CN115233454A - 一种仿羊皮手感烫金沙发面料生产工艺 - Google Patents
一种仿羊皮手感烫金沙发面料生产工艺 Download PDFInfo
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- CN115233454A CN115233454A CN202210771037.9A CN202210771037A CN115233454A CN 115233454 A CN115233454 A CN 115233454A CN 202210771037 A CN202210771037 A CN 202210771037A CN 115233454 A CN115233454 A CN 115233454A
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- Prior art keywords
- fabric
- gold stamping
- production process
- glue
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000004744 fabric Substances 0.000 title claims abstract description 93
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 title claims abstract description 24
- 229910052737 gold Inorganic materials 0.000 title claims abstract description 24
- 239000010931 gold Substances 0.000 title claims abstract description 24
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 39
- 239000003513 alkali Substances 0.000 claims abstract description 33
- 239000003292 glue Substances 0.000 claims abstract description 25
- 239000004814 polyurethane Substances 0.000 claims abstract description 25
- 239000011347 resin Substances 0.000 claims abstract description 25
- 229920005989 resin Polymers 0.000 claims abstract description 25
- 238000004043 dyeing Methods 0.000 claims abstract description 18
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- 239000000986 disperse dye Substances 0.000 claims abstract description 14
- 238000001035 drying Methods 0.000 claims abstract description 13
- 238000007639 printing Methods 0.000 claims abstract description 12
- 239000002585 base Substances 0.000 claims abstract description 11
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 11
- 238000005406 washing Methods 0.000 claims abstract description 9
- CTENFNNZBMHDDG-UHFFFAOYSA-N Dopamine hydrochloride Chemical compound Cl.NCCC1=CC=C(O)C(O)=C1 CTENFNNZBMHDDG-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229960001149 dopamine hydrochloride Drugs 0.000 claims abstract description 7
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- 239000005056 polyisocyanate Substances 0.000 claims abstract description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 5
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- 150000007942 carboxylates Chemical class 0.000 claims abstract description 5
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- 239000003795 chemical substances by application Substances 0.000 claims description 18
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 18
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 18
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- 239000004721 Polyphenylene oxide Substances 0.000 claims description 9
- 150000002191 fatty alcohols Chemical class 0.000 claims description 9
- 229920000570 polyether Polymers 0.000 claims description 9
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 8
- 150000003242 quaternary ammonium salts Chemical group 0.000 claims description 8
- 229910052708 sodium Inorganic materials 0.000 claims description 8
- 239000011734 sodium Substances 0.000 claims description 8
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 8
- 235000011152 sodium sulphate Nutrition 0.000 claims description 8
- 239000002562 thickening agent Substances 0.000 claims description 8
- 239000002994 raw material Substances 0.000 claims description 7
- JHWGFJBTMHEZME-UHFFFAOYSA-N 4-prop-2-enoyloxybutyl prop-2-enoate Chemical group C=CC(=O)OCCCCOC(=O)C=C JHWGFJBTMHEZME-UHFFFAOYSA-N 0.000 claims description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 6
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- VBICKXHEKHSIBG-UHFFFAOYSA-N beta-monoglyceryl stearate Natural products CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 claims description 4
- QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 claims description 4
- 229910000365 copper sulfate Inorganic materials 0.000 claims description 4
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims description 4
- 238000007598 dipping method Methods 0.000 claims description 4
- 239000006185 dispersion Substances 0.000 claims description 4
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 claims description 4
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- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 claims description 4
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 4
- ABTOQLMXBSRXSM-UHFFFAOYSA-N silicon tetrafluoride Chemical compound F[Si](F)(F)F ABTOQLMXBSRXSM-UHFFFAOYSA-N 0.000 claims description 4
- 238000002791 soaking Methods 0.000 claims description 4
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 4
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 4
- 238000009210 therapy by ultrasound Methods 0.000 claims description 4
- 229920001451 polypropylene glycol Polymers 0.000 claims description 3
- 238000012546 transfer Methods 0.000 claims description 3
- 238000007781 pre-processing Methods 0.000 claims 1
- 239000000835 fiber Substances 0.000 abstract description 11
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- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- 238000012360 testing method Methods 0.000 description 12
- 238000003860 storage Methods 0.000 description 6
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- 238000000859 sublimation Methods 0.000 description 5
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- 230000000052 comparative effect Effects 0.000 description 4
- 238000007788 roughening Methods 0.000 description 4
- 229910010271 silicon carbide Inorganic materials 0.000 description 4
- 238000000034 method Methods 0.000 description 3
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- 230000002265 prevention Effects 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- 235000019687 Lamb Nutrition 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 125000003368 amide group Chemical group 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 230000003373 anti-fouling effect Effects 0.000 description 2
- 230000015271 coagulation Effects 0.000 description 2
- 238000005345 coagulation Methods 0.000 description 2
- 238000007731 hot pressing Methods 0.000 description 2
- 125000002811 oleoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 238000002203 pretreatment Methods 0.000 description 2
- 238000004088 simulation Methods 0.000 description 2
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- 238000007711 solidification Methods 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
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- 239000003086 colorant Substances 0.000 description 1
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- 238000003912 environmental pollution Methods 0.000 description 1
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- 239000010985 leather Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 210000004761 scalp Anatomy 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
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- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
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- D04B21/16—Fabrics characterised by the incorporation by knitting, in one or more thread, fleece, or fabric layers, of reinforcing, binding, or decorative threads; Fabrics incorporating small auxiliary elements, e.g. for decorative purposes incorporating synthetic threads
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- D06P1/673—Inorganic compounds
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
本实施例公开了一种仿羊皮手感烫金沙发面料生产工艺，包括基布的制备、拉毛处理、染色、磨毛、含浸PU树脂、水凝固、水洗、碱处理、转移印花、烫金、三防整理、烘干。转移印花的分散油墨包括分散染料色浆、盐酸多巴胺、表面张力调节剂、聚碳化二亚胺类交联剂等；烫金时使用的胶水包括羟基聚丙烯酸酯、醇乙氧化物羧酸盐、聚异氰酸酯类交联剂、附着力促进剂。采用超细涤纶网格丝可以保证具有柔软的手感，并且所使用的分散油墨中采用了盐酸多巴胺等助剂提高染料与涤纶纤维的结合，不易发生色迁移的现象。并且对复合后的面料进行三防整理。并且烫金所使用的胶水中采用了羟基聚丙烯酸酯等助剂，提高了胶水与面料结合的牢度。
Description
技术领域
本发明涉及纺织面料技术领域，尤其是一种仿羊皮手感烫金沙发面料生产工艺。
背景技术
羊皮由于具有轻、薄、手感柔软等性能，是皮革服装的理想面料，制成的服装光泽柔和自然，轻薄柔软，富有弹性。但羊皮生产过程中的环境污染很严重，一直不能很好的得到解决。但是采用涤纶进行仿头皮手感的烫金面料，存在防污效果和防色迁移的效果不佳等缺点。
发明内容
本发明的目的是提供一种仿羊皮手感烫金沙发面料生产工艺，使得所制备的仿头皮手感的烫金面料具有良好的防污效果和防色迁移效果。
为解决上述技术问题，本发明的目的是这样实现的：
本发明所涉及的一种仿羊皮手感烫金沙发面料生产工艺，包括如下步骤：
S1、基布的制备：由涤纶收缩丝和75D/288F全涤复合网络丝加捻复合而成的复合丝为原料采用经编设备制备而成；
S2、拉毛处理：采用拉毛机对基布进行单面拉毛，拉毛长度为0.5-2mm；
S3、染色：将上一步骤所制备的面料经过前处理，再采用高温高压溢流染色机进行染色；
S4、磨毛：采用四辊磨毛机对上一步骤所制备的面料进行磨毛，磨毛的绒毛长度为0.3-1mm；
S5、含浸PU树脂：含浸后PU树脂所占的重量百分比为8～15％，且含浸时间为1-2分钟；PU树脂的模量可以为30、60、100中的任意一种；同时含浸的PU树脂内还含有助剂DMF、超支化聚酯丙烯酸酯；
S6、水凝固；
S7、水洗；
S8、碱处理：将面料浸渍70-85℃的碱处理液，5-10min；所述碱处理液中含有36°Be液碱、促进剂、渗透剂OT，所述液碱的用量为34-35％o.w.f，所述促进剂的用量为2-5g/L；所述渗透剂OT的用量为2-5g/L所述促进剂为季铵盐类有机物；
S9、转移印花：先对定型后的面料进行预处理，再采用转移印花设备和分散油墨对定型后的面料起行一侧进行印花，转移印花温度为200-210℃；
对定型面料的预处理，是将面料先在碱液中超声处理30min，再使用去离子水淋洗；
S10、烫金：通过激光雕刻凹版花辊过胶水槽，使得胶水在离型膜的表面形成与印花花型相匹配的花型，通过105-110℃的热辊将印花后的面料与离型膜的上胶面相粘合，使得胶水转移至印花后的面料上，形成仿皮效果；
S11、三防整理：将上一步骤所制备的复合面料浸渍三防整理液；
S12、烘干；
所述分散油墨包括25-30％的分散染料色浆、3-5％盐酸多巴胺、20-25％增稠剂、5-8％的保湿剂、0.5-1％的表面张力调节剂、0.2-0.4％的消泡剂、0.05-0.1％的抗凝剂、2-3％的无水硫酸铜、1-3％的聚碳化二亚胺类交联剂和余量的去离水；
步骤S10中，所使用的胶水包括10-20％的羟基聚丙烯酸酯、5-10％的醇乙氧化物羧酸盐、3-5％的聚醚改性聚硅氧烷、2-3％的油酰氨基酸钠、3-5％的聚异氰酸酯类交联剂、3-5％的四氟化硅疏水剂、1-3％的附着力促进剂和余量的去离子水。
在上述方案的基础上并作为上述方案的优选方案：所述增稠剂为双丙烯酸丁二酯或邻苯二甲酸二丙烯酯。
在上述方案的基础上并作为上述方案的优选方案：所述表面活性调节剂为：直链烷基苯磺酸钠、脂肪醇聚氧乙烯醚硫酸钠、脂肪醇聚氧乙烯醚硫酸铵、月桂醇硫酸钠、壬基酚聚氧乙烯醚、二乙醇酰胺、硬脂酸甘油单酯、木质素磺酸盐、重烷基苯磺酸盐、烷基磺酸盐、烷基聚醚和脂肪醇聚氧乙烯醚的一种或多种的混合物。
在上述方案的基础上并作为上述方案的优选方案：所述三防整理液中包括8-10％的封闭型肟类异氰酸酯分散液、3-5％的渗透剂OT和余量的去离子水。
在上述方案的基础上并作为上述方案的优选方案：所述分散染料色浆包括30-40％的分散染料、10-15％的脂肪醇聚氧丙烯、5-8％的聚丙烯酸钠和余量的去离子水。
在上述方案的基础上并作为上述方案的优选方案：所述季铵盐类有机物为阳离子季铵盐类有机物。
本发明的有益效果是：本发明所涉及的一种仿羊皮手感烫金沙发面料生产工艺，采用超细涤纶网格丝可以保证具有柔软的手感，并且所使用的分散油墨中采用了盐酸多巴胺等助剂使得该分散染料与涤纶纤维的结合能力，不易发生色迁移的现象。并且对复合后的面料进行三防整理，使得该科技布具有良好的三防效果。并且烫金所使用的胶水中采用了羟基聚丙烯酸酯、聚异氰酸酯类交联剂、聚醚改性聚硅氧烷等助剂，提高了胶水与面料结合的牢度。
具体实施方式
下面结合具体实施例对本发明进一步说明。
实施例一
本实施例所涉及的一种仿羊皮手感烫金沙发面料生产工艺，包括如下步骤：基布的制备、拉毛处理、染色、磨毛、含浸PU树脂、水凝固、水洗、碱处理、转移印花、烫金、三防整理、烘干。
在步骤S1基布的制备中，由涤纶收缩丝和75D/288F全涤复合网络丝加捻复合而成的复合丝为原料采用经编设备制备而成；所制备的基布的克重为300克每平方米。
在步骤S2拉毛处理中，采用拉毛机对基布进行单面拉毛，拉毛长度为0.5-2mm；在本实施例中拉毛在基布的一侧形成0.5mm长的绒毛。
在步骤S3染色中，将上一步骤所制备的面料经过前处理，再采用高温高压溢流染色机进行染色。对于涤纶面料的染色是现有技术，在此不作赘述。
在步骤S4、磨毛：采用四辊磨毛机对上一步骤所制备的面料进行磨毛，磨毛的绒毛长度为0.3-1mm，在本实施例中磨毛后的绒毛长度为0.3mm。第一磨毛辊和第二磨毛辊的表面采用200目的金刚砂，第三磨毛辊和第四磨毛辊表面采用300目金刚砂。
在步骤S5中，含浸PU树脂，含浸后PU树脂所占的重量百分比为8～15％，且含浸时间为1-2分钟；PU树脂的模量可以为30、60、100中的任意一种，本实施例中选择为60横量。同时含浸的PU树脂内还含有助剂DMF、超支化聚酯丙烯酸酯。助剂DMF的用量占PU树脂的10-15％，超支化聚酯丙烯酸酯占PU树脂的8-10％，在本实施例中分别选择为12％和10％。
在步骤S6、水凝固，是指放入常温的水中进行15分钟。
在步骤S7、水洗。
在步骤S8、碱处理：将面料浸渍85℃的碱处理液，5min；所述碱处理液中含有36°Be液碱、促进剂、渗透剂OT，所述液碱的用量为35％o.w.f，所述促进剂的用量为5g/L；所述渗透剂OT的用量为2g/L所述促进剂为季铵盐类有机物。
进一步的，所述季铵盐类有机物为阳离子季铵盐类有机物。
在步骤S9、转移印花：先对定型后的面料进行预处理，再采用转移印花设备和分散油墨对定型后的面料起行一侧进行印花，转移印花温度为200-210℃。
对定型面料的预处理，是将面料先在碱液中超声处理30min，再使用去离子水淋洗。
所述分散油墨包括30％的分散染料色浆、3％盐酸多巴胺、25％增稠剂、5％的保湿剂、1％的表面张力调节剂、0.2％的消泡剂、0.1％的抗凝剂、2％的无水硫酸铜、3％的聚碳化二亚胺类交联剂和余量的去离水。
进一步的，所述增稠剂为双丙烯酸丁二酯或邻苯二甲酸二丙烯酯。在本实施例中选择为双丙烯酸丁二酯。
进一步的，所述表面活性调节剂为：直链烷基苯磺酸钠、脂肪醇聚氧乙烯醚硫酸钠、脂肪醇聚氧乙烯醚硫酸铵、月桂醇硫酸钠、壬基酚聚氧乙烯醚、二乙醇酰胺、硬脂酸甘油单酯、木质素磺酸盐、重烷基苯磺酸盐、烷基磺酸盐、烷基聚醚和脂肪醇聚氧乙烯醚的一种或多种的混合物。在本实施例中选择为脂肪醇聚氧乙烯醚硫酸铵。
进一步的，所述分散染料色浆包括40％的分散染料、10％的脂肪醇聚氧丙烯、8％的聚丙烯酸钠和余量的去离子水。
在步骤S10、烫金：通过激光雕刻凹版花辊过胶水槽，使得胶水在离型膜的表面形成与印花花型相匹配的花型，通过105-110℃的热辊将印花后的面料与离型膜的上胶面相粘合，使得胶水转移至印花后的面料上，形成仿皮效果。
步骤S10中，所使用的胶水包括20％的羟基聚丙烯酸酯、5％的醇乙氧化物羧酸盐、5％的聚醚改性聚硅氧烷、2％的油酰氨基酸钠、5％的聚异氰酸酯类交联剂、3％的四氟化硅疏水剂、1％的附着力促进剂和余量的去离子水。
