发明的精神和原则之内，所作的任何修改、等同替换、改进等，均应包含在本发明的保护范围之内。

Claims (7)

1.一种高色牢度耐水洗的聚乙烯面料的制备工艺，其特征在于：所述制备工艺包括以下步骤：
S1：染料的制备：将染色剂、[2-羟基-4-(辛氧基)苯基]苯基酮、固色剂和一半的水混合均匀，砂磨20-30min，加入至剩余水中，搅拌均匀，升温至40-60℃，加入聚乙二醇，搅拌0.5-1h；
S2：聚乙烯织物的制备：在超高分子量聚乙烯中加入烷基磺酸钠、2，6-三级丁基-4-甲基苯酚、氢氧化镁，混合均匀，形成纤维，进行织造；
S3：聚乙烯基础面料的制备：将聚乙烯织物浸泡于盐酸多巴胺混合溶液中，再用染料进行染色；
S4：聚乙烯膜的制备：取超高分子量聚乙烯树脂，加热成熔融状，双向拉伸；
S5：聚乙烯面料的制备：将聚乙烯基础面料置于辊轧机上，表面覆上粘结剂胶膜，然后覆盖聚乙烯膜，设置工作温度为100-135℃，辊轧；
所述固色剂制备工艺为：
A：在水中加入氯化铵，混合均匀，使用氮气保护，升温至70-90℃；
B：加入二乙烯三胺，调节pH至9-10；
C：加入双氰胺，混合均匀，升温至130-150℃，反应40-50min，降温至80-100℃，加水，用冰醋酸调节pH至6.5-7，即得固色剂；
所述S3步骤中聚乙烯基础面料制备工艺为：
A：盐酸调节三羟甲基氨基甲烷水溶液pH至8-9，加入盐酸多巴胺和聚乙烯亚胺混合均匀；
B：将聚乙烯织物浸泡10-12h，反复洗涤，干燥后于无水硫酸铜水溶液中搅拌1-2h，洗涤，干燥；
C：干燥后浸泡于染料中，100-110℃浸泡1-2h，染色结束后，即得聚乙烯基础面料；
所述粘结剂胶膜制备工艺为：
A：将聚碳酸酯二醇100-120℃真空脱水1-2h，加入异佛尔酮二异氰酸酯、1-4丁二醇、有机铋催化剂，混合均匀，通氮气保护，70-90℃下反应1-2h；
B：加入2，2-二羟甲基丙酸继续反应1-2h，降温至40-50℃，加入甲基丙烯酸甲酯、丙烯酸丁酯、三乙胺后反应15-30min，加入水混合均匀，升温至70-90℃；
C：加入偶氮二异丁腈，反应3-5h，减压蒸馏，冷却后铺在聚四氟乙烯模板上，成膜2-3h，烘箱内脱模即得粘结剂胶膜。
2.根据权利要求1所述的一种高色牢度耐水洗的聚乙烯面料的制备工艺，其特征在于：所述S1步骤中的染料所需材料包括，以重量计：水30-50份、染色剂5-15份、[2-羟基-4-(辛氧基)苯基]苯基酮10-15份、固色剂10-15份、聚乙二醇2-8份。
3.根据权利要求1所述的一种高色牢度耐水洗的聚乙烯面料的制备工艺，其特征在于：所述固色剂所需材料包括，以重量计：水60-80份、氯化铵10-35份、二乙烯三胺10-20份、双氰胺20-30份、冰醋酸20-30份。
4.根据权利要求1所述的一种高色牢度耐水洗的聚乙烯面料的制备工艺，其特征在于：所述聚乙烯织物所需材料包括，以重量计：超高分子量聚乙烯30-50份、烷基磺酸钠0.5-2份2，6-三级丁基-4-甲基苯酚0.2-0.5份、氢氧化镁0.2-0.5份。
5.根据权利要求1所述的一种高色牢度耐水洗的聚乙烯面料的制备工艺，其特征在于：所述聚乙烯基础面料所需材料包括，以重量计：聚乙烯织物15-30份、染料1-10份、盐酸0.5-1份、三羟甲基氨基甲烷0.5-1份、盐酸多巴胺0.1-0.4份、聚乙烯亚胺0.2-0.5份、无水硫酸铜1-3份。
6.根据权利要求1所述的一种高色牢度耐水洗的聚乙烯面料的制备工艺，其特征在于：所述粘结剂胶膜所需材料包括，以重量计：聚碳酸酯二醇20-30份、异佛尔酮二异氰酸酯25-30份、1-4丁二醇2-6份、有机铋1-5份、2，2-二羟甲基丙酸1-5份、甲基丙烯酸甲酯5-20份、丙烯酸丁酯5-15份、三乙胺2-5份、水20-40份、偶氮二异丁腈5-10份。
7.根据权利要求1～6中任一项所述的一种高色牢度耐水洗的聚乙烯面料的制备工艺制备的聚乙烯面料。
CN202111002261.3A 2021-08-30 2021-08-30 一种高色牢度耐水洗的聚乙烯面料及其制备工艺 Active CN113696570B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202111002261.3A CN113696570B (zh) 2021-08-30 2021-08-30 一种高色牢度耐水洗的聚乙烯面料及其制备工艺

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202111002261.3A CN113696570B (zh) 2021-08-30 2021-08-30 一种高色牢度耐水洗的聚乙烯面料及其制备工艺

Publications (2)

