CN106049102A - 一种服装用织物固色剂及其制备方法 - Google Patents

一种服装用织物固色剂及其制备方法 Download PDF

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CN106049102A
CN106049102A CN201610369401.3A CN201610369401A CN106049102A CN 106049102 A CN106049102 A CN 106049102A CN 201610369401 A CN201610369401 A CN 201610369401A CN 106049102 A CN106049102 A CN 106049102A
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parts
fixing agent
color fixing
fabric
azodiisobutyronitrile
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张红桥
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Hongqiao Taicang Garments Co Ltd
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    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
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    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
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    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/642—Compounds containing nitrogen
    • D06P1/645—Aliphatic, araliphatic or cycloaliphatic compounds containing amino groups
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    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
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    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/653—Nitrogen-free carboxylic acids or their salts
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Abstract

本发明提供一种服装用织物固色剂，所述固色剂包括以下重量配比的原料：丙烯酸酯20~25份，偶氮二异丁腈1~4份，壳聚糖季铵盐8~10份，十八烷基二甲基胺5~8份，醋酸3~5份，二乙烯三胺6~8份，双氰胺4~6份，有机硅氧烷1~3份，水50~80份；本发明还提供了上述固色剂的制备方法，步骤如下：将配方量的丙烯酸酯与偶氮二异丁腈混合，加热至45~60℃，搅拌下反应2~4小时，冷却至室温后将剩余组分按配方量加入，搅拌下反应1~1.5小时，制得固色剂。所述固色剂无毒无甲醛，绿色环保，对人体没有伤害，固色牢度强，抗菌、抗皱、抗静电，且制备工艺简单、反应条件温和，原料易得。

Description

一种服装用织物固色剂及其制备方法
技术领域
本发明具体涉及一种服装用织物固色剂及其制备方法。
背景技术
在服装织物的织造过程中，有些染物虽然可以染得比较鲜艳的色泽，但由于湿处理牢度不佳，褪色和粘色的现象比较严重，不仅使得织物本身外观陈旧，同时染料还会从已染色的湿纤维上掉下来，沾污到白的或者染成其他色泽的纤维上；不同色泽的衣物在洗涤时还会互相沾色，搭色。因此，在染色工序中，需要加入固色剂，以增强染料的牢度。染料固色剂是指可以使染料和纤维之间更有效地固着的一类化合物，它能改善和提高染色织物的各类牢度。传统的固色剂含有甲醛等对人体健康有害的物质，可是随着经济水平的不断提高，人们对服装质量的要求也随之越来越高，越来越多的人热衷于“绿色服装”，但是目前市场上出现的无醛固色剂水洗牢度不理想，生产工艺复杂。
发明内容
为解决上述存在的问题，本发明的目的之一在于提供一种服装用织物固色剂，所述固色剂无毒无甲醛，绿色环保，固色牢度强，且抗菌、抗皱、抗静电。
为达到上述目的，本发明的技术方案是：
一种服装用织物固色剂，所述固色剂包括以下重量配比的原料：丙烯酸酯20～25份，偶氮二异丁腈1～4份，壳聚糖季铵盐8～10份，十八烷基二甲基胺5～8份，醋酸3～5份，二乙烯三胺6～8份，双氰胺4～6份，有机硅氧烷1～3份，水50～80份。
优选地，所述固色剂包括以下重量配比的原料：丙烯酸酯21～24份，偶氮二异丁腈2～4份，壳聚糖季铵盐8.5～9.5份，十八烷基二甲基胺6～7份，醋酸3.5～4.5份，二乙烯三胺6.5～7.5份，双氰胺4.5～5.5份，有机硅氧烷1.5～2.5份，水60～70份。
优选地，所述固色剂包括以下重量配比的原料：丙烯酸酯22份，偶氮二异丁腈3份，壳聚糖季铵盐9份，十八烷基二甲基胺6.5份，醋酸4份，二乙烯三胺7份，双氰胺5份，有机硅氧烷2份，水65份。
另，所述丙烯酸酯为丙烯酸甲酯或丙烯酸乙酯或丙烯酸丁酯。
另有，所述有机硅氧烷为甲基硅氧烷或乙基硅氧烷。
再，所述水为去离子水。
本发明的另一目的在于提供一种如上所述服装用织物固色剂的制备方法，其原料易得、制备工艺简单、反应条件温和，步骤如下：
将配方量的丙烯酸酯与偶氮二异丁腈混合，加热至45～60℃，搅拌下反应2～4小时，冷却至室温后将剩余组分按配方量加入，搅拌下反应1～1.5小时，制得固色剂。
本发明的有益效果在于：
与现有技术相比，本发明所提供的固色剂具有如下优点：(1)没有游离甲醛释放，绿色健康，对人体没有伤害；(2)通过固色剂分子中的阳离子基团与染料中的阴离子基团进行静电结合，在织物表面形成不溶性的色淀，进而封闭染料的水溶性基团，具有良好的固色效果，固色牢度强；(3)具有抗菌、抗皱、抗静电的功能；(4)原料易得，制备工艺简单，反应条件温和易于控制。
具体实施方式
下面将对本发明实施例中的技术方案进行清楚、完整的描述，显然，所描述的实施例仅仅是本发明一部分实施例，而不是全部的实施例。基于本发明中的实施例，本领域普通技术人员在没有作出创造性劳动的前提下所获得的所有其他实施例，都属于本发明保护的范围。
表1为本发明实施例所述一种服装用织物固色剂按重量配比的原料列表。
表1实施列所述一种服装用织物固色剂按重量配比的原料(单位：份)
本发明所述的一种服装用织物固色剂的制备方法为：
将配方量的丙烯酸酯与偶氮二异丁腈混合，加热至45～60℃，搅拌下反应2～4小时，冷却至室温后将剩余组分按配方量加入，搅拌下反应1～1.5小时，制得固色剂。
需要说明的是，以上实施例仅用以说明本发明的技术方案而非限制。尽管参照较佳实施例对本发明进行了详细说明，本领域的普通技术人员应当理解，可以对发明的技术方案进行修改或者等同替换，而不脱离本发明技术方案的范围，其均应涵盖在本发明的权利要求范围中。

Claims (7)

1.一种服装用织物固色剂，其特征在于，所述固色剂包括以下重量配比的原料：丙烯酸酯20~25份，偶氮二异丁腈1~4份，壳聚糖季铵盐8~10份，十八烷基二甲基胺5~8份，醋酸3~5份，二乙烯三胺6~8份，双氰胺4~6份，有机硅氧烷1~3份，水50~80份。
2.根据权利要求1所述的一种服装用织物固色剂，其特征在于，所述固色剂包括以下重量配比的原料：丙烯酸酯21~24份，偶氮二异丁腈2~4份，壳聚糖季铵盐8.5~9.5份，十八烷基二甲基胺6~7份，醋酸3.5~4.5份，二乙烯三胺6.5~7.5份，双氰胺4.5~5.5份，有机硅氧烷1.5~2.5份，水60~70份。
3.根据权利要求1所述的一种服装用织物固色剂，其特征在于，所述固色剂包括以下重量配比的原料：丙烯酸酯22份，偶氮二异丁腈3份，壳聚糖季铵盐9份，十八烷基二甲基胺6.5份，醋酸4份，二乙烯三胺7份，双氰胺5份，有机硅氧烷2份，水65份。
4.根据权利要求1或2或3所述的一种服装用织物固色剂，其特征在于，所述丙烯酸酯为丙烯酸甲酯或丙烯酸乙酯或丙烯酸丁酯。
5.根据权利要求1或2或3所述的一种服装用织物固色剂，其特征在于，所述有机硅氧烷为甲基硅氧烷或乙基硅氧烷。
6.根据权利要求1或2或3所述的一种服装用织物固色剂，其特征在于，所述水为去离子水。
7.权利要求1所述的服装用织物固色剂的制备方法，其特征在于，步骤如下：将配方量的丙烯酸酯与偶氮二异丁腈混合，加热至45~60℃，搅拌下反应2~4小时，冷却至室温后将剩余组分按配方量加入，搅拌下反应1~1.5小时，制得固色剂。
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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106676912A (zh) * 2016-12-05 2017-05-17 钦州市钦南区生产力促进中心 一种织物固色剂及其制备方法
CN107700249A (zh) * 2017-09-06 2018-02-16 江苏新瑞贝科技股份有限公司 一种棉织物固色剂的制备方法
CN107700255A (zh) * 2017-11-23 2018-02-16 苏州经贸职业技术学院 一种织物固色剂的制备方法
CN109097976A (zh) * 2018-08-19 2018-12-28 宁波元元光大服饰有限公司 一种除臭式服装布料制作工艺
CN109537308A (zh) * 2018-11-12 2019-03-29 苏州经贸职业技术学院 一种纳米植物染色剂及其制备方法
CN113696570A (zh) * 2021-08-30 2021-11-26 江苏厚生新能源科技有限公司 一种高色牢度耐水洗的聚乙烯面料及其制备工艺
CN114790254A (zh) * 2021-12-21 2022-07-26 盐城工学院 一种胍类化合物固色剂的制备方法及应用
CN114808486A (zh) * 2022-06-09 2022-07-29 杭州天瑞印染有限公司 一种棉织物的节能低耗免汽蒸印花及固色工艺

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CN102995472A (zh) * 2012-11-30 2013-03-27 王正泽 一种织物固色剂的制备方法
CN103669041B (zh) * 2013-11-27 2016-03-09 江苏中新资源集团有限公司 一种织物无醛固色剂及其制备方法

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CN102995472A (zh) * 2012-11-30 2013-03-27 王正泽 一种织物固色剂的制备方法
CN103669041B (zh) * 2013-11-27 2016-03-09 江苏中新资源集团有限公司 一种织物无醛固色剂及其制备方法

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106676912A (zh) * 2016-12-05 2017-05-17 钦州市钦南区生产力促进中心 一种织物固色剂及其制备方法
CN107700249A (zh) * 2017-09-06 2018-02-16 江苏新瑞贝科技股份有限公司 一种棉织物固色剂的制备方法
CN107700255A (zh) * 2017-11-23 2018-02-16 苏州经贸职业技术学院 一种织物固色剂的制备方法
CN109097976A (zh) * 2018-08-19 2018-12-28 宁波元元光大服饰有限公司 一种除臭式服装布料制作工艺
CN109537308A (zh) * 2018-11-12 2019-03-29 苏州经贸职业技术学院 一种纳米植物染色剂及其制备方法
CN113696570A (zh) * 2021-08-30 2021-11-26 江苏厚生新能源科技有限公司 一种高色牢度耐水洗的聚乙烯面料及其制备工艺
CN113696570B (zh) * 2021-08-30 2023-09-22 江苏厚生新能源科技有限公司 一种高色牢度耐水洗的聚乙烯面料及其制备工艺
CN114790254A (zh) * 2021-12-21 2022-07-26 盐城工学院 一种胍类化合物固色剂的制备方法及应用
CN114808486A (zh) * 2022-06-09 2022-07-29 杭州天瑞印染有限公司 一种棉织物的节能低耗免汽蒸印花及固色工艺

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