进一步的，所述三防整理液中包括10％的封闭型肟类异氰酸酯分散液、5％的渗透剂OT和余量的去离子水。
在步骤S11、三防整理：将上一步骤所制备的复合面料浸渍三防整理液；
在步骤S12、烘干。
实施例二
本实施例所涉及的一种仿羊皮手感烫金沙发面料生产工艺，包括如下步骤：基布的制备、拉毛处理、染色、磨毛、含浸PU树脂、水凝固、水洗、碱处理、转移印花、烫金、三防整理、烘干。
在步骤S1基布的制备中，由涤纶收缩丝和75D/288F全涤复合网络丝加捻复合而成的复合丝为原料采用经编设备制备而成；所制备的基布的克重为300克每平方米。
在步骤S2拉毛处理中，采用拉毛机对基布进行单面拉毛，拉毛长度为0.5-2mm；在本实施例中拉毛在基布的一侧形成0.5mm长的绒毛。
在步骤S3染色中，将上一步骤所制备的面料经过前处理，再采用高温高压溢流染色机进行染色。对于涤纶面料的染色是现有技术，在此不作赘述。
在步骤S4、磨毛：采用四辊磨毛机对上一步骤所制备的面料进行磨毛，磨毛的绒毛长度为0.3-1mm，在本实施例中磨毛后的绒毛长度为0.3mm。第一磨毛辊和第二磨毛辊的表面采用200目的金刚砂，第三磨毛辊和第四磨毛辊表面采用300目金刚砂。
在步骤S5中，含浸PU树脂，含浸后PU树脂所占的重量百分比为8～15％，且含浸时间为1-2分钟；PU树脂的模量可以为30、60、100中的任意一种，本实施例中选择30模量；同时含浸的PU树脂内还含有助剂DMF、超支化聚酯丙烯酸酯。助剂DMF的用量占PU树脂的10-15％，超支化聚酯丙烯酸酯占PU树脂的8-10％，在本实施例中分别选择为12％和10％。
在步骤S6、水凝固，是指放入常温的水中进行15分钟。
在步骤S7、水洗。
在步骤S8、碱处理：将面料浸渍70℃的碱处理液，10min；所述碱处理液中含有36°Be液碱、促进剂、渗透剂OT，所述液碱的用量为34％o.w.f，所述促进剂的用量为2g/L；所述渗透剂OT的用量为5g/L所述促进剂为季铵盐类有机物。
进一步的，所述季铵盐类有机物为阳离子季铵盐类有机物。
在步骤S9、转移印花：先对定型后的面料进行预处理，再采用转移印花设备和分散油墨对定型后的面料起行一侧进行印花，转移印花温度为200-210℃。
对定型面料的预处理，是将面料先在碱液中超声处理30min，再使用去离子水淋洗。
所述分散油墨包括25％的分散染料色浆、5％盐酸多巴胺、20％增稠剂、8％的保湿剂、0.5％的表面张力调节剂、0.4％的消泡剂、0.05％的抗凝剂、3％的无水硫酸铜、1％的聚碳化二亚胺类交联剂和余量的去离水。
进一步的，所述增稠剂为双丙烯酸丁二酯或邻苯二甲酸二丙烯酯。在本实施例中选择为双丙烯酸丁二酯。
进一步的，所述表面活性调节剂为：直链烷基苯磺酸钠、脂肪醇聚氧乙烯醚硫酸钠、脂肪醇聚氧乙烯醚硫酸铵、月桂醇硫酸钠、壬基酚聚氧乙烯醚、二乙醇酰胺、硬脂酸甘油单酯、木质素磺酸盐、重烷基苯磺酸盐、烷基磺酸盐、烷基聚醚和脂肪醇聚氧乙烯醚的一种或多种的混合物。在本实施例中选择为脂肪醇聚氧乙烯醚硫酸铵。
进一步的，所述分散染料色浆包括30％的分散染料、5％的脂肪醇聚氧丙烯、5％的聚丙烯酸钠和余量的去离子水。
在步骤S10、烫金：通过激光雕刻凹版花辊过胶水槽，使得胶水在离型膜的表面形成与印花花型相匹配的花型，通过105-110℃的热辊将印花后的面料与离型膜的上胶面相粘合，使得胶水转移至印花后的面料上，形成仿皮效果。
步骤S10中，所使用的胶水包括10％的羟基聚丙烯酸酯、10％的醇乙氧化物羧酸盐、3％的聚醚改性聚硅氧烷、3％的油酰氨基酸钠、3％的聚异氰酸酯类交联剂、5％的四氟化硅疏水剂、3％的附着力促进剂和余量的去离子水。
进一步的，所述三防整理液中包括8％的封闭型肟类异氰酸酯分散液、3％的渗透剂OT和余量的去离子水。
在步骤S11、三防整理：将上一步骤所制备的复合面料浸渍三防整理液；
在步骤S12、烘干。
对比例：
本对例所选择的一种高仿真小羊皮面料，由涤纶收缩丝和海岛长丝复合而成的复合丝为原料。其中，涤纶收缩丝的规格为75D，海岛长丝的规格为130D。
高仿真小羊皮面料的制造工艺，包括以下步骤：
(1)以复合丝为原料，针织得到坯布；(2)进行第一次碱减量开纤；(3)烘干；(4)进行双面磨毛；(5)含浸：选用PU树脂进行含浸；(6)水凝固；(7)水洗；(8)进行第二次碱减量开纤；(9)水洗；(10)烘干；(11)染色；(12)烘干；(13)检验、成品。
步骤(1)中，在28英寸大圆机上织成坯布。
步骤(2)，选用NaOH溶液进行碱减量开纤，且NaOH溶液的浓度为5％，并在100℃的温度条件下进行，用时160min，浴比1:15。
步骤(3)的烘干温度为140℃，车速为11m/min；所述步骤(10)的烘干温度为140℃，车速为11m/min；所述步骤(12)的烘干温度为140℃，车速为11m/min。
步骤(5)，含浸后PU树脂所占的重量百分比为12％，且含浸时间为1.5分钟。
步骤(6)，放入常温的水中进行15分钟的水凝固。
步骤(8)，选用NaOH溶液进行碱减量开纤，且NaOH溶液的浓度为4％，并在100℃的温度条件下进行，用时170min，浴比1:15。
对实施例一及实施例二、对比例所制备的仿羊皮面料进行防色迁移测试，包括耐升华牢度和耐贮存色牢度。
当温度达到一定温度时，纤维里的染料从粉末状固体直接变成气体逸出，而逸出的染料遇冷后又凝结成固体，沾到织物表面或其他织物上，通常表现为分散染料，这是一种热迁移现象，也是常称的耐升华牢度，一般采用耐干热(热压除外)色牢度进行测试。耐升华牢度的测试标准为：GB/T 5718-1997《纺织品色牢度试验耐干热(热压除外)色牢度》。
当温度低于染料升华温度和不能升华的染料情况时，不同颜色组成的织物在储存或使用中发生染料由一处向另一处迁移，通常是深色部分向浅色部分转移，通常这种现象称为染料迁移(色迁移)，可用染料转移性能或耐贮存色牢度测试。耐贮存色牢度测试标准为GB/T 32008-2015《纺织品色牢度试验耐贮存色牢度》。方法概述：将待测试样与预湿的多纤维贴衬或指定织物形成组合，组合试样夹到耐汗渍色牢度仪试验架中并固定好试验架，将试验架放入规定的试验条件的恒温恒湿装置中，用灰色样卡评定试样的变色和多纤维贴衬或指定织物的沾色。试验条件是24±2℃、相对湿度为80±5％，时间为48小时。
测试结果如下：
| 实施例一 | 实施例二 | 对比例 | |
| 耐升华牢度 | 4 | 4 | 2-3 |
| 耐贮存色牢度 | 4-5 | 4-5 | 3 |
可见实施例一及实施例二所制备的烫金面料具有良好的防色迁移效果。
以上详细描述了本发明的较佳具体实施例。应当理解，本领域的普通技术人员无需创造性劳动就可以根据本发明的构思做出诸多修改和变化。因此，凡本技术领域中技术人员依本发明的构思在现有技术的基础上通过逻辑分析、推理或者有限的实验可以得到的技术方案，皆应在由权利要求书所确定的保护范围内。
Claims (6)
1.一种仿羊皮手感烫金沙发面料生产工艺，其特征在于，包括如下步骤：
S1、基布的制备：由涤纶收缩丝和75D/288F全涤复合网络丝加捻复合而成的复合丝为原料采用经编设备制备而成；
S2、拉毛处理：采用拉毛机对基布进行单面拉毛，拉毛长度为0.5-2mm；
S3、染色：将上一步骤所制备的面料经过前处理，再采用高温高压溢流染色机进行染色；
S4、磨毛：采用四辊磨毛机对上一步骤所制备的面料进行磨毛，磨毛的绒毛长度为0.3-1mm；
S5、含浸PU树脂：含浸后PU树脂所占的重量百分比为8～15％，且含浸时间为1-2分钟；PU树脂的模量可以为30、60、100中的任意一种；同时含浸的PU树脂内还含有助剂DMF、超支化聚酯丙烯酸酯；
S6、水凝固；
S7、水洗；
S8、碱处理：将面料浸渍70-85℃的碱处理液，5-10min；所述碱处理液中含有36°Be液碱、促进剂、渗透剂OT，所述液碱的用量为34-35％o.w.f，所述促进剂的用量为2-5g/L；所述渗透剂OT的用量为2-5g/L所述促进剂为季铵盐类有机物；
S9、转移印花：先对定型后的面料进行预处理，再采用转移印花设备和分散油墨对定型后的面料起行一侧进行印花，转移印花温度为200-210℃；
对定型面料的预处理，是将面料先在碱液中超声处理30min，再使用去离子水淋洗；
S10、烫金：通过激光雕刻凹版花辊过胶水槽，使得胶水在离型膜的表面形成与印花花型相匹配的花型，通过105-110℃的热辊将印花后的面料与离型膜的上胶面相粘合，使得胶水转移至印花后的面料上，形成仿皮效果；
S11、三防整理：将上一步骤所制备的复合面料浸渍三防整理液；
S12、烘干；
所述分散油墨包括25-30％的分散染料色浆、3-5％盐酸多巴胺、20-25％增稠剂、5-8％的保湿剂、0.5-1％的表面张力调节剂、0.2-0.4％的消泡剂、0.05-0.1％的抗凝剂、2-3％的无水硫酸铜、1-3％的聚碳化二亚胺类交联剂和余量的去离水；
步骤S10中，所使用的胶水包括10-20％的羟基聚丙烯酸酯、5-10％的醇乙氧化物羧酸盐、3-5％的聚醚改性聚硅氧烷、2-3％的油酰氨基酸钠、3-5％的聚异氰酸酯类交联剂、3-5％的四氟化硅疏水剂、1-3％的附着力促进剂和余量的去离子水。
2.根据权利要求1所述的一种仿羊皮手感烫金沙发面料生产工艺，其特征在于，所述增稠剂为双丙烯酸丁二酯或邻苯二甲酸二丙烯酯。
3.根据权利要求1所述的一种仿羊皮手感烫金沙发面料生产工艺，其特征在于，所述表面活性调节剂为：直链烷基苯磺酸钠、脂肪醇聚氧乙烯醚硫酸钠、脂肪醇聚氧乙烯醚硫酸铵、月桂醇硫酸钠、壬基酚聚氧乙烯醚、二乙醇酰胺、硬脂酸甘油单酯、木质素磺酸盐、重烷基苯磺酸盐、烷基磺酸盐、烷基聚醚和脂肪醇聚氧乙烯醚的一种或多种的混合物。
4.根据权利要求1所述的一种仿羊皮手感烫金沙发面料生产工艺，其特征在于，所述三防整理液中包括8-10％的封闭型肟类异氰酸酯分散液、3-5％的渗透剂OT和余量的去离子水。
5.根据权利要求1所述的一种仿羊皮手感烫金沙发面料生产工艺，其特征在于，所述分散染料色浆包括30-40％的分散染料、10-15％的脂肪醇聚氧丙烯、5-8％的聚丙烯酸钠和余量的去离子水。
6.根据权利要求1所述的一种仿羊皮手感烫金沙发面料生产工艺，其特征在于，所述季铵盐类有机物为阳离子季铵盐类有机物。
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