Publication Number Publication Date
CN113696570A CN113696570A (zh) 2021-11-26
CN113696570B true CN113696570B (zh) 2023-09-22

Family

ID=78656598

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202111002261.3A Active CN113696570B (zh) 2021-08-30 2021-08-30 一种高色牢度耐水洗的聚乙烯面料及其制备工艺

Country Status (1)

Country Link
CN (1) CN113696570B (zh)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114775310A (zh) * 2022-05-24 2022-07-22 浙江爱利斯染整有限公司 麂皮绒面料的耐水洗砂洗染色工艺
CN115233454A (zh) * 2022-06-30 2022-10-25 海宁市饰雅纺织有限公司 一种仿羊皮手感烫金沙发面料生产工艺

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102797170A (zh) * 2012-09-06 2012-11-28 苏州联胜化学有限公司 一种无醛固色剂及其制备方法
CN104452035A (zh) * 2014-11-21 2015-03-25 绍兴市南门防静电纺织有限公司 一种户外、工装防护有色面料的生产方法
CN106049102A (zh) * 2016-05-30 2016-10-26 太仓红桥服饰有限公司 一种服装用织物固色剂及其制备方法
CN109016764A (zh) * 2018-10-09 2018-12-18 湖北冠誉塑料包装股份有限公司 一种超高分子量聚乙烯膜复合面料及其制备工艺
CN109457536A (zh) * 2018-11-02 2019-03-12 广东天元汇邦新材料股份有限公司 一种无甲醛的装饰胶膜纸及其制备方法
CN113026396A (zh) * 2021-04-08 2021-06-25 绍兴盛鑫印染有限公司 一种固色剂及应用该固色剂的棉布轧染染色工艺
CN113201939A (zh) * 2021-05-10 2021-08-03 浙江理工大学上虞工业技术研究院有限公司 一种抑菌剂及其应用、超高分子量聚乙烯抑菌纤维及其制备方法

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102797170A (zh) * 2012-09-06 2012-11-28 苏州联胜化学有限公司 一种无醛固色剂及其制备方法
CN104452035A (zh) * 2014-11-21 2015-03-25 绍兴市南门防静电纺织有限公司 一种户外、工装防护有色面料的生产方法
CN106049102A (zh) * 2016-05-30 2016-10-26 太仓红桥服饰有限公司 一种服装用织物固色剂及其制备方法
CN109016764A (zh) * 2018-10-09 2018-12-18 湖北冠誉塑料包装股份有限公司 一种超高分子量聚乙烯膜复合面料及其制备工艺
CN109457536A (zh) * 2018-11-02 2019-03-12 广东天元汇邦新材料股份有限公司 一种无甲醛的装饰胶膜纸及其制备方法
CN113026396A (zh) * 2021-04-08 2021-06-25 绍兴盛鑫印染有限公司 一种固色剂及应用该固色剂的棉布轧染染色工艺
CN113201939A (zh) * 2021-05-10 2021-08-03 浙江理工大学上虞工业技术研究院有限公司 一种抑菌剂及其应用、超高分子量聚乙烯抑菌纤维及其制备方法

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
刘建平.棉用固色剂.《染整助剂综合实训》.东华大学出版社,2011, *
商成杰.紫外光稳定剂SUV.《新型染整助剂手册》.中国纺织出版社,2022,第230页. *

Also Published As

Publication number Publication date
CN113696570A (zh) 2021-11-26

Similar Documents

Publication Publication Date Title
CN113696570B (zh) 一种高色牢度耐水洗的聚乙烯面料及其制备工艺
CN103603197B (zh) 一种改善超细纤维合成革基布染色性能的方法
CN112341597B (zh) 一种水性聚氨酯湿摩擦牢度提升剂的制备方法
CN103669041A (zh) 一种织物无醛固色剂及其制备方法
WO2021136412A1 (zh) 一种锦纶56与纤维素纤维混纺织物碱性轧染染色方法
CN111607990A (zh) 一种印花糊料的制备方法
CN113529428A (zh) 一种耐磨防穿刺面料及其加工工艺
CN104562793B (zh) 一种苎麻纤维织物改性后涂料染色的方法
CN113605114A (zh) 一种丝巾及其加工工艺
CN112553919A (zh) 一种涤棉一浴染色工艺
CN112813701A (zh) 天然姜黄素抗菌棉内衣用织物的制备方法
CN110670358A (zh) 一种浸轧交联成膜整理方法
CN112341594B (zh) 一种水性聚氨酯固色剂的制备方法
CN108384225B (zh) 一种高色牢度低熔点聚酰胺用色母粒
CN105421118A (zh) 一种新型环保无甲醛固色剂及其制备方法
CN115894911A (zh) 环氧改性超支化聚酰胺-胺高分子聚合物、制备方法及应用
CN110680171B (zh) 一种通过浸轧交联成膜制备遮光窗帘的方法
CN114750484A (zh) 一种长效抗污面料及其制备方法
CN106996046A (zh) 一种长效环保型固色剂的生产配方及生产工艺
CN113802240A (zh) 一种白坯布的制备工艺
CN112921682A (zh) 一种高效环保酸性固色剂及其制备方法
CN110835386A (zh) 聚二甲基二烯丙基氯化胺聚合物及其制备方法和应用
CN112482046A (zh) 一种无甲醛具有耐久光泽的棉织物加工方法
CN111809410A (zh) 一种涤纶面料的染色工艺
CN114293389B (zh) 一种改性功能性聚酯纤维上染酸性染料的染色工艺

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant